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Open AccessArticle

Synthesis and Structural Characterization of Amidine, Amide, Urea and Isocyanate Derivatives of the Amino-closo-dodecaborate Anion [B12H11NH3]

1
Department of Chemistry, Zhejiang University, 38 Zheda Road, Hangzhou 310027, China
2
Key Laboratory of Biomass Chemical Engineering of Ministry of Education, Department of Chemical and Biological Engineering, Zhejiang University, 38 Zheda Road, Hangzhou 310027, China
3
Department of Chemistry, University of Zurich, Winterthurerstrasse 190, 8057 Zurich, Switzerland
*
Author to whom correspondence should be addressed.
These authors contributed equally to this work.
Molecules 2018, 23(12), 3137; https://doi.org/10.3390/molecules23123137
Received: 1 November 2018 / Revised: 14 November 2018 / Accepted: 16 November 2018 / Published: 29 November 2018
(This article belongs to the Special Issue Advances in Materials Derived from Polyhedral Boron Clusters)
The synthesis and structural characterization of new derivatives of [B12H12]2− is of fundamental interest and is expected to allow for extended applications. Herein we report on the synthesis of a series of amidine, amide, urea and isocyanate derivatives based on the amino-closo-dodecaborate anion [B12H11NH3]. Their structures have been confirmed by spectroscopic methods, and nine crystal structures are presented. View Full-Text
Keywords: dodecaborate; boron cluster; borane; amidine; amide; urea; isocyanate dodecaborate; boron cluster; borane; amidine; amide; urea; isocyanate
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MDPI and ACS Style

Zhang, Y.; Sun, Y.; Wang, T.; Liu, J.; Spingler, B.; Duttwyler, S. Synthesis and Structural Characterization of Amidine, Amide, Urea and Isocyanate Derivatives of the Amino-closo-dodecaborate Anion [B12H11NH3]. Molecules 2018, 23, 3137.

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