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Catalysts, Volume 11, Issue 4

April 2021 - 117 articles

Cover Story: Multi-enzyme catalysis has emerged as a new frontier for the synthesis of complex chemicals. At the same time, the in vitro operation of multiple enzymes requires new strategies for increasing the operational performance of enzymatic cascade reactions. Advances in synthetic biology and protein engineering have therefore led to bioinspired co-localization strategies for scaffolding and compartmentalization of enzymes. In the future, genetically encoded co-localization mechanisms could become platforms for autonomously self-organizing biocatalytic systems. Such genetically programmable systems could be produced by cell factories or emerging cell-free systems. View this paper
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Articles (117)

  • Article
  • Open Access
3 Citations
3,117 Views
13 Pages

20 April 2021

Palladium catalysts have attracted widespread attention as advanced electrocatalysts for the formic acid oxidation (FAO) due to their excellent electrocatalytic activity and relatively high abundance. At present, electrodeposition methods have been w...

  • Article
  • Open Access
5 Citations
2,596 Views
12 Pages

20 April 2021

A flower-like TiO2-based composite (denoted as Zn-Ti-6) was prepared using a flower-like zinc oxide template for adsorption–photocatalytic degradation of high-chroma methylene blue. The reaction took place in an alkaline environment following hydroch...

  • Article
  • Open Access
11 Citations
3,308 Views
19 Pages

20 April 2021

This study describes the use of new ZnO/PAAH hybrid nanomaterials (PAAH = polyacrylic acid) as copper catalyst supports for the hydrogenolysis of glycerol. A study of the synthesis parameters (washing process, temperatures of synthesis and calcinatio...

  • Article
  • Open Access
12 Citations
3,836 Views
17 Pages

In Situ IR Studies on the Mechanism of Dimethyl Carbonate Synthesis from Methanol and Carbon Dioxide

  • Khalid A. Almusaiteer,
  • Sulaiman I. Al-Mayman,
  • Aghaddin Mamedov and
  • Yousef S. Al-Zeghayer

20 April 2021

The synthesis of dimethyl carbonate (DMC) from methanol and Carbon dioxide (CO2) has been investigated over 5% Rh/Al2O3 catalyst. Diffuse Reflectance Infrared Fourier Transfer Spectroscopy (DRIFTS) was used to probe the reaction adsorbates which show...

  • Feature Paper
  • Article
  • Open Access
13 Citations
4,426 Views
12 Pages

Lipase Immobilized on MCFs as Biocatalysts for Kinetic and Dynamic Kinetic Resolution of sec-Alcohols

  • Dominika Stradomska,
  • Monika Heba,
  • Aleksandra Czernek,
  • Nikodem Kuźnik,
  • Danuta Gillner,
  • Katarzyna Maresz,
  • Wojciech Pudło,
  • Andrzej Jarzębski and
  • Katarzyna Szymańska

20 April 2021

Dynamic kinetic resolution (DKR) is one of the most attractive methods for enantioselective synthesis. In the reported studies, lipase B from Candida antarctica (CALB) immobilized on siliceous mesoporous cellular foams (MCF) functionalized with diffe...

  • Article
  • Open Access
23 Citations
6,002 Views
16 Pages

Catalytic Combustion of Toluene over Highly Dispersed Cu-CeOx Derived from Cu-Ce-MOF by EDTA Grafting Method

  • Wenjie Sun,
  • Yijia Huang,
  • Xiaomin Li,
  • Zhen Huang,
  • Hualong Xu and
  • Wei Shen

20 April 2021

In this work, Cu-CeOx-MOF catalysts with well-dispersed Cu in different contents were synthesized via the ethylenediaminetetraacetic acid (EDTA) grafting method. EDTA was grafted in Ce-MOF-808 to anchor Cu and then the metal-organic frameworks (MOFs)...

  • Article
  • Open Access
17 Citations
4,533 Views
13 Pages

20 April 2021

Transaminases have arisen as one of the main biocatalysts for amine production but despite their many advantages, their stability is still a concern for widespread application. One of the reasons for their instability is the need to use an excess of...

  • Feature Paper
  • Review
  • Open Access
29 Citations
6,021 Views
63 Pages

20 April 2021

Formation of disinfection byproducts (DBPs) in drinking water treatment (DWT) as a result of pathogen removal has always been an issue of special attention in the preparation of safe water. DBPs are formed by the action of oxidant-disinfectant chemic...

  • Review
  • Open Access
27 Citations
6,608 Views
22 Pages

20 April 2021

In recent years, due to the impact of global warming, environmental pollution, and the energy crisis, international attention and demand for clean energy are increasing. Hydrogen energy is recognized as one of the clean energy sources. Water is consi...

  • Article
  • Open Access
9 Citations
6,043 Views
12 Pages

Mechanism of Guaiacol Hydrodeoxygenation on Cu (111): Insights from Density Functional Theory Studies

  • Destiny Konadu,
  • Caroline Rosemyya Kwawu,
  • Richard Tia,
  • Evans Adei and
  • Nora Henriette de Leeuw

20 April 2021

Understanding the mechanism of the catalytic upgrade of bio-oils via the process of hydrodeoxygenation (HDO) is desirable to produce targeted oxygen-deficient bio-fuels. We have used calculations based on the density functional theory to investigate...

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Catalysts - ISSN 2073-4344Creative Common CC BY license