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P(MMA-EMA) Random Copolymer Electrolytes Incorporating Sodium Iodide for Potential Application in a Dye-Sensitized Solar Cell

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Institute of Graduate Studies, University of Malaya, 50603 Kuala Lumpur, Malaysia
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School of Chemistry Science and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor Darul Ehsan, Malaysia
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Centre for Foundation Studies in Science, University of Malaya, 50603 Kuala Lumpur, Malaysia
*
Author to whom correspondence should be addressed.
Academic Editor: Thomas Junkers
Polymers 2015, 7(2), 266-280; https://doi.org/10.3390/polym7020266
Received: 19 December 2014 / Revised: 26 January 2015 / Accepted: 1 February 2015 / Published: 9 February 2015
Polymer electrolytes based on 90 wt% of methyl methacrylate and 10 wt% of ethyl methacrylate (90MMA-co-10EMA) incorporating different weight ratios of sodium iodide were prepared using the solution casting method. The complexation between salt and copolymer host has been investigated using Fourier transform infrared spectroscopy. The ionic conductivity and thermal stability of the electrolytes were measured using impedance spectroscopy and differential scanning calorimetry, respectively. Scanning electron microscopy was used to study the morphology of the polymer electrolytes. The ionic conductivity and glass transition temperature increased up to 20 wt% of sodium iodide (5.19 × 10−6 S·cm−1) and decreased with the further addition of salt concentration, because of the crosslinked effect. The morphology behavior of the highest conducting sample also showed smaller pores compared to the other concentration. The total ionic transference number proved that this system was mainly due to ions, and the electrochemical stability window was up to 2.5 V, which is suitable for a dye-sensitized solar cell application. This sample was then tested in a dye-sensitized solar cell and exhibited an efficiency of 0.62%. View Full-Text
Keywords: ionic conductivity; polymer electrolyte; transference number; electrochemical stability; dye-sensitized solar cell ionic conductivity; polymer electrolyte; transference number; electrochemical stability; dye-sensitized solar cell
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Dzulkurnain, N.A.; Ahmad, A.; Mohamed, N.S. P(MMA-EMA) Random Copolymer Electrolytes Incorporating Sodium Iodide for Potential Application in a Dye-Sensitized Solar Cell. Polymers 2015, 7, 266-280.

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