Metallic Nanoparticles and Polymeric Nanocomposites: Synthesis and Applications

A special issue of Polymers (ISSN 2073-4360). This special issue belongs to the section "Polymer Composites and Nanocomposites".

Deadline for manuscript submissions: 15 May 2024 | Viewed by 2840

Special Issue Editors


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Guest Editor
Department of Nanomaterials Chemistry, Centro de Investigación en Química Aplicada, 25294 Saltillo, Mexico
Interests: synthesis of metallic nanoparticles; synthesis of nanoparticle–polymer composites; surface modification of nanoparticles; electrically conductive polymer composites; thermal conductive polymer composites; antimicrobial polymers; photocatalyst/polymer composites; polymer–carbon composites; polymer composites for water treatment
Special Issues, Collections and Topics in MDPI journals

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Guest Editor
Department of Nanomaterials Chemistry, Centro de Investigación en Química Aplicada, Saltillo 25294, Mexico
Interests: synthesis of metallic nanoparticles; synthesis of nanoparticle–polymer composites; modification surface of nanoparticles; applications of polymers in enhanced recovery oil; biosynthesis of nanoparticles

Special Issue Information

Dear Colleagues,

It is well-known that polymers or matrix polymers have been used for different purposes in order to meet the most recurrent needs of society in all areas so as to improve living standards. The use of organic and inorganic nanoparticles added to polymers has been intensively investigated in the last decade due to improvements in the physicochemical properties possessed by polymers. One advantage of using natural or functionalized polymers in the synthesis of in situ nanoparticles is the control of their composition, size and shape. This Special Issue will explore the synthesis of new nanocomposites with synthetic or natural polymers and with organic and inorganic nanoparticles, and the in situ synthesis of inorganic nanoparticles, as well as the synthesis and biosynthesis of nanoparticles with antimicrobial, conductive and thermal properties. This Special Issue will allow readers to optimize and learn about new nanocomposites design and new functionalized nanoparticles, which will lead to a new perspective in research aimed at specific applications. Original full articles, reviews and communications are welcome.

The topics covered by this Special Issue include:

  • Synthesis of nanoparticles through natural polymers in situ;
  • Synthesis of nanoparticles through functionalized polymers in situ;
  • Synthesis of nanocomposites with antimicrobial, conductive and thermal properties;
  • Synthesis of nanocomposites by different processes (molten-blown, molten extrusion, solution extrusion, etc.) and their possible application;
  • Synthesis of inorganic and organic nanoparticles with antimicrobial, optical, and conductive properties;
  • Characterization of nanocomposites (Polymer-nanoparticle) with application potentials.

Dr. Marissa Pérez-Alvarez
Dr. Gregorio Cadenas-Pliego
Guest Editors

Manuscript Submission Information

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Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Polymers is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2700 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • engineering polymer
  • metal nanoparticles (copper, titanium oxide, zirconium oxide, selenium, silver, copper oxide, zinc oxide nanoparticles, etc.)
  • carbon nanoparticles (carbon black, graphene, MWCN nanoparticles, etc.)
  • antimicrobial properties
  • natural polymers
  • nanocomposites

Published Papers (2 papers)

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Research

19 pages, 6149 KiB  
Article
Nanostructured Copper Selenide Coatings for Antifouling Applications
by Sergio Mancillas-Salas, José Ángel Ledón-Smith, Marissa Pérez-Álvarez, Gregorio Cadenas-Pliego, José Manuel Mata-Padilla, Marlene Andrade-Guel, Sandra Cecilia Esparza-González, Gregorio Vargas-Gutiérrez, Uriel Alejandro Sierra-Gómez and Esmeralda Monserrat Saucedo-Salazar
Polymers 2024, 16(4), 489; https://doi.org/10.3390/polym16040489 - 09 Feb 2024
Viewed by 749
Abstract
The accumulation of microorganisms, plants, algae, or small animals on wet surfaces that have a mechanical function causes biofouling, which can result in structural or other functional deficiencies. The maritime shipping industry must constantly manage biofouling to optimize operational performance, which is a [...] Read more.
The accumulation of microorganisms, plants, algae, or small animals on wet surfaces that have a mechanical function causes biofouling, which can result in structural or other functional deficiencies. The maritime shipping industry must constantly manage biofouling to optimize operational performance, which is a common and long-lasting problem. It can occur on any metal structure in contact with or submerged in ocean water, which represents additional costs in terms of repairs and maintenance. This study is focused on the production of antifouling coatings, made with nanoparticles of copper selenide (CuSe NPs) modified with gum arabic, within a water-base acrylic polymeric matrix. During the curing of the acrylic resin, the CuSe NPs remain embedded in the resin, but this does not prevent the release of ions. The coatings released copper and selenium ions for up to 80 days, and selenium was the element that was released the most. The adhesion of film coatings to metallic substrates showed good adhesion, scale 5B (ASTM D3359 standard). Antimicrobial activity tests show that the coatings have an inhibitory effect on Escherichia coli and Candida albicans. The effect is more noticeable when the coating is detached from the substrate and placed on a growing medium, compared to the coating on a substrate. Scanning electron microscopy (SEM) observations show that nanostructured CuSe coatings are made up of rod-shaped and spherical particles with an average particle size of 101.6 nm and 50 nm, respectively. The energy dispersive X-ray spectroscopy (EDS) studies showed that the ratio of selenium nanoparticles is greater than that of copper and that their distribution is homogeneous. Full article
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15 pages, 6917 KiB  
Article
Anticancer Drug-Loaded Chitosan Nanoparticles for In Vitro Release, Promoting Antibacterial and Anticancer Activities
by Naushad Ahmad, Mohammad Rizwan Khan, Subramanian Palanisamy and Sonaimuthu Mohandoss
Polymers 2023, 15(19), 3925; https://doi.org/10.3390/polym15193925 - 28 Sep 2023
Cited by 1 | Viewed by 1583
Abstract
Targeted drug delivery to tumor cells may be possible using nanoparticles containing human therapeutic drugs. The present study was carried out to develop cisplatin (CP) and 5-fluorouracil (FA) encapsulated chitosan nanoparticles (CSNPs), crosslinked with sodium tripolyphosphate (TPP) by an ionic gelation method and [...] Read more.
Targeted drug delivery to tumor cells may be possible using nanoparticles containing human therapeutic drugs. The present study was carried out to develop cisplatin (CP) and 5-fluorouracil (FA) encapsulated chitosan nanoparticles (CSNPs), crosslinked with sodium tripolyphosphate (TPP) by an ionic gelation method and in vitro release, promoting antibacterial and anticancer activities. The prepared CSNPs, before and after CP and FA encapsulation, have been studied using various characterization techniques such as FTIR, XRD, SEM, and TEM-SAED patterning. The composites were well-dispersed, with an average particle size diameter of about 395.3 ± 14.3 nm, 126.7 ± 2.6 nm, and 82.5 ± 2.3 nm, respectively. In vitro release studies indicated a controlled and sustained release of CP and FA from the CSNPs, with the release amounts of 72.9 ± 3.6% and 94.8 ± 2.9%. The antimicrobial activity of the CSNPs-FA (91.37 ± 4.37% and 89.28 ± 3.19%) showed a significantly better effect against E. coli and S. aureus than that shown by the CSNPs-CP (63.41 ± 3.84% and 57.62 ± 4.28%). The HCT-116 cell lines were selected for in vitro cell cytotoxicity and live/dead assay to evaluate the preliminary anticancer efficacy of the CSNPs-CP and CSNPs-FA towards successfully inhibiting the growth of cancer cells. Full article
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