Dimethyl 2-{[2-(2-Methoxy-1-methoxycarbonyl-2-oxoethyl)-4,5,7-trimethoxy-3-(2,4,5-trimethoxyphenyl)-2,3-dihydro-1H-inden-1-yl]methyl}malonate
by
Maksim A. Boichenko 1, Alexey O. Chagarovskiy 2,3,*, Victor B. Rybakov 1, Igor V. Trushkov 2,3 and Olga A. Ivanova 1,2,*
Maksim A. Boichenko 1, Alexey O. Chagarovskiy 2,3,*, Victor B. Rybakov 1, Igor V. Trushkov 2,3 and Olga A. Ivanova 1,2,*
1
Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie gory 1-3, Moscow 119991, Russia
2
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky pr. 47, Moscow 119991, Russia
3
Laboratory of Chemical Synthesis, Dmitry Rogachev National Medical Research Center of Pediatric Hematology, Oncology and Immunology, Samory Mashela 1, Moscow 117997, Russia
*
Authors to whom correspondence should be addressed.
Molbank 2020, 2020(1), M1107; https://doi.org/10.3390/M1107
Received: 25 December 2019 / Revised: 9 January 2020 / Accepted: 11 January 2020 / Published: 14 January 2020
(This article belongs to the Section Organic Synthesis)
A simple synthetic approach to dimethyl 2-{[2-(2-methoxy-1-methoxycarbonyl-2-oxoethyl)-4,5,7-trimethoxy-3-(2,4,5-trimethoxyphenyl)-2,3-dihydro-1H-inden-1-yl]methyl}malonate has been developed, based on a B(C6F5)3-induced domino dimerization of 2-(2,4,5-trimethoxyphenyl)cyclopropane-1,1-diester.
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MDPI and ACS Style
Boichenko, M.A.; Chagarovskiy, A.O.; Rybakov, V.B.; Trushkov, I.V.; Ivanova, O.A. Dimethyl 2-{[2-(2-Methoxy-1-methoxycarbonyl-2-oxoethyl)-4,5,7-trimethoxy-3-(2,4,5-trimethoxyphenyl)-2,3-dihydro-1H-inden-1-yl]methyl}malonate. Molbank 2020, 2020, M1107.
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