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Membranes, Volume 10, Issue 4

April 2020 - 24 articles

Cover Story: We prepared and characterized mixed-matrix membranes based on amorphous PPO and particles of the molecular sieve ZIF-8. The inclusion of ZIF-8 with loadings as high as 45 wt % led to a remarkable, up to eight-fold, increase in gas permeability and to a significant decrease in the activation energy of diffusion and permeation. The ideal He/CO2 selectivity also increased, albeit to a lower extent, reaching a maximum at a filler loading of 35 wt %. The additive behavior observed in density measurements and the morphological analysis of the composite films indicate good adhesion between the two phases. The use of commercial materials enables the possibility of scaling-up the technology, and the results encourage applications at high temperatures. View this paper
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Articles (24)

  • Article
  • Open Access
11 Citations
3,681 Views
19 Pages

The paper presents a method of obtaining composite polyacrylonitrile-based (PAN) membranes with the addition of reduced graphene oxide (rGO). The membranes were obtained using phase inversion method from a homogeneous rGO dispersion in a solution of...

  • Feature Paper
  • Article
  • Open Access
20 Citations
6,406 Views
34 Pages

Enhancing the Separation Performance of Glassy PPO with the Addition of a Molecular Sieve (ZIF-8): Gas Transport at Various Temperatures

  • Francesco M. Benedetti,
  • Maria Grazia De Angelis,
  • Micaela Degli Esposti,
  • Paola Fabbri,
  • Alice Masili,
  • Alessandro Orsini and
  • Alberto Pettinau

In this study, we prepared and characterized composite films formed by amorphous poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) and particles of the size-selective Zeolitic Imidazolate Framework 8 (ZIF-8). The aim was to increase the permselectivity pr...

  • Article
  • Open Access
21 Citations
5,004 Views
15 Pages

In this work, a poly(1-trimethylsilyl-1-propyne) (PTMSP) mixed-matrix membrane was fabricated for the selective removal of 1-butanol from aqueous solutions through pervaporation. Silica nanoparticles (SNPs), which were surface-modified with surfactan...

  • Article
  • Open Access
14 Citations
5,212 Views
18 Pages

Influence of Spacer Design and Module Geometry on the Filtration Performance during Skim Milk Microfiltration with Flat Sheet and Spiral-Wound Membranes

  • Martin Hartinger,
  • Jonas Napiwotzki,
  • Eva-Maria Schmid,
  • Dominik Hoffmann,
  • Franziska Kurz and
  • Ulrich Kulozik

Spacer design in spiral-wound membranes (SWMs) significantly affects the axial pressure drop in the flow channel but also the deposit layer removal. However, the effects of the spacer design and feed flow distribution in the module on the filtration...

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Membranes - ISSN 2077-0375