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State of the Art: Surface and Coating Technologies

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Manufacturing Processes and Systems".

Deadline for manuscript submissions: closed (10 June 2023) | Viewed by 6911

Special Issue Editors


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Guest Editor
Faculty of Metals Engineering and Industrial Computer Science, AGH University of Science and Technology, Mickiewicza 30, PL-30059 Krakow, Poland
Interests: materials science; electron microscopy; materials characterization; nickel-based superalloys; metal matrix composites; additive manufacturing of metallic materials

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Guest Editor
Faculty of Metals Engineering and Industrial Computer Science, AGH University of Science and Technology, Mickiewicza 30, PL-30059 Krakow, Poland
Interests: surface engineering; thin films; pulsed laser deposition; laser surface treatment; wear resistance
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Special Issue Information

Dear Colleagues,

The progress in surface and coating engineering is closely related to the development of modern materials, and enables the dynamic development of innovative technologies for producing products with improved surface properties.

Of particular interest are new methods of modifying mechanical and physical properties and improving resistance to aggressive environmental conditions. Among these, the methods of modern thermo-chemical treatment; surface modification by directed energy techniques (laser beam, electron beam, ion beam); mechanical methods (e.g., friction stir processing); the production of thin films by PVD, CVD, and ALD methods; and the production of coatings by sol–gel, thermal spraying, or cold gas spraying are of great importance.

The use of modern surface engineering technologies allows for the intensive development of areas such as electronics (e.g., thin films with special electrical properties, gas sensors), medicine (e.g., implants), power engineering (e.g., materials for hydrogen storage, thin-film fuel cells), and transport (e.g., anti-wear coatings, thermal barrier coatings), and contributes to both environmental protection by reducing energy consumption, as well as increasing human safety (e.g., bactericidal and virucidal coatings and thin films).

In this Special Issue of Materials, we want to present innovative achievements in the field of surface and coating technologies, which will allow the exchange of experiences and inspire further development of material technologies. We invite you to submit full scientific articles as well as articles that present a critical review of the literature on modern surface and coating technologies.

Dr. Beata Dubiel
Dr. Sławomir Kąc
Guest Editors

Manuscript Submission Information

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Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Materials is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • surface layers
  • coatings
  • thin films
  • thermo-chemical treatment
  • spraying technologies
  • directed energy techniques

Published Papers (5 papers)

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Research

17 pages, 3655 KiB  
Article
Simulation and Optimization of the Auxiliary Cathode for Inter-Electrode Discharge Electric Field in Microarc Oxidation
by Pengxiang Lv, Xiaozhou Zhang, Lei Chen, Shixuan Wang, Zhen Wang, Rongguo He and Le Guan
Materials 2023, 16(14), 5065; https://doi.org/10.3390/ma16145065 - 18 Jul 2023
Viewed by 731
Abstract
Currently, research on the edge effect issue in the micro-arc oxidation process primarily focuses on investigating process conditions and enhancing additives. However, some scholars have utilized finite element analysis software to simulate the edge effect during the simulation process, overlooking the investigation of [...] Read more.
Currently, research on the edge effect issue in the micro-arc oxidation process primarily focuses on investigating process conditions and enhancing additives. However, some scholars have utilized finite element analysis software to simulate the edge effect during the simulation process, overlooking the investigation of the morphology of the auxiliary cathode. This study analyzes the growth characteristics of the oxide film on aluminum alloy 2A12 during micro-arc oxidation. Additionally, the inter-electrode discharge electric field is simulated using the finite element analysis method. The auxiliary cathode is optimized to mitigate the influence of the edge effect on the film layer. The findings indicate that employing a cylindrical shape as the auxiliary cathode instead of a rectangular groove leads to an increased thickness of the micro-arc oxidation film. However, it also results in an augmented length of the film layer affected by the edge effect at both ends of the workpiece. Decreasing the distance between the auxiliary cathode and the workpiece surface leads to a higher thickness of the obtained micro-arc oxidation film. Decreasing the length of the auxiliary cathode results in a reduction in both the thickness of the film layer on the workpiece surface and the area affected by the edge effect. Increasing the eccentric cone ratio of the auxiliary cathode enhances the uniformity of the micro-arc oxidation film layer. In this study, we present a novel auxiliary cathode model that incorporates a smaller cylindrical shell at the center and eccentric cone shells on each side. This model has the potential to enhance the optimization rate of the micro-arc oxidation film layer on cylindrical workpieces by 17.77%. Full article
(This article belongs to the Special Issue State of the Art: Surface and Coating Technologies)
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13 pages, 4799 KiB  
Article
The Influence of Buffer Layer Type on the Electrical Properties of Metallic Layers Deposited on Composite Textile Substrates in the PVD Process
by Marcin Lebioda and Ewa Korzeniewska
Materials 2023, 16(13), 4856; https://doi.org/10.3390/ma16134856 - 06 Jul 2023
Cited by 5 | Viewed by 740
Abstract
In the era of developing wearable electronics, the miniaturization of electronic systems and their implementation in the textile industry is one of the key issues. For this reason, it is important to select the appropriate textile substrates upon which it is possible to [...] Read more.
In the era of developing wearable electronics, the miniaturization of electronic systems and their implementation in the textile industry is one of the key issues. For this reason, it is important to select the appropriate textile substrates upon which it is possible to produce electroconductive structures, as well as their selection from the point of view of the electrical parameters’ stability. For this purpose, research related to the effect of heating a substrate on the resistance of the structures produced in the process of physical vacuum planting was conducted. Textile composites with a buffer layer made of polyurethane, Teflon, and acrylic were used as substrates in the tests. Such layers are an integral part of textile composites and a necessary element for producing structures with continuous electrical conductivity. The conducted tests showed that a buffer layer made of polyurethane (thermal conductivity, e.g., PERMACOL 5450 resin 0.16 W/mK) heated to 15 °C above room temperature was a layer that introduced changes into the surface resistance of the structures. The resistance values of the samples produced on a substrate containing a buffer layer of polyurethane varied in the range of 9–23%, depending on the manufacturer of the composite in the case of a self-heating mode, and in the case of an external heating mode, these changes were smaller and ranged from 8 to 16%. Such a phenomenon occurred regardless of the type of applied metal, and this was not observed in the case of composites with a Teflon or acrylic sublayer. For this reason, it is necessary to take into account the fact that textronic structures made on substrates containing a polyurethane layer may change the surface resistance depending on the temperature. The electrical parameters of such structures were checked by heating the structure using an external heater and self-heating mechanism. The same phenomenon was observed in both cases. Full article
(This article belongs to the Special Issue State of the Art: Surface and Coating Technologies)
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16 pages, 6255 KiB  
Article
Ni–Cr Powders Modified with Rhenium as a Novel Coating Material—Physical Properties, Microstructure, and Behavior in Plasma Plume
by Adriana Wrona, Marcin Lis, Krzysztof Pęcak, Izabela Kalemba-Rec, Stanisław Dymek, Mirosław Wróbel, Katarzyna Bilewska, Katarzyna Kustra, Marek Stanisław Węglowski and Piotr Śliwiński
Materials 2022, 15(11), 3844; https://doi.org/10.3390/ma15113844 - 27 May 2022
Cited by 2 | Viewed by 1382
Abstract
The aim of this work was to develop a new coating material based on Ni20Cr alloy modified with up to 50%wt. rhenium. The modification was carried out by the mechanical mixing of the base powder and ammonium perrhenate with the subsequent thermoreduction in [...] Read more.
The aim of this work was to develop a new coating material based on Ni20Cr alloy modified with up to 50%wt. rhenium. The modification was carried out by the mechanical mixing of the base powder and ammonium perrhenate with the subsequent thermoreduction in an H2 atmosphere. The obtained powder consists of a nickel–chromium core surrounded by a rhenium shell. The characterization of the powders—including their microstructure, phase and chemical composition, density, flowability, particle size distribution, and specific surface area—was performed. The influence of plasma current intensity and hydrogen gas flow on in-flight particle temperature and velocity were investigated. The results indicate that there is interdiffusion between the base Ni20Cr and the rhenium shell, resulting in intermediary solid solution(s). The modified powders have a higher specific surface area and a lower flowability, but this does not prevent them from being used as feedstock in plasma spraying. In-flight measurements reveal that increasing the content of rhenium allows for the higher temperature of particles, though it also reduces their speed. Full article
(This article belongs to the Special Issue State of the Art: Surface and Coating Technologies)
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15 pages, 18381 KiB  
Article
Impact of Deposition of the (TiBx/TiSiyCz) x3 Multilayer on M2 HSS on the Cutting Force Components and Temperature Generated in the Machined Area during the Milling of 316L Steel
by Agnieszka Twardowska, Łukasz Ślusarczyk and Marcin Kowalski
Materials 2022, 15(3), 746; https://doi.org/10.3390/ma15030746 - 19 Jan 2022
Cited by 1 | Viewed by 1211
Abstract
High-speed steel (HSS) tools account for 20 percent of the cutting tools materials’ global market. This is due to both their significant toughness and resistance to cracking, compared to cemented carbides. Covering steel tools with hard coatings clearly improves their mechanical properties, wear [...] Read more.
High-speed steel (HSS) tools account for 20 percent of the cutting tools materials’ global market. This is due to both their significant toughness and resistance to cracking, compared to cemented carbides. Covering steel tools with hard coatings clearly improves their mechanical properties, wear resistance, and significantly increases their durability. Physical vapor deposition methods are preferred for coating metal substrates, as they allow low temperature deposition. The most widely deposited coating materials are carbides, nitrides, and borides. They are combined with softer ones in the multilayer structure to promote increased resistance to cracking and delamination in comparison to monolayered structures. In this paper, the M2 steel end mills were coated by (TiBx/TiSiyCz) x3 multilayer by the pulsed laser deposition method. Coated and uncoated tools were tested in the cylindrical down milling of AISI 316L steel. Components of the cutting force and temperature generated in the machined area during dry milling were measured under two variants of operating conditions: V1 and V2. Tool wear mechanism was examined using scanning electron microscopy (SEM), accompanied by EDS analysis of worn areas. It was found that milling with higher speed (variant V2) is accompanied by lower cutting force components and a lower temperature generated in cutting area. The presence of the coating allowed lower cutting forces and temperature in the case of variant V1. The temperature measured during milling did not exceed 200 °C. The SEM observation of the edges of cutting tools indicated that the main mechanism of wear for both types of tools was abrasion. The built-up edge formation was observed in the case of tools tested at the V1 cutting parameters variant. It was assumed that it was the reason for higher cutting forces measured during milling according to this variant. The chemical composition of built-up edges was different for coated and uncoated tools. Tribo-chemical reactions were responsible for the reduction of the cutting force and temperature components observed during milling with a coated tool at V1 variant. Boron and titanium were the elements of the coating that enabled the tribo-oxidation reactions thanks to which friction was reduced. Our results show that this beneficial effect occurs with (TiBx/TiSiyCz) x3 coated tools, but can easily be lost with inadequately selected cutting parameters. Full article
(This article belongs to the Special Issue State of the Art: Surface and Coating Technologies)
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12 pages, 33161 KiB  
Article
The Influence of Pd and Zr Co-Doping on the Microstructure and Oxidation Resistance of Aluminide Coatings on the CMSX-4 Nickel Superalloy
by Jolanta Romanowska, Jerzy Morgiel and Maryana Zagula-Yavorska
Materials 2021, 14(24), 7579; https://doi.org/10.3390/ma14247579 - 09 Dec 2021
Cited by 2 | Viewed by 1773
Abstract
Pd + Zr co-doped aluminide coatings were deposited on the CMSX-4 nickel superalloy, widely used in the aircraft industry, in order to investigate their microstructure and improvement of oxidation resistance. Palladium was deposited by the electrochemical method, whereas zirconium and aluminum by the [...] Read more.
Pd + Zr co-doped aluminide coatings were deposited on the CMSX-4 nickel superalloy, widely used in the aircraft industry, in order to investigate their microstructure and improvement of oxidation resistance. Palladium was deposited by the electrochemical method, whereas zirconium and aluminum by the chemical vapor deposition (CVD) method. Coatings consist of two zones: the additive and the interdiffusion one. The additive zone contains β–(Ni,Pd)Al phase with some zirconium-rich precipitates close to the coating’s surface, whereas the interdiffusion zone consists of the same β–(Ni,Pd)Al phase with inclusions of refractory elements that diffused from the substrate, so called topologically closed-packed phases. Palladium dissolves in the β–NiAl phase and β–(Ni,Pd)Al phase is being formed. Pd + Zr co-doping improved the oxidation resistance of analysed coatings better than Pd mono-doping. Mechanisms responsible for this phenomenon and the synergistic effect of palladium and zirconium are discussed. Full article
(This article belongs to the Special Issue State of the Art: Surface and Coating Technologies)
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