Catalysts, Volume 8, Issue 11

A novel approach to the in situ regeneration of a spent alumina-supported cobalt–iron catalyst for catalytic methane decomposition is reported in this work. The spent catalyst was obtained after testing fresh catalyst in catalytic methane decom...

Floating photocatalytic devices are highly sought-after as they represent good candidates for practical application in pollutant remediation of large water basins. Here, we present a multilayer floating device for the photocatalytic remediation of co...

Biodiesel can be a significant alternative for diesel. Usually, it is produced through transesterification with a base catalyst. Using heterogeneous catalysts for transesterification, the process can be more efficient. Among the possible catalysts th...

The water-gas shift (WGS) reaction is a well-known industrial process used for the production of hydrogen. During the last few decades, it has attracted renewed attention due to the need for high-purity hydrogen for fuel-cell processing systems. The...

V-containing mixed oxide catalytic materials are well known as active for partial oxidation reactions. Oxidation reactions are used in industrial chemistry and for the abatement of pollutants. An analysis of the literature in this field during the pa...

Three components of pillared metal-organic frameworks (MOFs, three components = metal ion, carboxylic acid ligand, and N-chelating ligand) were controlled for CO₂ cycloaddition catalysts to synthesize organic cyclic carbonates. Among the divalent met...

We have demonstrated a convenient method of synthesizing nickel nanowires (NiNWs), which could be easily tuned to produce materials with a carefully defined nanostructure. By varying the concentration of the Ni precursor, pH of the medium or reaction...

New ligand platforms of the type p- or m-Ph{-CR(3,6-tBu₂Flu)(Cp)}₂ (para-, R = Me (2a), H (2b); meta-, R = Me (2c)) were synthesized via nucleophilic addition of the 3,6-tBu₂-fluorenyl-anion onto the parent phenylene-bridged difulvenes (1a–c)....

This review summarizes recent progress in the development of cobalt-based catalytic centers as the most potentially useful alternatives to noble metal-based electrocatalysts (Pt-, Ir-, and Ru-based) towards the oxygen reduction reaction (ORR), oxygen...

High-loading Ni–Mo carbide catalysts were prepared by the modified gel-combustion method under various thermal treatment conditions. All samples were studied by X-ray diffraction (XRD) analysis, which showed that the catalysts could contain cub...

Corynebacterium glutamicum is an industrial strain used for the production of valuable chemicals such as L-lysine and L-glutamate. Although C. glutamicum has various industrial applications, a limited number of tunable systems are available to engine...

Deriving photocatalysts by the calcination of hydrotalcite-like compounds has attracted growing interest for extending their photocatalytic activity to the visible and even near-infrared (NIR) light regions. Herein, we describe the acquisition of a Z...

Perovskite-structure SrTiO₃ (STO) and graphitic carbon nitride (g-C₃N₄, CN) have attracted considerable attention in photocatalytic technology due to their unique properties, but also suffer from some drawbacks. The development of composite photocata...

Nanotubes of the transition metal oxide, TiO₂, prepared by electrochemical anodization have been investigated and utilized in many fields because of their specific physical and chemical properties. However, the usage of bare anodic TiO₂ nanotubes in...

In recent years, various modular micro channel reactors have been developed to overcome limitations in challenging chemical reactions. Direct synthesis of hydrogen peroxide from hydrogen and oxygen is a very interesting process in this regard. Howeve...

The aminohydroxylation reaction of olefins is a key organic transformation reaction, typically carried out homogeneously with toxic and expensive osmium (Os) catalysts. Therefore, heterogenisation of this reaction can unlock its industrial potential...

In this report, the use of immobilized nicotine hydroxylase from Pseudomonas sp. ZZ-5 (HSPH_ZZ) for the production of 2,5-dihydroxypyridine (2,5-DHP) from 6-hydroxy-3-succinoylpyridine (HSP) in the presence of nicotinamide adenine dinucleotide (NADH)...

N-heterocyclic carbene organocatalysis under oxidizing conditions provides a vast range of various synthetic procedures via diverse mechanisms. The available catalysts, bases, oxidants, and oxidizing methods afford numerous opportunities for developi...

DNAzymes are catalytically active DNA molecules that are normally isolated through in vitro selection methods, among which RNA-cleaving DNAzymes that catalyze the cleavage of a single RNA linkage embedded within a DNA strand are the most studied grou...

Water splitting plays an important role in the electrochemical and photoelectrochemical conversion of energy devices. Electrochemical water splitting by the hydrogen evolution reaction (HER) is a straightforward route to producing hydrogen (H₂), whic...

Pd/DNA catalysts were prepared in a mixed H₂O/EtOH solvent using palladium precursors, Pd(OAc)₂ and PdCl₂, in different dosages and salmon fish sperm DNA. As prepared, the Pd/DNA contained Pd(II) and Pd(0) nanoparticles of various sizes and morpholog...

This article reviews the efforts of the last two decades to deNOxify the atmospheric environment with TiO₂-based photocatalytic materials supported on various cementitious-like substrates. Prior to undertaking this important aspect of applied photoca...

A research and technological challenge for fuel processors integrated with High Temperature Polymer Electrolyte Membrane Fuel Cells (HT-PEMFCs), also known as Internal Reforming Methanol Fuel Cells (IRMFCs), operating at 200–220 °C, is the...

Powder materials containing copper ions supported on ZSM-5 (Cu-Zeolite Socony Mobil-5) and SSZ-13 (Cu-Standard Oil synthesised zeolite-13), and predominantly CuO nanoparticles on amorphous SiO ${}_2$ were synthesised, characterised, wash-coated on...

Layer by layer metal-organic framework (MOF) supported on zirconium phosphate (ZrP) was synthesized at very mild conditions and used for the liquid phase oxidation of cyclohexene in solvent free condition in the presence of molecular oxygen. The MOF-...

After its discovery in the early 1980s and successful application on an industrial scale (Ruhrchemie/Rhone-Poulenc process) [...]

Low-noble metal electrocatalysts are attracting massive attention for anode and cathode reactions in fuel cells. Pt transition metal alloy nanostructures have demonstrated their advantages in high performance low-noble metal electrocatalysts due to s...

The Meerwein–Ponndorf–Verley (MPV) reaction is an environmentally-friendly process consisting of the reduction of a carbonyl compound through hydrogen transfer from a secondary alcohol. This work deals with MPV reduction of furfural to fu...

This paper describes an electrochemical treatment process of hydrochlorothiazide (HDZ) under different conditions such as initial concentration, sodium chloride and applied voltage. In this present study, HDZ was treated by electrochemical oxidation...

A series of poisoned catalysts with various forms and contents of sodium salts (Na₂SO₄ and Na₂S₂O₇) were prepared using the wet impregnation method. The influence of sodium salts poisoned catalysts on SO₂ oxidation and NO reduction was investigated....

Facet-selective gold or platinum-nanoparticle deposition on decahedral-shaped anatase titania particles (DAPs) exposing {001} and {101} facets via photodeposition (PD) from metal-complex sources was reexamined using DAPs prepared with gas-phase react...

Utilizing catalysts in microcombustors is probably an excellent practical solution to stabilize fuel combustion because of the relatively fast reaction speed. In the present work, the monolithic catalyst Pd/A₂O₃/Fe-Ni with metal foam as matrix was us...

Al-modified hexagonal mesoporous silica (HMS) materials were synthesized using dodecylamine as a template according to the methods reported in the literature. FT-IR spectra proved that Al³⁺ ions entered in the HMS framework in Al-HMS (prepared by sol...

Ceria in nanoscale with different morphologies, rod, tube and cube, were prepared through a hydrothermal process. The structure, morphology and textural properties were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), tra...

Hydroisomerization of long chain paraffins for the production of branched alkanes has recently been intensively studied due to a large availability of these compounds. The most interesting research topics have been the development of novel bifunction...

Some of the most promising results for bacterial alkane hydroxylation to alcohols have been obtained with the cytochrome P450 monooxygenase CYP153A6. CYP153A6 belongs to the class I CYPs and is generally expressed from an operon that also encodes the...

Ionic liquids with [BMIM], [Et₃NH], and [BPy] cations and Al_nCl⁻_3n+1, Zn_nCl⁻_2n+1, and Cu_nCl⁻_n+1 anions were used as the catalysts for the chlorination of toluene with Cl₂. The Zn_nCl⁻_2n+1 containing ionic liquids with high Lewi...

This editorial is written to recognize Professor Emeritus Calvin H. Bartholomew, who celebrated his 75th birthday in 2018, and to introduce the commemorative issue of Catalysts compiled in his honor. Following a brief biography that celebrates the ca...

N-doped and N,S-co-doped SrTiO₃ photocatalysts were prepared using glycine and L-histidine amino acids as nitrogen sources and L-cysteine as nitrogen and sulphur source. The samples were characterized by X-ray diffraction (XRD), scanning electron mic...

The so-called OPPenauer oxidation is well known for its ability to oxidize valuable alcohols into their corresponding aldehydes or ketones. In particular, it has proven to be extremely successful in the oxidation of sterols. On the other hand, its ap...

[NiFe]-hydrogenases are gas-processing metalloenzymes that catalyze the conversion of dihydrogen (H₂) to protons and electrons in a broad range of microorganisms. Within the framework of green chemistry, the molecular proceedings of biological hydrog...

Improving onsite energy generation and recovering value-added products are common goals for sustainable used water reclamation. A new process called autocatalytic pyrolysis was developed at bench scale in our previous work by using biochar produced f...

Chemical Looping Combustion (CLC) has been considered as one of the most promising technologies to implement CO₂ capture with low energy penalty. A comprehensive three-dimensional numerical model integrating gas–solid flow and reactions, based...

Acetate, which is an abundant carbon source, is a potential feedstock for microbial processes that produce diverse value-added chemicals. In this study, we produced 3-hydroxypropionic acid (3-HP) from acetate with engineered Escherichia coli. For the...

Acidic oil, which is easily obtained and with lower cost, is a potential raw material for biodiesel production. Apart from containing large quantity of FFAs (free fatty acids), acidic oil usually contains some amount of inorganic acid, glycerides and...

Isomerate, the product of a light naphtha Isomerization unit, is a clean, high-octane gasoline blending component, which is free of sulfur content, aromatics, and olefins. However, the isomerization of the long-chain alkanes, such as n-heptane, is pr...

Recycling carbon fiber from residual carbon fiber reinforced plastics (CFRP) is one of the key aspects of the future in the field of waste management. This work presents the possibility of recovering chemical compounds through the thermo-catalytic tr...

Co-Ni bi-metallic catalysts supported on Ce-Al₂O₃ (CA) were prepared with different Co ratios, and the catalytic behaviors were assessed in the n-decane steam reforming reaction with the purpose of obtaining high H₂ yield with lower inactivation by c...

A facile aqueous method to construct a platinum nanoflowers (PtNFs)/three-dimensional (3D) graphene electrode for electrochemical catalysis was demonstrated. PtNFs composed of thin Pt nanowires with the length of 6–16 nm and the diameter of 2&n...

A meso-mesityl-2,6-iodine substituted boron dipyrromethene (BODIPY) dye is investigated using a suite of computational methods addressing its functionality as photosensitizer, i.e., in the scope of light-driven hydrogen evolution in a two-component a...