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Nanomaterials, Volume 7, Issue 7

2017 July - 44 articles

Cover Story: Advancements in plasma-enabled synthesis have led to the development of novel and effective methods to convert low-cost natural waste resources into high quality nanomaterials with a wide range of applications. In this work, we report rapid reforming of sugarcane bagasse, a low-value by-product of the sugarcane industry, into high-quality vertically-oriented graphene nanosheets at a relatively low temperature of 400 °C. We show that thus-fabricated nanostructures have antifouling and antibacterial properties that are similar to (e.g., Escherichia coli) or slightly exceed (e.g., Staphylococcus aureus) those of graphene nanosheets fabricated from high-purity, expensive methane under similar conditions. View the paper
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Articles (44)

  • Article
  • Open Access
78 Citations
9,188 Views
13 Pages

Cinnamon essential oil (CEO) was successfully encapsulated into chitosan (CS) nanoparticles at different loading amounts (1%, 1.5%, 2%, and 2.5% v/v) using oil-in-water (o/w) emulsion and ionic-gelation methods. In order to form active packaging, pol...

  • Communication
  • Open Access
21 Citations
5,758 Views
9 Pages

A Simple and Highly Sensitive Thymine Sensor for Mercury Ion Detection Based on Surface Enhanced Raman Spectroscopy and the Mechanism Study

  • Hao Yang,
  • Sui-Bo Ye,
  • Yu Fu,
  • Weihong Zhang,
  • Fangyan Xie,
  • Li Gong,
  • Ping-Ping Fang,
  • Jian Chen and
  • Yexiang Tong

Mercury ion (Hg2+) is recognized as one of the most toxic metal ions for the environment and for human health. Techniques utilized in the detection of Hg2+ are an important factor. Herein, a simple thymine was successfully employed as the surface enh...

  • Article
  • Open Access
31 Citations
6,525 Views
19 Pages

Optimization of the Silver Nanoparticles PEALD Process on the Surface of 1-D Titania Coatings

  • Aleksandra Radtke,
  • Tomasz Jędrzejewski,
  • Wiesław Kozak,
  • Beata Sadowska,
  • Marzena Więckowska-Szakiel,
  • Ewa Talik,
  • Maarit Mäkelä,
  • Markku Leskelä and
  • Piotr Piszczek

Plasma enhanced atomic layer deposition (PEALD) of silver nanoparticles on the surface of 1-D titania coatings, such as nanotubes (TNT) and nanoneedles (TNN), has been carried out. The formation of TNT and TNN layers enriched with dispersed silver pa...

  • Review
  • Open Access
382 Citations
20,540 Views
17 Pages

Even though cancer treatment has improved over the recent decades, still more specific and effective treatment concepts are mandatory. Surgical removal is not always possible, metastases are challenging and chemo- and radiotherapy can not only have s...

  • Article
  • Open Access
37 Citations
6,788 Views
13 Pages

Nanoemulsions are particularly suitable as a platform in the development of delivery systems. The type of nanoemulsion with a higher stability will offer an advantage in the preparation of a delivery system for lipophilic drugs. Nanoemulsions can be...

  • Article
  • Open Access
60 Citations
11,958 Views
13 Pages

Highly Efficient Near Infrared Photothermal Conversion Properties of Reduced Tungsten Oxide/Polyurethane Nanocomposites

  • Tolesa Fita Chala,
  • Chang-Mou Wu,
  • Min-Hui Chou,
  • Molla Bahiru Gebeyehu and
  • Kuo-Bing Cheng

In this work, novel WO3-x/polyurethane (PU) nanocomposites were prepared by ball milling followed by stirring using a planetary mixer/de-aerator. The effects of phase transformation (WO3 → WO2.8 → WO2.72) and different weight fractions of tungsten ox...

  • Article
  • Open Access
23 Citations
8,086 Views
14 Pages

Plenty of studies have been performed to probe the diverse properties of ZnO nanowires, but only a few have focused on the physical properties of a single nanowire since analyzing the growth mechanism along a single nanowire is difficult. In this stu...

  • Article
  • Open Access
140 Citations
10,688 Views
14 Pages

In this work, the effect of graphene oxide nanosheet (GONS) additives on the properties of cement mortar and ultra-high strength concrete (UHSC) is reported. The resulting GONS-cement composites were easy to prepare and exhibited excellent mechanical...

  • Review
  • Open Access
38 Citations
9,225 Views
32 Pages

Carbon nanotubes (CNTs) possess unique mechanical, physical, electrical and absorbability properties coupled with their nanometer dimensional scale that renders them extremely valuable for applications in many fields including nanotechnology and chro...

  • Article
  • Open Access
15 Citations
6,452 Views
15 Pages

A new series of alkali-based complexes, AM@GenAu (AM = Li, Na, and K), have been theoretically designed and investigated by means of the density functional theory calculations. The geometric structures and electronic properties of the species are sys...

  • Article
  • Open Access
73 Citations
11,787 Views
9 Pages

Yttrium fluoride (YF3) and yttrium oxide (Y2O3) protective coatings prepared using an atmospheric plasma spraying technique were used to investigate the relationship between surface erosion behaviors and their nanoparticle generation under high-densi...

  • Article
  • Open Access
46 Citations
6,474 Views
15 Pages

Nano-Silica Sol-Gel and Carbon Nanotube Coupling Effect on the Performance of Cement-Based Materials

  • Weiwen Li,
  • Weiming Ji,
  • Forood Torabian Isfahani,
  • Yaocheng Wang,
  • Gengying Li,
  • Yi Liu and
  • Feng Xing

Carbon nanotubes (CNTs) have shown promise for improving the mechanical performance of cement composites through crack-bridging and frictional pull-out. The interactive behaviors between CNTs and cement matrix act are crucial in optimizing the reinfo...

  • Article
  • Open Access
86 Citations
10,595 Views
18 Pages

Herein, a new approach was proposed to produce reduced graphene oxide (rGO) from graphene oxide (GO) using various oil palm wastes: oil palm leaves (OPL), palm kernel shells (PKS) and empty fruit bunches (EFB). The effect of heating temperature on th...

  • Article
  • Open Access
17 Citations
4,994 Views
9 Pages

Ion beam irradiation-induced nanoporous structure formation was investigated on GaSb, InSb, and Ge surfaces via controlled point defect creation using a focused ion beam (FIB). ‎This paper compares the nanoporous structure formation under the same ex...

  • Communication
  • Open Access
14 Citations
4,504 Views
8 Pages

Dissolution-Induced Nanowire Synthesis on Hot-Dip Galvanized Surface in Supercritical Carbon Dioxide

  • Aaretti Kaleva,
  • Ville Saarimaa,
  • Saara Heinonen,
  • Juha-Pekka Nikkanen,
  • Antti Markkula,
  • Pasi Väisänen and
  • Erkki Levänen

In this study, we demonstrate a rapid treatment method for producing a needle-like nanowire structure on a hot-dip galvanized sheet at a temperature of 50 °C. The processing method involved only supercritical carbon dioxide and water to induce a reac...

  • Article
  • Open Access
19 Citations
6,363 Views
16 Pages

Use of Polycaprolactone Electrospun Nanofibers as a Coating for Poly(methyl methacrylate) Bone Cement

  • Morshed Khandaker,
  • Shahram Riahinezhad,
  • Harsha G. Jamadagni,
  • Tracy L. Morris,
  • Alexis V. Coles and
  • Melville B. Vaughan

Poly(methyl methacrylate) (PMMA) bone cement has limited biocompatibility. Polycaprolactone (PCL) electrospun nanofiber (ENF) has many applications in the biomedical field due to its excellent biocompatibility and degradability. The effect of coating...

  • Article
  • Open Access
107 Citations
8,232 Views
14 Pages

The Effect of Silver Nanoparticles Size, Produced Using Plant Extract from Arbutus unedo, on Their Antibacterial Efficacy

  • Nicholas Skandalis,
  • Anastasia Dimopoulou,
  • Anthie Georgopoulou,
  • Nikolaos Gallios,
  • Dimitrios Papadopoulos,
  • Dimitrios Tsipas,
  • Ioannis Theologidis,
  • Nikolaos Michailidis and
  • Maria Chatzinikolaidou

Silver nanoparticles (AgNPs) have been demonstrated to restrain bacterial growth, while maintaining minimal risk in development of bacterial resistance and human cell toxicity that conventional silver compounds exhibit. Several physical and chemical...

  • Article
  • Open Access
15 Citations
7,017 Views
14 Pages

Acaricidal nylon 66 fabrics (AN66Fs) grafted with clove oil-loaded microcapsules (COMCs) were developed against Dermatophagoides farina (D. gallinae). The average diameter was about 2.9 µm with a range of 100 nm–8.5 µm. COMCs carried clove oil loadin...

  • Article
  • Open Access
15 Citations
8,184 Views
10 Pages

Cultivating Fluorescent Flowers with Highly Luminescent Carbon Dots Fabricated by a Double Passivation Method

  • Shuai Han,
  • Tao Chang,
  • Haiping Zhao,
  • Huanhuan Du,
  • Shan Liu,
  • Baoshuang Wu and
  • Shenjun Qin

In this work, we present the fabrication of highly luminescent carbon dots (CDs) by a double passivation method with the assistance of Ca(OH)2. In the reaction process, Ca2+ protects the active functional groups from overconsumption during dehydratio...

  • Article
  • Open Access
25 Citations
8,391 Views
17 Pages

Non-Noble Metal Oxide Catalysts for Methane Catalytic Combustion: Sonochemical Synthesis and Characterisation

  • Przemysław J. Jodłowski,
  • Roman J. Jędrzejczyk,
  • Damian K. Chlebda,
  • Anna Dziedzicka,
  • Łukasz Kuterasiński,
  • Anna Gancarczyk and
  • Maciej Sitarz

The aim of this study was to obtain nanocrystalline mixed metal-oxide–ZrO2 catalysts via a sonochemically-induced preparation method. The effect of a stabiliser’s addition on the catalyst parameters was investigated by several characterisation method...

  • Article
  • Open Access
25 Citations
5,624 Views
7 Pages

Selective Dielectric Metasurfaces Based on Directional Conditions of Silicon Nanopillars

  • José Francisco Algorri,
  • Braulio García-Cámara,
  • Alexander Cuadrado,
  • José Manuel Sánchez-Pena and
  • Ricardo Vergaz

Dielectric metasurfaces based on high refractive index materials have been proposed recently. This type of structure has several advantages over their metallic counterparts. In this work, we demonstrate that dielectric metasurfaces can be theoretical...

  • Review
  • Open Access
61 Citations
8,623 Views
10 Pages

Recent Advances in Magnetic Microfluidic Biosensors

  • Ioanna Giouroudi and
  • Georgios Kokkinis

The development of portable biosening devices for the detection of biological entities such as biomolecules, pathogens, and cells has become extremely significant over the past years. Scientific research, driven by the promise for miniaturization and...

  • Article
  • Open Access
24 Citations
8,592 Views
12 Pages

High Ultraviolet Absorption in Colloidal Gallium Nanoparticles Prepared from Thermal Evaporation

  • Flavio Nucciarelli,
  • Iria Bravo,
  • Sergio Catalan-Gomez,
  • Luis Vázquez,
  • Encarnación Lorenzo and
  • Jose Luis Pau

New methods for the production of colloidal Ga nanoparticles (GaNPs) are introduced based on the evaporation of gallium on expendable aluminum zinc oxide (AZO) layer. The nanoparticles can be prepared in aqueous or organic solvents such as tetrahydro...

  • Article
  • Open Access
47 Citations
6,206 Views
16 Pages

The Influence of Copolymer Composition on PLGA/nHA Scaffolds’ Cytotoxicity and In Vitro Degradation

  • Esperanza Díaz,
  • Igor Puerto,
  • Silvie Ribeiro,
  • Senentxu Lanceros-Mendez and
  • José Manuel Barandiarán

The influence of copolymer composition on Poly(Lactide-co-Glycolide)/nanohydroxyapatite (PLGA/nHA) composite scaffolds is studied in the context of bone tissue engineering and regenerative medicine. The composite scaffolds are fabricated by thermally...

  • Article
  • Open Access
19 Citations
5,611 Views
11 Pages

The morphological control of polymer micellar aggregates is an important issue in applications such as nanomedicine and material science. Stimuli responsive soft materials have attracted significant attention for their well-controlled morphologies. H...

  • Review
  • Open Access
32 Citations
7,252 Views
23 Pages

Chiral Nanotubes

  • Andrea Nitti,
  • Aurora Pacini and
  • Dario Pasini

Organic nanotubes, as assembled nanospaces, in which to carry out host–guest chemistry, reversible binding of smaller species for transport, sensing, storage or chemical transformation purposes, are currently attracting substantial interest, both as...

  • Article
  • Open Access
19 Citations
5,957 Views
10 Pages

Effect of Precursor on Antifouling Efficacy of Vertically-Oriented Graphene Nanosheets

  • Karthika Prasad,
  • Chaturanga D. Bandara,
  • Shailesh Kumar,
  • Gurinder Pal Singh,
  • Bastian Brockhoff,
  • Kateryna Bazaka and
  • Kostya (Ken) Ostrikov

Antifouling efficacy of graphene nanowalls, i.e., substrate-bound vertically-oriented graphene nanosheets, has been demonstrated against biofilm-forming Gram-positive and Gram-negative bacteria. Where graphene nanowalls are typically prepared using c...

  • Article
  • Open Access
53 Citations
6,699 Views
15 Pages

Reduced Graphene Oxides: Influence of the Reduction Method on the Electrocatalytic Effect towards Nucleic Acid Oxidation

  • Daniela F. Báez,
  • Helena Pardo,
  • Ignacio Laborda,
  • José F. Marco,
  • Claudia Yáñez and
  • Soledad Bollo

For the first time a critical analysis of the influence that four different graphene oxide reduction methods have on the electrochemical properties of the resulting reduced graphene oxides (RGOs) is reported. Starting from the same graphene oxide, ch...

  • Article
  • Open Access
8 Citations
5,716 Views
9 Pages

Overcoming the Intrinsic Difference between Hydrophilic CH3NH3PbI3 and Hydrophobic C60 Thin Films to Improve the Photovoltaic Performance

  • Lung-Chien Chen,
  • Yu-Shiang Lin,
  • Zong-Liang Tseng,
  • Chiale Wu,
  • Feng-Sheng Kao and
  • Sheng-Hui Chen

Dimethylformamide/dimethyl sulfoxide solvent mixtures were used as the CH3NH3PbI3 (MAPbI3) precursor solvent in a one-step spin coating method to fabricate smooth and hydrophilic crystalline MAPbI3 thin films on top of hydrophobic carbon-60 (C60) thi...

  • Article
  • Open Access
93 Citations
8,930 Views
16 Pages

Interleukin-10 Conjugation to Carboxylated PVP-Coated Silver Nanoparticles for Improved Stability and Therapeutic Efficacy

  • Dieudonné R. Baganizi,
  • Elijah Nyairo,
  • Skyla A. Duncan,
  • Shree R. Singh and
  • Vida A. Dennis

Interleukin-10 (IL-10) is a key anti-inflammatory and immunosuppressive cytokine and therefore represents a potential therapeutic agent especially in inflammatory diseases. However, despite its proven therapeutic efficacy, its short half-life and pro...

  • Communication
  • Open Access
31 Citations
6,366 Views
6 Pages

In this study, citrus pectin-derived, green, and tunable carbon microspheres with superior adsorption capacity and high adsorption rate, as well as good reusability toward methylene blue adsorption, were prepared by a facile hydrothermal method witho...

  • Article
  • Open Access
30 Citations
8,779 Views
15 Pages

Biological Fate of Fe3O4 Core-Shell Mesoporous Silica Nanoparticles Depending on Particle Surface Chemistry

  • Estelle Rascol,
  • Morgane Daurat,
  • Afitz Da Silva,
  • Marie Maynadier,
  • Christophe Dorandeu,
  • Clarence Charnay,
  • Marcel Garcia,
  • Joséphine Lai-Kee-Him,
  • Patrick Bron and
  • Joël Chopineau
  • + 6 authors

The biological fate of nanoparticles (NPs) for biomedical applications is highly dependent of their size and charge, their aggregation state and their surface chemistry. The chemical composition of the NPs surface influences their stability in biolog...

  • Article
  • Open Access
41 Citations
4,628 Views
10 Pages

Synthesis, Characterization, and Nanomedical Applications of Conjugates between Resorcinarene-Dendrimers and Ibuprofen

  • Luis D. Pedro-Hernández,
  • Elena Martínez-Klimova,
  • Sandra Cortez-Maya,
  • Sonia Mendoza-Cardozo,
  • Teresa Ramírez-Ápan and
  • Marcos Martínez-García

Ibuprofen has been reported to possess anticancer activity. In the present work, four ibuprofen conjugates of resorcinarene-Polyamidoamine PAMAM-dendrimers were synthesized with eight or 16 ibuprofen moieties. The ibuprofen was released from the dend...

  • Article
  • Open Access
3 Citations
5,168 Views
9 Pages

The V-centered bicapped hexagonal antiprism structure (A), as the most stable geometry of the cationic V15+ cluster, is determined by using infrared multiple photo dissociation (IR-MPD) in combination with density functional theory computations. It i...

  • Article
  • Open Access
109 Citations
9,047 Views
9 Pages

Cancer therapy with two different modalities can enhance treatment efficacy and reduce side effects. This paper describes a new method for combined chemo- and photothermal therapy of cancer using poly dopamine nanoparticles (PDA-NPs), where PDA-NPs s...

  • Article
  • Open Access
46 Citations
6,305 Views
11 Pages

Controllable Charge Transfer in Ag-TiO2 Composite Structure for SERS Application

  • Yaxin Wang,
  • Chao Yan,
  • Lei Chen,
  • Yongjun Zhang and
  • Jinghai Yang

The nanocaps array of TiO2/Ag bilayer with different Ag thicknesses and co-sputtering TiO2-Ag monolayer with different TiO2 contents were fabricated on a two-dimensional colloidal array substrate for the investigation of Surface enhanced Raman scatte...

  • Article
  • Open Access
48 Citations
8,232 Views
16 Pages

Thermoelectric and Transport Properties of Delafossite CuCrO2:Mg Thin Films Prepared by RF Magnetron Sputtering

  • Inthuga Sinnarasa,
  • Yohann Thimont,
  • Lionel Presmanes,
  • Antoine Barnabé and
  • Philippe Tailhades

P-type Mg doped CuCrO2 thin films have been deposited on fused silica substrates by Radio-Frequency (RF) magnetron sputtering. The as-deposited CuCrO2:Mg thin films have been annealed at different temperatures (from 450 to 650 °C) under primary vacuu...

  • Feature Paper
  • Article
  • Open Access
69 Citations
14,217 Views
8 Pages

I-V and C-V Characterization of a High-Responsivity Graphene/Silicon Photodiode with Embedded MOS Capacitor

  • Giuseppe Luongo,
  • Filippo Giubileo,
  • Luca Genovese,
  • Laura Iemmo,
  • Nadia Martucciello and
  • Antonio Di Bartolomeo

We study the effect of temperature and light on the I-V and C-V characteristics of a graphene/silicon Schottky diode. The device exhibits a reverse-bias photocurrent exceeding the forward current and achieves a photoresponsivity as high as 2.5 ...

  • Article
  • Open Access
17 Citations
6,041 Views
9 Pages

Indium titanium zinc oxide (InTiZnO) as the channel layer in thin film transistor (TFT) grown by RF sputtering system is proposed in this work. Optical and electrical properties were investigated. By changing the oxygen flow ratio, we can suppress ex...

  • Article
  • Open Access
5 Citations
5,380 Views
12 Pages

Biodegradable FeMnSi Sputter-Coated Macroporous Polypropylene Membranes for the Sustained Release of Drugs

  • Jordina Fornell,
  • Jorge Soriano,
  • Miguel Guerrero,
  • Juan De Dios Sirvent,
  • Marta Ferran-Marqués,
  • Elena Ibáñez,
  • Leonardo Barrios,
  • Maria Dolors Baró,
  • Santiago Suriñach and
  • Eva Pellicer
  • + 2 authors

Pure Fe and FeMnSi thin films were sputtered on macroporous polypropylene (PP) membranes with the aim to obtain biocompatible, biodegradable and, eventually, magnetically-steerable platforms. Room-temperature ferromagnetic response was observed in bo...

  • Feature Paper
  • Article
  • Open Access
18 Citations
6,834 Views
16 Pages

Characterisation of the Chemical Composition and Structural Features of Novel Antimicrobial Nanoparticles

  • Yuen-Ki Cheong,
  • Jesus Calvo-Castro,
  • Lena Ciric,
  • Mohan Edirisinghe,
  • Elaine Cloutman-Green,
  • Upulitha Eranka Illangakoon,
  • Qiang Kang,
  • Suntharavathanan Mahalingam,
  • Rupy Kaur Matharu and
  • Guogang Ren
  • + 1 author

Three antimicrobial nanoparticle types (AMNP0, AMNP1, and AMNP2) produced using the TesimaTM thermal plasma technology were investigated and their compositions were determined using a combination of analytical methods. Scanning electron micrographs p...

  • Feature Paper
  • Article
  • Open Access
25 Citations
13,046 Views
17 Pages

The Electrosome: A Surface-Displayed Enzymatic Cascade in a Biofuel Cell’s Anode and a High-Density Surface-Displayed Biocathodic Enzyme

  • Alon Szczupak,
  • Dror Aizik,
  • Sarah Moraïs,
  • Yael Vazana,
  • Yoav Barak,
  • Edward A. Bayer and
  • Lital Alfonta

The limitation of surface-display systems in biofuel cells to a single redox enzyme is a major drawback of hybrid biofuel cells, resulting in a low copy-number of enzymes per yeast cell and a limitation in displaying enzymatic cascades. Here we prese...

  • Article
  • Open Access
30 Citations
6,402 Views
16 Pages

Synergistic Effect of MoS2 and SiO2 Nanoparticles as Lubricant Additives for Magnesium Alloy–Steel Contacts

  • Hongmei Xie,
  • Bin Jiang,
  • Xingyu Hu,
  • Cheng Peng,
  • Hongli Guo and
  • Fusheng Pan

The tribological performances of the SiO2/MoS2 hybrids as lubricant additives were explored by a reciprocating ball-on-flat tribometer for AZ31 magnesium alloy/AISI 52100 bearing steel pairs. The results demonstrated that the introduction of SiO2/MoS...

  • Article
  • Open Access
13 Citations
4,487 Views
14 Pages

Mesoporous Silica Matrix as a Tool for Minimizing Dipolar Interactions in NiFe2O4 and ZnFe2O4 Nanoparticles

  • Maider Virumbrales,
  • Regino Saez-Puche,
  • María José Torralvo and
  • Veronica Blanco-Gutierrez

NiFe2O4 and ZnFe2O4 nanoparticles have been prepared encased in the MCM (Mobile Composition of Matter) type matrix. Their magnetic behavior has been studied and compared with that corresponding to particles of the same composition and of a similar si...

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Nanomaterials - ISSN 2079-4991