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Inorganics 2018, 6(3), 92; https://doi.org/10.3390/inorganics6030092

Manganese Fluorene Phosphonates: Formation of Isolated Chains

1
Normandie Univ, ENSICAEN, UNICAEN, CNRS, CRISMAT, 14000 Caen, France
2
Normandie Univ, ENSICAEN, UNICAEN, CNRS, LCMT, 6 Bd du Maréchal Juin, 14050 Caen CEDEX, France
3
CEMCA UMR CNRS 6521, Université de Brest, IBSAM, 6 Avenue Victor Le Gorgeu, 29238 Brest, France
4
IPCMS, UMR Unistra-CNRS 7504, 23 rue du Loess, BP 43, 67034 Strasbourg CEDEX 2, France
*
Authors to whom correspondence should be addressed.
Received: 17 July 2018 / Revised: 31 August 2018 / Accepted: 3 September 2018 / Published: 5 September 2018
(This article belongs to the Special Issue Metal Phosphates and Phosphonates)
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Abstract

9,9-dimethylfluorenyl-2-phosphonic acid 1 was reacted with manganese nitrate tetrahydrate to produce under hydrothermal conditions the crystalline manganese phosphonate Mn(H2O)2[O2(OH)PC15H13]2·2H2O which crystallize in the P21/c space group. This compound is a rare example of Mn-phosphonate material featuring isolated chains. The interactions between these chains containing the 9,9-dimethylfluorenyl moieties, result from Van der Waals interactions involving the fluorene ligands and C···H–C hydrogen bonds as revealed by Hirshfeld Surfaces. This material features antiferromagnetic exchange interactions as revealed by the magnetic susceptibility as a function of the temperature. View Full-Text
Keywords: metal-phosphonate; fluorene; magnetism; hybrid material metal-phosphonate; fluorene; magnetism; hybrid material
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).

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Bloyet, C.; Rueff, J.-M.; Caignaert, V.; Raveau, B.; Lohier, J.-F.; Roger, M.; Rogez, G.; Jaffrès, P.-A. Manganese Fluorene Phosphonates: Formation of Isolated Chains. Inorganics 2018, 6, 92.

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