Physics

This review explores the foundations of non-relativistic quantum electrodynamics (QED) and its application to atoms and molecules. It follows the traditional route of placing classical electrodynamics in an Hamiltonian framework, followed by Dirac’s canonical quantisation algorithm. The properties of the resulting quantum Hamiltonian are reviewed from a non-perturbative perspective. It discusses the gauge invariance of the S-matrix, the Coulomb interaction, and the challenges posed by infinities in classical and quantum electrodynamics. The paper examines the mathematical frameworks used to address these issues, including the use of distributions and the Colombeau algebra. The review also highlights the limitations of the Coulomb Hamiltonian in explaining molecular structure and chemistry, emphasizing the need for additional theoretical modifications to bridge quantum mechanics and chemical phenomena.

We address the spatially nonlocal dielectric functions of graphene at any frequency derived starting from the first principles of thermal quantum field theory using the formalism of the polarization tensor. After a brief review of this formalism, the longitudinal and transverse dielectric functions are considered at any relationship between the frequency and the wave vector. The analytic properties of their real and imaginary parts are investigated at low and high frequencies. Emphasis is given to the double pole at zero frequency, which arises in the transverse dielectric function. The role of this unusual property in solving the problem of disagreement between experiment and theory in the Casimir effect is discussed. We believe that a more complete dielectric response of ordinary metals should also be spatially nonlocal and its transverse part may possess the double pole in the region of evanescent waves.

Partially ionized plasma physics has attracted increased attention recently due to numerous technological applications made possible by the increased sophistication of computer modelling, the depth of the theoretical analysis, and the technological applications to a vast field of manufacturing for computer components. Partially ionized plasma is characterized by a significant presence of neutral particles in contrast to the fully ionized plasma. The theoretical analysis is based upon solutions of the kinetic Boltzmann equation, yielding the non-Maxwellian electron energy distribution function (EEDF), thereby emphasizing the difference with a fully ionized plasma. The impact of the effect on discharges in inert and molecular gases is described in detail, yielding the complex nonlinear phenomena resulting in plasma selforganization. A few examples of such phenomena are given, including the non-monotonic EEDFs in the discharge afterglow in a mixture of argon with the molecular gas NF₃; the explosive generation of cold electron populations in capacitive discharges, hysteresis of EEDF in inductively coupled plasmas. Recently, highly advanced computer codes were developed in order to address the outstanding challenges in plasma technology. These developments are briefly described in general terms.