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19 pages, 9965 KB  
Article
Zircon U–Pb and Lu–Hf Signatures for the Gold Porphyry Deposits in the Alta Floresta Gold Province (Amazonian Craton, Brazil): Implications for Regional Exploration
by Léo Adriano de Oliveira, Natã José de França, Antônio João Paes de Barros, André Campos Rocha Pinto, Guilherme Loriato Potratz, Armando Dias Tavares, Luiz Pinheiro and Mauro Cesar Geraldes
Minerals 2026, 16(8), 789; https://doi.org/10.3390/min16080789 - 29 Jul 2026
Viewed by 939
Abstract
The present work focuses on investigating U–Pb and Lu–Hf ages of zircon grains obtained from Au mineralized granitic rocks from Alta Floresta Gold Province (AFGP), in the Amazonia craton, Brazil. Also, detrital zircon grains from recent Au-rich sediments were analyzed for U–Pb ages [...] Read more.
The present work focuses on investigating U–Pb and Lu–Hf ages of zircon grains obtained from Au mineralized granitic rocks from Alta Floresta Gold Province (AFGP), in the Amazonia craton, Brazil. Also, detrital zircon grains from recent Au-rich sediments were analyzed for U–Pb ages and Lu–Hf isotopic signatures to apply to regional gold exploration in the AFGP to define targets consisting of deep-seated mineralized bodies using isotopic tracers. U–Pb ages of magmatic rocks, obtained from zircon grains, indicate crystallization ages ranging from 1896 Ma to 1825 Ma for rocks associated with gold deposits, and TDM model ages between 2.65 and 1.96 Ga and εHf values between +8.0 and −4.6. U–Pb ages obtained from 89 detrital zircon grains indicate peaks at 2055–1980 Ma, 1889–1985 Ma, 1790–1700 Ma, and 1600–1550 Ma. The first group is related to the basement, represented by the rocks of the Cuiu-Cuiu Complex (TDM 2.0–1.9 Ga and εHf from +8.7 to −1.32). The second group concerns the mineralized magmatic rocks in the AFPG, and the ages range from 18,896 to 1825 Ma, TDM ages ranging from 2.90 to 2.75 Ga, and the εHf values from +15 to −8. The age ranging from 1790 to 1700 is associated with anorogenic magmatism (TDM 2.0–1.9 Ga and εHf from +5.36 to −8.46). The youngest group comprises ages from 1600 to 1550 Ma, probably correlated to the Serra da Providencia suite with TDM of 1,6 to 1,50 Ga and εHf from +5,0 to −10. In this way, it was possible to identify the age range of detrital zircon grains concerning the ages of mineralized granites and characterize the Hf signatures associated with the mineralization processes. In this sense, the zircon grains associated with the magmatic processes responsible for the concentration of noble metals exhibited U–Pb ages and εHf values interpreted as having been generated in magmas originating from a depleted mantle. As suggested in the literature, the magma characteristics reported here are coherent with a hot, hydrous, Fe-rich, high-K calc-alkaline, and subvolcanic emplacement. Based on the model that correlates gold deposits with porphyritic magmatic processes, significant discoveries with world-class volumes may result from better characterization of the deposit types found in the province. Full article
(This article belongs to the Special Issue Feature Papers in Mineral Exploration Methods and Applications 2025)
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28 pages, 21950 KB  
Article
Geochemistry and Geological Significance of the Granite Porphyry in the Dulong Sn Polymetallic Deposit, Southeastern Yunnan, China
by Xin Li, Zhigang Kong, Yu Wang, Tao Yang, Songyan Ni, Minghai Mou, Qinfu Ye and Huling Li
Minerals 2026, 16(6), 567; https://doi.org/10.3390/min16060567 - 24 May 2026
Viewed by 539
Abstract
The giant Dulong Sn-Zn polymetallic deposit, located in the eastern part of the southeastern Yunnan metallogenic belt, is a world-class ore system. Despite extensive research on the source of tin and its mineralization processes, the specific ore-related intrusion and the source of copper [...] Read more.
The giant Dulong Sn-Zn polymetallic deposit, located in the eastern part of the southeastern Yunnan metallogenic belt, is a world-class ore system. Despite extensive research on the source of tin and its mineralization processes, the specific ore-related intrusion and the source of copper remain highly debated. Recent deep exploration has revealed a deep-seated granite porphyry, yet its geochronological and geochemical characteristics, along with its genetic link to mineralization, are poorly constrained. This study presents new zircon U-Pb age, whole-rock geochemistry, and Sr-Nd-Hf isotopic compositions of this granite porphyry, integrated with a regional comparison to multi-phase Laojunshan granites. LA-ICP-MS zircon U-Pb dating yields a Late Cretaceous age of 85.1 ± 1.2 Ma. The Dulong granite porphyry is strongly peraluminous and high-K calc-alkaline to shoshonitic, exhibiting typical S-type granite affinities with enrichment in Rb, U, and Ta, as well as depletions in Ba, Sr, Nb, and Eu. Isotopic signatures (εNd(t) = −12.5 to −12.0, tDM2(Nd) = 1.87 to 1.91 Ga; zircon εHf(t) = −10.24 to −1.44, tDM2(Hf) = 1.24 to 1.79 Ga) suggest that the parental magma was derived from the partial melting of ancient crust, with possible minor input of mantle-derived components in an extensional tectonic setting. The Dulong granite porphyry represents a moderate-to-high temperature, reduced, and highly evolved magmatic system. Notably, its high concentrations of Sn, W, Zn, and Cu indicate that the parental melt was metal-rich, possessing potential for Sn and Cu mineralization. Accordingly, future exploration should prioritize areas characterized by well-developed granite porphyry dykes, skarn–wallrock contact zones, and deep-seated structural intersections. Full article
(This article belongs to the Special Issue Advances in Granite Geochronology and Geochemistry)
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59 pages, 14350 KB  
Review
REE Mineralogical Evolution in a F-Rich Peralkaline System: A Review on the REE Mineralization Associated with the Madeira Sn-Nb-Ta-Cryolite (REE, U, Th, Zr, Li) Deposit (Amazonas, Brazil)
by Artur C. Bastos Neto, Ingrid W. Hadlich, Harald G. Dill and Vitor P. Pereira
Minerals 2026, 16(4), 417; https://doi.org/10.3390/min16040417 - 17 Apr 2026
Cited by 1 | Viewed by 1031
Abstract
This study is centered on REE distribution in several minerals exhibiting exceptionally rare mineralogical and chemical compositions in the 1.8 Ga Madeira albite-enriched granite (AEG). This is a peralkaline A-type granite and corresponds to the Madeira Sn-Nb-Ta-cryolite (REE, Th, U, Zr, Li) world-class [...] Read more.
This study is centered on REE distribution in several minerals exhibiting exceptionally rare mineralogical and chemical compositions in the 1.8 Ga Madeira albite-enriched granite (AEG). This is a peralkaline A-type granite and corresponds to the Madeira Sn-Nb-Ta-cryolite (REE, Th, U, Zr, Li) world-class deposit (195 Mt) (Amazonas, Brazil). The REE mineralization ranks among the major deposits associated with alkaline and peralkaline magmatism in intracontinental and extensional anorogenic environments in terms of tonnage and grades. However, with respect to REE paragenesis and structure, it differs from all other known REE deposits. The REE mineralization (xenotime, gagarinite, fluocerite, thorite, pyrochlore, zircon, fluorite, and cryolite) is disseminated and zoned. In addition, in the central part of the deposit, there is a massive hydrothermal cryolite body, whose feasibility for REE extracting has been demonstrated. The evolution of rare earth minerals followed a precise order, with minimal formation of compound minerals and minerals with compositions distinct from their typical occurrences. Small pegmatites very rich in xenotime and gagarinite occur in the core AEG. These characteristics are due to the very high F activity in the magma, buffered by cryolite crystallization, to progressive, undisturbed crystallization from the margins toward the center, and to minimal CO2 activity. The alteration of primary REE minerals by F-rich hydrothermal fluids, the origin of these fluids, and the formation of secondary REE minerals are also discussed. Full article
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13 pages, 5433 KB  
Article
Applications of Airborne Hyperspectral Imagery in Rare Earth Element Exploration: A Case Study of the World-Class Bayan Obo Deposit, China
by Cai Liu, Junting Qiu, Junchuan Yu, Yanbo Zhao, Yuanquan Xu, Xin Zhang, Bin Chen, Rong Xu, Qianli Ma, Gang Liu and Jinzhong Yang
Remote Sens. 2026, 18(8), 1110; https://doi.org/10.3390/rs18081110 - 8 Apr 2026
Viewed by 848
Abstract
Rare earth elements (REEs) play an important role in emerging renewable energy technology, the production of advanced materials, energy conservation, and high-end manufacturing industries, making them an irreplaceable strategic resource. The diagnostic spectral absorption features of REEs in the visible and near-infrared spectrum [...] Read more.
Rare earth elements (REEs) play an important role in emerging renewable energy technology, the production of advanced materials, energy conservation, and high-end manufacturing industries, making them an irreplaceable strategic resource. The diagnostic spectral absorption features of REEs in the visible and near-infrared spectrum can be effectively used for identifying the occurrences of REEs on the Earth’s surface. This study systematically compared three airborne hyperspectral sensors—HyMap, CASI-1500h, and AisaFENIX 1K—for detecting REEs in the Bayan Obo area of Inner Mongolia, China. The CASI-1500h imagery performed most effectively in identifying the locations of REEs among the three sensors evaluated here. Additionally, this study proposed a hyperspectral workflow for REE identification, which enabled the detection of REE-bearing minerals regardless of the host rock types—including carbonatites and associated dikes, fenite-syenites, and metamorphic feldspar-quartz sandstone. Laboratory-based spectroscopy and mineral chemistry analyses indicated that the absorption features of the REE-bearing mineral monazite within the 400–1000 nm range can be ascribed to Nd3+. This study demonstrates the potential of airborne hyperspectral technology for efficient and large-scale exploration of REE deposits. Full article
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21 pages, 6586 KB  
Article
Whole-Rock Element Analyses Constraining the Magmatic Evolution and Metallogenesis of the Jiaojia Fault Zone, Jiaodong Gold Province
by Jiabao Jia, Yueliang Hu, Lin Gao, Yulu Lv, Junjie Wang, Xiaomei Yang, Yan Liu, Xiaoliang Shi, Jing Lv, Yanbo Xu, Mengmeng Zhang and Wu Li
Minerals 2026, 16(4), 350; https://doi.org/10.3390/min16040350 - 26 Mar 2026
Cited by 1 | Viewed by 816 | Correction
Abstract
The Jiaodong Peninsula constitutes a world-class gold province in eastern China, containing more than 5000 t of identified gold resources. The Jiaojia gold deposit is one of the largest deposits within this gold province, and mineralization is primarily distributed along the northern segment [...] Read more.
The Jiaodong Peninsula constitutes a world-class gold province in eastern China, containing more than 5000 t of identified gold resources. The Jiaojia gold deposit is one of the largest deposits within this gold province, and mineralization is primarily distributed along the northern segment of the Jiaojia Fault. The structural characteristics and mineralization processes of the northern segment have been extensively documented. In contrast, the ore-forming mechanisms of the southern Jiaojia Fault remain poorly constrained, hindering further exploration targeting. We chose several gold deposits and one drill core along the Jiaojia Fault, then present whole-rock major and trace elements data to evaluate magmatic affinities and their ore-forming potential. The results show that the lithological differences in plutonic and stratigraphic units suggest that variations in petrogenesis may have exerted a fundamental control on mineralization styles. Almost all samples are characterized by enrichment in light rare earth elements, relative enrichment in Europium, and pronounced depletion in heavy rare earth elements. Alteration characteristics indicate the northern segment is dominated by advanced argillic alteration, whereas phyllic alteration is more prevalent in the southern segment. The rare earth elements discrimination plot clearly suggests differentiation from the northern and southern fault segments. Consequently, we propose that the northern segment records synorogenic arc magmatism, while the southern segment experienced both synorogenic and a subsequent intraplate extensional transitional stage. Full article
(This article belongs to the Special Issue Gold–Polymetallic Deposits in Convergent Margins)
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23 pages, 4500 KB  
Article
Formation of Niujuan Ag-Au Deposit, North China Craton: Constraints from Pyrite Textures and In-Situ Trace Element and H-O-S Isotope Geochemistry
by Chunlai Liu, Ruiming Cao, Wei Li, Xiaoxuan Liu, Ke Huang, Wei Pan, Wei Cui and Linan Cui
Minerals 2026, 16(3), 264; https://doi.org/10.3390/min16030264 - 28 Feb 2026
Viewed by 520
Abstract
The North China Craton (NCC) hosts numerous world-class Au deposits and these Au deposits can be classified into the Au-only and Ag-Au polymetallics, respectively. The former is mostly located in the eastern NCC, such as in the giant Jiaodong Province, and the latter [...] Read more.
The North China Craton (NCC) hosts numerous world-class Au deposits and these Au deposits can be classified into the Au-only and Ag-Au polymetallics, respectively. The former is mostly located in the eastern NCC, such as in the giant Jiaodong Province, and the latter is mostly distributed along the northern and southern margins of the NCC. Compared with Au-only deposits, the ore genesis of the Ag-Au deposits remains controversial. This paper focuses on the Niujuan Ag-Au deposit in the Fengning ore cluster of the northern margin of the NCC. Detailed deposit geology investigation, texture analysis, and analyses of the in situ trace element and sulfur isotope compositions of pyrite, coupled with H-O isotope compositions of quartz from different stages, were conducted to elucidate the ore-forming processes and metal sources. The results showed that the formation of the Niujuan deposit can be divided into four stages, including a pre-ore siliceous breccia stage (stage 1), syn-ore quartz-pyrite stage (stage 2), syn-ore polymetallic sulfide stage (stage 3), and post-ore fluorite-calcite stage (stage 4). Among these, stage 3 represents the major Ag-Au mineralization stage. Pyrite is well developed within stage 2 and stage 3, representing the intensive sulfidation of the wall rock. Microscopic analytical techniques including gamma-enhanced reflected light and scanning electron microscopy backscattered electron (BSE) reveal that pyrite samples from stage 2 and stage 3 have distinct textures. Pyrite (Py1) from stage 2 is homogeneous but with numerous pores. In contrast, pyrite (Py2) from stage 3 has overgrowth textures, and be divided into three sub-stages from core to rim (Py2a, Py2b, and Py2c) with different BSE brightness levels. LA-ICP-MS trace elements analyses results show that these different stages of pyrite show different composition such as Au, As, Ag, Co, and Ni. Py1 has low Au and Ag concentrations ranging from <0.1 ppm to 0.02 ppm and <0.1 ppm to 21.8 ppm, respectively. Py2a has low Au and Ag concentrations ranging from <0.1 ppm to 0.4 ppm and 0.4 ppm to 118.4 ppm, respectively. Py2b is characterized by high As and low Au contents, with average values of 6670.8 ppm for As and 1.4 ppm for Au. Py2c shows relatively low Co and Ni concentrations ranging from 0.02 ppm to 255.2 ppm and <0.1 ppm to 9.9 ppm, respectively. The sulfur isotope composition of Py1 and Py2 is relatively consistent, ranging from 3.8‰ to 6.7‰. The H and O isotope compositions of quartz from stage 1, stage 2, and stage 3 have insignificant variations, ranging from −119.5‰ to −101.3‰ for δD and −6.8‰ to −3.7‰ for δ18Ofluid, respectively. The results show that sulfur and, possibly, Au and Ag were mainly derived from magmatic hydrothermal fluids, and a significant amount of meteoric water was involved. Combined with the published mineralizing ages (~140 Ma), this paper suggests that the Niujuan Ag-Au deposit formed during the Early Cretaceous under an extensional setting in response to the eastward retreating subduction of the Paleo-Pacific oceanic plate. Evidence from deposit geology and geochemistry reveals that the mixture of magmatic and meteoric water, together with intensive sulfidation, is the key factor controlling Au and Ag deposition. Full article
(This article belongs to the Section Mineral Deposits)
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25 pages, 26414 KB  
Article
Decoding the Structural Architecture of the Northern Copper Belt (Carajás Province) and Bacajá Domain Using Airborne Geophysics (Brazil)
by Luiz Fernandes Dutra, Gustavo Henrique Coelho de Melo, Brener Otávio Luiz Ribeiro and Filipe Altoé Temporim
Minerals 2026, 16(3), 240; https://doi.org/10.3390/min16030240 - 26 Feb 2026
Cited by 1 | Viewed by 1301
Abstract
Copper is a critical metal for the global energy transition. Yet, declining discovery rates and increasing demand necessitate more efficient mineral exploration strategies grounded in a mineral systems approach. The Carajás Province (Amazonian Craton, Brazil) is one of the world’s premier copper-producing regions, [...] Read more.
Copper is a critical metal for the global energy transition. Yet, declining discovery rates and increasing demand necessitate more efficient mineral exploration strategies grounded in a mineral systems approach. The Carajás Province (Amazonian Craton, Brazil) is one of the world’s premier copper-producing regions, hosting several iron oxide–copper–gold (IOCG) and related deposits. The Northern Copper Belt (NCB), located near the boundary between the Carajás and Bacajá domains, records a multiphase deformational and metallogenetic evolution from the Neoarchaean to Paleoproterozoic. Despite extensive previous studies, uncertainties remain regarding the geometry, depth, and continuity of the regional structures that control copper mineralization, as well as the nature of the tectonic boundary between the Carajás and Bacajá domains. As a result, through an integration of airborne magnetic, gravity, gamma-ray spectrometry, morpholineament, and spatial analyses, we characterized the tectono-structural framework of the NCB and the southern Bacajá Domain. This will provide new constraints on the geodynamic evolution of this world-class copper metallogenic belt, elucidating crustal-scale structures and patterns of hydrothermal alteration and fluid pathways, and enhancing understanding of the potential for further discoveries. Full article
(This article belongs to the Section Mineral Exploration Methods and Applications)
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23 pages, 13317 KB  
Article
Geochemical Distribution Characteristics, Traceability, and Health Risk Assessment of Potential Toxic Elements in Granite Weathering Crust-Type Rare Earth Mine and Its Surrounding Areas, Southeast China
by Chenge Ma, Siwen Liu, Qing Sun, Jixin Wei, Chunli Xu, Qiang Xue, Taotao Yan, Shanshan Hou and Manman Xie
Appl. Sci. 2026, 16(3), 1441; https://doi.org/10.3390/app16031441 - 30 Jan 2026
Cited by 1 | Viewed by 826
Abstract
The Z.D. granite weathering crust rare earth deposit in Ganzhou, China is a world-class resource. In situ leaching extraction may mobilize potentially toxic elements (PTEs) into surrounding soils. This study analyzed nine PTEs (As, Cd, Cr, Cu, Hg, Mn, Ni, Pb, Zn) in [...] Read more.
The Z.D. granite weathering crust rare earth deposit in Ganzhou, China is a world-class resource. In situ leaching extraction may mobilize potentially toxic elements (PTEs) into surrounding soils. This study analyzed nine PTEs (As, Cd, Cr, Cu, Hg, Mn, Ni, Pb, Zn) in top soils within and around the mining area. A multi-method approach was employed, integrating geochemical assessment, pollution and ecological risk indices, and probabilistic health risk evaluation via Monte Carlo simulation and source apportionment using Positive Matrix Factorization (PMF) combined with Geographic Information System (GIS) analysis. Results indicated generally low background levels, though with localized Pb enrichment, and an overall low level of pollution and ecological risk. However, for children in nearby areas with prolonged exposure, there was a 9.11% probability of non-carcinogenic risk and a 13.82% probability of carcinogenic risk. PMF-GIS analysis traced PTEs to four sources: natural parent material, industrial emissions, mining/riverine transport, and agriculture. In conclusion, while current soil environmental risks in the Z.D. mining area remain manageable, the study underscores the need to monitor progressive PTE accumulation and children’s health risks. This work provides a scientific basis for targeted soil management and ecological restoration in rare earth mining regions. Full article
(This article belongs to the Special Issue Current Approaches in Applied Geochemistry)
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28 pages, 17533 KB  
Article
Discussion on the Genesis of Vein-Type Copper Deposits in the Northern Lanping Basin, Western Yunnan
by Zhangyu Chen, Xiaohu Wang, Yucai Song and Teng Liu
Minerals 2026, 16(1), 33; https://doi.org/10.3390/min16010033 - 27 Dec 2025
Viewed by 1617
Abstract
The Sanjiang Tethys orogenic belt in Southwest China is a globally important polymetallic metallogenic domain, hosting numerous world-class Cu-Pb-Zn deposits. Among these, the Lanping Basin is a typical ore concentration area, characterized by complex tectonic evolution and extensive hydrothermal mineralization. Although numerous vein-type [...] Read more.
The Sanjiang Tethys orogenic belt in Southwest China is a globally important polymetallic metallogenic domain, hosting numerous world-class Cu-Pb-Zn deposits. Among these, the Lanping Basin is a typical ore concentration area, characterized by complex tectonic evolution and extensive hydrothermal mineralization. Although numerous vein-type Cu deposits occur in the northern and western parts of the basin, research in the north region remains less comprehensive. This study investigates three typical vein-type Cu deposits (Hetaoqing, Hemeigou, and Songpingzi) in the northern Lanping Basin using rare-earth element (REE) analysis, S-Pb-Sr isotope determinations, and tectonic stress inversion. Results show that 206Pb/204Pb ratios range from 18.374 to 18.691, and δ34SV-CDT values vary from –11.7‰ to +9.4‰, indicating mixed sources of ore-forming materials dominated by deep magmatic sources, particularly related to alkaline rocks around the basin. Sulfur sources are closely associated with thermochemical sulfate reduction (TSR). Additionally, 87Sr/86Sr ratios range from 0.710949 to 0.711864, ΣREE values range from 85.87 × 10–6 to 111.86 × 10–6, Ce/Ce* ratios range from 0.86 to 0.92, and Eu/Eu* ratios range from 1.06 to 2.99. Fluid inclusion microthermometry yields temperatures of 217–252 °C (average 238 °C), indicating that ore-forming fluids experienced water–rock interaction during migration and ultimately exhibited mixed properties. Tectonic stress field inversion reveals that the structures formed by NE–SW compressive stress field before mineralization stage provided ore-hosting spaces and fluid migration pathways, while a late Cenozoic abrupt stress field change promoted the precipitation of ore-forming materials. Full article
(This article belongs to the Section Mineral Deposits)
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24 pages, 7830 KB  
Article
Research on the Metallogenic Enrichment Model of Poly-Metallic Black Shales and Their Geological Significance: A Case Study of the Cambrian Niutitang Formation
by Kai Shi, Zhiyong Ni, Ganggang Shao, Wen Zhang and Nuo Cheng
Processes 2025, 13(11), 3537; https://doi.org/10.3390/pr13113537 - 4 Nov 2025
Viewed by 1205
Abstract
The Lower Cambrian Niutitang Formation was deposited precisely during the Cambrian Explosion period, a short-lived interval marked by drastic shifts in oceanic chemistry and climate. This stratigraphic sequence preserves a comprehensive record of early-ocean evolution and constitutes a world-class reservoir for rare and [...] Read more.
The Lower Cambrian Niutitang Formation was deposited precisely during the Cambrian Explosion period, a short-lived interval marked by drastic shifts in oceanic chemistry and climate. This stratigraphic sequence preserves a comprehensive record of early-ocean evolution and constitutes a world-class reservoir for rare and precious metals, widely termed the “poly-metallic enrichment layer”. Despite its metallogenic prominence, the genetic model for metal enrichment in the Niutitang Formation remains contentious. In this study, we employed inductively coupled plasma mass spectrometry (ICP-MS), carbon and sulfur analyzer, and X-ray fluorescence spectrometry (XRF) to quantify trace-metal abundances, redox-sensitive element distribution patterns, rare-earth element signatures, and total organic carbon contents. Results reveal that metal enrichment in the Niutitang Formation was governed by temporally distinct mechanisms. Member I records extreme enrichment in As, Ag, V, Re, Ba, Cr, Cs, Ga, Ge, Se and In. This anomaly was driven by the Great Oxidation Event and intensified upwelling that oxidized surface waters, elevated primary productivity and delivered abundant organic matter. Subsequent microbial sulfate reduction generated high H2S concentrations, converting the water column to euxinic conditions. Basin restriction imposed persistent anoxia in bottom waters, establishing a pronounced redox stratification. Concurrent vigorous hydrothermal activity injected large metal fluxes, leading to efficient scavenging of the above metals at the sulfidic–anoxic interface. In Members II and III, basin restriction waned, permitting enhanced water-mass exchange and a concomitant shift from euxinic to anoxic–suboxic conditions. Hydrothermal metal fluxes declined, yet elevated organic-matter fluxes continued to sequester Ag, Mo, Ni, Sb, Re, Th, Ga, and Tl via carboxyl- and thiol-complexation. Thus, “organic ligand shuttling” superseded “sulfide precipitation” as the dominant enrichment mechanism. Collectively, the polymetallic enrichment in the Niutitang Formation reflects a hybrid model controlled by seawater redox gradients, episodic hydrothermal metal supply, and organic-complexation processes. Consequently, metal enrichment in Member I was primarily governed by the interplay between vigorous hydrothermal flux and a persistently sulfidic water column, whereas enrichment in Members II and III was dominated by organic-ligand complexation and fluctuations in the marine redox interface. This study clarifies the stage-dependent metal enrichment model of the Niutitang Formation and provides a theoretical basis for accurate prediction and efficient exploration of polymetallic resources in the region. Full article
(This article belongs to the Section Energy Systems)
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26 pages, 4017 KB  
Article
Research on Multi-Source Information-Based Mineral Prospecting Prediction Using Machine Learning
by Jie Xu, Yongmei Li, Wei Liu, Shili Han, Kaixuan Tan, Yanshi Xie and Yi Zhao
Minerals 2025, 15(10), 1046; https://doi.org/10.3390/min15101046 - 1 Oct 2025
Cited by 3 | Viewed by 1836
Abstract
The Shizhuyuan polymetallic deposit in Hunan Province, China, is a world-class ore field rich in tungsten (W), tin (Sn), molybdenum (Mo), and bismuth (Bi), now facing resource depletion due to prolonged exploitation. This study addresses the limitations of traditional geological prediction methods in [...] Read more.
The Shizhuyuan polymetallic deposit in Hunan Province, China, is a world-class ore field rich in tungsten (W), tin (Sn), molybdenum (Mo), and bismuth (Bi), now facing resource depletion due to prolonged exploitation. This study addresses the limitations of traditional geological prediction methods in complex terrain by integrating multi-source datasets—including γ-ray spectrometry, high-precision magnetometry, induced polarization (IP), and soil radon measurements—across 5049 samples. Unsupervised factor analysis was employed to extract five key ore-indicating factors, explaining 82.78% of data variance. Based on these geological features, predictive models including Support Vector Machine (SVM), Random Forest (RF), and Extreme Gradient Boosting (XGBoost) were constructed and compared. SHAP values were employed to quantify the contribution of each geological feature to the prediction outcomes, thereby transforming the machine learning “black-box models” into an interpretable geological decision-making basis. The results demonstrate that machine learning, particularly when integrated with multi-source data, provides a powerful and interpretable approach for deep mineral prospectivity mapping in concealed terrains. Full article
(This article belongs to the Section Mineral Exploration Methods and Applications)
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17 pages, 11781 KB  
Article
Identifying New Copper Mineralization via Multispectral Remote Sensing (MSRS) and Short-Wave Infrared (SWIR) Spectral Analysis in Dingyang, Western Gangdese Belt, Xizang
by Zhibin Li, Zhaxi PuBu, Xian Che, Gen Chen, Jiangang Wei, Deng Pan and Xiaojia Jiang
Minerals 2025, 15(10), 1045; https://doi.org/10.3390/min15101045 - 1 Oct 2025
Cited by 4 | Viewed by 1939
Abstract
The Gangdese metallogenic belt (GMB), spanning nearly 2000 km across central Tibet, represents the primary copper–polymetallic metallogenic belt in Tibet and a world-class porphyry copper province. However, extreme high-altitude conditions, ecological fragility, and limited accessibility in western GMB have significantly constrained the efficacy [...] Read more.
The Gangdese metallogenic belt (GMB), spanning nearly 2000 km across central Tibet, represents the primary copper–polymetallic metallogenic belt in Tibet and a world-class porphyry copper province. However, extreme high-altitude conditions, ecological fragility, and limited accessibility in western GMB have significantly constrained the efficacy of conventional exploration methods. Identifying effective mineralogical indicators and rapidly delineating mineralization–hydrothermal centers within this metallogenic system remain critical challenges for exploration geologists. This study integrates multispectral remote sensing (MSRS; Sentinel-2) with short-wave infrared (SWIR) spectral analysis to establish mineral spectroscopic exploration indicators for the periphery of the Zhunuo porphyry copper ore-concentrated area. Principal Component Analysis (PCA) and band ratio techniques were employed to delineate remote sensing alteration anomalies, followed by SWIR spectral features to identify mineralization–hydrothermal centers. Hydrothermal alteration in the study area is dominated by sericite, chlorite, and epidote, with subordinate carbonate and sulfate minerals. Multispectral anomalies (Al-OH, ferric contamination, and carbonate alterations) in the Dingyang area exhibit intensity and compositional patterns comparable to those of the Cimabanshuo, Beimulang, and Zhigunong deposits, indicating high mineralization potential. SWIR analysis identified sericite-based exploration indicators (Pos2200 < 2203 nm, Dep2200 > 0.3, SWIR-IC > 1.6). A Spectral Feature-Based Geological Content Method (SFGCM) model was developed to delineate mineralization–hydrothermal centers, revealing new malachite and azurite mineralization in the Dingyang area. The MSRS-SWIR provides a novel perspective for applying spectroscopy to rapidly identify porphyry copper mineralized hydrothermal centers in high-altitude, ecologically fragile areas. Full article
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33 pages, 8120 KB  
Article
Origin of the World-Class Eagle, Eagle East, and Tamarack Ni-Cu-PGE Deposits
by Robert Nowak, Chad Deering and Espree Essig
Minerals 2025, 15(8), 871; https://doi.org/10.3390/min15080871 - 18 Aug 2025
Viewed by 2813
Abstract
The 1.1 Ga Mesoproterozoic Midcontinent rift hosts the Eagle, Eagle East, and Tamarack Ni-Cu-PGE deposits and Embayment Prospect. These deposits are hosted by ultramafic igneous rocks and have some of the highest Ni-Cu grades on Earth. We use new bulk-rock data and published [...] Read more.
The 1.1 Ga Mesoproterozoic Midcontinent rift hosts the Eagle, Eagle East, and Tamarack Ni-Cu-PGE deposits and Embayment Prospect. These deposits are hosted by ultramafic igneous rocks and have some of the highest Ni-Cu grades on Earth. We use new bulk-rock data and published datasets (bulk-rock, mineral chemistry, and isotopic analyses) to examine major, minor, and trace element trends of both Midcontinent rift-related alkaline and tholeiitic intrusions. In addition, we compare the geochemical data to local kimberlite-hosted lower-crustal xenoliths and local igneous (Archean) and sedimentary (Paleoproterozoic) country rocks. We found the peridotite magma compositions dominantly consist of primitive mantle compositions with varying abundances of subduction-related components, alkaline-transitional melts, and local country rock contaminates (e.g., Baraga and Animikie Basin sediments). The subduction-related components are interpreted to be derived from previous Archean and Paleoproterozoic subduction events and likely hosted within the sub-continental lithospheric mantle. Importantly, these subduction-related components are also interpreted to have acted as oxidizing agents within the melt, stabilizing sulfate (+2 FMQ (fayalite–magnetite–quartz) to FMQ) while inhibiting sulfide crystallization as the magma ascended through ~50 km of the Superior craton. This study largely corroborates the previous findings with respect to the contribution of local country rock contamination to the Eagle–Tamarack peridotite host rocks, which is estimated to be minimal (<5%). However, the incorporation of <5% reductive pelitic siltstone contamination results in strong shifts in the oxygen fugacity of the peridotite melt, from +2 FMQ to slightly below FMQ, as determined from spinel Fe3+/∑Fe ratios. This shift in oxygen fugacity resulted in the transition from total sulfate (+2 FMQ) to sulfate + sulfide (<+2 FMQ to FMQ) to total sulfide (<FMQ). This shift in oxygen fugacity is a key contributor to the formation of Ni-Cu-PGE-rich massive sulfides within the Eagle peridotite. This study presents an expanded geochemical interpretation for the exploration of Midcontinent rift-related Ni-Cu-PGE deposits to include peridotites with subduction-like signatures and contaminated via <5% reductive sedimentary country rocks. Full article
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53 pages, 7076 KB  
Article
The Diversity of Rare-Metal Pegmatites Associated with Albite-Enriched Granite in the World-Class Madeira Sn-Nb-Ta-Cryolite Deposit, Amazonas, Brazil: A Complex Magmatic-Hydrothermal Transition
by Ingrid W. Hadlich, Artur C. Bastos Neto, Vitor P. Pereira, Harald G. Dill and Nilson F. Botelho
Minerals 2025, 15(6), 559; https://doi.org/10.3390/min15060559 - 23 May 2025
Cited by 3 | Viewed by 3227
Abstract
This study investigates pegmatites with exceptionally rare mineralogical and chemical signatures, hosted by the 1.8 Ga peralkaline albite-enriched granite, which corresponds to the renowned Madeira Sn-Nb-Ta-F (REE, Th, U) deposit in Pitinga, Brazil. Four distinct pegmatite types are identified: border pegmatites, pegmatitic albite-enriched [...] Read more.
This study investigates pegmatites with exceptionally rare mineralogical and chemical signatures, hosted by the 1.8 Ga peralkaline albite-enriched granite, which corresponds to the renowned Madeira Sn-Nb-Ta-F (REE, Th, U) deposit in Pitinga, Brazil. Four distinct pegmatite types are identified: border pegmatites, pegmatitic albite-enriched granite, miarolitic pegmatite, and pegmatite veins. The host rock itself has served as the source for the fluids that gave rise to all these pegmatites. Their mineral assemblages mirror the rare-metal-rich paragenesis of the host rock, including pyrochlore, cassiterite, riebeckite, polylithionite, zircon, thorite, xenotime, gagarinite-(Y), genthelvite, and cryolite. These pegmatites formed at the same crustal level as the host granite and record a progressive magmatic–hydrothermal evolution driven by various physicochemical processes, including tectonic decompressing, extreme fractionation, melt–melt immiscibility, and internal fluid exsolution. Border pegmatites crystallized early from a F-poor, K-Ca-Sr-Zr-Y-HREE-rich fluid exsolved during solidification of the pluton’s border and were emplaced in contraction fractures between the pluton and country rocks. Continued crystallization toward the pluton’s core produced a highly fractionated melt enriched in Sn, Nb, Ta, Rb, HREE, U, Th, and other HFSE, forming pegmatitic albite-enriched granite within centimetric fractures. A subsequent pressure quench—likely induced by reverse faulting—triggered the separation of a supercritical melt, further enriched in rare metals, which migrated into fractures and cavities to form amphibole-rich pegmatite veins and miarolitic pegmatites. A key process in this evolution was melt–melt immiscibility, which led to the partitioning of alkalis between two phases: a K-F-rich aluminosilicate melt (low in H2O), enriched in Y, Li, Be, and Zn; and a Na-F-rich aqueous melt (low in SiO2). These immiscible melts crystallized polylithionite-rich and cryolite-rich pegmatite veins, respectively. The magmatic–hydrothermal transition occurred independently in each pegmatite body upon H2O saturation, with the hydrothermal fluid composition controlled by the local degree of melt fractionation. These highly F-rich exsolved fluids caused intense autometasomatic alteration and secondary mineralization. The exceptional F content (up to 35 wt.% F in pegmatite veins), played a central role in concentrating strategic and critical metals such as Nb, Ta, REEs (notably HREE), Li, and Be. These findings establish the Madeira system as a reference for rare-metal magmatic–hydrothermal evolution in peralkaline granites. Full article
(This article belongs to the Special Issue Critical Metal Minerals, 2nd Edition)
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30 pages, 200218 KB  
Article
Tectonic Evolution and Structural Control of Dike-Hosted Orogenic Gold Deposits in the Yana–Kolyma Collision Orogen (Eastern Siberia): Insights from the Eastern Margin of the Siberian Craton
by Valery Yurievich Fridovsky and Maxim Vasilievich Kudrin
Geosciences 2025, 15(5), 168; https://doi.org/10.3390/geosciences15050168 - 7 May 2025
Cited by 2 | Viewed by 2721
Abstract
The Yana–Kolyma collision orogen, Eastern Siberia, is one of world-class gold economic belts, where large gold deposits are localized, mainly in the Upper Paleozoic and Lower Mesozoic clastic rocks. Dike-hosted orogenic gold deposits are found and to a lesser extent studied, but they [...] Read more.
The Yana–Kolyma collision orogen, Eastern Siberia, is one of world-class gold economic belts, where large gold deposits are localized, mainly in the Upper Paleozoic and Lower Mesozoic clastic rocks. Dike-hosted orogenic gold deposits are found and to a lesser extent studied, but they are important for understanding the structural control of mineralization within the framework of the orogen. Orogenic gold deposits of the Vyun ore field are hosted in Kimmeridgian–Titonian mafic, intermediate and felsic dikes, but they have no genetic connection with dikes. The late formation of deposits led to the fact that previously reactivated polydeformed structures were subsequently mineralized. The study of the structural control of mineralization is also complicated by superimposed late tectonic events. Based on the analysis of collected field materials, this paper presents the results of the study of deformation structures of the Vyun ore field within the framework of the Mesozoic evolution history throughout the geological time of the eastern convergent margin of the Siberian Craton. Four stages of deformations are identified. The pre-mineralization deformations and metamorphic and magmatic events share a common NE-SW shortening (D1 phase), which is related to the subduction of the Oymyakon oceanic slab and collision of the Kolyma–Omolon superterrane from the eastern margin of the Siberian Craton. This first stage is characterized by the superposition of several tectonic events under conditions of compression and progressive deformations (D1/1 and D1/2). Ore mineralization was formed at the end of compression in the same stress field (D1/2). Its structural control is determined by reactivation of older dikes and faults. Dikes are areas of heterogeneous stress and heterogeneous strain, being favorable for the concentration of ore fluids. The metallogenic time of formation of the gold mineralization is synchronous with the tectonic event, which likely reflects the final stages of the Kolyma–Omolon microcontinent–Siberian Craton collision of the Valanginian during crustal thickening. The main impulse of the Au mineralization D1/2 phase coincided with a slowdown in convergence. The post-mineralization tectonic regime was related to the Aptian–Late Cretaceous tectonic transition from compression to transpression. Transpressional tectonics were determined accordingly by W-E (D2 phase) and N-S (D3 phase) stress fields caused by several accretion events in the Cretaceous on the northern and eastern margins of Siberia. D4 phase extensional structures were caused by the opening of the Eurasian Oceanic basin in the Arctic in the Paleocene. The obtained results have a first-order impact on the understanding of the structural control of orogenic gold deposits and their relationship to the evolution of the host orogen. The new findings improve the tectonic knowledge of an area of interest for ore deposit exploration targeting orogenic gold deposits in Phanerozoic terranes of craton margins. Full article
(This article belongs to the Section Structural Geology and Tectonics)
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