New In Situ Catalysts Based on Nitro Functional Pyrazole Derivatives and Copper (II) Salts for Promoting Oxidation of Catechol to o-Quinone
Abstract
:1. Introduction
2. Experimental Section
2.1. Materials and Characterization Techniques
2.2. Synthesis and Characterization
2.2.1. Preparation of Compounds L1–L4
2.2.2. Characterization
3. Study of Conversion Reaction of Catechol to o-Quinone
3.1. Effect of Concentration
3.1.1. Catalytic Studies Using Ligand/Metal Ratio as 1L/1M in MeOH
3.1.2. Catalytic Studies Using Ligand/Metal Ratio as (2L/1M) in Methanol
3.2. Solvent Effect
3.3. Kinetic Study
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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L/M | Cu(NO3)2 | Cu(CH3COO)2 | CuSO4 | CuCl2 |
---|---|---|---|---|
L1 | 0.6667 | 1.9167 | 3.0104 | 0.1458 |
L2 | 12.5521 | 14.010 | 14.115 | 4.1042 |
L3 | 1.1875 | 0.5625 | 4.5833 | 4.5729 |
L4 | 0.1562 | 1.4166 | 0.7292 | 1.7083 |
2L/1M | Cu(NO3)2 | Cu(CH3COO)2 | CuSO4 | CuCl2 |
---|---|---|---|---|
L1 | 1.1041 | -------- | 1.3854 | -------- |
L2 | 22.3956 | 32.2917 | 16.6563 | 1.3021 |
L3 | 6.8333 | 4.4895 | -------- | -------- |
L4 | 0.4375 | 1.5104 | 0.0937 | -------- |
2L2/Copper (II) Salt | Solvents | V (μmol·L−1·min−1) |
---|---|---|
2L2/Cu(NO3)2 | MeOH | 22.3958 |
THF | 1.1667 | |
CH3CN | 0.0417 | |
CHCl3 | 0.3021 | |
2L2/Cu(CH3COO)2 | MeOH | 32.2917 |
THF | 5.5625 | |
CH3CN | 0.0417 | |
CHCl3 | 0.1458 | |
2L2/CuSO4 | MeOH | 16.6563 |
CH3CN | 0.1458 | |
CHCl3 | 0.2604 | |
2L2/CuCl2 | MeOH | 0.1302 |
THF | 0.1812 | |
CH3CN | 0.0021 | |
CHCl3 | 0.0208 |
2L2/Cu(II) Salt | Vmax (μmol·L−1·min−1) | Km (mol·L−1) |
---|---|---|
2L2/Cu(NO3)2 | 32.86 | 0.04 |
2L2/Cu(CH3COO)2 | 41.67 | 0.02 |
2L2/CuSO4 | 33.56 | 0.06 |
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Titi, A.; Zaidi, K.; Alzahrani, A.Y.A.; El Kodadi, M.; Yousfi, E.B.; Moliterni, A.; Hammouti, B.; Touzani, R.; Abboud, M. New In Situ Catalysts Based on Nitro Functional Pyrazole Derivatives and Copper (II) Salts for Promoting Oxidation of Catechol to o-Quinone. Catalysts 2023, 13, 162. https://doi.org/10.3390/catal13010162
Titi A, Zaidi K, Alzahrani AYA, El Kodadi M, Yousfi EB, Moliterni A, Hammouti B, Touzani R, Abboud M. New In Situ Catalysts Based on Nitro Functional Pyrazole Derivatives and Copper (II) Salts for Promoting Oxidation of Catechol to o-Quinone. Catalysts. 2023; 13(1):162. https://doi.org/10.3390/catal13010162
Chicago/Turabian StyleTiti, Abderrahim, Kaoutar Zaidi, Abdullah Y. A. Alzahrani, Mohamed El Kodadi, El Bekkaye Yousfi, Anna Moliterni, Belkheir Hammouti, Rachid Touzani, and Mohamed Abboud. 2023. "New In Situ Catalysts Based on Nitro Functional Pyrazole Derivatives and Copper (II) Salts for Promoting Oxidation of Catechol to o-Quinone" Catalysts 13, no. 1: 162. https://doi.org/10.3390/catal13010162