3.1. Battery Model
In the literature, various battery models exist for simulating the electrical characteristics of batteries [
31,
32,
33,
34,
35,
36,
37,
38,
39]. Within the concept phase of vehicle development based on the V-Model methodology, the main goal of a battery model is its ability to simulate, at minimum, all defined metrics. In other words, the model should only incorporate a minimum number of parameters necessary to simulate the metrics defined in
Section 2.1. It is standard practice to use electrical equivalent circuit models (ECMs). The basic model considers an OCV with an internal resistance in series at a minimum, cf. [
33,
36,
40]. Resistor-capacitor circuit elements (RC) can be added to simulate the dynamic behavior of the battery [
33,
35,
36,
40]. Other elements can be added in order to simulate the battery more precisely, cf. [
33,
36]. However, these additions also need more effort for parameterization. Therefore, the basic model serves as a starting point for this paper and is extended if required.
The basic model is displayed in
Figure 4. Here, the OCV is
and the voltage over the resistor is
.
equals the battery’s internal resistance. The battery voltage
is given by Equation (1) and the battery current by Equation (2). The charged or discharged power
POCV is calculated by Equation (3) and the terminal power
Pbat by Equation (4):
The characteristics of batteries are typically dependent on SOC and temperature [
41,
42]. Both the OCV and the internal resistance can be modeled dependent on SOC and temperature. However, as demonstrated in other publications, for example [
42,
43], it has been determined that the internal resistance is not significantly SOC dependent. Therefore, the following paragraph will analyze which dependencies must be added to the basic battery model based on vehicle and battery measurements. As none of the defined metrics listed in
Table 1 exceed 80% or fall below 10% SOC, the relevant SOC range is predefined between 10 and 80%. The relevant temperature range is assumed to be −7 to 23 °C, as outlined in [
22], which defines both metrics:
residual acceleration and
residual acceleration at −7 °C.
The OCV is first analyzed.
Figure 5 presents the OCV maps for each battery listed in
Table 6, showing their dependency on SOC and temperature. These maps were gathered from a validated simulation model, which was parameterized based on the cell data provided by the respective battery suppliers. The model consists of an ohmic resistance with three RC elements connected in series, as previously applied in [
39,
44], and serves as the reference for this analysis. The voltage of the OCV maps is normalized to their upper cut-off voltage. The operating points for the three metrics of residual acceleration are also shown.
It can be seen that the gradient of the normalized OCV in the SOC direction is qualitatively higher than in direction of temperature
T. However, Equation (7) is used for a quantitative evaluation in both directions for all three metrics of residual acceleration. In order to compare both directions equally, both gradient maps are normalized using the minimum and maximum value of SOC and temperature between 0 and 1. The normalizations are
, Equation (5), and
, Equation (6).
Table 7 shows the results of the gradient evaluation in the direction of SOC in volts per normalized SOC, and
Table 8 in the direction of temperature in volts per normalized temperature. It can be seen that the absolute values of the gradient in the direction of temperature are significantly smaller compared to the absolute values of the gradient in direction of SOC, being on average 163 times lower for both NMC batteries and 56 times lower for both LFP batteries. Therefore, the OCV will be modeled as SOC-dependent only. A comparison of OCV on battery system level between 23 °C and −7 °C using the test bench of
Section 2.4 and battery 1 from
Table 6 can be found in
Appendix A.1, which underlines this conclusion. It is noteworthy that, for both NMC batteries, the gradient in direction of SOC is higher than for the two LFP batteries. The reason for this is that LFP batteries show, in general, a lower OCV increase dependent on SOC, cf. [
45,
46,
47].
Another simplification can be made if it is assumed that, in the context of the battery design, only the range from 10 to 80% SOC is relevant. This assumption is underlined by the metrics defined in
Table 1. As a result, the OCV is linearized by Equation (8). Here, the linear factor
k in
is introduced. The theoretical voltage at 0% SOC is
.
Figure 6 shows the comparison between the measured/simulated OCV (solid lines) alongside their linear approximations (dashed lines) for all four batteries.
Table 9 provides a quantitative comparison between the actual and approximated values. Three evaluation criteria were used:
Pearson correlation coefficient R;
Mean relative error (MRE);
Root-mean-square error (RMSE).
Table 9 demonstrates that the linear approximation yields accurate results, particularly for the two NMC batteries (battery 1 and 2), with correlation coefficients of 0.995 and 0.998, respectively. Even for the LFP batteries (battery 3 and 4), the correlation remains above 0.92, indicating that the linear model is suitable across different chemistries. The MRE is below 0.5% for all batteries, with the LFP batteries showing intermediate values between the two NMC batteries. In relation to the nominal voltage of 3.7 V for battery 1 shown in
Table 6, the RMSE is low, reaching only 0.019 V for battery 1. These result confirm that the linear approach provides sufficient accuracy and can be reliably used within the proposed design methodology. As mentioned above and calculated in
Table 7, LFP batteries show a lower SOC gradient than NMC batteries. Based on the similar error values for all batteries shown in
Table 9 combined with the SOC-limitation between 10 and 80%, no higher error rates are expected for LFP compared to NMC.
Second, the battery’s internal resistance
Ri is analyzed. This is conducted in a similar manner as for OCV.
Figure 7 shows the normalized internal resistance for the batteries of
Table 6, dependent on SOC and temperature. Similarly to OCV, these maps were gathered from a validated simulation model, which was parameterized based on the cell data provided by the respective supplier. The model consists of an ohmic resistance with three RC elements connected in series as previously applied in [
39,
44], and serves as the reference for this analysis. The normalization is performed by using the maximum resistance. Battery dynamics or a differentiation for charging and discharging is not considered here. In
Figure 7, the sum of the ohmic resistance and the three resistors of the RC elements was used. The operating points for the three metrics of residual acceleration are also shown.
It is obvious that the temperature influences
Ri qualitatively more than the SOC (
Figure 7). To analyze this assumption quantitatively, a similar evaluation as for OCV shall be made by using the normalized gradient in both directions. Equations (5) and (6) apply to this evaluation as well. However, as the internal resistance is evaluated, the normalized gradient calculation must be adapted for it, which is shown in Equation (9).
Based on the gradient evaluations in
Table 10 and
Table 11, the metric
residual acceleration at −7 °C exhibits the highest absolute gradient values in the temperature direction across all batteries. For example, battery 3 shows an absolute gradient of 33.886 mΩ/-, which is significantly higher than any other value in both tables. In contrast, the corresponding absolute gradient in the SOC direction for the same metric is only 0.616 mΩ/-, highlighting a pronounced directional difference. The pattern is consistent across all batteries: the gradient in direction of temperature for
residual acceleration at −7 °C is at least nine times higher than the SOC gradient, with battery 3 showing a factor of 55. When comparing the gradients of
residual acceleration and
residual acceleration at 10%, the gradients in both directions for each of the metrics do not show such a contrast. This indicates that the influence of SOC on internal resistance is less significant and cannot be clearly distinguished based on gradient behavior for all batteries. Nevertheless, the internal resistance is also dependent on SOC as the gradient in direction of SOC for the metric
residual acceleration at 10% shows which can result in deviations for low SOC values. In conclusion, the temperature, particularly at −7 °C, has the strongest impact on the internal resistance, making
residual acceleration at −7 °C the most sensitive metric. Therefore, the dependency of SOC on resistance is reasonably neglected in the context of the design method. This conclusion is consistent with the results reported in [
42,
43]. However, as temperature variation was excluded from this publication in the Introduction, a temperature-dependent internal resistance is not further analyzed here.
In order to consider the metrics
range,
energy consumption,
DC charging time from 10 to 80% SOC, and
max. recharged range in 10 min, the SOC has to be calculated using
POCV, Equation (10). In this instance, the maximum battery energy
EBat,Max in Ws is used, which can be calculated using the defined range
r in km and the defined energy consumption
η in
, Equation (11). By solving Equation (10) for
dt, the charging time
tch can be calculated using its integral from
SOC1 to final
SOC2, Equation (12). Lastly, the maximal recharged range
rrech in
is used to determine a maximal charging power
PCh,Max in W, Equation (13). In combination with the metric
residual charging power at 80% SOC, a charging curve can be derived based on the charging methods presented in
Section 2.3:
With the presented model, all defined metrics for the concept phase in the context of longitudinal dynamics, range, and charging are considered. Therefore, no further model enhancements are needed at this point.
3.2. Proposed Design Method
Basis for the design method is the model deduced in
Section 3.1. The first step is to calculate the maximum energy content of the battery using Equation (11) and the metrics ID 2.1 and 2.2. The maximum energy content will be the usable net energy analogous to the SOC definition. The maximal charging power using Equation (13) and the metrics ID 2.2 and 3.2 can also be calculated.
The next step in the process is to incorporate the battery model and the operating points, which have been defined by the metrics. The main goal here is to determine values for Ri, k, , and Iconst (CC-CV) or Pconst (CP-CV), respectively. The three operating points are as follows:
ID 1.1: Residual acceleration;
ID 1.2: Residual acceleration at 10% SOC;
ID 3.3: Residual charging power at 80% SOC.
Current and voltage can be determined for each operating point. For IDs 1.1 and 1.2, either a measurement, for instance
Table 3, or a backward-calculating longitudinal dynamics model can be used. Using a simulation model is especially useful in the early concept development; this is previewed in [
14] and will be presented in a future publication. Current and voltage for ID 1.1 are
IID1.1 and
UID1.1 and for ID 1.2 are
IID1.2 and
UID1.2. ID 1.2 is always defined at 10% SOC. Usually, ID 1.1 is defined at 80% SOC; however, it can also be defined at other SOC values, given that the 80% definition is rather regarded as a “worst case” design. This SOC value is
SOCID1.1. For the third operating point ID 3.3
P80, it is assumed that the constant voltage
Uconst is valid. Therefore, the current at this point can be calculated as follows:
It should be noted that, for VCP, the current at this point is given by the profile. Therefore, ID 3.3 is needed only for CC-CV or CP-CV. For CC, the constant current is calculated by
Using CP, power is constant; therefore,
Pconst equals
PCh,Max. If VCP is used, neither current nor power have to be constant, because current is given by the profile. Using Equations (1), (2) and (8), a system of three linear equations in the form
is deployed, which can be solved for
,
k and
Ri:
The parameterization process is shown in
Figure 8 by using an example. As demonstrated in
Section 3.1, the internal resistance, which is the slope of each line, remains equal for all operating points. First, ID 1.1
residual acceleration is considered at its defined SOC (1. in
Figure 8). Second, ID 3.3
residual charging power at 80% SOC defines another line with the same slope and adding the constant voltage
Uconst (2. in
Figure 8). Third, ID 1.2
residual acceleration at 10% SOC is considered as the third line, adding the theoretical voltage at 0% SOC
(3. in
Figure 8). The displacement in voltage is considered by the linear factor
k. Equation (16) can also be interpreted as a plane in three-dimensional space, as shown in 4. in
Figure 8.
The last step is to consider the charging time, ID 3.1, using Equation (12) in order to achieve the desired constant voltage
Uconst in the CV phase. In this case,
POCV(
SOC) depends on the chosen charging method (
Section 2.2). Equations (17)–(19) show the charging time calculations split in CC (
tCC), CV (
tCV), and CP (
tCP). The constant current in Equation (17) is
Iconst, the constant voltage in Equation (18) is
Uconst, and the constant power in Equation (19) is
Pconst. The detailed derivation of the equations can be found in
Appendix A.2 (CC), 3 (CV), and 4 (CP).
In Equations (17)–(19),
SOCx is the transition from CC or CP to CV. For CC-CV, the value is determined by the intersection between CC and CV:
For CP-CV, the value is determined by the intersection between CP and CV:
Finally, the complete charging times can be determined by adding the particular charging times:
For VCP, the defined current profile
IVCP(
SOC) can directly be used for Equation (12):
As all of the methods cannot be solved for
Uconst and Equations (17)–(19) and (26) are non-linear, a non-linear root-finding algorithm, e.g., Newton’s method or False-position method [
48,
49], is used to find the desired value for
Uconst.
3.3. Validation
Firstly, this section compares the method with the existing vehicle measurement, shown in
Figure 2. The method used mean measured operating points for the longitudinal dynamics metrics, as measured in
Table 2, are presented in
Table 3. The remaining measured metrics are listed in
Table 4 for range and
Table 5 for charging. All of these metrics and their operating points are inserted into the model in order to apply the design method, in this case the one using VCP. The simulation’s VCP is equivalent to the measured current. The result of this DC charging maneuver in comparison to the measurement can be seen in
Figure 9.
It is obvious that the current (
Figure 9 right) is almost identical, as it is predefined. However, voltage differs from the measurement, especially below 40% SOC (
Figure 9 middle). Consequently, the terminal power also differs below 45% SOC (
Figure 9 left). The underlying cause of this is that neither battery dynamics nor the SOC dependency of the internal resistance at low SOC levels are modeled. This tradeoff has already been mentioned in
Section 3.1. However, if one compares time-dependent measurements and simulations quantitatively using
R, MRE, and RMSE (
Table 12), it can be seen that this method achieves a good first estimation for DC charging in the concept phase.
R is close to 1 for current, voltage, and power, indicating a high correlation between measurement and simulation. The MRE remains below 1.1% for all parameters, with the lowest deviation observed for current and slightly higher values for voltage and power. These low error rates confirm the reliability of the simulation in capturing the key characteristics of the charging process. Lastly, the RMSE values are within acceptable ranges for early-phase estimations when compared to the maximal values shown in
Figure 9.
Secondly, both CC-CV and CP-CV are used to design a virtual battery. The resulting parameters are validated. However, during the publication’s creation process, it was impossible to create an entirely new battery for validation. Therefore, battery 1 of
Table 6 served as the target design, as it was available for measurement and validation. The first step is to find a solution for the battery parameters using CC-CV and CP-CV, respectively, that matches with the parameters identified by the DC charging maneuver from
Figure 9. This is achieved by using an optimization algorithm. In the second step, the identified current profiles are applied to the battery test bench, prescribed as input current. In the final step, the measured data is compared to the simulation results for each charging method. These comparisons are illustrated in
Figure 10 and
Figure 11. It should be noted that the metric
DC charging time from 10 to 80% does not match the value shown in
Table 5. The reason for this is that the value in
Table 5 would require a current profile exceeding 400 A, which surpasses the maximum current limit of the test bench, as specified in
Section 2.4. Therefore, this metric was adjusted to 21.7 min to comply with the test bench limitations. This adjustment does not affect the validity of the comparison between the measurement and simulation. It should be noted that another unavoidable effect is evident in the measurement, especially with regard to the voltage. At about 41% and 54% SOC, the charging process had to be stopped for cooling because the battery reached its maximum temperature. Otherwise, the BMS would throw an error and open the main switch. The cooling sections are excluded from the diagrams. In this case, the battery’s environment and the battery itself were initially conditioned at 23 °C by the TMS. However, during the charging process, the cooling liquid was set to 15 °C to delay the reaching of the battery’s maximum temperature. Regarding OCV or internal resistance, the cooling has almost no influence, as both do not vary significantly above 23 °C in combination with
SOC ≥ 45%, cf.
Figure 5 and
Figure 7 in combination with
Figure 10 and
Figure 11. However, it can be seen that, for both CC-CV and CP-CV charging, the dynamics have an influence on the voltage, especially below 45% SOC, where the internal resistance varies additionally.
Compared to VCP, CC-CV and CP-CV measurements indicate better values for
R, MRE, and RMSE, as demonstrated in
Table 13 and
Table 14, respectively, for the time-dependent values. As with VCP, for both CC-CV and CP-CV current was predefined and, hence, it correlates with
R = 1. Voltage achieves a value for
R only near to 1 because of the unconsidered effects of internal resistance dependency at low SOC. This is also reflected in a worse MRE for the voltage compared to the current. However, compared to the absolute maximum values, the RMSE is low for power, voltage, and current. In conclusion, all of the analyzed charging methods, VCP, CC-CV, and CP-CV, show a high reliability for early-phase estimations. Especially in the concept phase, where precise real-world data may not yet be available, these results demonstrate that the method provides a robust first approximation.