Soil-Groundwater Pollution Investigations

A special issue of Water (ISSN 2073-4441). This special issue belongs to the section "Soil and Water".

Deadline for manuscript submissions: 28 February 2025 | Viewed by 9967

Special Issue Editors


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Guest Editor
School of Water Resources and Environment, China University of Geosciences, Beijing, China
Interests: groundwater monitoring; groundwater dynamic variations; groundwater anomaly identification; groundwater response to crustal deformation and earthquakes; hydrogeological parameters variations; groundwater-surface water interactions
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Guest Editor
Center for Hydrogeology and Environmental Geology Survey, China Geological Survey, Baoding, China
Interests: soil and groundwater pollution; geogenic trace elements in soil and groundwater; CO2 geological sequestration and risk assessment; geothermal energy exploration; utilization and environmental impact
School of Environmental Science and Engineering, Qingdao University, Qingdao, China
Interests: groundwater pollution; water quality evaluation; contaminations transport and transformation; water-rock interaction; in-situ pyrolysis of oil shale and the influences on deep fluids geochemistry
School of Water Resources and Environment, China University of Geosciences, Beijing, China
Interests: hydrobiogeochemical processes in hyporheic zone; soil and groundwater pollution; stable and radioactive isotopes tracing; solute transport simulation; basin hydrogeochemical processes; pollution risk

Special Issue Information

Dear Colleagues,

Soil and groundwater pollution have been a global issue with regard to ecological-environment security and human health risk. Pollution in soil and groundwater is often very closely interlinked. Water infiltration reaches the aquifer through the soil, which could bring contaminants to the soil or leach the soil contaminants into groundwater. Both groundwater and soil pollution could pose the great threats to water quality and ecosystem security. More and more researchers suggest that the investigation into pollution in groundwater and soil should be integrated. Insights from soil-groundwater pollution investigations can benefit its systemic prevention and control.

The purpose of this Special Issue is to bring together broad views on investigation methods, transport mechanisms, and treatment of soil-groundwater pollution for various kinds of pollutants at varied spatial and temporal scales. Research areas may include (but are not limited to) the following: the characterization of soil/groundwater pollution at various scales (e.g., site and regional scale) using effective investigation methods (field investigation, experiments, and simulation); the identification and apportionment of pollution sources; the transport and reactive processes of contaminants in soil, groundwater, and the soil-groundwater interface under dynamic hydrological conditions; the hydrobiogeochemical processes associated with the migration and transformation of contaminants; pollution in the soil and groundwater near the river/lake/wetland affected by surface water-groundwater interaction; the evaluation of water quality under natural and anthropogenic influences and the associated risks to the ecological environment and human health; and the theoretical treatment and remediation engineering of contaminated soil-groundwater. In this Special Issue, original research articles and reviews are welcome.

Prof. Dr. Guangcai Wang
Prof. Dr. Dongguang Wen
Dr. Shuya Hu
Dr. Liao Fu
Guest Editors

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Keywords

  • the investigation methods of soil/groundwater pollution
  • contaminants transport and transformation
  • pollution under surface water-groundwater interaction conditions
  • water quality evaluation
  • assessment of ecological environment and human health risks
  • treatment and remediation of contaminated soil-groundwater

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Published Papers (7 papers)

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Research

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12 pages, 2245 KiB  
Article
Influence of Sub-CMC Rhamnolipid Flushing on the Mobilization and Solubilization of Residual Dodecane in Saturated Porous Media
by Xin Yang, Hua Zhong, Guansheng Liu, Lili Huo and Zonghua Wang
Water 2024, 16(21), 3152; https://doi.org/10.3390/w16213152 - 4 Nov 2024
Viewed by 556
Abstract
The potential of monorhamnolipid (monoRL) biosurfactant to enhance the removal of residual dodecane from a porous medium was investigated under monoRL concentration varying from sub-CMC to hyper-CMC conditions by one-dimension column experiments. In the immiscible displacement experiment, 76% of the total volume of [...] Read more.
The potential of monorhamnolipid (monoRL) biosurfactant to enhance the removal of residual dodecane from a porous medium was investigated under monoRL concentration varying from sub-CMC to hyper-CMC conditions by one-dimension column experiments. In the immiscible displacement experiment, 76% of the total volume of dodecane is removed by flushing of 150 μM monoRL solution. The solubilization of dodecane could be enhanced by rhamnolipid even at monorhamnolipid concentrations as low as 50 μM/L. The higher solubilization concentration (500 μM/L) of monoRL solution results in higher solubilized dodecane concentration (160 μM/L) due to the larger quantity of micelle formation. Compared to solubilization, immiscible displacement, or mobilization, is far more effective in removing residual dodecane. The interfacial partitioning tracer tests (IPTT) method is applied to measure the variation in specific dodecane-water interface areas (Anw). The results showed that the flushing of monoRL increased the Anw from 2.04 to 3.54 cm2/cm3. This investigation implies that low-concentration monorhamnolipid flushing and subsequent micelle solubilization is an economic method to remediate NAPL-contaminated fields. Full article
(This article belongs to the Special Issue Soil-Groundwater Pollution Investigations)
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17 pages, 3020 KiB  
Article
Hydrochemical Characteristics and Quality Evaluation of Groundwater in Jinta Basin, Northwest China
by Xiaoyan Wang, Shuangbao Han, Mengnan Zhang, Sai Wang, Dechao Yin, Xi Wu, Huqun Cui and Yonghui An
Water 2023, 15(23), 4171; https://doi.org/10.3390/w15234171 - 1 Dec 2023
Cited by 2 | Viewed by 1601
Abstract
The ecological environment of the northwest inland basin is fragile. The groundwater environment is a crucial influencing factor for the harmonious and sustainable development of the local social economy and the ecological environment. It is significant to investigate the groundwater chemical characteristics, water [...] Read more.
The ecological environment of the northwest inland basin is fragile. The groundwater environment is a crucial influencing factor for the harmonious and sustainable development of the local social economy and the ecological environment. It is significant to investigate the groundwater chemical characteristics, water quality, and the factors that influence groundwater chemistry for groundwater resources development and construction of the ecological environment. In this study, the Jinta Basin (JB), Gansu Province, was the selected study area. Three hundred and fifty groups of shallow groundwater samples in the JB were collected and analyzed, and the characteristics and controlling factors of groundwater were determined by using Piper diagram, Gibbs plot, ion ratio relationship, and factor analysis. Single index evaluation method, comprehensive evaluation method, and entropy-weighted water quality index method were used to evaluate the water quality of the groundwater. The results indicated that the shallow pore water in the JB was alkaline as a whole; the ranges of total dissolved solids (TDS) in the Beidahe River impact area (BIA), the transition area (TA) and the Heihe River impact area (HIA) were 328.4–12,400 mg·L−1, 372.70–3774.0 mg·L−1, and 366.30–75,200.0 mg·L−1, respectively; the major anions and cations of the shallow pore water were SO42−/Cl and Mg2+/Na+, respectively. The Piper diagram illustrated that the hydrochemical type of groundwater in the JB were mainly HCO3·SO4-Mg type, SO4·HCO3-Mg type, SO4-Mg·Na type, SO4·Cl-Na·Mg type, and Cl-Na type. The overall water quality of the shallow groundwater in the JB was relatively poor, mainly falling into Class IV-V water quality. Sulfate, total hardness (TH), TDS, chloride and sodium were the main influencing factors of water quality. The chemical characteristics of groundwater in the JB were controlled by a variety of natural factors, including rock weathering, evaporative concentration, and cation exchange, among which the main controlling factors of shallow pore water were leaching, evaporative concentration and anthropogenic activities (contribution rate of 73.94%), and sulfate rock and carbonate rock dissolution (contribution rate of 14.91%). Full article
(This article belongs to the Special Issue Soil-Groundwater Pollution Investigations)
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19 pages, 7484 KiB  
Article
Groundwater Hydrogeochemical Processes and Potential Threats to Human Health in Fengfeng Coal Mining Area, China
by Zhiqiang Zhang, Haixue Li, Fawang Zhang, Jiazhong Qian, Shuangbao Han and Fenggang Dai
Water 2023, 15(22), 4024; https://doi.org/10.3390/w15224024 - 20 Nov 2023
Cited by 1 | Viewed by 1316
Abstract
The Fengfeng mining area is in the transition zone between the North China Plain and the Taihang Mountains, and groundwater is the main source of water supply in the district. Under the combined influence of human activities and natural geological conditions, the quality [...] Read more.
The Fengfeng mining area is in the transition zone between the North China Plain and the Taihang Mountains, and groundwater is the main source of water supply in the district. Under the combined influence of human activities and natural geological conditions, the quality of different types of groundwater varies greatly, posing a potential threat to the safety of drinking water. In this study, hydrogeochemical processes in different types of groundwater were analyzed using multivariate statistical analysis methods with ion–ratio relationships, and a groundwater quality and health risk assessment model was developed. The research findings show that the main chemical components and TDS in the groundwater have obvious spatial distribution characteristics, i.e., the content of deep karst water (DKW) in the west is significantly lower than that of shallow pore water (SPW) in the east, and the hydrochemical type has changed from HCO3–Ca to SO4–Ca. The chemical components of SPW and DKW are mainly derived from silicates and carbonates, accompanied by weathering dissolution of sulphidic minerals, especially SPW. The chemical components of the groundwater was also influenced by the cation exchange reaction and human activities. The quality of the SPW was significantly worse than that of the DKW, and the nitrates in SPW carry a high non-carcinogenic risk, especially to children. The shallow pore water is not suitable for drinking water. This study can provide guidance on the safety of drinking water in the Fengfeng coal mining area and other areas with intensive industrial, mining, and agricultural activities. Full article
(This article belongs to the Special Issue Soil-Groundwater Pollution Investigations)
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21 pages, 4158 KiB  
Article
Intrinsic Vulnerability Assessment of the Qingduo Karst System, Henan Province
by Leihao Yin, Beiyi Xu, Wutian Cai, Pengpeng Zhou and Li Yang
Water 2023, 15(19), 3425; https://doi.org/10.3390/w15193425 - 28 Sep 2023
Viewed by 1144
Abstract
Groundwater vulnerability assessments are vital for protecting valuable resources by revealing susceptibility to contamination. This study developed an enhanced index model to assess the intrinsic vulnerability of a supplied karst aquifer in Qingduo, Henan Province. The model considered the 3-D geological structure and [...] Read more.
Groundwater vulnerability assessments are vital for protecting valuable resources by revealing susceptibility to contamination. This study developed an enhanced index model to assess the intrinsic vulnerability of a supplied karst aquifer in Qingduo, Henan Province. The model considered the 3-D geological structure and modified indices to account for Northern China’s mild karstification. Emphasizing the absolute infiltration capacity of surface contaminants, the model also integrated the groundwater sources and sinks (SS) index. The vulnerability map revealed that over 60% of the aquifers, including the Qingduo wellfield, exhibited very low to low vulnerability. Conversely, only small areas (<5%) along the Kejing (KJ) fault’s southern wall were classified as highly vulnerable. These findings highlighted the significant role of groundwater flow alongside aquifer conditions. The upward groundwater flow through the Fengmenkou (FMK) faults slowed the downward infiltration of surface contaminants into the lower karst aquifer, effectively reducing vulnerabilities. Lower levels of dissolved lead (Pb) and nitrate (NO3) in Qingduo groundwater aligned with PISSR vulnerability mapping. Sensitivity analysis assessed the results’ sensitivity to index weight assignment. The inclusion of the sources and sinks (SS) index holds implications for semi-quantitatively assessing dynamic groundwater vulnerability by delineating flow patterns. Full article
(This article belongs to the Special Issue Soil-Groundwater Pollution Investigations)
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13 pages, 2364 KiB  
Article
Study on the Release Law of Phenol during Water-Oil Shale Interaction Process
by Zhaoxia Sun, Qingyu Li, Quansheng Zhao and Shuya Hu
Water 2023, 15(11), 2017; https://doi.org/10.3390/w15112017 - 26 May 2023
Cited by 1 | Viewed by 1367
Abstract
Oil shale, as a reserve resource of conventional energy, has gradually attracted attention. However, water-rock interactions occur during in-situ shale oil extraction, and pollutants generated during this process can contaminate surrounding geological formations and groundwater environments. This article focuses on phenol produced by [...] Read more.
Oil shale, as a reserve resource of conventional energy, has gradually attracted attention. However, water-rock interactions occur during in-situ shale oil extraction, and pollutants generated during this process can contaminate surrounding geological formations and groundwater environments. This article focuses on phenol produced by water-rock interactions and investigates the release behavior of phenol under different reaction temperatures and times, as well as how total organic carbon (TOC), total petroleum hydrocarbons (TPH), and pore size changes affect phenol. The study found that the release concentration of phenol increased with the increase in reaction temperature, reaction time, and the average pore size of the mineral. In addition, with the increase of TOC and TPH concentrations, the concentration of phenol also increased continuously. Full article
(This article belongs to the Special Issue Soil-Groundwater Pollution Investigations)
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15 pages, 13938 KiB  
Article
Impact of Inorganic Solutes’ Release in Groundwater during Oil Shale In Situ Exploitation
by Qingyu Li, Laijun Lu, Quansheng Zhao and Shuya Hu
Water 2023, 15(1), 172; https://doi.org/10.3390/w15010172 - 31 Dec 2022
Cited by 42 | Viewed by 2381
Abstract
Oil shale can produce oil and shale gas by heating the oil shale at 300–500 °C. The high temperature and the release of organic matter can change the physical and mechanical properties of rocks and make the originally tight impervious layer become a [...] Read more.
Oil shale can produce oil and shale gas by heating the oil shale at 300–500 °C. The high temperature and the release of organic matter can change the physical and mechanical properties of rocks and make the originally tight impervious layer become a permeable layer under in situ exploitation conditions. To realize the potential impact of the in situ exploitation of oil shale on groundwater environments, a series of water–rock interaction experiments under different temperatures was conducted. The results show that, with the increase of the reaction temperature, the anions and cations in the aqueous solution of oil shale, oil shale–ash, and the surrounding rock show different trends, and the release of anions and cations in the oil shale–ash solution is most affected by the ambient temperature. The hydrochemical type of oil shale–ash solution is HCO3-SO4-Na-K at 80 °C and 100 °C, which changes the water quality. The main reasons are that (1) the high temperature (≥80 °C) can promote the dissolution of FeS in oil shale and (2) the porosity of oil shale increases after pyrolysis, making it easier to react with water. This paper is an important supplement to the research on the impact of the in situ exploitation of oil shale on the groundwater environment. Therefore, the impacts of in situ mining on groundwater inorganic minerals should be taken into consideration when evaluating in situ exploitation projects of oil shale. Full article
(This article belongs to the Special Issue Soil-Groundwater Pollution Investigations)
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Review

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57 pages, 3124 KiB  
Review
An Extensive Review of Leaching Models for the Forecasting and Integrated Management of Surface and Groundwater Quality
by Stephanos D. V. Giakoumatos, Christina Siontorou and Dimitrios Sidiras
Water 2024, 16(23), 3348; https://doi.org/10.3390/w16233348 - 21 Nov 2024
Viewed by 661
Abstract
The present study reviews leachate models useful for proactive and rehab actions to safeguard surface and subsurface soft water, which have become even more scarce. Integrated management plans of water basins are of crucial importance since intensively cultivated areas are adding huge quantities [...] Read more.
The present study reviews leachate models useful for proactive and rehab actions to safeguard surface and subsurface soft water, which have become even more scarce. Integrated management plans of water basins are of crucial importance since intensively cultivated areas are adding huge quantities of fertilizers to the soil, affecting surface water basins and groundwater. Aquifers are progressively being nitrified on account of the nitrogen-based fertilizer surplus, rendering water for human consumption not potable. Well-tested solute leaching models, standalone or part of a model package, provide rapid site-specific estimates of the leaching potential of chemical agents, mostly nitrates, below the root zone of crops and the impact of leaching toward groundwater. Most of the models examined were process-based or conceptual approaches. Nonetheless, empirical prediction models, though rather simplistic and therefore not preferrable, demonstrate certain advantages, such as less demanding extensive calibration database information requirements, which in many cases are unavailable, not to mention a stochastic approach and the involvement of artificial intelligence (AI). Models were categorized according to the porous medium and agents to be monitored. Integrated packages of nutrient models are irreplaceable elements for extensive catchments to monitor the terrestrial nitrogen-balanced cycle and to contribute to policy making as regards soft water management. Full article
(This article belongs to the Special Issue Soil-Groundwater Pollution Investigations)
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