- Article
This study investigates the thermodynamic consequences of substitutional doping in bilayer graphene using a minimal tight-binding model in which doping is encoded as a reduction in the intralayer hopping amplitude in one sheet. The interlayer coupling fixes the low-energy window, while
introduces spectral asymmetry without generating new energy scales. The results show that decreasing redistributes the density of states toward the Fermi level, producing an enhancement of the low-energy density of states within the hybridized inner branches. As a consequence, the total electronic entropy vanishes in the limit of zero temperature () and increases smoothly with temperature for all , consistent with the third law of thermodynamics. Layer-resolved analysis reveals that the doped sheet acquires a larger electronic entropy than the pristine one for
, giving rise to a finite entropic polarization. The maximum polarization follows a linear scaling, demonstrating that the entropy imbalance is continuously controlled by the hopping asymmetry and does not involve critical behavior. These results establish a direct connection between doping-induced spectral redistribution and thermodynamic layer polarization in bilayer graphene.
26 May 2026







