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Membranes, Volume 9, Issue 9 (September 2019)
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Cover Story (view full-size image) Facilitated O2 transport membrane is one of the most attractive materials for efficient O2/N2 [...] Read more. Facilitated O2 transport membrane is one of the most attractive materials for efficient O2/N2 separation. In this work, due to its reversible interaction with O2, cobalt porphyrin (T(p-OCH3)PPCoCl) is used as an oxygen carrier in the Pebax TFC membrane to facilitate O2 transport. This carrier exhibits good compatibility with the Pebax due to the hydrogen bond, leading to uniformity of the membrane. The addition of the T(p-OCH3)PPCoCl increases O2 permeability and O2/N2 selectivity simultaneously. Overall, this work provides a potential membrane for O2/N2 separation. View this paper