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In this review, we present an overview on metal amidoboranes, which have recently been considered as hydrogen storage materials for fueling of the low temperature fuel cells. We focus on amidoborane salts containing only metal cations and amidoborate...

Over the past two decades, the high hydrogen content and favorable dehydrogenation conditions of multi-metallic amidoboranes have gained significant attention for their potential in hydrogen storage. Among them, Al-based complex hydrides have shown p...

A novel species of metal amidoborane ammoniate, [Al(NH₂BH₃)₆³⁻][Al(NH₃)₆³⁺] has been successfully synthesized in up to 95% via the one-step reaction of AlH₃·OEt₂ with liquid NH₃BH₃·nNH₃ (n = 1~6) at 0 °C. This solution based reaction method provides...