Surface Microstructure Regulation of Low-Dimensional Nanomaterials Photocatalysts for Energy and Environmental Applications

A special issue of Nanomaterials (ISSN 2079-4991). This special issue belongs to the section "Energy and Catalysis".

Deadline for manuscript submissions: 19 September 2025 | Viewed by 568

Special Issue Editors


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Guest Editor
Shandong Provincial Key Laboratory of Molecular Engineering, School of Chemistry and Pharmaceutical Engineering, Qilu University of Technology, Jinan 250353, China
Interests: porous photocatalytic nanomaterials for solar energy conversion; energy and environmental applications
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Co-Guest Editor
Shandong Provincial Key Laboratory of Molecular Engineering, School of Chemistry and Pharmaceutical Engineering, Qilu University of Technology, Jinan 250353, China
Interests: nanomaterials for photocatalysis and electrocatalysis

Special Issue Information

Dear Colleagues,

Given the explosive growth of the global economy, the excessive consumption of conventional fossil fuels has caused an energy crisis and environmental concerns—two serious obstacles for the progress of human society. Semiconductor photocatalysis, which converts ubiquitous, inexhaustible, and clean solar power into high energy density chemical energy, is considered as one of the most promising technologies to solve these problems, exhibiting tremendous potential for application in many important fields, such as CO2 reduction, water splitting for hydrogen evolution, pollution degradation, organic synthesis, and N2 fixation. Compared with their bulk counterparts, low-dimensional nanomaterial photocatalysts commonly have smaller sizes and larger specific surface areas, can expose more active sites, and contribute to the subsequent structural modifications and reactant absorption. More importantly, low-dimensional photocatalysts possess a shorter bulk diffusion distance compared to photoinduced carriers, which reduces electron–hole pair recombination. On the other hand, the surface microstructure of nanomaterials has an important effect on the physical and chemical properties of the materials. Optimizing the electronic band structure and surface properties of low-dimensional photocatalysts through surface microstructure regulation strategies such as crystal plane engineering, defect engineering, and surface modification, as well as morphology and size control is of great significance to further enhance their photocatalytic performance and promote their applications in the fields of energy and the environment.

Prof. Dr. Wei Zhou
Prof. Dr. Zhenzi Li
Guest Editors

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Keywords

  • nanomaterials
  • semiconductor photocatalysis
  • low dimension
  • surface microstructure
  • crystal plane engineering
  • defect engineering
  • surface modification
  • energy
  • environment

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Published Papers (1 paper)

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Research

15 pages, 14909 KiB  
Article
Dual Defect-Engineered BiVO4 Nanosheets for Efficient Peroxymonosulfate Activation
by Jiabao Wu, Meiyu Xu, Zhenzi Li, Mingxia Li and Wei Zhou
Nanomaterials 2025, 15(5), 373; https://doi.org/10.3390/nano15050373 - 28 Feb 2025
Viewed by 499
Abstract
Defects and heteroatom doping are two refined microstructural factors that significantly affect the performance of photocatalytic materials. Coupling defect and doping engineering is a powerful approach for designing efficient photocatalysts. In this research, we successfully construct dual defect-engineered BiVO4 nanosheets (BVO-N-OV) by [...] Read more.
Defects and heteroatom doping are two refined microstructural factors that significantly affect the performance of photocatalytic materials. Coupling defect and doping engineering is a powerful approach for designing efficient photocatalysts. In this research, we successfully construct dual defect-engineered BiVO4 nanosheets (BVO-N-OV) by introducing N doping and oxygen vacancies through ammonium oxalate-assisted thermal treatment of BiVO4 nanosheets. Due to the combined enhancement of band structure and surface properties from N doping and oxygen vacancies, the obtained BVO-N-OV nanosheets demonstrate improved visible light absorption, effective charge transfer efficiency, and increased active sites. As a result, the constructed BVO-N-OV/PMS system demonstrates significantly enhanced ciprofloxacin (CIP) removal performance under visible light illumination. The highest rate constant for CIP degradation over BVO-N-OV/PMS system is 7.9, 1.9, and 6.6 times greater than pristine BiVO4 (BVO), oxygen vacancy-enriched BiVO4 (BVO-OV), and N-doped BiVO4 (BVO-N), respectively. Even in a broad pH range (3.0–11.0) with various anions, the BVO-N-OV/PMS/Vis system still demonstrates stable and excellent CIP removal performance. This study seeks to provide valuable insights into the interaction between defect and doping engineering in photocatalytic activation of PMS, thereby proposing new strategies for designing effective photocatalyst/PMS systems for wastewater treatment. Full article
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