Research of Hydrogen Embrittlement Behavior in Alloy Steels

A special issue of Metals (ISSN 2075-4701). This special issue belongs to the section "Metal Failure Analysis".

Deadline for manuscript submissions: closed (30 September 2023) | Viewed by 1292

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Department of Mechanical Engineering, University of Bonab, Velayat Highway, Bonab, Iran
Interests: fracture and failure analysis; materials characterization; corrosion; mechanical properties
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Special Issue Information

Dear Colleagues,

The ingress of hydrogen into the microstructure of steel alloys may create severe failure. This failure decreases the ductility and strength of steel. This problem arises due to the small size of hydrogen atoms, which enables them to diffuse through different microstructural defects. Several theories about hydrogen degradation in steel alloys, including the internal pressure theory, hydrogen-enhanced decohesion, and hydrogen-enhanced localized plasticity. Based on the internal pressure theory, hydrogen atoms diffuse through the steel microstructure and accumulate in hydrogen traps such as grain boundaries, interstitials, voids, and the space between the inclusions and metal matrix. The combination of hydrogen atoms forms hydrogen molecules. This process creates a high amount of pressure, and when this pressure reaches a critical value, the hydrogen-induced cracks initiate. In the hydrogen-enhanced decohesion theory, the hydrogen atoms diffuse through different defects and weaken the interatomic bonds leading to a break of atomic binding to start slipping. Finally, according to hydrogen-enhanced localized plasticity theory, the mobility of dislocations is increased in the presence of solute atoms, leading to a decrease in the required stress for dislocation movement. In steel alloys suffering from hydrogen embrittlement, both intergranular and transgranular cracks are observed, and these steels show fractures, which are far below the non-affected steels yield strength. The level of hydrogen embrittlement in steel alloys depends on various factors such as steel microstructure, the distribution of inclusions and precipitates, the density of hydrogen traps and dislocations, grain size, residual stress, and crystallographic texture.

Dr. Mohammad Ali Mohtadi-Bonab
Guest Editor

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Keywords

  • hydrogen embrittlement
  • steel alloys
  • microstructure
  • failure, dislocation
  • crystallographic texture
  • crack
  • ductility

Published Papers (1 paper)

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Research

15 pages, 3883 KiB  
Article
Effect of Hydrogen Pressure and Punch Velocity on the Hydrogen Embrittlement Susceptibility of Pipeline Steels Using Small Punch Tests under Gaseous Hydrogen Environments at Room Temperature
by Hyung-Seop Shin, Sungbeom Kang, Richard Pascua, Kyung-Oh Bae, Jaeyoung Park and Un-Bong Baek
Metals 2023, 13(12), 1939; https://doi.org/10.3390/met13121939 - 27 Nov 2023
Viewed by 884
Abstract
The in situ small punch (SP) test method is a simple screening technology developed to assess the hydrogen embrittlement (HE) characteristics of structural steels. This method can easily adjust the influencing parameters such as test temperature, gas pressure, and punch velocity depending on [...] Read more.
The in situ small punch (SP) test method is a simple screening technology developed to assess the hydrogen embrittlement (HE) characteristics of structural steels. This method can easily adjust the influencing parameters such as test temperature, gas pressure, and punch velocity depending on the hydrogen service environment. With increased hydrogen consumption, using pipelines for mass hydrogen transportation is being considered. This study evaluated the HE susceptibility of API-X52 and API-X70 steels, considering the hydrogen usage environment. The study investigated the effects of hydrogen pressure and punch velocity on the HE behaviors of each pipe steel at room temperature using the SP energy and relative reduction in thickness (RRT) to determine their effect on HE susceptibility quantitatively. The study found that hydrogen pressure produced a different HE effect; the lower the hydrogen pressure, the more HE was relieved. Particularly, when the punch velocity was high, such as 1 mm/min, the HE effect was significantly relaxed. However, when the punch velocity was below 0.01 mm/min, HE occurred even at low hydrogen pressure conditions, meaning hydrogen diffusion within the specimen during the SP testing reached a critical hydrogen concentration to create a brittle fracture. Both pipeline steels showed similar HE behaviors under a wide range of H2 pressures and punch velocities, showing an inverse S-curve for quantitative factors of SP energy and RRT against the H2 pressure at 1.0 mm/min punch velocity. The study classified the observed HE behaviors into four types based on quantitative and qualitative aspects. These findings confirm that the in situ SP test is a useful screening technique, and the factor RRT can be effectively applied to the HE screening of pipeline steels in low and high-pressure hydrogen environments. Full article
(This article belongs to the Special Issue Research of Hydrogen Embrittlement Behavior in Alloy Steels)
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