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16 November 2025

Elastic Origins of Hardness in Quenchable High-Pressure Metal Nitrides: A Unified Structure-Elasticity Baseline

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1
School of Materials Science and Engineering, Jilin Jianzhu University, Changchun 130012, China
2
State Key Laboratory of High Pressure and Superhard Materials, College of Physics, Jilin University, Changchun 130012, China
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Author to whom correspondence should be addressed.
Metals2025, 15(11), 1251;https://doi.org/10.3390/met15111251 
(registering DOI)
This article belongs to the Special Issue Recent Insights into Mechanical Properties of Metallic Alloys

Abstract

We review bulk transition-metal nitrides synthesized at high pressure–high temperature and recoverable at ambient conditions. We establish an elasticity-anchored framework that links crystal structure and bonding to elastic descriptors and hardness at the phase-resolved level, enabling fair cross-study comparison. Overall, hardness shows a robust association with the shear modulus G, while the Pugh ratio k = G/B modulates relative rankings across phases. When metallic bonding or non-stoichiometry/defects are pronounced, systematic deviations arise; accordingly, elasticity-based models are best used for cross-phase trends and qualitative guidance rather than absolute predictions, especially for metallic or defect-rich phases. Building on this baseline, we outline application pathways and future research directions, and we propose a minimal reporting checklist to improve reproducibility and cross-study comparability.

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