Table of Contents
Catalysts, Volume 8, Issue 10 (October 2018) – 80 articles
- Issues are regarded as officially published after their release is announced to the table of contents alert mailing list.
- You may sign up for e-mail alerts to receive table of contents of newly released issues.
- PDF is the official format for papers published in both, html and pdf forms. To view the papers in pdf format, click on the "PDF Full-text" link, and use the free Adobe Reader to open them.
Cover Story (view full-size image) Colloidal Pd nanoparticles capped with octanethiolate ligands show good regio- and [...] Read more. Colloidal Pd nanoparticles capped with octanethiolate ligands show good regio- and stereoselectivity toward the mono-hydrogenation of ester-conjugated allenes to either Z or E olefinic isomers depending on the substitution pattern around C=C bonds. Kinetic studies indicate that the reaction progresses through the hydrogenation of less hindered C=C bond to produce internal Z olefinic isomers. The high selectivity of Pd nanoparticles averting an additional hydrogenation is steered from the controlled electronic and geometric properties of the Pd surface, which are the result of thiolate-induced partial poisoning and surface crowding, respectively. View this paper.