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Condens. Matter, Volume 10, Issue 3 (September 2025) – 11 articles

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10 pages, 701 KiB  
Article
Beyond Wave-Nature Signatures: h-Independent Transport in Strongly-Scattering Quasi-2D Quantum Channels
by Er’el Granot
Condens. Matter 2025, 10(3), 46; https://doi.org/10.3390/condmat10030046 - 14 Aug 2025
Viewed by 161
Abstract
The Landauer-Büttiker formalism provides a fundamental framework for mesoscopic transport, typically expressing conductance in units of the quantum of conductance, e2/h. Here, we present a theoretical study of electron transport in a quasi two-dimensional (2D) quantum wire. This system [...] Read more.
The Landauer-Büttiker formalism provides a fundamental framework for mesoscopic transport, typically expressing conductance in units of the quantum of conductance, e2/h. Here, we present a theoretical study of electron transport in a quasi two-dimensional (2D) quantum wire. This system features a wide transverse confinement and a longitudinal, high-energy, narrow potential barrier. The derivation, performed within the Landauer framework, yields an analytical expression for the total conductance that is explicitly independent of Planck’s constant (h). Instead, the conductance is found to depend solely on the Fermi energy, the electron effective mass, the wire width, and the effective barrier strength. We interpret this as an emergent phenomenon where the explicit signature of the electron’s wave-like nature, commonly manifest through Planck’s constant (h) in the overall scaling of conductance, is effectively absorbed within the energy- and geometry-dependent sum of transmission probabilities. This allows the conductance to be primarily governed by the Fermi energy, representing a ‘state-counting’ quantum parameter rather than more wave-like characteristic. Full article
(This article belongs to the Section Quantum Materials)
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13 pages, 346 KiB  
Article
The Solution to Hardy’s Paradox
by Ivan Arraut
Condens. Matter 2025, 10(3), 45; https://doi.org/10.3390/condmat10030045 - 10 Aug 2025
Viewed by 220
Abstract
By using both the weak-value formulation as well as the standard probabilistic approach, we analyze Hardy’s experiment introducing a complex and dimensionless parameter (ϵ), which eliminates the assumption of complete annihilation when both the electron and the positron departing from a [...] Read more.
By using both the weak-value formulation as well as the standard probabilistic approach, we analyze Hardy’s experiment introducing a complex and dimensionless parameter (ϵ), which eliminates the assumption of complete annihilation when both the electron and the positron departing from a common origin cross the intersection point P. We then find that the paradox does not exist for all the possible values taken by the parameter. The apparent paradox only appears when ϵ=1, which is just a singular value. In this paper we demonstrate that this particular value is forbidden inside the scenario proposed by the experiment. Full article
(This article belongs to the Section Condensed Matter Theory)
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15 pages, 5436 KiB  
Article
Effect of Surface Passivation on the Quasi-Two-Dimensional Perovskite X2Cs(n−1) PbnI(3n+1)
by Min Li, Haoyan Zheng, Xianliang Ke, Dawei Zhang and Jie Huang
Condens. Matter 2025, 10(3), 44; https://doi.org/10.3390/condmat10030044 - 9 Aug 2025
Viewed by 185
Abstract
The two-dimensional (2D) Ruddlesden–Popper perovskite exhibits superior chemical stability but suffers from compromised photoelectric properties due to the van der Waals gap. This study presents a novel investigation of surface passivation effects on quasi-2D perovskite X2Csn−1PbnI3n+1 [...] Read more.
The two-dimensional (2D) Ruddlesden–Popper perovskite exhibits superior chemical stability but suffers from compromised photoelectric properties due to the van der Waals gap. This study presents a novel investigation of surface passivation effects on quasi-2D perovskite X2Csn−1PbnI3n+1 (n = 1–6; X = MA, FA, PEA) using DFT methods, revealing three key advances: First, we demonstrate that organic cation passivation (MA+, FA+, PEA+) enables exceptional stability improvements, with FA-passivated structures showing optimal stability—a crucial finding for materials design. Second, we identify a critical thickness effect (n > 3) where bandgaps converge to <1.6 eV (approaching bulk values) while maintaining strong absorption, establishing the minimum layer requirement for optimal performance. Third, we reveal that effective masses balance and absorption strengthens significantly when n > 3. These fundamental insights provide a transformative strategy to simultaneously enhance both stability and optoelectronic properties in quasi-2D perovskites. Full article
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11 pages, 223 KiB  
Essay
Beyond Space and Time: Quantum Superposition as a Real-Mental State About Choices
by Antoine Suarez
Condens. Matter 2025, 10(3), 43; https://doi.org/10.3390/condmat10030043 - 6 Aug 2025
Viewed by 371
Abstract
This contribution aims to honour Guido Barbiellini’s profound interest in the interpretation and impact of quantum mechanics by examining the implications of the so-called before–before Experiment on quantum entanglement. This experiment was inspired by talks and discussions with John Bell at CERN. This [...] Read more.
This contribution aims to honour Guido Barbiellini’s profound interest in the interpretation and impact of quantum mechanics by examining the implications of the so-called before–before Experiment on quantum entanglement. This experiment was inspired by talks and discussions with John Bell at CERN. This was during the years when John and Guido co-worked, promoting the mission of the laboratory: “to advance the boundaries of human knowledge”. As the experiment uses measuring devices in motion, it can be considered a complement to entanglement experiments using stationary measuring devices, which have meanwhile been awarded the 2022 Nobel Prize in Physics. The before–before Experiment supports the idea that the quantum realm exists beyond space and time and that the quantum state is a real mental entity concerning choices. As it also leads us to a better understanding of the ‘quantum collapse’ and the measurement process, we pay homage to Guido’s work on detectors, such as his collaborations on the DELPHI experiment at CERN, on cosmic ray detection at the International Space Station, and gamma-ray astrophysics during a large NASA space mission. Full article
8 pages, 2120 KiB  
Perspective
Axion Searches at the CERN SPS: From Their Dawn to Current Prospects
by Paolo Crivelli and Martina Mongillo
Condens. Matter 2025, 10(3), 42; https://doi.org/10.3390/condmat10030042 - 5 Aug 2025
Viewed by 305
Abstract
This mini-review traces the evolution of axion searches at the CERN Super Proton Synchrotron (SPS), beginning with the early proposal by Guido Barbiellini in 1982 and culminating in the recent advances of the NA62 and NA64 experiments. We discuss the experimental strategies employed [...] Read more.
This mini-review traces the evolution of axion searches at the CERN Super Proton Synchrotron (SPS), beginning with the early proposal by Guido Barbiellini in 1982 and culminating in the recent advances of the NA62 and NA64 experiments. We discuss the experimental strategies employed in early beam dump searches, the current status of axion and axion-like particle (ALP) searches at the CERN SPS and future directions. This review serves as a tribute to Guido Barbiellini’s scientific legacy and his visionary contributions to this field. Full article
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11 pages, 1745 KiB  
Article
Comprehensive Investigation of Structural and Photocatalytic Properties of Cobalt and Nickel Co-Doped Magnesium Oxide Nanoparticles
by Shafaq Arif, Amna Sarwar and M. S. Anwar
Condens. Matter 2025, 10(3), 41; https://doi.org/10.3390/condmat10030041 - 4 Aug 2025
Viewed by 326
Abstract
Cobalt and Nickel (Co, Ni) co-doped magnesium oxide (MgO) nanoparticles (NPs) have been synthesized using the coprecipitation method. The structural, chemical, and optical properties of the as-synthesized NPs are systematically investigated using X-ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), and UV-visible spectroscopy. [...] Read more.
Cobalt and Nickel (Co, Ni) co-doped magnesium oxide (MgO) nanoparticles (NPs) have been synthesized using the coprecipitation method. The structural, chemical, and optical properties of the as-synthesized NPs are systematically investigated using X-ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), and UV-visible spectroscopy. It is found that the optical bandgap of co-doped MgO NPs reduces from 2.30 to 1.98 eV (14%) with increasing Ni dopant concentrations up to 7%. The Co0.05Ni0.07Mg0.88O NPs exhibit a high photocatalytic degradation efficiency of 93% for methylene blue dye (MB) under natural sunlight irradiation for 240 min. Our findings indicate that the Co0.05NixMg0.95−xO NPs have strong potential for use as photocatalysts in industrial wastewater treatment. Full article
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11 pages, 962 KiB  
Article
Possible Realization of Hyperbolic Plasmons in Few-Layered Rhenium Disulfide
by Ravi Kiran, Dimitar Pashov, Mark van Schilfgaarde, Mikhail I. Katsnelson, Arghya Taraphder and Swagata Acharya
Condens. Matter 2025, 10(3), 40; https://doi.org/10.3390/condmat10030040 - 19 Jul 2025
Viewed by 416
Abstract
Hyperbolic plasmons are a highly desired property in optoelectronics and biomolecular sensing. The necessary condition to realize hyperbolic plasmons is a significant anisotropy of the principal components of the dielectric function, such that at a certain frequency range, one component is negative and [...] Read more.
Hyperbolic plasmons are a highly desired property in optoelectronics and biomolecular sensing. The necessary condition to realize hyperbolic plasmons is a significant anisotropy of the principal components of the dielectric function, such that at a certain frequency range, one component is negative and the other is positive, i.e., one component is metallic, and the other one is dielectric. Here, we study the effect of anisotropy in ReS2, and our theory shows that ReS2 can host hyperbolic plasmons in the ultraviolet frequency range. The operating frequency range of the hyperbolic plasmons can be tuned with the number of ReS2 layers. However, we note that the significantly large imaginary part of the macroscopic dielectric response in all layered variants of ReS2 can result in substantial losses for the hyperbolic plasmons, as in the case with other known hyperbolic materials, with the exception of MoOCl2. We also note that ReS2 hosts ultraviolet hyperbolic plasmons while ZrSiSe, WTe2, and CuS nanocrystals host infrared plasmons, providing a novel platform for optoelectronics in the ultraviolet range. Full article
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16 pages, 1799 KiB  
Article
Skyrmion Crystal in Bilinear–Biquadratic–Bicubic Model on a Centrosymmetric Triangular Lattice
by Satoru Hayami
Condens. Matter 2025, 10(3), 39; https://doi.org/10.3390/condmat10030039 - 18 Jul 2025
Viewed by 444
Abstract
We numerically investigate the effect of multi-spin interactions on the stability of skyrmion crystals and other multiple-Q magnetic states, with a particular emphasis on the momentum-resolved bicubic interaction. By performing simulated annealing for an effective spin model that incorporates bilinear, biquadratic, and [...] Read more.
We numerically investigate the effect of multi-spin interactions on the stability of skyrmion crystals and other multiple-Q magnetic states, with a particular emphasis on the momentum-resolved bicubic interaction. By performing simulated annealing for an effective spin model that incorporates bilinear, biquadratic, and bicubic interactions on a two-dimensional triangular lattice, we construct the corresponding low-temperature phase diagram. Our results reveal that a positive bicubic interaction stabilizes a skyrmion crystal with a skyrmion number of two, whereas a negative bicubic interaction favors a single-Q spiral state. Moreover, we demonstrate that the stability region of the field-induced skyrmion crystal with the skyrmion number of one is largely enlarged in the presence of a positive bicubic interaction. Full article
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24 pages, 7332 KiB  
Article
High-Performance Natural Dye-Sensitized Solar Cells Employing a New Semiconductor: Gd2Ru2O7 Pyrochlore Oxide
by Assohoun F. Kraidy, Abé S. Yapi, Joseph K. Datte, Michel Voue, Mimoun El Marssi, Anthony Ferri and Yaovi Gagou
Condens. Matter 2025, 10(3), 38; https://doi.org/10.3390/condmat10030038 - 14 Jul 2025
Viewed by 781
Abstract
We investigated a novel natural dye-sensitized solar cell (DSSC) utilizing gadolinium ruthenate pyrochlore oxide Gd2Ru2O7 (GRO) as a photoanode and compared its performance to the TiO2-Gd2Ru2O7 (TGRO) combined-layer configuration. The films [...] Read more.
We investigated a novel natural dye-sensitized solar cell (DSSC) utilizing gadolinium ruthenate pyrochlore oxide Gd2Ru2O7 (GRO) as a photoanode and compared its performance to the TiO2-Gd2Ru2O7 (TGRO) combined-layer configuration. The films were fabricated using the spin-coating technique, resulting in spherical grains with an estimated mean diameter of 0.2 µm, as observed via scanning electron microscopy (SEM). This innovative photoactive gadolinium ruthenate pyrochlore oxide demonstrated strong absorption in the visible range and excellent dye adhesion after just one hour of exposure to natural dye. X-ray diffraction confirmed the presence of the pyrochlore phase, where Raman spectroscopy identified various vibration modes characteristic of the pyrochlore structure. Incorporating Gd2Ru2O7 as the photoanode significantly enhanced the overall efficiency of the DSSCs. The device configuration FTO/compact-layer/Gd2Ru2O7/Hibiscus-sabdariffa/electrolyte(I/I3)/Pt achieved a high efficiency of 9.65%, an open-circuit voltage (Voc) of approximately 3.82 V, and a current density of 4.35 mA/cm2 for an active surface area of 0.38 cm2. A mesoporous TiO2-based DSSC was fabricated under the same conditions for comparison. Using impedance spectroscopy and cyclic voltammetry measurements, we provided evidence of the mechanism of conductivity and the charge carrier’s contribution or defect contributions in the DSSC cells to explain the obtained Voc value. Through cyclic voltammetry measurements, we highlight the redox activities of hibiscus dye and electrolyte (I/I3), which confirmed electrochemical processes in addition to a photovoltaic response. The high and unusual obtained Voc value was also attributed to the presence in the photoanode of active dipoles, the layer thickness, dye concentration, and the nature of the electrolyte. Full article
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5 pages, 197 KiB  
Communication
Nevanlinna Analytical Continuation of the Central Charge in 2D Conformal Field Theory
by Bernardo Barbiellini
Condens. Matter 2025, 10(3), 37; https://doi.org/10.3390/condmat10030037 - 8 Jul 2025
Viewed by 324
Abstract
We present an analytic continuation of the central charge c in two-dimensional conformal field theory (2D CFT), modeled as a Nevanlinna function—an analytic map from the upper half-plane to itself. Motivated by the structure of vacuum energies arising from the quantization of spin- [...] Read more.
We present an analytic continuation of the central charge c in two-dimensional conformal field theory (2D CFT), modeled as a Nevanlinna function—an analytic map from the upper half-plane to itself. Motivated by the structure of vacuum energies arising from the quantization of spin-j conformal fields on the circle, we derive a discrete spectrum of central charges c(j)=1+6j(j+1) and extend it continuously via c(z)=1+6z. The Möbius-inverted form f(z)=16/z satisfies the conditions of a Nevanlinna function, providing a physically consistent analytic structure that captures both the unitarity of minimal models (c<1) and the continuous spectrum for c1. This unified framework highlights the connection between spectral theory, analyticity, and conformal symmetry in quantum field theory. Full article
18 pages, 1546 KiB  
Article
Ultrasound-Assisted Synthesis for the Control of Silver Nanoparticle Size: A Preliminary Study on the Influence of Pressure and pH
by Paula Riascos, Daniel Llamosa, Jahaziel Amaya and Hansen Murcia
Condens. Matter 2025, 10(3), 36; https://doi.org/10.3390/condmat10030036 - 7 Jul 2025
Viewed by 639
Abstract
The use of plasmonic nanoparticles for biosensor technology is dependent on nanoparticle size and morphology. This study determined the effect of pH and pressure on synthesizing silver nanoparticle size. In Method 1, a mixture of NaBH4 and sodium citrate was added to [...] Read more.
The use of plasmonic nanoparticles for biosensor technology is dependent on nanoparticle size and morphology. This study determined the effect of pH and pressure on synthesizing silver nanoparticle size. In Method 1, a mixture of NaBH4 and sodium citrate was added to a solution of AgNO3 monodispersed by ultrasound energy. In Method 2, the reducer was added to the precursor–dispersant mixture solution. The effect of pH was evaluated by using buffer solutions at pH 4.0, pH 7.0, and pH 10.0 and water as control. To determine the effect of pressure, AgNPs were subjected to 0, 4, and 23 h to 1.75 MPa at 200 °C. AgNPs produced with Method 1 showed a more symmetric SPR and a smaller nanoparticle diameter (±6 nm). The SPR with Method 1 at pH 10.0 produced a higher UV peak with a shift around 20 nm. In the case of the pressure treatment, a shift of approximately 20 nm was observed at all time conditions studied, and a higher AgNP diameter was found in contrast to Method 1. Finally, EDX and Raman analysis confirm the presence of AgNPs and a mild oxidation of these. These results suggest that alkalinity and pressure can affect the diameter of AgNPs. Full article
(This article belongs to the Section Physics of Materials)
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