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Carbon Nanomaterials for Multifunctional Applications

A special issue of Materials (ISSN 1996-1944). This special issue belongs to the section "Carbon Materials".

Deadline for manuscript submissions: closed (20 April 2025) | Viewed by 6220

Special Issue Editor


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Guest Editor
School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing, China
Interests: multifunctional applications of graphene macroscopic assemblies; multifunctional applications of graphene/polymer composites
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

Carbon nanomaterials have revolutionized the field of materials science, and their multifunctional applications continue to expand. From the discovery of graphene's remarkable properties to the development of novel carbon nanotubes and other carbon-based structures, these materials have opened up new possibilities for various industries. This Special Issue, titled "Carbon Nanomaterials for Multifunctional Applications", aims to explore the latest advances in harnessing the unique properties of carbon nanomaterials for diverse applications. Carbon nanomaterials, such as graphene, carbon nanotubes, and fullerenes, exhibit exceptional properties, including high mechanical strength, electrical conductivity, thermal stability, and a large surface area. These attributes make them invaluable for a wide range of applications, from electronics and energy storage to aerospace and biomedical devices.

We invite researchers to contribute their original research articles, communications, and reviews to this Special Issue. Topics of interest include, but are not limited to:

  1. Novel Fabrication Techniques: Exploring innovative methods for the synthesis and production of carbon nanomaterials, pushing the boundaries of what is possible in terms of structure, purity, and scalability.
  2. Design of Multifunctional Materials: Investigating the design and development of advanced materials that incorporate carbon nanomaterials to achieve multifunctionality. This may include flexible composites, coatings, and hybrids with tailored properties.
  3. Advanced Characterization: Presenting cutting-edge techniques and tools for characterizing the microstructure and properties of carbon nanomaterials, shedding light on their behavior in various environments.
  4. Applications in Emerging Fields: Highlighting the use of carbon nanomaterials in exciting and emerging fields, such as nanoelectronics, sensor technology, energy conversion and storage, catalysis, and more.
  5. Carbon Nanomaterials for Environmental Solutions: Exploring how carbon nanomaterials can address environmental challenges, such as gas adsorption and separation, water purification, and sustainable energy generation.
  6. Safety and Toxicology: Discussing the safety and potential toxicological concerns associated with the use of carbon nanomaterials, along with strategies for responsible research and application.

Dr. Ying Wu
Guest Editor

Manuscript Submission Information

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Keywords

  • carbon nanomaterials
  • graphene
  • carbon nanotubes
  • fullerenes
  • multifunctional materials
  • nanoelectronics

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Related Special Issue

Published Papers (5 papers)

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Research

12 pages, 5100 KiB  
Article
Inter-Ply Slipping Behaviors and Kinetic Equation of Carbon Fiber-Reinforced Epoxy Prepregs for Hot Diaphragm Preforming
by Haoxuan Zhang, Jintong Liu, Congfa Zhang, Hongfu Li, Guangquan Yue, Baozhong Sun and Boyan He
Materials 2024, 17(22), 5592; https://doi.org/10.3390/ma17225592 - 15 Nov 2024
Viewed by 790
Abstract
Wrinkles are urgent problems to be solved in the process of hot diaphragm preforming. Inter-ply slipping resistance is one of the causes of wrinkles. In this paper, based on the vertical inter-ply slipping test system, the inter-ply slipping behaviors of carbon fiber-reinforced epoxy [...] Read more.
Wrinkles are urgent problems to be solved in the process of hot diaphragm preforming. Inter-ply slipping resistance is one of the causes of wrinkles. In this paper, based on the vertical inter-ply slipping test system, the inter-ply slipping behaviors of carbon fiber-reinforced epoxy resin composite prepregs were characterized. The mechanism of wrinkles caused by inter-ply slipping resistance was analyzed. According to the different characteristics expressed by the fiber and resin during the slip process, the inter-ply slipping behaviors of the prepregs were divided into three stages. The effect of temperature on the inter-ply slipping stresses was shown. The temperature will affect the viscosity of the prepregs. When the viscosity of the prepregs is low, the inter-ply slipping resistance will decrease. Based on the Coulomb friction law and the hydrodynamic equation, the inter-ply slipping kinetic equation of the prepregs was established. The inter-ply slipping kinetic equation was introduced into the ABAQUS main program by the ‘vfriction’ subroutine. The introduction of inter-ply slipping dynamics improved the accuracy of predicting the shape and position of wrinkles. Full article
(This article belongs to the Special Issue Carbon Nanomaterials for Multifunctional Applications)
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14 pages, 11202 KiB  
Article
Fabrication, Microstructural Evolution, and Mechanical Properties of SiC/(Hf0.25Ta0.25Zr0.25Nb0.25)C/C Nanocomposites
by Zhenyue Wang, Tianci Zhou, Xiantao Yang, Yuenong Liu, Qingbo Wen and Zhaoju Yu
Materials 2024, 17(21), 5294; https://doi.org/10.3390/ma17215294 - 31 Oct 2024
Viewed by 954
Abstract
A dense monolithic SiC/(Hf0.25Ta0.25Zr0.25Nb0.25)C/C high-entropy ceramic nanocomposite was prepared using a polymer-derived ceramic (PDC) method combined with spark plasma sintering (SPS). The microstructural evolution and mechanical properties of the obtained nanocomposites were characterized by X-ray [...] Read more.
A dense monolithic SiC/(Hf0.25Ta0.25Zr0.25Nb0.25)C/C high-entropy ceramic nanocomposite was prepared using a polymer-derived ceramic (PDC) method combined with spark plasma sintering (SPS). The microstructural evolution and mechanical properties of the obtained nanocomposites were characterized by X-ray diffractometer (XRD), transmission electron microscope (TEM), scanning-electron microscope (SEM), and nanoindentation. The results indicate that the phase composition of SiC/(Hf0.25Ta0.25Zr0.25Nb0.25)C/C can be adjusted by modifying the metal content of the single-source precursor (SSP) through molecular design. The resulting precursor exhibits an exceptionally high ceramic yield, with mass retention of over 90% at 1100 °C, which guarantees the densification of the final SiC/(Hf0.25Ta0.25Zr0.25Nb0.25)C/C composites. The PDC route facilitates the in situ formation of a high-entropy phase within the ceramic matrix under low temperature pyrolysis conditions. Combined with SPS, a dense monolithic SiC/(Hf0.25Ta0.25Zr0.25Nb0.25)C/C nanocomposite was obtained, exhibiting an open porosity of 0.41 vol%, nano-hardness of 27.47 ± 0.46 GPa, elastic modulus of 324.00 ± 13.60 GPa, and fracture toughness of 3.59 ± 0.24 MPa·m0.5, demonstrating excellent mechanical properties. Full article
(This article belongs to the Special Issue Carbon Nanomaterials for Multifunctional Applications)
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15 pages, 7883 KiB  
Article
A Two-Layer Graphene Nonwoven Fabric for Effective Electromagnetic Interference Shielding
by Ying Wu, Haijun Tang, Liying Kang, Hongfu Li and Naisheng Jiang
Materials 2024, 17(15), 3747; https://doi.org/10.3390/ma17153747 - 29 Jul 2024
Viewed by 1155
Abstract
Rapid advancements and proliferation of electronic devices in the past decades have significantly intensified electromagnetic interference (EMI) issues, driving the demand for more effective shielding materials. Herein, we introduce a novel two-layer graphene nonwoven fabric (2-gNWF) that shows excellent EMI shielding properties. The [...] Read more.
Rapid advancements and proliferation of electronic devices in the past decades have significantly intensified electromagnetic interference (EMI) issues, driving the demand for more effective shielding materials. Herein, we introduce a novel two-layer graphene nonwoven fabric (2-gNWF) that shows excellent EMI shielding properties. The 2-gNWF fabric comprises a porous fibrous upper layer and a dense conductive film-like lower layer, specifically designed to enhance EMI shielding through the combined mechanisms of reflection, multiple internal reflections, and absorption of electromagnetic waves. The 2-gNWF exhibits a remarkable EMI shielding effectiveness (SE) of 80 dB while maintaining an impressively low density of 0.039 g/cm3, surpassing the performance of many existing graphene-based materials. The excellent EMI shielding performance of 2-gNWF is attributed to the multiple interactions of incident electromagnetic waves with its highly conductive network and porous structure, leading to efficient energy dissipation. The combination of high EMI SE and low density makes 2-gNWF ideal for applications that require lightweight yet effective shielding properties, demonstrating the significant potential for advanced EMI shielding applications. Full article
(This article belongs to the Special Issue Carbon Nanomaterials for Multifunctional Applications)
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11 pages, 3371 KiB  
Article
Synthesis and Electrochemical Characterization of Nitrate-Doped Polypyrrole/Ag Nanowire Nanorods as Supercapacitors
by Hyo-Kyung Kang, Ki-Hyun Pyo, Yoon-Hee Jang, Youn-Soo Kim and Jin-Yeol Kim
Materials 2024, 17(9), 1962; https://doi.org/10.3390/ma17091962 - 24 Apr 2024
Viewed by 1047
Abstract
Polypyrrole (PPy)-capped silver nanowire (Ag NW) nanomaterials (core–shell rod-shaped Ag NW@PPy) were synthesized using a one-port suspension polymerization technique. The thickness of the PPy layer on the 50 nm thickness/15 μm length Ag NW was effectively controlled to 10, 40, 50, and 60 [...] Read more.
Polypyrrole (PPy)-capped silver nanowire (Ag NW) nanomaterials (core–shell rod-shaped Ag NW@PPy) were synthesized using a one-port suspension polymerization technique. The thickness of the PPy layer on the 50 nm thickness/15 μm length Ag NW was effectively controlled to 10, 40, 50, and 60 nm. Thin films cast from one-dimensional conductive Ag NW@PPy formed a three-dimensional (3D) conductive porous network structure and provided excellent electrochemical performance. The 3D Ag NW@PPy network can significantly reduce the internal resistance of the electrode and maintain structural stability. As a result, a high specific capacitance of 625 F/g at a scan rate of 1 mV/s was obtained from the 3D porous Ag NW@PPy composite film. The cycling performance over a long period exceeding 10,000 cycles was also evaluated. We expect that our core–shell-structured Ag NW@PPy composites and their 3D porous structure network films can be applied as electrochemical materials for the design and manufacturing of supercapacitors and other energy storage devices. Full article
(This article belongs to the Special Issue Carbon Nanomaterials for Multifunctional Applications)
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13 pages, 5078 KiB  
Article
Sensitive Characterization of the Graphene Transferred onto Varied Si Wafer Surfaces via Terahertz Emission Spectroscopy and Microscopy (TES/LTEM)
by Dongxun Yang, Jesse Henri Laarman and Masayoshi Tonouchi
Materials 2024, 17(7), 1497; https://doi.org/10.3390/ma17071497 - 26 Mar 2024
Viewed by 1550
Abstract
Graphene shows great potential in developing the next generation of electronic devices. However, the real implementation of graphene-based electronic devices needs to be compatible with existing silicon-based nanofabrication processes. Characterizing the properties of the graphene/silicon interface rapidly and non-invasively is crucial for this [...] Read more.
Graphene shows great potential in developing the next generation of electronic devices. However, the real implementation of graphene-based electronic devices needs to be compatible with existing silicon-based nanofabrication processes. Characterizing the properties of the graphene/silicon interface rapidly and non-invasively is crucial for this endeavor. In this study, we employ terahertz emission spectroscopy and microscopy (TES/LTEM) to evaluate large-scale chemical vapor deposition (CVD) monolayer graphene transferred onto silicon wafers, aiming to assess the dynamic electronic properties of graphene and perform large-scale graphene mapping. By comparing THz emission properties from monolayer graphene on different types of silicon substrates, including those treated with buffered oxide etches, we discern the influence of native oxide layers and surface dipoles on graphene. Finally, the mechanism of THz emission from the graphene/silicon heterojunction is discussed, and the large-scale mapping of monolayer graphene on silicon is achieved successfully. These results demonstrate the efficacy of TES/LTEM for graphene characterization in the modern graphene-based semiconductor industry. Full article
(This article belongs to the Special Issue Carbon Nanomaterials for Multifunctional Applications)
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