Manganese Fluorene Phosphonates: Formation of Isolated Chains
Abstract9,9-dimethylfluorenyl-2-phosphonic acid 1 was reacted with manganese nitrate tetrahydrate to produce under hydrothermal conditions the crystalline manganese phosphonate Mn(H2O)2[O2(OH)PC15H13]2·2H2O which crystallize in the P21/c space group. This compound is a rare example of Mn-phosphonate material featuring isolated chains. The interactions between these chains containing the 9,9-dimethylfluorenyl moieties, result from Van der Waals interactions involving the fluorene ligands and C···H–C hydrogen bonds as revealed by Hirshfeld Surfaces. This material features antiferromagnetic exchange interactions as revealed by the magnetic susceptibility as a function of the temperature. View Full-Text
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Bloyet, C.; Rueff, J.-M.; Caignaert, V.; Raveau, B.; Lohier, J.-F.; Roger, M.; Rogez, G.; Jaffrès, P.-A. Manganese Fluorene Phosphonates: Formation of Isolated Chains. Inorganics 2018, 6, 92.
Bloyet C, Rueff J-M, Caignaert V, Raveau B, Lohier J-F, Roger M, Rogez G, Jaffrès P-A. Manganese Fluorene Phosphonates: Formation of Isolated Chains. Inorganics. 2018; 6(3):92.Chicago/Turabian Style
Bloyet, Clarisse; Rueff, Jean-Michel; Caignaert, Vincent; Raveau, Bernard; Lohier, Jean-François; Roger, Mélissa; Rogez, Guillaume; Jaffrès, Paul-Alain. 2018. "Manganese Fluorene Phosphonates: Formation of Isolated Chains." Inorganics 6, no. 3: 92.
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