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Article

A Modified Acrylic Binder Used for the Graphite Negative Electrode in LithiumIon Batteries

Shaanxi Key Laboratory of Energy Chemical Process Intensification, School of Chemical Engineering and Technology, Xi’an Jiaotong University, No. 28, Xianning West Road, Xi’an 710049, China
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Batteries 2025, 11(5), 190; https://doi.org/10.3390/batteries11050190
Submission received: 25 December 2024 / Revised: 28 April 2025 / Accepted: 1 May 2025 / Published: 13 May 2025
(This article belongs to the Special Issue Functional Binders and Additives for Rechargeable Batteries)

Abstract

The water-based binder has the advantages of non-toxic, non-flammable, small odor, and no pollution to the environment. However, there are problems such as low bond strength and poor battery cycle life of commonly used binders on the market. In this paper, the acrylic binder is modified. In addition, acrylic acid/methacrylic acid, acrylonitrile, and octadecyl acrylate/octadecyl methacrylate are copolymerized at high temperature, and a new binder for graphite anode is successfully developed. The binder can significantly improve the affinity between the graphite anode and the electrolyte and the integrity of the graphite particles during the cycle, so that the battery has better electrochemical performance. During the charge and discharge cycle of 1 C, the graphite anode coated with PAANa as a binder was able to cycle 360 cycles and remain stable, which is far better than the 192 cycles of the commercial binder LA133. It is proved that the experimental formula has a certain commercial application prospect.
Keywords: binder; lithium metal batteries; graphite binder; lithium metal batteries; graphite

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MDPI and ACS Style

Feng, L.; Chen, W.; Hai, F.; Gao, X.; Ban, Y.; Xue, W.; Yan, W.; Yang, Y.; Li, M. A Modified Acrylic Binder Used for the Graphite Negative Electrode in LithiumIon Batteries. Batteries 2025, 11, 190. https://doi.org/10.3390/batteries11050190

AMA Style

Feng L, Chen W, Hai F, Gao X, Ban Y, Xue W, Yan W, Yang Y, Li M. A Modified Acrylic Binder Used for the Graphite Negative Electrode in LithiumIon Batteries. Batteries. 2025; 11(5):190. https://doi.org/10.3390/batteries11050190

Chicago/Turabian Style

Feng, Lianxiang, Wenting Chen, Feng Hai, Xin Gao, Yuyu Ban, Weicheng Xue, Wentao Yan, Yunxiao Yang, and Mingtao Li. 2025. "A Modified Acrylic Binder Used for the Graphite Negative Electrode in LithiumIon Batteries" Batteries 11, no. 5: 190. https://doi.org/10.3390/batteries11050190

APA Style

Feng, L., Chen, W., Hai, F., Gao, X., Ban, Y., Xue, W., Yan, W., Yang, Y., & Li, M. (2025). A Modified Acrylic Binder Used for the Graphite Negative Electrode in LithiumIon Batteries. Batteries, 11(5), 190. https://doi.org/10.3390/batteries11050190

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