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New Advances in Ionic Liquids

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Energy Materials".

Deadline for manuscript submissions: closed (31 October 2021) | Viewed by 2690

Special Issue Editors


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Guest Editor
Research Centre in Chemistry of University of Porto (CIQUP), Institute of Molecular Sciences (IMS), Porto, Portugal
Interests: ionic liquids; electric double layer; interfacial electrochemistry; capacitors; carbon; electrical properties; electrodes materials; biosensing; batteries; renewable energy; energy management
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Guest Editor
CIQUP - Research Center in Chemistry, Faculty of Sciences, University of Porto, Rua do Campo Alegre, 4169-007 Porto, Portugal
Interests: carbon nanomaterials; ionic liquids; deep eutectic solvents; energy storage; electrodeposition; environmental security; cytotoxicity; ecotoxicity

Special Issue Information

Dear Colleagues,

Low-temperature molten salts—ionic liquids (IL)—and deep eutectic solvents, due to their unique and advantageous physical-chemical properties, have been at the forefront of relevant scientific innovation for a wide range of applications. The dual ionic and organic nature of ionic liquids and deep eutectic solvents is characterized by a complex microscopic heterogeneous structure and the core of their unpaired properties; however, the structure–function relationship is still a blurry landscape. In many fields of chemistry and physics, it is critical to understand the bulk and interfacial organization of dense ionic fluids, thus giving new insight into their unique properties.

Despite these designable solvents having gained popularity as sustainable green solvents for ionic liquid-based technology, their widespread application at a larger scale still faces relevant techno-economic challenges. In order to become a cost-effective solution in the future, these challenges must be addressed, particularly the need to scale up production and implement at a large scale, as well as establishing cost and availability, stability, recovery, and recycling of air- and water-stable novel liquids.

The main aim of this Special Issue is to publish original research articles on the recent current state and future trends in the field of ionic liquids, ensuring coverage of both the scientific fundaments and industrial applications. This issue will contribute to rationalizing both fundamental and applied findings and to understanding the role of IL structure in its performance, synthesis, properties, environmental impact, application frontiers and technologies.

Dr. Renata Costa
Prof. Dr. Carlos Pereira
Guest Editors

Manuscript Submission Information

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Keywords

  • ionic liquids
  • dense ionic fluids
  • green solvents
  • physical-chemical properties
  • electrolytes
  • design solvents
  • bulk properties
  • interfacial properties
  • molecular modeling and simulation
  • molecular-level interactions
  • catalysis
  • analytical chemistry
  • reaction media
  • organic chemistry

Published Papers (1 paper)

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Research

14 pages, 3282 KiB  
Article
New Low-Melting Triply Charged Homoleptic Cr(III)-Based Ionic Liquids in Comparison to Their Singly Charged Heteroleptic Analogues
by Tim Peppel and Martin Köckerling
Materials 2021, 14(10), 2676; https://doi.org/10.3390/ma14102676 - 20 May 2021
Cited by 2 | Viewed by 1775
Abstract
A series of new low-melting triply charged homoleptic Cr(III)-based ionic liquids of the general formula (RMIm)3[Cr(NCS)6] (R = methyl, ethyl, n-butyl, benzyl) is reported. Their syntheses and properties are described in comparison to their singly [...] Read more.
A series of new low-melting triply charged homoleptic Cr(III)-based ionic liquids of the general formula (RMIm)3[Cr(NCS)6] (R = methyl, ethyl, n-butyl, benzyl) is reported. Their syntheses and properties are described in comparison to their singly charged heteroleptic analogues of the general formula (RMIm)[Cr(NCS)4L2] (R = methyl, ethyl, n-butyl, benzyl; L = pyridine, γ-picoline). In total, sixteen new Reineckate related salts with large imidazolium cations are described. Out of these, five compounds were crystallized, and their structures determined by single-crystal X-ray structure analyses. They all consisted of discrete anions and cations with octahedrally coordinated Cr(III) ions. In the structures, various hydrogen contacts interconnect the entities to build up hydrogen bonded networks. Thermal investigations showed relatively low melting points for the homoleptic complexes. The compounds with the [Cr(NCS)6]3− anion melt without decomposition and are stable up to 200 K above their melting points. The complex salts with the [Cr(NCS)4L2] anion, in contrast, start to decompose and lose L molecules (Pyr or Pic) already at the melting point. Full article
(This article belongs to the Special Issue New Advances in Ionic Liquids)
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