- Article
The Role of Aluminum-Based Compounds as Buffer Materials in Deep and Symmetric Geological Repositories: Experimental and Modeling Studies
- Esra Güneri and
- Selin Baş
Depending on the factors to which the soils are exposed, many properties and engineering parameters may change. In particular, the temperature parameter affects the strength of the soils, the degree of compressibility, permeability, void ratio, Atterberg limits, and many other parameters. In areas where high temperatures occur, such as heat piles and nuclear waste storage areas, alternative soil mixtures are needed that can stabilize or better optimize the behavior of the soils. For this purpose, additives with high heat transfer capacity and symmetry can be used. In this study, aluminum additive, which is known to have high conductivity, was used together with zeolite–bentonite mixtures. Aluminum-added mixtures were kept at different temperatures, and their thermal conductivity values were measured at the end of different periods. Measurements were first carried out at room temperature for all mixtures. Then, measurements were repeated at the end of 1, 3, and 10 days for 55 °C and 80 °C temperature values. At the end of the heating periods, the samples were left to cool to room temperature, and the thermal conductivity values were examined at the end of the heating–cooling cycle. Experimental results showed that thermal conductivity increased as temperature increased when the same period was taken as a basis, but an increase was observed for 1 and 3 day heating periods, while the thermal conductivity values for the 10th day decreased. The initial increase is attributed to the densification of the material due to the removal of free and weakly bound water or to the improvement of solid–solid contact paths. The subsequent decrease is due to microstructural deterioration, such as increased air-filled porosity, drying shrinkage, and microcracking due to thermal stresses, and material degradation caused by prolonged heating. In addition, thermal conductivity values of the mixtures under high temperature were estimated for days 100 and 365 using the DeepSeek method. The results showed that the thermal conductivity coefficients symmetrically decreased with increasing time.
24 December 2025







