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16 December 2025

Deposition and Properties of Nanostructured Multilayer Cr/(Cr/a-C)ml Coating on Stainless Steels

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1
Department of Material Science and Technology of Materials, Faculty of Industrial Technology, Technical University of Sofia, 1756 Sofia, Bulgaria
2
Department of Theory of Mechanisms and Machines, Faculty of Industrial Technology, Technical University of Sofia, 1756 Sofia, Bulgaria
3
Department of Mechanical Engineering, Manufacturing Engineering and Thermal Engineering, Faculty of Engineering and Pedagogy—Branch Sliven, Technical University of Sofia, 8800 Sliven, Bulgaria
4
Faculty of Industrial Technology, Technical University of Sofia, 1756 Sofia, Bulgaria
Materials2025, 18(24), 5654;https://doi.org/10.3390/ma18245654 
(registering DOI)
This article belongs to the Special Issue Micro/Nano-Structured Material Surfaces and Their Functional Coatings

Abstract

This work presents the results of deposition by magnetron sputtering nanostructured multilayer Cr/(Cr/a-C)ml coatings on AISI 316L and AISI 321 steel substrates. Chemical compositions were confirmed through EDX analysis with scanning electron microscopy. The coating thickness was measured with Calotester (KaloMAX II) and the total thickness of the coatings obtained ranged from 1.684 ± 0.193 μm for AISI 316L to 1.749 ± 0.123 μm for AISI 321. A Daimler-Benz Rockwell indentation test for adhesion quality and a nanoindentation test with a Berkovich indenter were carried out. According to the Raman spectroscopy analysis and in agreement with mechanical tests, it is supposed that it is the formation of a diamond-like carbon phase which enhances the mechanical properties. The hardness values obtained for the nanostructured multilayer Cr/(Cr/a-C)ml coatings were improved compared to those of the base stainless steels.

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