α- and β-Phase Ni-Mg Hydroxide for High Performance Hybrid Supercapacitors
Abstract
:1. Introduction
2. Experimental Section
2.1. Preparation of Samples
2.2. Characterization of Samples
2.3. Electrochemical Measurements
3. Results and Discussion
3.1. Characterization Results of NiMg-OH
3.2. Electrochemical Performance of 2D NiMg-OH
3.3. Asymmetric Supercapacitor
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Conflicts of Interest
References
- Miller, J.R.; Simon, P. Materials science-electrochemical capacitors for energy management. Science 2008, 321, 651–652. [Google Scholar] [CrossRef] [PubMed]
- Li, M.; Yang, W.; Huang, Y.; Yu, Y. Hierarchical mesoporous Co3O4@ZnCo2O4 hybrid nanowire arrays supported on Ni foam for high-performance asymmetric supercapacitors. Sci. China Mater. 2018, 61, 1167–1176. [Google Scholar] [CrossRef]
- Xu, J.; Sun, Y.; Lu, M.; Wang, L.; Zhang, J.; Tao, E.; Qian, J.; Liu, X. Fabrication of the porous MnCo2O4 nanorod arrays on Ni foam as an advanced electrode for asymmetric supercapacitors. Acta Mater. 2018, 152, 162–174. [Google Scholar] [CrossRef]
- Gregoire, B.; Ruby, C.; Carteret, C. Hydrolysis of mixed Ni2+-Fe3+ and Mg2+-Fe3+ solutions and mechanism of formation of layered double hydroxides. Dalton. Trans. 2013, 42, 15687–15698. [Google Scholar] [CrossRef]
- Xu, J.; Zhang, H.; Xu, P.; Wang, R.; Tong, Y.; Lu, Q.; Gao, F. In situ construction of hierarchical Co/MnO@graphite carbon composites for highly supercapacitive and OER electrocatalytic performances. Nanoscale 2018, 10, 13702–13712. [Google Scholar] [CrossRef]
- Li, M.; Yang, W.; Li, J.; Feng, M.; Li, W.; Li, H.; Yu, Y. Porous layered stacked MnCo2O4 cubes with enhanced electrochemical capacitive performance. Nanoscale 2018, 10, 2218–2225. [Google Scholar] [CrossRef]
- Du, K.; Wei, G.; Zhao, F.; An, C.; Wang, H.; Li, J.; An, C. Urchin-like FeOOH hollow microspheres decorated with MnO2 for enhanced supercapacitor performance. Sci. China Mater. 2017, 61, 48–56. [Google Scholar] [CrossRef]
- Du, W.; Liu, R.; Jiang, Y.; Lu, Q.; Fan, Y.; Gao, F. Facile synthesis of hollow Co3O4 boxes for high capacity supercapacitor. J. Power Sources 2013, 227, 101–105. [Google Scholar] [CrossRef]
- Xie, M.J.; Xu, Z.C.; Duan, S.Y.; Tian, Z.F.; Zhang, Y.; Xiang, K.; Lin, M.; Guo, X.F.; Ding, W.P. Facile growth of homogeneous Ni(OH)2 coating on carbon nanosheets for high-performance asymmetric supercapacitor applications. Nano Res. 2018, 11, 216–224. [Google Scholar] [CrossRef]
- Yan, J.; Fan, Z.J.; Sun, W.; Ning, G.Q.; Wei, T.; Zhang, Q.; Zhang, R.F.; Zhi, L.J.; Wei, F. Advanced asymmetric supercapacitors based on Ni(OH)2/graphene and porous graphene electrodes with high energy density. Adv. Funct. Mater. 2012, 22, 2632–2641. [Google Scholar] [CrossRef]
- Liu, F.; Chu, X.; Zhang, H.; Zhang, B.; Su, H.; Jin, L.; Wang, Z.; Huang, H.; Yang, W. Synthesis of self-assembly 3D porous Ni(OH)2 with high capacitance for hybrid supercapacitors. Electrochim. Acta 2018, 269, 102–110. [Google Scholar] [CrossRef]
- Wang, D.; Guan, B.; Li, Y.; Li, D.; Xu, Z.; Hu, Y.; Wang, Y.; Zhang, H. Morphology-controlled synthesis of hierarchical mesoporous α-Ni(OH)2 microspheres for high-performance asymmetric supercapacitors. J. Alloys Comp. 2018, 737, 238–247. [Google Scholar] [CrossRef]
- Li, M.; Lei, W.; Yu, Y.; Yang, W.; Li, J.; Chen, D.; Xu, S.; Feng, M.; Li, H. High-performance asymmetric supercapacitors based on monodisperse MnO nanocrystals with high energy densities. Nanoscale 2018, 10, 15926–15931. [Google Scholar] [CrossRef] [PubMed]
- Xu, J.; Sun, Y.; Lu, M.; Wang, L.; Zhang, J.; Liu, X. One-step electrodeposition fabrication of Ni3S2 nanosheet arrays on Ni foam as an advanced electrode for asymmetric supercapacitors. Sci. China Mater. 2018, 62, 699–710. [Google Scholar] [CrossRef]
- Cui, H.; Xue, J.; Wang, M. Synthesis of high electrochemical performance Ni(OH)2 nanosheets through a solvent-free reaction for application in supercapacitor. Adv. Powder Techol. 2015, 26, 434–438. [Google Scholar] [CrossRef]
- Jiang, L.; Qiu, Y.; Luo, P.; Yu, Y. Nickel hydroxide-impregnated and-coated carbon nanotubes using an easily manipulated solvothermal route for supercapacitors. Ceram. Int. 2016, 42, 11634–11639. [Google Scholar] [CrossRef]
- Ke, X.; Zhang, Z.; Cheng, Y.; Liang, Y.; Tan, Z.; Liu, J.; Liu, L.; Shi, Z.; Guo, Z. Ni(OH)2 nanoflakes supported on 3D hierarchically nanoporous gold/Ni foam as superior electrodes for supercapacitors. Sci. China Mater. 2017, 61, 353–362. [Google Scholar] [CrossRef]
- Lee, J.W.; Ko, J.M.; Kim, J.-D. Hierarchical microspheres based on α-Ni(OH)2 nanosheets intercalated with different anions: Synthesis, anion exchange, and effect of intercalated anions on electrochemical capacitance. J. Phys. Chem. C 2011, 115, 19445–19454. [Google Scholar] [CrossRef]
- Dai, J.; Li, S.F.Y.; Xiao, T.D.; Wang, D.M.; Reisner, D.E. Structural stability of aluminum stabilized alpha nickel hydroxide as a positive electrode material for alkaline secondary batteries. J. Power Sources 2000, 89, 40–45. [Google Scholar] [CrossRef]
- Nunes, C.V.; Danczuk, M.; Bortoti, A.A.; Gonçalves, J.M.; Araki, K.; Anaissi, F.J. Unexpected effect of drying method on the microstructure and electrocatalytic properties of bentonite/alpha-nickel hydroxide nanocomposite. J. Power Sources 2015, 297, 408–412. [Google Scholar] [CrossRef]
- Xie, M.; Duan, S.; Shen, Y.; Fang, K.; Wang, Y.; Lin, M.; Guo, X. In-situ-grown Mg(OH)2-derived hybrid α-Ni(OH)2 for highly stable supercapacitor. ACS Energy Lett. 2016, 1, 814–819. [Google Scholar] [CrossRef]
- Yuan, S.; Wang, X.; Lu, C.; Chen, C. The fine control of porous pompon-like Mg-incorporated α-Ni(OH)2 for enhanced supercapacities. Funct. Mater. Lett. 2016, 9, 1650057. [Google Scholar] [CrossRef]
- Zhao, Y.L.; Wang, J.M.; Chen, H.; Pan, T.; Zhang, J.Q.; Cao, C.N. Al-substituted α-nickel hydroxide prepared by homogeneous precipitation method with urea. Int. J. Hydrogen Energy 2004, 29, 889–896. [Google Scholar] [CrossRef]
- Huang, J.; Lei, T.; Wei, X.; Liu, X.; Liu, T.; Cao, D.; Yin, J.; Wang, G. Effect of Al-doped β-Ni(OH)2 nanosheets on electrochemical behaviors for high performance supercapacitor application. J. Power Sources 2013, 232, 370–375. [Google Scholar] [CrossRef]
- Shangguan, E.; Li, J.; Guo, D.; Guo, L.; Nie, M.; Chang, Z.; Yuan, X.-Z.; Wang, H. A comparative study of structural and electrochemical properties of high-density aluminum substituted α-nickel hydroxide containing different interlayer anions. J. Power Sources 2015, 282, 158–168. [Google Scholar] [CrossRef]
- Liu, H.; Yu, T.; Su, D.; Tang, Z.; Zhang, J.; Liu, Y.; Yuan, A.; Kong, Q. Ultrathin Ni-Al layered double hydroxide nanosheets with enhanced supercapacitor performance. Ceram. Int. 2017, 43, 14395–14400. [Google Scholar] [CrossRef]
- Xia, Q.X.; San Hui, K.; Hui, K.N.; Kim, S.D.; Lim, J.H.; Choi, S.Y.; Zhang, L.J.; Mane, R.S.; Yun, J.M.; Kim, K.H. Facile synthesis of manganese carbonate quantum dots/Ni(HCO3)2–MnCO3 composites as advanced cathode materials for high energy density asymmetric supercapacitors. J. Mater. Chem. A 2015, 3, 22102–22117. [Google Scholar] [CrossRef]
- Liang, D.; Wu, S.; Liu, J.; Tian, Z.; Liang, C. Co-doped Ni hydroxide and oxide nanosheet networks: Laser-assisted synthesis, effective doping, and ultrahigh pseudocapacitor performance. J. Mater. Chem. A 2016, 4, 10609–10617. [Google Scholar] [CrossRef]
- Wang, Y.; Yin, Z.; Wang, Z.; Li, X.; Guo, H.; Wang, J.; Zhang, D. Facile construction of Co(OH)2@Ni(OH)2 core-shell nanosheets on nickel foam as three dimensional free-standing electrode for supercapacitors. Electrochim. Acta 2019, 293, 40–46. [Google Scholar] [CrossRef]
- Jin, H.; Yuan, D.; Zhu, S.; Zhu, X.; Zhu, J. Ni-Co layered double hydroxide on carbon nanorods and graphene nanoribbons derived from MOFs for supercapacitors. Dalton. Trans. 2018, 47, 8706–8715. [Google Scholar] [CrossRef]
- Le, K.; Wang, Z.; Wang, F.; Wang, Q.; Shao, Q.; Murugadoss, V.; Wu, S.; Liu, W.; Liu, J.; Gao, Q.; et al. Sandwich-like NiCo layered double hydroxide/reduced graphene oxide nanocomposite cathodes for high energy density asymmetric supercapacitors. Dalton. Trans. 2019, 48, 5193–5202. [Google Scholar] [CrossRef] [PubMed]
- Wang, L.; Song, C.; Shi, Y.; Dang, L.; Jin, Y.; Jiang, H.; Lu, Q.; Gao, F. Generalized low-temperature fabrication of scalable multi-type two-dimensional nanosheets with a green soft template. Chem. Eur. J 2016, 22, 5575–5582. [Google Scholar] [CrossRef] [PubMed]
- You, Z.; Shen, K.; Wu, Z.; Wang, X.; Kong, X. Electrodeposition of Zn-doped α-nickel hydroxide with flower-like nanostructure for supercapacitors. Appl. Surf. Sci. 2012, 258, 8117–8123. [Google Scholar] [CrossRef]
- Zhu, Y.; Huang, C.; Li, C.; Fan, M.; Shu, K.; Chen, H.C. Strong synergetic electrochemistry between transition metals of α phase Ni-Co-Mn hydroxide contributed superior performance for hybrid supercapacitors. J. Power Sources 2019, 412, 559–567. [Google Scholar] [CrossRef]
- Liang, T.; Xuan, H.; Xu, Y.; Gao, J.; Han, X.; Yang, J.; Han, P.; Wang, D.; Du, Y. Rational assembly of CoAl-layered double hydroxide on reduced graphene oxide with enhanced electrochemical performance for energy storage. ChemElectroChem 2018, 5, 2424–2434. [Google Scholar] [CrossRef]
- Xiao, Y.; Su, D.; Wang, X.; Wu, S.; Zhou, L.; Fang, S.; Li, F. Layered double hydroxides with larger interlayer distance for enhanced pseudocapacitance. Sci. China Mater. 2017, 61, 263–272. [Google Scholar] [CrossRef] [Green Version]
- Hall, D.S.; Lockwood, D.J.; Poirier, S.; Bock, C.; MacDougall, B.R. Raman and infrared spectroscopy of alpha and beta phases of thin nickel hydroxide films electrochemically formed on nickel. J. Phys. Chem. A 2012, 116, 6771–6784. [Google Scholar] [CrossRef] [Green Version]
- Zhang, G.; Sun, S.; Li, R.; Sun, X. New insight into the conventional replacement reaction for the large-scale synthesis of various metal nanostructures and their formation mechanism. Chem. Eur. J 2010, 16, 10630–10634. [Google Scholar] [CrossRef]
- Huang, C.; Song, X.; Qin, Y.; Xu, B.; Chen, H.C. Cation exchange reaction derived amorphous bimetal hydroxides as advanced battery materials for hybrid supercapacitors. J. Mater. Chem. A 2018, 6, 21047–21055. [Google Scholar] [CrossRef]
- Miao, C.; Zhu, Y.; Zhao, T.; Jian, X.; Li, W. Synthesis and electrochemical performance of mixed phase α/β nickel hydroxide by codoping with ca2+ and PO4 3−. Ionics 2015, 21, 3201–3208. [Google Scholar] [CrossRef]
- Aghazadeh, M.; Ghaemi, M.; Sabour, B.; Dalvand, S. Electrochemical preparation of α-Ni(OH)2 ultrafine nanoparticles for high-performance supercapacitors. J. Solid State Electr. 2014, 18, 1569–1584. [Google Scholar] [CrossRef]
- Gao, M.; Sheng, W.; Zhuang, Z.; Fang, Q.; Gu, S.; Jiang, J.; Yan, Y. Efficient water oxidation using nanostructured α-nickel-hydroxide as an electrocatalyst. J. Am. Chem. Soc. 2014, 136, 7077–7084. [Google Scholar] [CrossRef] [PubMed]
- Morishita, M.; Kakeya, T.; Ochiai, S.; Ozaki, T.; Kawabe, Y.; Watada, M.; Sakai, T. Structural analysis by synchrotron X-ray diffraction, X-ray absorption fine structure and transmission electron microscopy for aluminum-substituted α-type nickel hydroxide electrode. J. Power Sources 2009, 193, 871–877. [Google Scholar] [CrossRef]
- Cheng, M.Y.; Hwang, B.J. Control of uniform nanostructured α-Ni(OH)2 with self-assembly sodium dodecyl sulfate templates. J. Colloid Interf. Sci. 2009, 337, 265–271. [Google Scholar] [CrossRef]
- Aksoy, S.; Caglar, Y.; Ilican, S.; Caglar, M. Sol–gel derived Li–Mg Co-doped ZnO films: Preparation and characterization via XRD, XPS, FESEM. J. Alloys Comp. 2012, 512, 171–178. [Google Scholar] [CrossRef]
- Du, H.; Jiao, L.; Cao, K.; Wang, Y.; Yuan, H. Polyol-mediated synthesis of mesoporous α-Ni(OH)2 with enhanced supercapacitance. ACS Appl. Mater. Interfaces 2013, 5, 6643–6648. [Google Scholar] [CrossRef]
- Du, H.; Wang, Y.; Yuan, H.; Jiao, L. Facile synthesis and high capacitive performance of 3D hierarchical Ni(OH)2 microspheres. Electrochim. Acta 2016, 196, 84–91. [Google Scholar] [CrossRef]
- Yue, X.; Pan, J.; Sun, Y.; Wang, Z. Synthesis and electrochemical properties of nano–micro spherical β-Ni(OH)2 with super high charge–discharge speed. Ind. Eng. Chem. Res. 2012, 51, 8358–8365. [Google Scholar] [CrossRef]
- Dong, C.; He, G.; Zheng, W.; Bian, T.; Li, M.; Zhang, D. Study on antibacterial mechanism of Mg(OH)2 nanoparticles. Mater. Lett. 2014, 134, 286–289. [Google Scholar] [CrossRef]
- Bernard, M.C.; Bernard, P.; Keddam, M.; Senyarich, S.; Takenouti, H. Characterisation of new nickel hydroxides during the transformation of α-Ni(OH)2 to β-Ni(OH)2 by ageing. Electrochim. Acta 1996, 41, 91–93. [Google Scholar] [CrossRef]
- Hu, X.; Liu, S.; Li, C.; Huang, J.; Luv, J.; Xu, P.; Liu, J.; You, X. Facile and environmentally friendly synthesis of ultrathin nickel hydroxide nanosheets with excellent supercapacitor performances. Nanoscale 2016, 8, 11797–11802. [Google Scholar] [CrossRef] [PubMed]
- Szytula, A.; Murasik, A.; Balanda, M. Neutron diffraction study of Ni(OH)2. Phys. Status Solidi B 1971, 43, 125–128. [Google Scholar] [CrossRef]
- Bode, H.; Dehmelt, K.; Witte, J. Zur kenntnis der nickelhydroxidelektrode—I. Über das nickel (II)-hydroxidhydrat. Electrochim. Acta 1966, 11, 1079–1087. [Google Scholar] [CrossRef]
- Li, H.B.; Yu, M.H.; Wang, F.X.; Liu, P.; Liang, Y.; Xiao, J.; Wang, C.X.; Tong, Y.X.; Yang, G.W. Amorphous nickel hydroxide nanospheres with ultrahigh capacitance and energy density as electrochemical pseudocapacitor materials. Nat. Commun. 2013, 4, 1894. [Google Scholar] [CrossRef] [Green Version]
- Wang, W.; Zhang, N.; Shi, Z.; Ye, Z.; Gao, Q.; Zhi, M.; Hong, Z. Preparation of Ni-Al layered double hydroxide hollow microspheres for supercapacitor electrode. Chem. Eng. J. 2018, 338, 55–61. [Google Scholar] [CrossRef]
- Tang, Y.; Liu, Y.; Yu, S.; Guo, W.; Mu, S.; Wang, H.; Zhao, Y.; Hou, L.; Fan, Y.; Gao, F. Template-free hydrothermal synthesis of nickel cobalt hydroxide nanoflowers with high performance for asymmetric supercapacitor. Electrochim. Acta 2015, 161, 279–289. [Google Scholar] [CrossRef]
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Yin, J.; Zhou, G.; Gao, X.; Chen, J.; Zhang, L.; Xu, J.; Zhao, P.; Gao, F. α- and β-Phase Ni-Mg Hydroxide for High Performance Hybrid Supercapacitors. Nanomaterials 2019, 9, 1686. https://doi.org/10.3390/nano9121686
Yin J, Zhou G, Gao X, Chen J, Zhang L, Xu J, Zhao P, Gao F. α- and β-Phase Ni-Mg Hydroxide for High Performance Hybrid Supercapacitors. Nanomaterials. 2019; 9(12):1686. https://doi.org/10.3390/nano9121686
Chicago/Turabian StyleYin, Jingzhou, Guolang Zhou, Xiaoliang Gao, Jiaqi Chen, Lili Zhang, Jiaying Xu, Pusu Zhao, and Feng Gao. 2019. "α- and β-Phase Ni-Mg Hydroxide for High Performance Hybrid Supercapacitors" Nanomaterials 9, no. 12: 1686. https://doi.org/10.3390/nano9121686