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Magnetochemistry, Volume 10, Issue 11

November 2024 - 11 articles

Cover Story: The strong magnetic interaction in a "sweet couple" of a radical coordinated to a metal ion is attractive for the design of molecular magnetic materials. The octahedral cobalt(II) complexes of nitroxides are non-trivial in terms of modelling their magnetic behavior due to the unquenched orbital momentum of Co2+. For the dimer, {Co-bisnitroxide-Co}, the experimental magnetic study indicates a strong antiferromagnetic coupling between the metal ion and the diradical, as well as between the spins of the latter, thus forming a spin-frustrated system. An original theoretical approach has been developed to determine the range of possible values for both types of exchange integrals. The ab initio computation results for the χT(T) and M(H) dependences are in good agreement with the experimental data. View this paper
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Articles (11)

  • Article
  • Open Access
1 Citations
2,188 Views
16 Pages

Cellular therapies exhibit immense potential in treating complex diseases with sustained responses. The manufacture of cell therapies involves the purification and engineering of specific cells from a donor or patient to achieve a therapeutic respons...

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Magnetochemistry - ISSN 2312-7481