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Manganese Fluorene Phosphonates: Formation of Isolated Chains

Normandie Univ, ENSICAEN, UNICAEN, CNRS, CRISMAT, 14000 Caen, France
Normandie Univ, ENSICAEN, UNICAEN, CNRS, LCMT, 6 Bd du Maréchal Juin, 14050 Caen CEDEX, France
CEMCA UMR CNRS 6521, Université de Brest, IBSAM, 6 Avenue Victor Le Gorgeu, 29238 Brest, France
IPCMS, UMR Unistra-CNRS 7504, 23 rue du Loess, BP 43, 67034 Strasbourg CEDEX 2, France
Authors to whom correspondence should be addressed.
Inorganics 2018, 6(3), 92;
Received: 17 July 2018 / Revised: 31 August 2018 / Accepted: 3 September 2018 / Published: 5 September 2018
(This article belongs to the Special Issue Metal Phosphates and Phosphonates)
9,9-dimethylfluorenyl-2-phosphonic acid 1 was reacted with manganese nitrate tetrahydrate to produce under hydrothermal conditions the crystalline manganese phosphonate Mn(H2O)2[O2(OH)PC15H13]2·2H2O which crystallize in the P21/c space group. This compound is a rare example of Mn-phosphonate material featuring isolated chains. The interactions between these chains containing the 9,9-dimethylfluorenyl moieties, result from Van der Waals interactions involving the fluorene ligands and C···H–C hydrogen bonds as revealed by Hirshfeld Surfaces. This material features antiferromagnetic exchange interactions as revealed by the magnetic susceptibility as a function of the temperature. View Full-Text
Keywords: metal-phosphonate; fluorene; magnetism; hybrid material metal-phosphonate; fluorene; magnetism; hybrid material
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Bloyet, C.; Rueff, J.-M.; Caignaert, V.; Raveau, B.; Lohier, J.-F.; Roger, M.; Rogez, G.; Jaffrès, P.-A. Manganese Fluorene Phosphonates: Formation of Isolated Chains. Inorganics 2018, 6, 92.

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