Isocyanide
A special issue of Molecules (ISSN 1420-3049). This special issue belongs to the section "Organic Chemistry".
Deadline for manuscript submissions: closed (1 July 2017) | Viewed by 5058
Special Issue Editor
Interests: isocyanide chemistry; multicomponent reactions; organometallic chemistry; mechanistic studies; electrochemistry
Special Issue Information
Dear Colleagues,
Isocyanides are immensely valuable building-blocks used in both ionic and radical processes. These versatile synthons are well-designed for Multicomponent Reactions (MCRs), as attested by the huge success of the Ugi reaction. The development of new isocyanide-based MCRs (IMCRs), as well as the development of new cascades involving an IMCR, are of paramount importance to enlarge, even more, the molecular diversity attainable within a few synthetic steps. In addition to their interest for MCRs, isocyanides are isoelectronic with carbon monoxide and behave as non-toxic and are easily-handled analogues towards transition metals. Isocyanides have been known to be efficient metal ligands for a long time, and, since the early 1970s, a wide range of organometallic complexes have been described. Very recently, imidoylative metal-catalyzed processes have attracted intense research efforts and had a tremendous impact in heterocyclic synthesis. In this Special Issue, we intend to collect original contributions to provide a broad survey of the state-of-the-art in isocyanide chemistry. Reviews articles by experts in the field will also be welcome.
Dr. Laurence Grimaud
Guest Editor
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Keywords
- multicomponent reactions
- Ugi and Passerini reactions
- radical additions
- heterocyclic Chemistry
- organometallic complexes
- imidoylative processes
- isocyanide insertion
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