Search Results (341)

Based on admirable porous media performance and the popularity of additive manufacturing technology, gradient porous media are progressively being applied in increasing fields. In this study, convection heat transfer within a square vented cavity, partially occupied by two copper metal foam layers of $10$ and $20$ PPI saturated with nanofluid, was assessed numerically. The left wall was heated uniformly and non-uniformly by applying multi-frequency spatial heating following a sinusoidal function. Governing equations, including continuity, the Darcy–Brinkmann–Forchheimer model, and local thermal non-equilibrium energy equations, were adopted and solved by employing the finite volume method. The influences of relevant parameters, including nanoparticle concentrations $\left(0\%\le \phi \le 10\%\right)$, Reynolds number ($1\le Re\le 100$), inlet and outlet port aspect ratios $\left(0.1\le D/H\le 0.4\right)$, three outlet vent opening locations ($\left(S_o=0\right)$ left, ($S_o=\left(H/2-D/2\right)$) middle, and ($S_o=\left(H-D\right)$) right), sinusoidal offset temperature (${\theta }_o=0.5$, $1$), frequency ($f=1, 3, 5$), and amplitude ($A=0-1$), were examined. The results demonstrate that flow and heat transfer fields are impacted mainly by these parameters. Streamlines are more intensified at the upper-left corner when the outlet opening vent is shifted towards the right-corner upper wall. Fluid- and solid-phase Nusselt number increases $Re$, $D/H$, ${\theta }_o$, $A$, and $f$ are raised, specifically when $A\ge 0.3$. The Nusselt number remains constant when the frequency is raised from $3$ to $5$, definitely when $D/H\ge 0.25$. In uniform and non-uniform heating cases, the Nusselt number of both phases remains constant as the outlet port is shifted right for $Re\le 10$ and slightly for higher $Re$ as the outlet vent location is translated from left to right. Full article

Strawberry post-harvest losses are estimated at 50%, due to improper handling and harvest timing, necessitating the use of non-invasive methods. This study develops a non-invasive in situ bioelectrical spectroscopy for strawberry peduncles. Based on traditional assessments and invasive metrics, 100 physiologically ripe (PR) and 100 commercially mature (CM) strawberries were distinguished. Spectra from their peduncles were measured from 1 kHz to 1 MHz, collecting four parameters (magnitude (Z(f)), phase angle (θ(f)), resistance (R(f)), and reactance (X(f))), resulting in 80,000 raw data points. Through systematic spectral preprocessing, Bode and Cole–Cole plots revealed a distinction between PR and CM strawberries. Frequency selection identified seven key frequencies (1, 5, 50, 75, 100, 250, 500 kHz) for deriving 37 engineered features from spectral, extrema, and derivative parameters. Feature selection reduced these to 6 parameters: phase angle at 50 kHz (θ (50 kHz)); relaxation time (τ); impedance ratio (|Z_1k/Z_250k|); dispersion coefficient (α); membrane capacitance (Cm); and intracellular resistivity (ρi). Four algorithms (TabPFN, CatBoost, GPC, EBM) were evaluated with Monte Carlo cross-validation with five iterations, ensuring robust evaluation. CatBoost achieved the highest accuracy at 93.3% ± 2.4%. Invasive reference metrics showed strong correlations with bioelectrical parameters (r = 0.74 for firmness, r = −0.71 for soluble solids). These results demonstrate a solution for precise harvest classification, reducing post-harvest losses without compromising marketability. Full article

A SiO₂-Al₂O₃-B₂O₃-CaO-MgO-Na₂O glass-based protective lubricant coating was developed for Ti-6Al-4V alloy forging, featuring a fully non-toxic formulation. The coating consisted of a composite glass matrix formed by blending two phases with distinct softening temperatures, extending its operational window to 700–950 °C. The composite glass showed initial softening at 700 °C and complete melting at 800 °C, with contact angle measurements confirming superior wettability (θ < 90°) across the forging range (800~950 °C). With an increase in temperature, the surface tension of the composite glass melt decreased, and subsequently, the wettability of the composite glass melt was significantly improved. XRD revealed that the uncoated Ti-6Al-4V formed a 22 μm thick rutile TiO₂ scale with a porous structure and interfacial cracks, while the coated sample retained an amorphous glass layer with no TiO₂. Cross-sectional SEM showed a crack-free, poreless interface with strong metallurgical bonding, in contrast to the uncoated sample’s spalled oxide layer. EDS showed minimal oxygen diffusion of the glass coating into the substrate. Ring upsetting tests showed that the coating reduced friction from 0.5–0.7 to 0.3 (50–57% decrease). Collectively, the glass protective lubricant coating showed good performance in terms of protection and lubrication. Full article

Both ZnO and BeO semiconductors crystallize in the hexagonal wurtzite (wz), cubic rock salt (rs), and zinc-blende (zb) phases, depending upon their growth conditions. Low-dimensional heterostructures ZnO/Be_xZn_1-xO and Be_xZn_1-xO ternary alloy-based devices have recently gained substantial interest to design/improve the operations of highly efficient and flexible nano- and micro-electronics. Attempts are being made to engineer different electronic devices to cover light emission over a wide range of wavelengths to meet the growing industrial needs in photonics, energy harvesting, and biomedical applications. For zb materials, both experimental and theoretical studies of lattice dynamics ${\mathsf{\omega }}_{\mathrm{j}}\left(\overrightarrow{\mathrm{q}}\right)$ have played crucial roles for understanding their optical and electronic properties. Except for zb ZnO, inelastic neutron scattering measurement of ${\mathsf{\omega }}_{\mathrm{j}}\left(\overrightarrow{\mathrm{q}}\right)$ for BeO is still lacking. For the Be_xZn_1-xO ternary alloys, no experimental and/or theoretical studies exist for comprehending their structural, vibrational, and thermodynamical traits (e.g., Debye temperature ${\mathsf{\Theta }}_{\mathrm{D}}\left(\mathrm{T}\right);$ specific heat ${\mathrm{C}}_{\mathrm{v}}\left(\mathrm{T}\right))$. By adopting a realistic rigid-ion model, we have meticulously simulated the results of lattice dynamics, and thermodynamic properties for both the binary zb ZnO, BeO and ternary Be_xZn_1-xO alloys. The theoretical results are compared/contrasted against the limited experimental data and/or ab initio calculations. We strongly feel that the phonon/thermodynamic features reported here will encourage spectroscopists to perform similar measurements and check our theoretical conjectures. Full article

The addition of beryllium (Be) to Al–Cu alloys enhances their mechanical properties and corrosion resistance. This study aims to investigate the effects of solidification cooling rates and the addition of Be on the microstructural refinement and corrosion behavior of an Al–5wt.%Cu–1wt.%Si–0.5wt.%Be alloy. Radial solidification under unsteady-state conditions was performed using a stepped brass mold, producing four distinct cooling rates. An experimental growth law, λ₂ = 26${\dot{\mathrm{T}}}^{-1/3}$, was established, confirming the influence of Be and the cooling rate on dendritic size reduction. The final microstructure was characterized by an α-Al dendritic matrix with eutectic compounds (α-Al + θ-Al₂Cu + Si + Fe-rich phase) confined to the interdendritic regions. No Be-containing intermetallic phases were detected, and beryllium remained homogeneously distributed within the eutectic. Notably, Be addition promoted a morphological transformation of the Fe-rich phases from angular or acicular forms into a Chinese-script-like structure, which is associated with reduced local stress concentrations. Tensile tests revealed an ultimate tensile strength of 248.8 ± 11.2 MPa and elongation of approximately 6.4 ± 0.5%, indicating a favorable balance between strength and ductility. Corrosion resistance assessment by EIS and polarization tests in a 0.06 M NaCl solution showed a corrosion rate of 28.9 µm·year⁻¹ and an Epit of −645 mV for the Be-containing alloy, which are lower than those measured for the reference Al–Cu and Al–Cu–Si alloys. Full article

Background: Alzheimer’s disease (AD) is a progressive neurodegenerative disorder characterized by cognitive dysfunction and working memory impairment, with early hippocampal damage being a prominent feature. Transcranial magneto-acoustic stimulation (TMAS) has been shown to target specific brain regions for neuroregulation. Methods: This study investigated the effects of TMAS on cognitive function, working memory, and hippocampal CA3 neural rhythms in AD rats by specifically stimulating the hippocampal region. Results: The novel object recognition test and T-maze test were employed to assess behavioral performance, while time-frequency analyses were conducted to evaluate memory-related activity, neural synchronization, and cross-frequency phase-amplitude coupling. TMAS significantly improved cognitive and working memory deficits in AD rats, enhancing long-term memory performance. Additionally, the abnormal energy levels observed in the θ and γ rhythm power spectra of the CA3 region were markedly restored, suggesting the recovery of normal neural function. This improvement was accompanied by a partial resurgence of neural activity, indicating enhanced inter-neuronal communication. Furthermore, the previously damaged coupling between the θ-fast γ and θ-slow γ rhythms was successfully improved, resulting in a notable enhancement of synchronized activity. Conclusions: These findings suggest that TMAS effectively alleviates cognitive and working memory impairments in AD rats and may provide experimental support for developing new treatments for AD. Full article

This article studies the effects of a laser remelting treatment on the microstructure and properties of Al-Cu-Mn alloy surfaces, as well as the effects of a heat treatment process on the microstructure and mechanical properties of the matrix zone and remelting zone. The results showed that the remelting zone structure was mainly composed of equiaxed dendrites and fine columnar dendrites. The α(Al) phase and θ(Al₂Cu) phase were greatly refined after laser remelting. The T(Al₁₂CuMn₂) phase was completely dissolved into the α(Al) matrix. The hardness of the remelting zone increased significantly with an increase in the height of the molten pool, and the strengthening mechanism was mainly fine grain strengthening and second phase strengthening. For identical aging treatments, the solution treatment at 530 °C for 4 h yielded the highest hardness. Relative to samples aged without prior solution treatment, hardness increased by 80% in the matrix zone and 59.1% in the remelting zone. When the solid solution process was the same, the time to reach peak hardness was shortened when the aging temperature increased, and the hardness of both the matrix zone and remelting zone reached its peak at 175 °C for 8 h of aging. After aging, the friction coefficient of the alloy decreased due to the increase in the strength of the alloy. Full article

Magnetic shape memory alloys have attracted considerable attention due to their multifunctional properties. Among these materials, Ni-Mn-Ga alloys are distinguished by their ability to achieve up to 10% strain when exposed to a magnetic field, a characteristic predominantly observed in single-crystal samples. Consequently, it is essential to develop nanomaterials with a crystal structure closely resembling that of a single crystal. In this study, an epitaxial Ni-Mn-Ga thin film was fabricated using Pulsed Laser Deposition on an Al₂O₃ $\left(11\overline{2}0\right)$ single-crystal substrate. The crystal structure was characterised through X-ray diffraction methodologies, such as symmetrical $2\theta -\omega$ scans, pole figures, and reciprocal space maps. The results indicated that the sample was mainly in a slightly distorted cubic austenite phase, and some incipient martensite phase also appeared. A detailed microstructural analysis, performed by transmission electron microscopy, confirmed that certain regions of the sample exhibited an incipient transformation to the martensite phase. Regions closer to the substrate retained the austenite phase, suggesting that the constraint imposed by the substrate inhibits the phase transition. These results indicate that it is possible to grow high crystalline quality thin films of Ni-Mn-Ga by Pulsed Laser Deposition. Full article

Background/Objectives: Smoking during pregnancy endangers maternal and infant health outcomes, posing significant risks such as preterm birth and developmental complications. Applying the Three Delays Framework, this study examines how smoking behaviors impact maternal health in Alabama, focusing on barriers to prenatal care. Methods: This cross-sectional study utilized PRAMS Phase 8 data collected from 2016 to 2021, comprising 533 observations from the Alabama Department of Public Health. Prenatal care barriers were categorized into three domains: seeking, reaching, and receiving care. Analyses included descriptive statistics, hierarchical clustering of barrier items, derivation of an informational barrier latent score using item-response theory (θ_info), and multivariable logistic regression adjusted for age, race/ethnicity, income, and BMI. Results: Multivariable logistic regression analysis revealed that informational barriers (OR = 2.42, p < 0.001) and system-level barriers (OR = 1.77, p = 0.047) were significant predictors of adverse maternal health outcomes. In the baseline model, which included sociodemographic covariates, prenatal smoking was not significantly associated with poor maternal health (OR = 0.83, 95% CI [0.58, 1.17]). After adjusting for informational, structural, and system barriers, the association further attenuated and remained non-significant (adjusted OR = 0.72, 95% CI [0.50, 1.03]). Conclusions: While smoking during pregnancy remains a modifiable health behavior, informational and system barriers emerged as the more immediate determinants of poor maternal outcomes in this cohort. Addressing these barriers through targeted prenatal education initiatives and system-level improvements can enhance care utilization and improve maternal and infant health outcomes, even among pregnant smokers. Full article

The increasing demand for the real-time monitoring of engine oil quality has driven the development of novel diagnostic methods. Traditional techniques primarily rely on physicochemical assessments, which, while effective, are often time consuming and require specialized laboratory equipment. This study explores the feasibility of using electrical property measurements to assess engine oil quality, offering a potential alternative for rapid, cost-effective diagnostics. A proprietary measurement system utilizing two innovative sensors—rectangular and concentric—was employed to evaluate the electrical characteristics of five commercially available synthetic engine oils. Key parameters, including impedance (|Z|), phase shift angle (θ), conductance (G), susceptance (B), parallel equivalent capacitance (Cp), and quality factor (Q), were measured across a frequency range of 100 Hz to 1.2 MHz. These results were correlated with conventional physicochemical parameters, specifically viscosity and infrared spectroscopy data, to determine the reliability and accuracy of electrical diagnostics in assessing oil degradation and quality variations. The findings indicate a correlation between selected electrical parameters and traditional laboratory measurements, particularly within the 1 kHz to 10 kHz frequency range, where the measurement repeatability was the highest. The study also identifies key challenges associated with sensor sensitivity to environmental factors and provides insights into optimizing the measurement process. The results contribute to the ongoing development of alternative, real-time oil condition monitoring techniques, potentially improving the reliability of automotive and industrial lubrication systems. Full article

Polyethylene films prepared from orientation-dependent methods are strong and resilient, have reduced permeability, and possess higher tensile strength. A molecular dynamics investigation is performed to reveal the emergence of chain folding and lamellar crystal axis alignment along the stretching axis (tilt angle) in the stretch-induced crystallization (SIC) of high-density polyethylene (HDPE), which mimics the internal structure of the fiber. The morphology in phase transition is assessed by the total density (ρ), degree of crystallinity (%${\chi }_c$), average number of entanglements per chain (<Z>), elastic modulus of the mechanical property, and lamellar chain tilt angle (θ) from the stretch-axis. The simulation emphasizes crystal formation by changing the total ρ from 0.85 g·cm⁻³ to 0.90 g·cm⁻³ and by tracking the gradual increase in %${\chi }_c$ during stretching (~40%) and relaxation processes (~50%). Moreover, the primitive path analysis-based <Z> decreased during stretching and further in the subsequent relaxation process, supporting the alignment and thickening of the lamellar chain structure and chain folding from the random coil structure. The elastic modulus of ~350–400 MPa evidences the high alignment of the lamellar chains along the stretching axis. Consistent with the chain tilt angle of the HDPE in SAXS/WAXS experiments, the model estimated the lamellar chain title angle (θ) relative to the stretching axis to be ~20–35°. In conclusion, SIC is a convenient approach for simulating high stiffness, tensile strength, reduced permeability, and chain alignment in fiber film models, which can help design new fiber morphology-based polymers or composites. Full article

Wireless power transfer (WPT) systems are critical for enabling safe and efficient charging of inspection drones in flammable oilfield environments, yet existing solutions struggle with multi-target compatibility and reactive power losses. This study proposes a novel frequency-regulated LCC-S topology that achieves both constant current (CC) and constant voltage (CV) charging modes for heterogeneous drones using a single hardware configuration. By dynamically adjusting the operating frequency, the system minimizes the input impedance angle (θ < 10°) while maintaining load-independent CC and CV outputs, thereby reducing reactive power by 92% and ensuring spark-free operation in explosive atmospheres. Experimental validation with two distinct oilfield inspection drones demonstrates seamless mode transitions, zero-phase-angle (ZPA) resonance, and peak efficiencies of 92.57% and 91.12%, respectively. The universal design eliminates the need for complex alignment mechanisms, offering a scalable solution for multi-drone fleets in energy, agriculture, and disaster response applications. Full article

In this work, the effects of the Cu/Li ratio on the mechanical properties and corrosion behavior of Sc-containing Al-Cu-Li alloys were systematically investigated by utilizing age-hardening behavior, tensile property, corrosion behavior, and electrochemical behavior, complemented by microstructural characterization through EBSD and TEM. The results show that the peak aging strength of the alloys remained relatively consistent but slightly decreased with the decrease in Cu/Li ratio, and the yield strengths were 585 MPa, 578 MPa, and 573 MPa, respectively. The changes in the Cu/Li ratio caused different matching patterns of precipitates in the peak aging alloys. The cumulative precipitation strengthening by T₁, θ′, δ′, and S′ phases are equal within the alloys with different Cu/Li ratios. However, the strength contribution of the T₁ phase decreases from 81% to 66% with the decrease in the Cu/Li ratio. Concurrently, the precipitates of LAGBs gradually increase in number and are continuously distributed, and the precipitates of HAGBs become larger in size with lower Cu content as the Cu/Li ratio decreases, all of which leads to a weakening of the intergranular corrosion (IGC) resistance within the low Cu/Li ratio alloy. Full article

The influence of Cu content (3.10, 3.50, and 3.80 wt.%) on the precipitation behavior and mechanical properties of Al-Cu-Li alloys under two aging conditions (direct aging at 175 °C vs. 3.5% pre-stretching followed by aging at 155 °C) was systematically investigated. The alloys were characterized using hardness testing, tensile property evaluation, and transmission electron microscopy (TEM) to correlate microstructural evolution with performance. The results revealed that increased Cu content accelerated early-stage hardening kinetics and elevated peak hardness and strength. Aging at 175 °C/36 h produced T₁ phase-dominated microstructures with θ′ phases. With the increase of Cu content, the enhancement effect on the precipitation of T₁ and θ′ phases becomes more pronounced, gradually overshadowing the initial promotion effect on precipitate growth. Pre-deformation prior to 155 °C/36 h aging induced significant T₁ phase refinement and proliferation, with increasing Cu content continuously reducing T₁ phase sizes while moderately enlarging θ′ precipitates. Precipitation-strengthening analysis revealed a transition in T₁ strengthening from bypass to shearing dominance under 155 °C/36 h aging after pre-deformation, enhanced by Cu-promoted T₁ refinement, which collectively drove superior strength in high-Cu alloys. These findings provide valuable insights for the composition design and mechanical property optimization of Al-Cu-Li alloys. Full article

Existing covert communication schemes based on On–Off Keying (OOK) have not considered asymmetric noise environments, which limits their applicability in complex communication scenarios such as terahertz and underwater acoustic covert communications. To address this issue, this paper proposes a phase-based OOK coding scheme. In particular, the transmitter Alice can adjust the initial phase of the transmitted symbol to align the signal with the stronger noise components in asymmetric noise communication scenarios, thereby exploiting the masking effect of noise to achieve covert transmission. To quantify performance, the KL divergence and mutual information of the OOK coding scheme are adopted as measures of covertness and transmission performance, respectively. An optimization problem involving the input signal distribution $a_n$, signal amplitude $\beta$, and initial phase angle $\theta$ is formulated and solved to obtain the maximum covert transmission rate. Numerical results demonstrate that in asymmetric noise systems, the initial phase angle and the Gaussian noise components on the real and imaginary axes of the complex plane influence both covertness performance and transmission rate. Adjusting the initial phase towards the direction with lower noise components can maximally suppress noise interference, thereby improving the covertness performance. Full article