2021 April - 117 articles
A flower-like TiO2-based composite (denoted as Zn-Ti-6) was prepared using a flower-like zinc oxide template for adsorption–photocatalytic degradation of high-chroma methylene blue. The reaction took place in an alkaline environment following hydroch...
This study describes the use of new ZnO/PAAH hybrid nanomaterials (PAAH = polyacrylic acid) as copper catalyst supports for the hydrogenolysis of glycerol. A study of the synthesis parameters (washing process, temperatures of synthesis and calcinatio...
The synthesis of dimethyl carbonate (DMC) from methanol and Carbon dioxide (CO2) has been investigated over 5% Rh/Al2O3 catalyst. Diffuse Reflectance Infrared Fourier Transfer Spectroscopy (DRIFTS) was used to probe the reaction adsorbates which show...
Dynamic kinetic resolution (DKR) is one of the most attractive methods for enantioselective synthesis. In the reported studies, lipase B from Candida antarctica (CALB) immobilized on siliceous mesoporous cellular foams (MCF) functionalized with diffe...
In this work, Cu-CeOx-MOF catalysts with well-dispersed Cu in different contents were synthesized via the ethylenediaminetetraacetic acid (EDTA) grafting method. EDTA was grafted in Ce-MOF-808 to anchor Cu and then the metal-organic frameworks (MOFs)...
Transaminases have arisen as one of the main biocatalysts for amine production but despite their many advantages, their stability is still a concern for widespread application. One of the reasons for their instability is the need to use an excess of...
Palladium catalysts have attracted widespread attention as advanced electrocatalysts for the formic acid oxidation (FAO) due to their excellent electrocatalytic activity and relatively high abundance. At present, electrodeposition methods have been w...
Formation of disinfection byproducts (DBPs) in drinking water treatment (DWT) as a result of pathogen removal has always been an issue of special attention in the preparation of safe water. DBPs are formed by the action of oxidant-disinfectant chemic...
In recent years, due to the impact of global warming, environmental pollution, and the energy crisis, international attention and demand for clean energy are increasing. Hydrogen energy is recognized as one of the clean energy sources. Water is consi...
Understanding the mechanism of the catalytic upgrade of bio-oils via the process of hydrodeoxygenation (HDO) is desirable to produce targeted oxygen-deficient bio-fuels. We have used calculations based on the density functional theory to investigate...
The performance of photocatalytic advanced oxidation must be improved in order for the technology to make the jump from academic research to widespread use. Research is needed on the factors that cause photocatalysis to become self-limiting. In this...
The main objective of this study was to achieve the continuous biorecovery and bioreduction of Pb(II) using an industrially obtained consortia as a biocatalyst. An upflow anaerobic sludge blanket reactor was used in the treatment process. The bioreme...
A formal homogeneous gold-catalyzed A3-coupling, starting from benzyl alcohols, is reported for the straightforward synthesis of propargylamines. This is the first process where these highly valuable compounds have been synthesized, starting from the...
Magnetite supported on multiwalled carbon nanotubes catalysts were synthesized by co-precipitation and hydrothermal treatment. The magnetic catalysts were characterized by X-ray diffraction, Fourier-transform infrared spectrometry, thermogravimetric...
“Non-thermal plasma technology” (NTP) has notably increased [...]
The separation of C3H4/C3H6 is one of the most energy intensive and challenging operations, requiring up to 100 theoretical stages, in traditional cryogenic distillation. In this investigation, the potential application of two MOFs (SIFSIX-3-Ni and N...
In this study, an Ag2S–CdS nanocomposite (AC11) was prepared through chemical co-precipitation of silver nitrate and cadmium acetate in an aqueous solution of thiourea. We then synthesized PACI, a nanocomposite of polyaniline (PANI) and AC11, through...
Biochar is a kind of carbon-rich material formed by pyrolysis of biomass at high temperature in the absence or limitation of oxygen. It has abundant pore structure and a large surface area, which could be considered the beneficial characteristics for...
Sustainable methods for producing enantiopure drugs have been developed. Chlorohydrins as building blocks for several β-blockers have been synthesized in high enantiomeric purity by chemo-enzymatic methods. The yield of the chlorohydrins increased by...
One of the most commonly produced industrial chemicals worldwide, bisphenol A (BPA), is used as a precursor in plastics, resins, paints, and many other materials. It has been proved that BPA can cause long-term adverse effects on ecosystems and human...
The interest in advanced photocatalytic technologies with metal oxide-based nanomaterials has been growing exponentially over the years due to their green and sustainable characteristics. Photocatalysis has been employed in several applications rangi...
Volatile organic compounds (VOCs) have a negative effect on both humans and the environment; therefore, it is crucial to minimize their emission. The conventional solution is the catalytic oxidation of VOCs by air; however, in some cases this method...
The outstanding optoelectronic performance and facile synthetic approach of metal halide perovskites has inspired additional applications well beyond efficient solar cells and light emitting diodes (LEDs). Herein, we present an alternative option ava...
Dimethyl-carbonate (DMC) is a green carboxymethylation agent for synthesis of the versatile long-chain alkyl carbonates through base-catalyzed transesterification with aliphatic alcohols. Herein, we demonstrated the facile preparation of a novel hete...
In this study, we report a 3D structured carbon foam electrode assembled from a bi-functional NiCo catalyst, carbon nanotubes (CNT), and a monolith 3D structured carbon foam (CF) as a highly active and stable electrode for oxygen evolution reaction (...
In this work, the effect of pretreatment conditions (10% H2/Ar flow rate 25 mL/min and 400 °C, 3 h or 600 °C, 17 h) on the catalytic performance of 1 wt.% Pd/γ-Al2O3 has been evaluated for hydrogenation of 2-methyl-3-butyn-2-ol in continuous-flow mod...
Structural design and morphological control of semiconductors is considered to be one of the most effective ways to improve their photocatalytic degradation properties. In the present work, a hexagonal WO3·0.33H2O hierarchical microstructure (HWHMS)...
Bioelectrocatalysis using redox enzymes appears as a sustainable way for biosensing, electricity production, or biosynthesis of fine products. Despite advances in the knowledge of parameters that drive the efficiency of enzymatic electrocatalysis, th...
The purpose of the study was the development of water-resistant catalyst and catalytic processes for the conversion of hydrous ethanol to 1-butanol. Water, in hydrous ethanol, strongly inhibits conversion to 1-butanol on solid catalysts. In this stud...
The present study demonstrates a simple approach to enhancing thermal stability of butyrylcholinesterase (BChE) by using natural polymers. Analysis of thermal inactivation of the tetrameric BChE in starch and gelatin gels at 50–64 °C showed that ther...
We present a molecular mechanics force field in AMBER format for the mixed-valence manganese vanadium oxide cluster [Mn
Boric acid is recently proved to be a good substitute for conventional acidic catalytic materials. However, few studies used boric acid as a catalyst in biomass pyrolysis. This study focused on the catalytic effects of boric acid (BA) on pyrolysis be...
Nickel-Fe3O4 nanoparticles supported on multi-walled carbon nanotubes (Ni-Fe3O4/MWCNTs) were synthesized by mechanical grinding of a sample of nickel salt, Fe3O4 and MWCNTs using a ball-mill mixer. The preparation method allows for bulk production of...
The increasing concentration of residual ciprofloxacin (CIP) can cause potential harm to the environment. Photocatalysis has been regarded as an effective method for the degradation of CIP. Bi/BiVO4 with excellent photocatalytic performance was synth...
The effects of Mg and Zn dopants on the catalytic performance of Pt/Al2O3 catalyst were investigated for dehydrogenation of perhydrodibenzyltoluene (H18-DBT) as a liquid organic hydrogen carrier. Al2O3 supports were modified with Mg and Zn to produce...
In this study, a Pt/anodized aluminum oxide (AAO) catalyst was prepared by the anodization of an Al alloy (Al6082, 97.5% Al), followed by the incorporation of Pt via an incipient wet impregnation method. Then, the Pt/AAO catalyst was evaluated for au...
Niobium containing SBA-15 was prepared by two methods: impregnation with different amounts of ammonium niobate(V) oxalate (Nb-15/SBA-15 and Nb-25/SBA-15 containing 15 wt.% and 25 wt.% of Nb, respectively) and mixing of mesoporous silica with Nb2O5 fo...
Halogen substituents often lead to a profound effect on the biological activity of organic compounds. Flavin-dependent halogenases offer the possibility of regioselective halogenation at non-activated carbon atoms, while employing only halide salts a...
Metal sulphides constitute cheap, naturally abundant, and environmentally friendly materials for energy storage applications and chemistry. In particular, iron (II) monosulphide (FeS, mackinawite) is a material of relevance in theories of the origin...
The specific roles played by both support and noble metals in light absorption, charge separation, and the formation of ·OH and O2− (ROS) are analyzed for light-triggered oxidation of phenol (Ph) over pristine and over noble metal (Ag, Au, Pt) -loade...
Hydrogen evolution reaction (HER) was investigated on reduced graphene oxide (rGO)-supported Au and PdAu nanoparticles in acid solution. The graphene spread over glassy carbon (rGO/GC) was used as a support for the spontaneous deposition of Au and Pd...
Electrochemical CO2 reduction is a promising carbon capture and utilisation technology. Herein, a continuous flow gas diffusion electrode (GDE)-cell configuration has been studied to convert CO2 via electrochemical reduction under atmospheric conditi...
In this study, we investigated the influence of different modes of magnetic mixing on effective enzyme activity of aspartate ammonia-lyase from Pseudomonas fluorescens immobilized onto epoxy-functionalized magnetic nanoparticles by covalent binding (...
Herein, we report a Pd4L2-type molecular cage (1) and catalyzed reactions of spiroepoxy naphthalenone (2) in water, where selective formation of 2-(hydroxymethyl)naphthalene-1,4-dione (3) via aerobic oxidation, or 1-hydroxy-2-naphthaldehyde (4) via p...
The electrochemical reduction of CO2 is a promising strategy to achieve efficient conversion and utilization. In this paper, a series of Zn catalysts were prepared by electrodeposition in different atmospheric conditions (N2, CO2, H2, CO). A fibrous...
Computational catalysis has been one of the most dynamic research fields over the last decade, and it now represents a critical tool for the analysis of chemical mechanisms and active sites [...]
Here, a simple method was developed to prepare an MgF2-modified hydrotalcite-derived composite, which was used as support for the Pt-In catalyst for isobutane direct dehydrogenation. The catalysts, composites, and their precursors were characterized...
In the present work, the degradation of p-nitrophenol (PNP) and its mineralization by a UV/Vis-based persulphate activation process was investigated. Firstly, a screening of processes as direct photolysis, persulphate alone and persulphate activated...
Transition metal catalyzed cross-coupling reactions have proved to be powerful tools for carbon–carbon as well as carbon–heteroatom bond formation in the development of synthetic methodologies for applications ranging from pharmaceuticals to material...
The release of methane from vehicles or/and stationary industrial sources must be reduced in order to control the emission of this greenhouse gas into the atmosphere [...]
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