Two New Phragmalin-Type Limonoids from Chukrasia tabularis var. velutina
Abstract
:1. Introduction
2. Results and Discussion
No. | 1 | 2 | ||
---|---|---|---|---|
δH (multi, J in Hz) | δC | δH (multi, J in Hz) | δC | |
1 | 82.3 | 82.9 | ||
2 | 74.0 | 74.8 | ||
3 | 3.35 (d 5.5) | 85.7 | 4.73 (s) | 86.1 |
4 | 43.1 | 43.9 | ||
5 | 2.44 (m ) | 36.7 | 2.60 * | 39.2 |
6a | 2.38 (dd 16.0, 3.3) | 29.6 | 1.94 * 2.47(dd 18.0, 11.0) | 31.9 |
6b | 2.94 (dd 16.0, 6.0) | |||
7 | 172.8 | 172.4 | ||
8 | 83.2 | 71.7 | ||
9 | 86.6 | 76.4 | ||
10 | 48.1 | 51.8 | ||
11 | 3.88 (dd 3.0, 8.6) | 67.3 | 5.11 (d 3.0) | 71.2 |
12 | 3.17 (dd 3.0, 5.0) | 73.4 | 4.96 (d 3.0) | 70.8 |
13 | 43.9 | 42.3 | ||
14 | 2.52 (d 4.5 ) | 43.4 | 2.60 * | 40.3 |
15a | 4.67 (d 4.5) | 92.4 | 2.76 (d 18.5) | 27.8 |
15b | 2.88(dd 18.5, 9.0) | |||
16 | 168.9 | |||
17 | 5.79 (s) | 67.5 | 6.00(s) | 70.2 |
18 | 1.29 (s, 3H) | 17.1 | 1.04 (s 3H) | 18.4 |
19a | 4.57 (d 12.5) | 67.9 | 1.19 (s 2H) | 15.3 |
19b | 5.27(d 12.5) | |||
20 | 121.5 | 121.4 | ||
21 | 7.59 (s) | 141.1 | 7.75 (s) | 141.7 |
22 | 6.42 (s) | 109.9 | 6.57 (t 1.0) | 109.7 |
23 | 7.68 (s) | 143.7 | 7.65 (t 1.5) | 143.2 |
28 | 0.88 (s 3H) | 14.9 | 0.70 (s 3H) | 14.6 |
29a | 1.46 (d 11.0) | 41.4 | 1.51 (d 11.0) | 40.8 |
29b | 1.92 (d 11.0) | 1.98(d 11.0) | ||
30 | 4.57 (s) | 65.7 | 4.98 (s) | 74.4 |
31 | 152.0 | |||
1' | 152.8 | |||
2' | 2.10 (q 7.5) | 26.0 | ||
3' | 1.04 (t, 7.5) | 10.9 | ||
7-OMe | 3.62 (s 3H) | 51.4 | ||
1-OH | 5.35 (s) | 6.46 (s) | ||
2-OH | 4.23 (s) | 5.06 (s) | ||
3-OH | 5.92 (d5.5) | |||
8-OH | 6.64 (s) | |||
9-OH | 4.42 (s) | |||
11-OH | 5.67 (d 8.6) | |||
12-OH | 5.14 (d 5.0) | |||
3-OAc | 170.0 | |||
2.22 (s 3H) | 20.4 | |||
11-OAc | 170.1 | |||
2.03 (s 3H) | 20.5 | |||
12-OAc | 168.9 | |||
1.91 (s 3H) | 20.4 | |||
17-OAc | 167.9 | 168.6 | ||
1.91 (s 3H) | 20.7 | 1.97 (s 3H) | 20.8 |
3. Experimental
3.1. General
3.2. Plant Material
3.3. Extraction and Isolation
4. Conclusions
Acknowledgments
References
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Sample Availability: Samples of the compounds 1 and 2 are available from the authors. |
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Li, Y.; Luo, J.; Li, H.; Kong, L.-Y. Two New Phragmalin-Type Limonoids from Chukrasia tabularis var. velutina. Molecules 2013, 18, 373-380. https://doi.org/10.3390/molecules18010373
Li Y, Luo J, Li H, Kong L-Y. Two New Phragmalin-Type Limonoids from Chukrasia tabularis var. velutina. Molecules. 2013; 18(1):373-380. https://doi.org/10.3390/molecules18010373
Chicago/Turabian StyleLi, Yi, Jun Luo, Hui Li, and Ling-Yi Kong. 2013. "Two New Phragmalin-Type Limonoids from Chukrasia tabularis var. velutina" Molecules 18, no. 1: 373-380. https://doi.org/10.3390/molecules18010373
APA StyleLi, Y., Luo, J., Li, H., & Kong, L.-Y. (2013). Two New Phragmalin-Type Limonoids from Chukrasia tabularis var. velutina. Molecules, 18(1), 373-380. https://doi.org/10.3390/molecules18010373