Search Results (381)

Organic acids could act as retarders in magnesium oxysulfide (MOS) systems, not only delaying setting and improving fluidity but also enhancing compressive strength and water resistance. These effects are generally attributed to both the presence of H⁺ ions and anion chelation. However, the enhancement efficiency of different organic acids in MOS systems varies significantly due to differences in their molecular structures. To determine the underlying mechanism, this study comparatively investigated the effects of amino trimethylene phosphonic acid (ATMP) and tartaric acid (TA) on the setting time, fluidity, compressive strength, and water resistance of the MOS system, with the two additives incorporated at mole ratios to MgO ranging from 0.002 to 0.006. The mechanism behind it was revealed by discussion on the hydration heat, hydrates, and pH value. Results showed that both ATMP and TA could effectively improve the fluidity, delay the setting process, and enhance the mechanical properties, including strength and water resistance. At a mole ratio of 0.006, the incorporation of ATMP increased the 28 d compressive strength and the softening coefficient by 214.12% and 37.29%, respectively, compared with the blank group. In contrast, under the same dosage, TA led to an increase of 55.13% in the 28 d strength and 22.03% in the softening coefficient. Furthermore, hydration heat, product analysis, and pH measurements indicated that both ATMP and TA inhibited hydration during the initial hours but promoted hydration at later stages. The potential reason could be divided into two aspects: (1) H⁺ ions from ATMP and TA suppressing the formation of Mg(OH)₂; (2) anion chelation with Mg²⁺ in the liquid phase, leading to a supersaturated solution with higher saturation, which further hindered Mg(OH)₂ formation and facilitated the later development of 5Mg(OH)₂·MgSO₄·7H₂O (517 phase). By contrast, under the same mole dosage of H⁺ or anions, the enhancement in compressive strength as well as the water resistance is superior when using ATMP. This was owing to its stronger chelating ability of ATMP, which more effectively inhibited Mg(OH)₂ formation and then promoted the formation of the 517 phase. These findings confirm that the chelating ability of anions exerts an important impact on the retarding effect as well as the enhancement of strength in MOS systems. Full article

This paper presents a formulation for the dynamic analysis of dam–reservoir–foundation systems, employing a coupled finite element model that integrates displacements and reservoir pressures. An innovative coupled approach, without separating the solid and fluid equations, is proposed to directly solve the single non-symmetrical governing equation for the whole system with non-proportional damping. For the modal analysis, a state–space method is adopted to solve the coupled eigenproblem, and complex eigenvalues and eigenvectors are computed, corresponding to non-stationary vibration modes. For the seismic analysis, a time-stepping method is applied to the coupled dynamic equation, and the stress–transfer method is introduced to simulate the nonlinear behavior, innovatively combining a constitutive joint model and a concrete damage model with softening and two independent scalar damage variables (tension and compression). This formulation is implemented in the computer program DamDySSA5.0, developed by the authors. To validate the formulation, this paper provides the experimental and numerical results in the case of the Cahora Bassa dam, instrumented in 2010 with a continuous vibration monitoring system designed by the authors. The good comparison achieved between the monitoring data and the dam–reservoir–foundation model shows that the formulation is suitable for simulating the modal response (natural frequencies and mode shapes) for different reservoir water levels and the seismic response under low-intensity earthquakes, using accelerograms measured at the dam base as input. Additionally, the dam’s nonlinear seismic response is simulated under an artificial accelerogram of increasing intensity, showing the structural effects due to vertical joint movements (release of arch tensions near the crest) and the concrete damage evolution. Full article

The strength parameters of fault gouge are critical factors that influence sealing capacity and fault reactivation in underground gas storage reservoirs. This study investigates the shear characteristics of remolded fault gouge under varying hydro-mechanical conditions, focusing on the coupled influence of water content and cementation. Sixty fault gouge samples are prepared using a mineral mixture of quartz, montmorillonite, and kaolinite, with five levels of water content (10–30%) and three cementation degrees (0%, 1%, 3%). Direct shear tests are conducted under four normal stress levels (100–400 kPa), and microstructural characteristics are examined using SEM. The results show that shear strength and cohesion exhibit a non-monotonic trend with water content, increasing initially and then decreasing, while the internal friction angle decreases continuously. Higher cementation degrees not only enhance shear strength and reduce the softening effect caused by water but also shift the failure mode from ductile sliding to brittle, cliff-type rupture. Moreover, clay content is found to modulate the degree—but not the trend—of strength parameter responses to water and cementation variations. Based on the observed mechanical behavior, a semi-empirical shear strength prediction model is developed by extending the classical Mohr–Coulomb criterion with water–cementation coupling terms. The model accurately predicts cohesion and internal friction angle as functions of water content and cementation degree, achieving strong agreement with experimental results (R² = 0.8309 for training and R² = 0.8172 for testing). These findings provide a practical and interpretable framework for predicting the mechanical response of fault gouge under complex geological conditions. Full article

Red-layer soft rock has characteristics such as softening when encountering water, loose structure, and significant rheological properties. In tunnel engineering, it is necessary to sort out and analyze the stress characteristics of its support structure. This paper focuses on the mechanical behavior and support effect during the construction of Neogene red-layer soft rock tunnels. Through field monitoring, it explores the mechanical characteristics of Huizhou Tunnel under complex geological conditions in depth. This study adopted a remote wireless monitoring system to conduct real-time monitoring of key indicators including tunnel surrounding rock pressure, support structure stress, and deformation, obtaining a large amount of detailed data. An analysis revealed that the stress experienced by rock bolts is complex and varies widely, with stress values between 105 and 330.5 MPa. The peak axial force at a depth of 2.5 m reflects that the thickness of the loosened zone in the surrounding rock is approximately 2.5 m. The compressive stress in the steel arches of the primary support does not exceed 305.3 MPa. Shotcrete effectively controls the surrounding rock deformation, but the timing of support installation needs careful selection. The stress in the secondary lining is closely related to the primary support. The research findings provide an important theoretical basis and practical guidance for optimizing the support design of red-bed soft rock tunnels and enhancing construction safety and reliability. Full article

Rainfall can easily cause local sliding and collapse of carbonaceous mudstone deep road cut slopes. In order to study the strength characteristics of carbonaceous mudstone under different water environments, large-scale horizontal push shear tests were conducted on carbonaceous mudstone rock masses in their natural state and after immersion in saturated water. The push shear force–displacement relationship curve and fracture surface shape characteristics of carbonaceous mudstone samples were analyzed, and the shear strength index of carbonaceous mudstone was obtained, and numerical simulations on the stability and support effect of carbonaceous mudstone slopes were conducted. The research results indicate that carbonaceous mudstone can exhibit good structural properties and typical strain softening characteristics under natural conditions. The fracture surface, shear strength, and shear deformation process of carbonaceous mudstone samples will undergo significant changes after being soaked in saturated water. The average cohesion decreases by 33% compared to the natural state, and the internal friction angle decreases by 15%. The numerical simulation results also fully verify the attenuation of mechanical properties of carbonaceous mudstone after immersion, as well as the effectiveness of prestressed anchor cables and frame beams in supporting carbonaceous mudstone slopes. The research results provide an effective method for understanding the shear performance of carbonaceous mudstone and practical guidance for evaluating the stability and reinforcement design of carbonaceous mudstone slopes. Full article

The long-term immersion of coal rock may affect its mechanical properties and failure modes, potentially impacting the stability of coal pillars. This work aims to investigate the influence of the immersion duration on the mechanical properties and fracture evolution processes of coal, employing acoustic emission detection and the digital image correlation (DIC) method. The work focuses on the weakening law of the coal pillar dam in contact with water and obtains a model of the strength deterioration after different periods of water immersion. The stress–strain curves of coal specimens with varying immersion durations are obtained. The results show that the peak absorption rate of coal samples immersed in water transpires within 24 h, with fundamental saturation being achieved at between 25 and 30 days at saturation moisture content of 1.97%. The specimen’s compressive stress after being immersed in water for 7 days is 3.34 MPa, with strain of 0.18%. The cracking stress is 15.60 MPa, with strain of 0.54%. The peak stress is recorded at 27.65 MPa, with strain of 0.92%. The complete rupture stress measures 23.37 MPa, with the maximum strain at 0.95%. During the yielding stage, the specimen has the highest strain increment of 0.38%. Short-term immersion brings about an increase in the coal sample’s plasticity, exhibiting a relatively minor softening impact of water, resulting in comparatively intact fragmentation and modest breakage. A negative exponential function relationship is observed between the compressive strength of coal and the immersion duration. The mechanical reduction relationship is utilized to analyze the failure patterns of coal pillars in underground reservoirs. With prolonged water immersion, the damage area expands to include the coal pillars and the surrounding rock of the excavation area. Full article

The mechanical performance of poly(methyl methacrylate) (PMMA) is highly sensitive to moisture absorption, which induces plasticization and softening. In this study, we investigated the ductilization mechanism of PMMA by incorporating various metal salts with different cations (Li⁺ and Mg²⁺) and controlling water absorption through hygroscopic interactions. A nonequilibrium constitutive model is introduced, in which localized water domains around salt-rich regions gradually diffuse into the PMMA matrix during tensile deformation. The stress–strain behavior is described by combining rigid (dry) and soft (hydrated) matrix components, connected through an internal kinetic variable governed by the strain-dependent diffusion rate. The model successfully reproduces experimental tensile data and captures the transition from brittle to ductile behavior as a function of the moisture content. Notably, Mg salts exhibit stronger water binding and slower moisture redistribution than Li salts, resulting in distinct mechanical responses. These findings provide a mechanistic framework for tailoring the ductility of hygroscopic polymer systems via ion–water–polymer interactions. Full article

This study aimed to improve the mechanical properties and water resistance of calcined gypsum from phosphogypsum (CGP) by incorporating organic additives and inorganic admixtures. The effects of the dosage of these additives—including kaolin, nano-SiO₂, polycarboxylic acid superplasticizer, and sodium methyl silicate—on the properties (flexural strength, compressive strength, water absorption, and softening coefficient) of CGP composites (CGPCs) were investigated. A high water resistance of the CGPCs was achieved using nano-SiO₂ and sodium methyl silicate modification, superplasticizer addition, and the partial replacement of gypsum with mineral admixtures. The results showed that the flexural and compressive strength of the composites hit 4.61 MPa and 19.54 MPa, respectively, while the softening coefficient was 0.70 and the water absorption rate was 19.85%. Microstructural investigation confirmed that the combination of nano-SiO₂ and kaolin led to the formation of calcium silicate hydrate. Additionally, the superplasticizer played a crucial role in reducing the water-to-cement ratio, while unhydrated mineral particles had a filling effect, thereby enhancing the density of the hardened paste. The sodium methyl silicate formed a hydrophobic film on the surface of the hardened paste, increasing the contact angle to 109.01° and improving the water resistance of the CGPCs. Full article

Fresh-cut vegetables are gaining economic importance around the world. They are highly perishable products, and in the context of global food waste challenges, any new solutions to reduce losses are in line with the expectations of producers, traders, and consumers. The aim of this study was to evaluate the effect of hot water treatment (HWT) on the quality and durability of two varieties of fresh-cut peppers at three storage temperatures: 3, 5, and 8 °C. Microscopic observations revealed changes in the tissue structure of the pepper sticks. During the storage of red-fruit “Yecla” peppers, the HWT samples retained better firmness. The peppers treated at 55 °C for 12 s maintained the best quality during storage. Cream-fruit “Blondy” peppers softened during storage, but the browning of the cut surface contributed the most to the reduction in quality. HWT at 53 °C for 3 min or 50 °C for 5 min effectively inhibited the development of destructive changes during storage. HWT is beneficial for fresh-cut peppers, but the temperature and duration of operation should be properly selected given the nature of the cultivar. Full article

Current hydrogels used for cartilage tissue engineering often lack the mechanical strength and structural integrity required to mimic native human cartilage. This study addresses this limitation by developing reinforced hydrogels based on a ternary polymer blend of poly(vinyl) alcohol (PVA), gelatin (GL), and chitosan (CH), with gentamicin sulfate (GS) as an antimicrobial agent and a crosslinker. The hydrogels were produced using two crosslinking methods, the freeze/thaw and heated cycles, and reinforced with forcespun polycaprolactone (PCL) nanofiber to improve mechanical performance. Chemical characterization revealed that GS forms weak hydrogen bonds with the ternary polymers, leading to esterification with PVA, and covalent bonds are formed as the result of the free amino group (-NH₂) of chitosan that reacts with the carboxylic acid group (-COOH) of gelatin. SEM images help us to see how the hydrogels are reinforced with polycaprolactone (PCL) fibers produced via force spinning technology, while mechanical properties were evaluated via uniaxial tensile and compressive tests. Water retention measurements were performed to examine the crosslinking process’s influence on the hydrogel’s water retention, while the hydrogel surface roughness was obtained via confocal microscopy images. A constitutive model based on non-Gaussian strain energy density was introduced to predict experimental mechanical behavior data of the hydrogel, considering a non-monotonous softening function. Loading and unloading tests demonstrated that GS enhanced crosslinking without compromising water retention or biocompatibility because of the reaction between the free amino group of CH and the carboxylic group of gelatin. The PCL-reinforced PVA/GL/CH hydrogel shows strong potential for cartilage repair and tissue engineering applications. Full article

In this study, novel biodegradable polycaprolactone (PCL)-based composites for sustainable packaging applications were developed by adding surface-treated wood fibers (WFs). Specifically, the WFs were treated with citric acid (CA) to improve the fiber/matrix adhesion and then melt compounded with a PCL matrix. The presence of an absorption peak at 1720 cm⁻¹ in the Fourier transform infrared (FTIR) spectra of CA-treated WFs, coupled with the increase in the storage modulus and complex viscosity in the rheological analysis, confirmed the occurrence of an esterification reaction between CA and WFs, with a consequent increase in interfacial interactions with the PCL matrix. Scanning electron microscopy (SEM) of the cryo-fractured surface of the composites highlighted that PCL was able to efficiently wet the fibers after the CA treatment, with limited fiber pull-out. Quasi-static tensile tests showed that the composites reinforced with CA-treated wood fibers exhibited a significant increase in yield strength (about 30% with a WF amount of 10% at 0 °C) and also a slight improvement in the VICAT softening temperature (about 6 °C with respect to neat PCL). Water absorption tests showed reduced water uptake in CA-treated composites, consistent with the reduced hydrophilicity confirmed by higher water contact angle values. Therefore, the results obtained in this work highlighted the potential of CA-treated WFs as reinforcement for PCL composites, contributing to the development of eco-sustainable and high-performance packaging materials. Full article

Expansive soils have significant characteristics of expansion by water absorption, contraction by water loss. Under the freeze–thaw (F-T) cycles, the engineering diseases are more significant, and the serious geotechnical engineering incidents are induced extremely easily. The aim is to investigate the mechanical response characteristics of geogrid-reinforced expansive soils (GRES) under F-T cycles. Based on a series of large-scale temperature-controlled triaxial tests, influencing factors were considered, such as the number of F-T cycles, the geogrid layers, and the confining pressure. The results showed that: (1) Friction between the expansive soil and geogrid and the geogrid’s embedded locking effect indirectly provided additional pressure, limited shear deformation. With the increase in reinforced layers, the stress–strain curve changed from a strain-softening to a strain-hardening type. (2) Elastic modulus, cohesion, and friction angle decreased significantly with increasing number of F-T cycles, whereas dynamic equilibrium was reached after six F-T cycles. (3) The three-layer reinforced specimens showed the best performance of F-T resistance, compared to the plain soil, the elastic modulus reduction amount decreases from 35.7% to 18.3%, cohesion from 24.5% to 14.3%, and friction angle from 7.6% to 4.5%. (4) A modified Duncan–Zhang model with the confining pressure, the F-T cycles, and the geogrid layers was proposed; the predicted values agreed with the measured values by more than 90%, which can be used as a prediction formula for the stress–strain characteristics of GRES under freeze–thaw cycling conditions. The research results can provide important theoretical support for the practical engineering design of GRES in cold regions. Full article

The South China region is characterized by diverse landforms and significant stratification of geological materials. The rock and soil layers in this area have obvious layering characteristics. The stability of layered slopes is a critical issue in the safe mining of southern ion-type rare earth ores. This study investigates the morphological changes, pore water pressure, and moisture content variation of layered ion-type rare earth ore slopes under the combined effects of rainfall and liquid infiltration through indoor model tests. A numerical simulation was conducted to analyze the variations in pore water pressure, moisture content, slope displacement, and safety factor under different working conditions. As rainfall intensity increases, the interface between soil layers in sandy–silty clay slopes is more likely to form a saturated water retention zone, causing rapid pore water pressure buildup and a significant reduction in shear strength. For the silty–sand clay slopes, the low permeability of the upper silty clay layer limits the infiltration rate of water, resulting in significant interlayer water retention effects, which induce softening and an increased instability risk. The higher the initial moisture content, the longer the infiltration time, which reduces the matrix suction of the soil and significantly weakens the shear strength of the slope. When the initial moisture content and rainfall intensity are the same, the safety factor of the silty–sand clay slope is higher than that of the sandy–silty clay slope. When rainfall intensity increases from 10 mm/h to 30 mm/h, the safety factor of the sandy–silty clay slope decreases from 1.30 to 1.15, indicating that the slope is approaching a critical instability state. Full article

The Loess Plateau region of China has an anomalous climate and frequent geological disasters. Hipparion laterite in seasonally frozen regions exhibits heightened susceptibility to freeze–thaw (F-T) cycling, which induces progressive structural weakening and significantly elevates the risk of slope instability through mechanisms including pore water phase transitions, aggregate disintegration, and shear strength degradation. This study focuses on the slip zone Hipparion laterite from the Nao panliang landslide in Fugu County, Shaanxi Province. We innovatively integrated F-T cycling tests with ring-shear experiments to establish a hydro-thermal–mechanical coupled multi-scale evaluation framework for assessing F-T damage in the slip zone material. The microstructural evolution of soil architecture and pore characteristics was systematically analyzed through scanning electron microscopy (SEM) tests. Quantitative characterization of mechanical degradation mechanisms was achieved using advanced microstructural parameters including orientation frequency, probabilistic entropy, and fractal dimensions, revealing the intrinsic relationship between pore network anisotropy and macroscopic strength deterioration. The experimental results demonstrate that Hipparion laterite specimens undergo progressive deterioration with increasing F-T cycles and initial moisture content, predominantly exhibiting brittle deformation patterns. The soil exhibited substantial strength degradation, with total reduction rates of 51.54% and 43.67% for peak and residual strengths, respectively. The shear stress–displacement curves transitioned from strain-softening to strain-hardening behavior, indicating plastic deformation-dominated shear damage. Moisture content critically regulates pore microstructure evolution, reducing micropore proportion to 23.57–28.62% while promoting transformation to mesopores and macropores. At 24% moisture content, the areal porosity, probabilistic entropy, and fractal dimension increased by 0.2263, 0.0401, and 0.0589, respectively. Temperature-induced pore water phase transitions significantly amplified mechanical strength variability through cyclic damage accumulation. These findings advance the theoretical understanding of Hipparion laterite’s engineering geological behavior while providing critical insights for slope stability assessment and landslide risk mitigation strategies in loess plateau regions. Full article

The strength of soft rock masses progressively deteriorates under dissolution effects, leading to extensive pore development and structural loosening within the rock matrix. This process induces water and sand inrush phenomena at excavation faces, posing substantial challenges to construction safety. This study systematically investigates the strength degradation mechanisms and engineering disaster evolution of soft rock subjected to water–rock interactions. Utilizing representative water-rich soft rock specimens from a tunnel in central Yunnan, a multi-scale analytical framework incorporating X-ray diffraction mineral analysis systems, triaxial mechanical testing systems for rocks, scanning electron microscopy (SEM), and nuclear magnetic resonance (NMR) was implemented. This integrated methodology comprehensively elucidates the macro–meso damage evolution mechanisms of soft rock under water–rock coupling interactions. The results indicate that as the dolomite content decreases and the impurity content increases, the softening grade of the rock rises, leading to more extensive pore development. Uniaxial compression tests revealed that the Poisson’s ratio of soft rock is significantly higher than that of typical rock. Triaxial compression tests demonstrated that confining pressure has a substantial impact on soft rock, particularly affecting Poisson’s ratio. Increased water content was found to significantly reduce the strength of the soft rock. Compared to loose soft rock, the radial strain of denser soft rock was markedly greater than the axial strain, and the soaking damage effect was more pronounced. This study provides a valuable insight into the mechanical and permeability behavior of soft rock under different conditions, and provides valuable insights into the solutions for soft rock in geological engineering such as tunnel excavations. Full article