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Magnetochemistry, Volume 11, Issue 9

September 2025 - 12 articles

Cover Story: Using a sulfur-containing ligand, a series of Ln9 clusters were synthesized with a unique asymmetric hourglass-like architecture: the upper and lower bases are bridged by μ4-OH and μ3-OH, respectivelyan unreported bridge mode in known Ln9 clusters. Magnetic analysis reveals Gd9 has a significant magnetocaloric effect (MCE), with maximum entropy change (−ΔSm) reaching a competitive value of 34.41 J kg−1 K−1 at 2 K and ΔH = 7 Tdespite having the highest molar mass among all reported Gd9 with MCE. Meanwhile, Dy9 exhibits distinct single-molecule magnet (SMM) characteristics. This work highlights the sulfur-containing ligand’s critical role in cluster structure and exchange interactions, offering new insights into high-performance MCE material synthesis and magneto-structural relationships. View this paper
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Articles (12)

  • Article
  • Open Access
2 Citations
1,028 Views
16 Pages

Parahydrogen-Based Hyperpolarization for the Masses at Millitesla Fields

  • Garrett L. Wibbels,
  • Clementinah Oladun,
  • Tanner Y. O’Hara,
  • Isaiah Adelabu,
  • Joshua E. Robinson,
  • Firoz Ahmed,
  • Zachary T. Bender,
  • Anna Samoilenko,
  • Joseph Gyesi and
  • Larisa M. Kovtunova
  • + 6 authors

Hyperpolarization (HP) techniques, such as Parahydrogen-Induced Polarization (PHIP), Signal Amplification by Reversible Exchange (SABRE), and dissolution Dynamic Nuclear Polarization (d-DNP), significantly enhance the sensitivity of nuclear magnetic...

  • Article
  • Open Access
903 Views
15 Pages

We developed a solvent-suppressed 1H nuclear magnetic resonance (NMR) method for the quantitative analysis of the components of rotigotine prolonged-release microspheres prepared for injection. Dimethyl terephthalate was used as an internal standard...

  • Article
  • Open Access
1,030 Views
12 Pages

The microstructure and magnetic properties of rare-earth-free, melt-spun Co74Zr16Mo4Si3B3 alloys were investigated to enhance their hard magnetic response and elucidate their coercivity mechanism. The alloys exhibit a polycrystalline microstructure c...

  • Review
  • Open Access
1,071 Views
26 Pages

The magnetic properties of molecular nanomagnets can be finely modulated by light, which provides great potential in optical switches, smart sensors, and data storage devices. Light-induced spin transition, structure changes, and radical formation co...

  • Editorial
  • Open Access
1 Citations
809 Views
5 Pages

The application of magnetism in water treatment processes has enhanced efficiency across various stages, including coagulation, flocculation, sedimentation, and filtration, representing a field with significant potential [...]

  • Article
  • Open Access
887 Views
12 Pages

A Dy2 Complex Constructed by TCNQ·− Radical Anions with Slow Magnetic Relaxation Behavior

  • Xirong Wang,
  • Shijia Qin,
  • Xiulan Li,
  • Wenjing Zuo,
  • Qinglun Wang,
  • Licun Li,
  • Yue Ma,
  • Jinkui Tang and
  • Bin Zhao

A centrosymmetric dinuclear complex, [Dy2(H2dapp)2(μ-OH)2(H2O)2]·4TCNQ·2CH3OH, was synthesized using the TCNQ·− radical anion (TCNQ = 7,7,8,8-tetracyanoquino-dimethane) and pentadentate nitrogen-containing Schiff base li...

  • Article
  • Open Access
792 Views
13 Pages

We investigated the effects of chemical and physical changes on the interplay between the Néel and Brown superspin relaxation mechanisms in ferrofluids containing 18 nm-diameter Co0.2Fe2.8O4 magnetic nanoparticles. We attempted to tune the fer...

  • Article
  • Open Access
901 Views
13 Pages

A Dinuclear Dysprosium(III) Single Molecule Magnet of Benzo[h]quinolin-10-ol

  • Limin Zhou,
  • Hongling Lv,
  • Yuning Liang,
  • Dongcheng Liu,
  • Zaiheng Yao,
  • Shuchang Luo and
  • Zilu Chen

To develop single molecule magnets, a dinuclear complex [Dy2(HOBQ)4Cl6] (1) was prepared from the reaction of DyCl3 with benzo[h]quinolin-10-ol (HOBQ). Each Dy(III) ion shows a compressed octahedral geometry and the two Dy(III) ions in 1 are bridged...

  • Article
  • Open Access
1 Citations
648 Views
18 Pages

Mössbauer Research and Magnetic Properties of Dispersed Microspheres from High-Calcium Fly Ash

  • Elena V. Fomenko,
  • Yuriy V. Knyazev,
  • Galina V. Akimochkina,
  • Sergey V. Semenov,
  • Vladimir V. Yumashev,
  • Leonid A. Solovyov,
  • Natalia N. Anshits,
  • Oleg A. Bayukov and
  • Alexander G. Anshits

High-calcium fly ash (HCFA), produced from the lignite combustion, has emerged as a global concern due to its fine particle size and adverse environmental impacts. This study presents the characteristics of dispersed microspheres from HCFA obtained u...

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Magnetochemistry - ISSN 2312-7481