1. Introduction
Dilatancy is a phenomenon that occurs in all geomaterials, characterized by a change in volume during shear deformation. In addition to the type of geomaterial and its structure [
1,
2,
3], dilatancy depends on the stress level, stress and strain history [
4,
5,
6], shear deformation mode [
7,
8], water content [
9,
10,
11], stress path [
12,
13], and grain shape [
14]. The minimum value of dilatancy for sands and over-consolidated remolded clay represents the maximum stress ratio (failure) state [
15,
16,
17]. However, for some geomaterials, such as artificially and naturally cemented soils, a lack of coexistence between the minimum dilatancy and failure states (FSs) has been observed [
2,
12,
18].
Various relationships between the stress ratio and plastic dilatancy have been proposed (e.g., [
19,
20,
21,
22]). The stress ratio–plastic dilatancy relationship is a crucial component of classical elastoplastic models of geomaterials [
19,
21,
23]. In these models, the relationship between the stress ratio and plastic dilatancy usually determines the plastic potential function [
24]. The phase transformation state, defined as the state in which the soil behavior changes from contraction to dilation [
25,
26], is another characteristic state of soil that can be identified from the relationship between stress ratio and dilatancy.
Based on dissipated energy balance considerations, a linear stress ratio–plastic dilatancy relationship has previously been obtained [
26]. That relationship is defined by the critical frictional state angle (
), stress path, and two (
,
) parameters of the frictional state concept (FSC). For drained triaxial compression, a stress ratio–plastic dilatancy relationship with constant parameter values
α and
β can be used to approximate the behavior of soil during different stages of shearing [
26].
In this study, published drained triaxial compression test data for various geomaterials are analyzed to obtain the stress ratio–plastic dilatancy relationship at the current state of shearing. This relationship is represented as a curve in the plane. A methodology for calculating the slope of the tangent (A) and the curvature (ϰ) at any point on this curve is presented. The state corresponding to the local maximum curvature closest to the failure state (FS) is called the dilatational failure state (DFS). A straight line approximating the DFS is called the dilatant failure state line (DFSL). The intersection point of this line with the vertical axis of the plane determines the critical frictional angle of the analyzed geomaterials.
2. General Stress Ratio–Plastic Dilatancy Relationship
The general stress ratio–plastic dilatancy relationship has the form [
26]
where
is the critical frictional state angle,
is the Lode angle for stress,
and
are the FSC parameters, and
and
are the elastic bulk and shear modulus, respectively [
26]. The elastic parameters are calculated using the following equations:
or
where
is the parameter of the geomaterial,
is the parameter of a Cam–Clay model,
is Poisson’s ratio,
is the void ratio, and
= 101 kPa is the atmospheric pressure.
For conventional drained triaxial compression,
=
=
,
= 3 [
27], and:
The same relationships are assumed for drained triaxial compression with stress path.
Figure 1 shows the relationships
and
for a conventional drained triaxial compression test conducted by Michalowski and Čermák [
28] on sand with 2% fibers at
100 kPa.
The
relationship for this test is shown in
Figure 1. A tangent line can be calculated at any non-singular point
M (
Figure 1) of the
relationship curve. The slope of this tangent line to the horizontal axis is [
29]:
The tangent line intersects the vertical axis at the point
(
Figure 1c). Hence, the parameters
(Equation (3)) and
(Equation (4)) of the stress ratio–plastic dilatancy relationship (Equation (1)) have a simple geometric interpretation.
3. Curvature of the Stress Ratio–Plastic Dilatancy Relationship Curve
At any non-singular point (
M) of the stress ratio–plastic dilatancy relationship curve (
Figure 2), an absolute curvature can be calculated as follows [
29]:
To calculate the slope (
) and curvature (
), it is convenient to segmentally approximate the stress ratio (
) and plastic dilatancy (
) using analytical functions (e.g., polynomials) of
, as follows:
The state of shear deformation in which the increment of plastic dilatancy changes from positive to negative is called the
plastic dilatancy increment transitional state (PDITS). In the PDITS, we have:
The slope of the tangent line and the curvature of the stress ratio–plastic dilatancy relationship curve cannot be calculated using Equations (35) and (36), respectively. The PDITS corresponds to the minimum plastic dilatancy state for the dilative behavior of the geomaterial during shear. The denominator of Equations (35) and (36) is also equal to zero in the state of shear deformation with constant plastic dilatancy, constant (). This state is called the constant plastic dilatancy state (CPDS). In the near pre- and post-PDITS states, as well as at the onset of the CPDS state, the values of are minimal, while the and () values are very large.
In this paper, we do not consider cases involving shear deformation with constant stress ratio and zero plastic dilatancy, where the nominator and denominator of Equations (35) and (36) have zero values and the slope and curvature of the relationship curve are not defined.
The asymptotic states, the critical state for loose granular materials and normally consolidated clays, and the steady states are the failure states for which the nominator and denominator of Equations (35) and (36) are equal to zero, may but don’t have to be dilatant failure states.
4. Methodology
Selected results of drained triaxial compression tests of some geomaterials presented in the literature are digitized and analyzed. Based on these digitized values of stresses and volumetric strains as a function of strain, the relationships , and were calculated.
The obtained and relationships were approximated segmentally using polynomials. Based on the authors’ experience, more accurate locations of the points representing the dilatant failure state in the , , , and planes were obtained without directly analyzing the relationship, but by analyzing the and relationships using Equations (35) and (36). To avoid overfitting, the experimental and relationships were approximated segmentally using polynomials of degree up to 5 or 6. If the approximation accuracy was insufficient, the number of segments was increased. In each segment, the approximation accuracy was determined in a conventional manner. Special attention was paid to the continuity in the and values, as well as their increments and at the contact points between adjacent segments. The values of the tangent line slope (), and curvature () of the curve of stress ratio–plastic dilatancy at any non-singular points were then calculated.
As an example, the obtained relationship in the planes
,
,
,
, and
for a conventional drained triaxial compression test on Toyoura sand, performed by Miura and Yamanouchi [
30], as shown in
Figure 3.
The maximum local curvatures of the
relationship were determined and marked on the
curve (
Figure 3f). The points corresponding to the local maximum curvature and failure state are shown in
Figure 3.
5. Dilatant Failure State
The DFS is the state in which the local maximum curvature is closest to the failure state (FS). The DFS and FS are marked in
Figure 3 as points F and F*, respectively. The DFS closest to FS does not always mean close, especially on the
,
,
,
, and
planes (
Figure 3).
In this paper, the results of selected drained triaxial compression tests were analyzed, and the DFSs were determined. The DFSL is described by the general stress ratio–plastic dilatancy relationship in Equation (1) as
where
where
,
are the stress ratio and plastic dilatancy at the DFS, respectively. The parameters
and
are FSC parameters describing the DFSL. Equation (26) defines
independently of the stress path.
In each analysis, it was assumed that
0. Hence,
, and the critical frictional state angle (
) can be calculated from the equation
In the FSC [
27],
is independent of deformation mode (Lode angle). To finally prove the correctness of the obtained
values, triaxial extension tests should be performed, and the resulting data should be analyzed in a similar way.
6. Dilatant Failure States in Drained Triaxial Compression Tests of Some Geomaterials
6.1. Toyoura Sand
Fine-grained quartz Toyoura sand has been extensively tested in geotechnical laboratories. Data from five conventional drained triaxial compression tests selected from the literature were analyzed in this work, comprising. Three tests at low and medium stress levels, conducted by Sun et al. [
31], and two tests at high stress levels, conducted by Miura and Yamanouchi [
30]. According to the methodology presented above, with the initial and elastic parameters shown in
Table A1, the relationships
,
,
,
, and
were obtained as shown in
Figure 4.
Points F and F* represent the DFS and FS, respectively, and are marked on the graph. DFSs slightly precede FSs for the dilative behavior during shear, whereas for tests performed at medium and high stress levels, which exhibit contractive behavior, DFSs significantly precede FSs (
Figure 4).
The DFSL closely approximates points representing DFSs on the
plane (
Figure 4c and
Figure 5). This DFSL intersects the vertical axis at the point
1.331 (
,
0) with slope
(
1.0). This means that the possible presence of grain crushing during drained triaxial compression shearing at high stress levels does not affect the slope and location of the DFS and
[
30,
31].
6.2. Crushed Concrete
As a popular anthropogenic soil, crushed concrete was conventionally triaxially compressed under drained conditions [
32]. Grains of crushed concrete are very sharp-edged. As a result, high stresses occur at the grain contact points, and the material is susceptible to crushing even at low stress levels. Data from five tests were analyzed using the elastic and initial state parameters shown in
Table A1. The results of the analysis are shown in
Figure 6.
Dilative behavior was observed in all the tests, and the maximum values of
and
correspond to the minimum plastic dilatancy states. For
45 and 90 kPa, DFS precedes FS, whereas for
200 and 400 kPa, FS precedes DFS, and for
270 kPa, DFS and FS are the same states. The DFSL, the best fitting DFS in the
plane, intersects the vertical axis at
1.532 with slope is
0.886 (
Figure 6c). Assuming
= 0 (
), we have
= 37.6° and
1.812.
> 1, or more precisely (
) > 0, quantifies the influence of grain crushing dissipation energy on the relationship
[
26].
6.3. Dog’s Bay Sand
Dog’s Bay sand is a biogenic carbonate sand, essentially consisting of foraminifera and Mollusca shells [
33]. Dog’s Bay sand grains are easily crushed. Coop [
33] extensively tested this sand. Drained and undrained triaxial compression tests on isotropically and
consolidated samples were performed. In the present work, three test results were selected for analysis: two drained triaxial compression tests conducted at constant mean effective stresses of
100 and 3286 kPa, and one conventional drained triaxial compression test performed at a constant
4020 kPa. The elastic and initial state parameters are shown in
Table A1. The analysis results are presented in
Figure 7.
The test at a constant mean stress
100 kPa exhibits dilative behavior, while the other two tests at high stress levels exhibit contractive behavior. In all of the tests, DFS significantly precedes FS (
Figure 7). DFSL intersects the vertical axis at
1.748 with slope
0.984 (
Figure 7c). Assuming that
0, we have
1.748. The critical frictional state angle
42.6° is greater than
40.3° [
33,
34]. The FSC parameter
2.36 (
Figure 7c). DFSL closely approximates the DFSs for tests at different stress levels and stress paths. In the case of dilative behavior, DFS corresponds to a state with minimum plastic dilatancy.
6.4. Cemented Portaway Sand
Marri [
35] tested Portaway sand with different values of the cement content. Four conventional drained triaxial compression test results with 5% of cement content were selected for analysis here. The calculation results are shown in
Figure 8 and
Table A1.
Dilative behavior is observed at a confining pressure of
1 MPa. Three tests performed at confining pressures of
4, 8, and 12 MPa exhibit contractive behavior, and FS precedes DFS for tests at confining pressures of
1 and 4 MPa (
Figure 8). In these tests, DFSs were observed at significant shear strains. The DFS and FS are equivalent for the test at a confining pressure of
8 MPa, whereas for the test at a confining pressure of
12 MPa, DFS significantly precedes the FS (
Figure 8). The points marked
represent the onset of a constant dilatant state (CDS) for which the slope (A) and curvature (ϰ) of the
curve cannot be calculated. DFSL closely approximates the DFSs, intersecting the vertical axis at
1.449 with slope
0.837 (
Figure 8c). Assuming
0,
1.449 corresponds to the critical frictional state angle
35.7°, the slope of the FSL
0.517 and
1.619. The value (
) = 0.619 > 0 represents the influence of debonding on the relationship for DFSs for Portaway cemented sand with 5% cement. The correctness of the parameters obtained for the FSC (
,
,
) of cemented sand should be verified by triaxial extension tests and an analog analysis of the results.
7. Conclusions
- (1)
The methodology presented here for determining DFS, based on the results of a drained triaxial compression test, is effective but time-consuming.
- (2)
For dilative behavior, the DFS corresponds to the state of minimum plastic dilatancy. For contractive behavior, the DFS must be determined using the calculation procedure introduced in this work.
- (3)
The distance between DFS and FS is not always small, especially in the case of contractive behavior.
- (4)
The DFS is essential for describing the behavior of geomaterials during shear.
- (5)
A value ( − 1) > 0 represents the effect of grain crushing or debonding at the DFS.
- (6)
DFSL and FSL are equivalent when there are no crushing and debonding effects.
- (7)
According to the FSC, the critical frictional state angle is independent of the deformation mode. Hence, the FSC parameters obtained from triaxial compression tests should be verified through triaxial extension tests, especially for bonded geomaterials.
Author Contributions
Conceptualization, Z.S. and W.S.; methodology, K.D.-S.; software, K.D.-S. and K.G.; validation, K.D.-S. and K.G.; formal analysis, K.D.-S. and Z.S.; investigation, K.G. and W.S.; writing—original draft preparation, K.D.-S. and K.G.; writing—review and editing, Z.S. and W.S.; visualization, K.D.-S. and K.G.; supervision, Z.S. and W.S. All authors have read and agreed to the published version of the manuscript.
Funding
This research was funded by the Ministry of Science and Education, Poland (Grant no. WZ/WB-IIL/2/2025) and through the Statutory Funds of Warsaw University of Life Sciences–SGGW, Poland.
Institutional Review Board Statement
Not applicable.
Informed Consent Statement
Not applicable.
Data Availability Statement
The original contributions presented in this study are included in the article. You can contact the corresponding authors if you have any other questions.
Acknowledgments
The investigations were conducted at the Bialystok University of Technology and at the Warsaw University of Life Sciences in Poland.
Conflicts of Interest
The authors declare no conflicts of interest.
Appendix A
Table A1.
Parameters for the dilatant failure and failure states.
Table A1.
Parameters for the dilatant failure and failure states.
|
Geo-Material
|
Reference
|
Initial Conditions
| DFS | FS | Elastic Parameters |
|---|
| | | | | | | | | | | | |
κ
|
ν
|
|---|
|
-
|
kPa
|
kPa
|
-
|
-
|
-
|
-
|
-
|
%
|
-
|
-
|
%
|
MPa
|
-
|
-
|
|---|
Toyoura sand | Sun et al. (2007) [31] | 0.680 | 200 | - | 1.331 | 0 | 1.000 | 1.614 | −0.543 | 6.70 | 1.620 | −0.541 | 6.10 | 25.0 | - | 0.3 |
| 0.665 | 1000 | - | 1.526 | −0.361 | 10.04 | 1.527 | −0.348 | 11.7 |
| 0.644 | 4000 | - | 1.317 | 0.058 | 12.00 | 1.317 | 0.052 | 12.6 |
Miura & Yamanouchi (1975) [30] | 0.564 | 7500 | - | 1.281 | 0.124 | 17.10 | 1.285 | 0.108 | 26.1 |
| 0.526 | 20,000 | - | 1.284 | 0.170 | 25.90 | 1.315 | 0.152 | 30.0 |
Crushed concrete | Gabryś et al. (2023) [32] | 0.572 | 45 | - | 1.532 | 0 | 1.812 | 2.106 | −0.633 | 1.91 | 2.106 | −0.628 | 2.23 | 26.5 | - | 0.15 |
| 0.570 | 90 | - | 1.957 | −0.478 | 2.06 | 1.958 | −0.466 | 2.35 |
| 0.491 | 200 | - | 1.629 | −0.145 | 8.15 | 1.629 | −0.145 | 8.15 |
| 0.564 | 270 | - | 1.790 | −0.300 | 5.44 | 1.794 | −0.308 | 4.89 |
| 0.513 | 400 | - | 1.598 | −0.083 | 10.29 | 1.599 | −0.077 | 9.26 |
Dog’s Bay sand | Luzzani & Coop (2002) [34] | 1.584 | - | 100 | 1.748 | 0 | 2.36 | 2.054 | −0.289 | 7.01 | 2.093 | −0.213 | 13.0 | - | 0.0075 | 0.3 |
| 1.075 | - | 3286 | 1.586 | 0.120 | 36.0 | 1.607 | 0.070 | 44.0 |
| 0.991 | 4020 | - | 1.388 | 0.429 | 28.0 | 1.477 | 0.292 | 32.0 |
Cemented Portaway sand | Marri (2010) [35] | 0.500 | 1000 | - | 1.449 | 0 | 1.619 | 1.733 | −0.317 | 6.60 | 1.739 | −0.297 | 4.99 | 40.0 | - | 0.35 |
| 0.480 | 4000 | - | 1.403 | 0.041 | 11.12 | 1.406 | 0.043 | 10.13 |
| 0.470 | 8000 | - | 1.346 | 0.114 | 17.34 | 1.346 | 0.114 | 17.34 |
| 0.450 | 12,000 | - | 1.279 | 0.243 | 16.28 | 1.307 | 0.140 | 22.83 |
References
- Gasparre, A.; Nishimura, S.; Coop, M.R.; Jardine, R.J. The influence of structure on the behaviour of London clay. Géotechnique 2007, 57, 19–31. [Google Scholar] [CrossRef]
- Porcino, D.D.; Marciano, V. Bonding degradation and stress-dilatancy response of weakly cemented sand. Geomech. Geoengin. 2017, 12, 221–233. [Google Scholar] [CrossRef]
- Gu, J.; Lyu, H.; Yang, J.; Zeng, C. Effects of cement content and curing period on geotechnical properties of cement-treated calcareous sands. Transp. Geotech. 2022, 33, 100732. [Google Scholar] [CrossRef]
- Gao, Z.; Zhao, J.; Yin, Z.-Y. Dilatancy relation for overconsolidated clay. Int. J. Geomech. 2016, 17, 06016035. [Google Scholar] [CrossRef]
- Casey, B.; Germaine, J.T.; Reynolds, R.T. The strength behavior of resedimented Presumpscot clay and a comparison with intact behavior. In 2nd Symp. on the Presumpscot Formation: Advances in Geotechnical, Geologic, and Construction Practice; Landon, M.E., Nickerson, C., Eds.; University of Maine: Portland, ME, USA, 2015. [Google Scholar]
- Wan, Z.; Yao, Y.P.; Gao, Z.W. Comparison study of constitutive models for overconsolidated clays. Acta Mech. Solida Sin. 2020, 33, 98–120. [Google Scholar] [CrossRef]
- Rowe, P.W. The relation between the shear strength of sands in triaxial compression, plane strain, and direct shear. Géotechnique 1969, 19, 75–86. [Google Scholar] [CrossRef]
- Bolton, M.D. The strength and dilatancy of sands. Géotechnique 1986, 36, 65–78. [Google Scholar] [CrossRef]
- Xu, X.; Cai, G.; Song, Z.; Li, J.; Xu, C.; Wang, H.; Zhao, C. Dilatancy characteristics and constitutive modelling of the unsaturated soil based on changes in the mass water content. Appl. Sci. 2021, 11, 4859. [Google Scholar] [CrossRef]
- Cai, G.; Han, B.; Asreazad, S.; Liu, C.; Zhou, A.; Li, J.; Zhao, C. Experimental study on critical state behaviour of unsaturated silty sand under constant matric suctions. Géotechnique 2024, 74, 409–430. [Google Scholar] [CrossRef]
- Chen, K.; He, X.; Liang, F.; Sheng, D. Strength and dilatancy of an unsaturated expansive soil at high suction levels. J. Rock Mech. Geotech. Eng. 2025, 17, 5079–5088. [Google Scholar] [CrossRef]
- Kandasami, R.K.; Singh, S.; Murthy, T.G. Experimental investigations of the stress path dependence of weakly cemented sand. J. Geotech. Geoenviron. Eng. 2021, 147, 04021007. [Google Scholar] [CrossRef]
- Zhang, D.; Luo, F.; Zhu, Z.; Liu, J.; Li, J.; Li, B.; Xue, T. Study on mechanical properties of gravely sand under different stress path. Adv. Civ. Eng. 2021, 2021, 8898814. [Google Scholar] [CrossRef]
- Arda, C.; Cinicioglu, O. Influence of grain shape on stress-dilatancy parameters. Granul. Matter 2021, 23, 22. [Google Scholar] [CrossRef]
- Bishop, A.W. Shear strength parameters for undisturbed and remolded soil specimens. In Proceedings of the Roscoe Memorial Symposium, Cambridge, UK, 29–31 March 1971; pp. 3–58. [Google Scholar]
- Ghafghazi, M.; Shuttle, D. Accurate determination of the critical state friction angle from triaxial tests. In Sea and Sky Géotechnique 2006, Proceedings of the 59th Canadian Geotechnical Conference, Vancouver, BC, Canada, 1–4 October 2006; X-CD Technologies Incorporated: San Francisco, CA, USA, 2006. [Google Scholar]
- Castonguay, V. Analyzing dilatancy from triaxial compression tests: How to get more out of a simple test’s data. In Proceedings of the 7th International Young Geotechnical Engineers Conference, Sydney, Australia, 29 April–1 May 2022; Scott, B., Ed.; Australian Geomechanics Society: Sydney, Australia, 2022; pp. 525–530. Available online: https://www.issmge.org/uploads/publications/48/118/7iYGEC_Castonguay.pdf (accessed on 4 September 2025).
- Wang, L.; Chu, J.; Wu, S.; Wang, H. Stress dilatancy behaviour of cemented sand: Comparison between bonding provided by cement and biocement. Acta Geotech. 2021, 16, 1441–1456. [Google Scholar] [CrossRef]
- Nova, R.; Wood, D.M. A constitutive model for soil under monotonic and cyclic loading. In Soil Mechanics—Transient and Cyclic Loading; Pande, G.N., Zienkiewicz, O.C., Eds.; John Wiley and Sons: New York, NY, USA, 1982; pp. 343–373. [Google Scholar]
- Jefferies, M.G. Nor-Sand: A simple critical state model for sand. Géotechnique 1993, 43, 91–103. [Google Scholar] [CrossRef]
- Imam, S.M.R.; Morgenstern, N.R.; Robertson, P.K.; Chan, D.H. A critical-state constitutive model for liquefiable sand. Can. Geotech. J. 2005, 42, 830–855. [Google Scholar] [CrossRef]
- Yin, Z.Y.; Chang, C.S. Stress-dilatancy behavior for sand under loading and unloading conditions. Int. J. Numer. Anal. Methods Geomech. 2013, 37, 855–870. [Google Scholar] [CrossRef]
- Weng, M.C. A generalized plasticity–based model for sandstone considering time-dependent behavior, wetting deterioration. Rock Mech. Rock Eng. 2014, 47, 1197–1209. [Google Scholar] [CrossRef]
- Rahimi, M. Review of proposed stress–dilatancy relationships and plastic potential functions for uncemented and cemented sands. J. Geol. Res. 2019, 1, 19–34. [Google Scholar] [CrossRef]
- Nguyen, H.B.K.; Rahman, M.M.; Fourie, A.B. Characteristic behavior of drained and undrained triaxial compression tests: DEM Study. J. Geotech. Geoenviron. Eng. 2018, 144, 04018060. [Google Scholar] [CrossRef]
- Szypcio, Z. Stress dilatancy behavior of calcareous sand. In Proceedings of the 8th International Symposium on Deformation Characteristics of Geomaterials (IS-PORTO 2023), Porto, Portugal, 3–6 September 2023; EDP Sciences: Les Ulis, France, 2024; Volume 544, p. 05004. [Google Scholar] [CrossRef]
- Szypcio, Z. Stress-dilatancy for soils. Part I: The frictional state theory. Stud. Geotech. Mech. 2016, 38, 51–57. [Google Scholar] [CrossRef]
- Michalowski, R.L.; Čermák, J. Triaxial compression of sand reinforced with fibers. J. Geotech. Geoenviron. Eng. 2003, 129, 125–136. [Google Scholar] [CrossRef]
- Pressley, A. Elementary Differential Geometry, 2nd ed.; Springer Undergraduate Mathematics Series; Springer: London, UK, 2010. [Google Scholar]
- Miura, M.; Yamanouchi, T. Effect of water on the behavior of a quartz-rich sand under high stresses. Soils Found. 1975, 15, 23–34. [Google Scholar] [CrossRef]
- Sun, D.; Huang, W.; Sheng, D.; Yamamoto, H. An elastoplastic model for granular materials exhibiting particle crushing. Key Eng. Mater. 2007, 340–341, 1273–1278. [Google Scholar] [CrossRef]
- Gabryś, K.; Dołżyk-Szypcio, K.; Szypcio, Z.; Sas, W. Stress-strain behavior of crushed concrete as a special anthropogenic soil. Materials 2023, 16, 7381. [Google Scholar] [CrossRef]
- Coop, M.R. The mechanics of uncemented carbonate sands. Géotechnique 1990, 40, 607–626. [Google Scholar] [CrossRef]
- Luzzani, L.; Coop, M.R. On the relationship between particle breakage and the critical state of sands. Soils Found. 2002, 42, 71–82. [Google Scholar] [CrossRef] [PubMed]
- Marri, A. The Mechanical Behaviour of Cemented Granular Materials at High Pressures. Ph.D. Thesis, University of Nottingham, Nottingham, UK, 2010. Available online: https://eprints.nottingham.ac.uk/id/eprint/11670 (accessed on 4 September 2025).
| Disclaimer/Publisher’s Note: The statements, opinions and data contained in all publications are solely those of the individual author(s) and contributor(s) and not of MDPI and/or the editor(s). MDPI and/or the editor(s) disclaim responsibility for any injury to people or property resulting from any ideas, methods, instructions or products referred to in the content. |
© 2025 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).