Advances in Metallocene Chemistry

Dear Colleagues,

Metallocenes are a class of unique organometallic compounds characterized by their “sandwich” structure, where a metal atom is surrounded by two cyclopentadienyl groups (Cp₂M). The discovery and characterization of ferrocene, (η⁵-C₅H₅)₂Fe, marked the beginning of a new era of organometallic chemistry. Back in the 1950s, it was discovered that variations in the structural motif “(η⁵-C₅H₅)₂Fe” were not only possible by the introduction of ring substituents but also by exchanging iron with other metals; this is when the large family of (true) “metallocenes”, i.e., compounds of the type “Cp₂M”, had come to life. Although not being “true” metallocenes, “half-sandwich compounds” with only one Cp ligand and “mixed sandwich complexes” with a transition metal sandwiched between two aromatic rings are often also called “metallocenes”. Research in metallocene chemistry spans not only basic chemistry but also extends into material science, catalysis, and bio-organometallic chemistry, among other interdisciplinary areas. This Special Issue, titled “Advances in Metallocene Chemistry”, aims to delve into the latest developments in metallocene chemistry, including the structure, chemical properties, synthetic methods, and applications of metallocenes across various fields.

This Special Issue will provide researchers with a comprehensive platform to share and discuss the latest research findings in metallocene chemistry, promoting scientific progress and technological innovation in this field. We look forward to your contributions and participation in advancing the development of metallocene chemistry together.

Prof. Dr. Karlheinz Sünkel
Guest Editor

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