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Keywords = water potential

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27 pages, 2567 KB  
Article
Economic Sustainability of Selected Individual On-Site Systems of Rural Sanitation Under Conditions in Poland
by Marcin K. Widomski and Anna Musz-Pomorska
Sustainability 2025, 17(22), 10241; https://doi.org/10.3390/su172210241 (registering DOI) - 16 Nov 2025
Abstract
The sustainability of rural areas depends on effective wastewater management to reduce human impact on the environment, including the risk of pollution to surface water, groundwater, and soil from human waste. However, organized sanitation systems, which include pipeline networks and wastewater treatment plants [...] Read more.
The sustainability of rural areas depends on effective wastewater management to reduce human impact on the environment, including the risk of pollution to surface water, groundwater, and soil from human waste. However, organized sanitation systems, which include pipeline networks and wastewater treatment plants in rural communities with low population densities, often have very low profitability and cost-efficiency, which greatly reduces their acceptance and residents’ willingness to pay. This study examines the economic profitability and cost-efficiency of selected on-site household sewage collection and treatment systems operating under real economic conditions in Poland. An evaluation was conducted on seven contemporary models of individual bioreactors, as well as a standard anaerobic septic tank equipped with drainage filters. Additionally, all options were tested on permeable and poorly permeable soils. For each variant, investment costs, as well as operation and maintenance expenses, were calculated. Financial evaluation utilized indicators of economic profitability and cost-efficiency, including the Payback Period, Net Present Value, Benefits–Cost Ratio, and Dynamic Generation Costs. The potential financial benefits included savings from avoiding the use of holding septic tanks and sewage transport by slurry wagons. All the studied designs of on-site sanitary sewage management showed significant economic feasibility and cost-efficiency. Full article
(This article belongs to the Section Economic and Business Aspects of Sustainability)
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18 pages, 2535 KB  
Article
Assessment of Exploited Stock and Management Implications of Kingfish (Scomberomorus commerson) in the Omani Waters
by Usama Aladawi, Samroz Majeed, Ibrahim Al-Anboori and S. M. Nurul Amin
Fishes 2025, 10(11), 589; https://doi.org/10.3390/fishes10110589 (registering DOI) - 15 Nov 2025
Abstract
The high demand and economic value of kingfish (Scomberomorus commerson) have led to intensive fishing of this species in the Omani waters. The increased fishing pressure has made the fishery vulnerable; hence, information on the current stock status is essential for [...] Read more.
The high demand and economic value of kingfish (Scomberomorus commerson) have led to intensive fishing of this species in the Omani waters. The increased fishing pressure has made the fishery vulnerable; hence, information on the current stock status is essential for the sustainability of the kingfish stock. Three length-based stock assessment approaches (TropFishR, spawning potential ratio, and Bayesian biomass method) were used to estimate growth, mortality, exploitation, spawning potential capacity, and relative biomass in relation to maximum sustainable yield (MSY). Asymptotic length (L) was 186.31 cm, and the growth coefficient (K) was 0.15 yr−1 for S. commerson. Fishing mortality was 0.45 yr−1, which was higher than natural mortality (M = 0.18 yr−1) and optimal fishing mortalities (F40% = 0.15 yr−1). The exploitation rate (E) was found to be 0.71 yr−1, higher than the optimum exploitation (E = 0.50), indicating a total overfishing of 42% of the S. commerson in Oman waters. The current length at first capture (Lc50 = 74.38 cm) was significantly smaller than the length at first maturity (Lm50 = 91.25 cm), indicating growth overfishing. The current spawning potential ratio (SPR) was 10%, which was significantly below the reference point (SPR = 20%), indicating that the stock was severely overfished. Biomass was critically low (B/Bo = 0.17), and lower than the reference point of 0.20. Additionally, the current biomass was 44% of Bmsy (B/Bmsy = 0.44), which is significantly lower than the reference point of 1, indicating that the stock biomass was below the maximum sustainable yield level, suggesting recruitment overfishing. Stock indicators revealed that the fishery was primarily targeting immature/juvenile fish, as well as older and larger fish, which indicated stocks were both growth- and recruitment-overfished. Therefore, carrying out commercial fishing for an optimum size range (118 to 144 cm) and reducing fishing pressure to a sustainable level (F = M, 0.18 yr−1) would sustain a healthy stock biomass of kingfish in Omani waters. Full article
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34 pages, 71927 KB  
Article
Residual Flexural Strength of Concrete Reinforced with Recycled Carbon Fibers from Wind Turbine Blades
by Julita Krassowska
Materials 2025, 18(22), 5195; https://doi.org/10.3390/ma18225195 (registering DOI) - 15 Nov 2025
Abstract
The study aims to assess the potential of recycled carbon fibers recovered from end-of-life wind turbine blades as a sustainable reinforcement material for concrete and to establish correlations between fiber parameters and the mechanical behavior of fiber-reinforced concrete. The research focuses on how [...] Read more.
The study aims to assess the potential of recycled carbon fibers recovered from end-of-life wind turbine blades as a sustainable reinforcement material for concrete and to establish correlations between fiber parameters and the mechanical behavior of fiber-reinforced concrete. The research focuses on how fiber length, content, and cement type affect the residual flexural strength and cracking behavior of FRC. The experimental program included 48 concrete mix series with varying fibre lengths (25, 38, and 50 mm), dosages (0, 2, 4, and 8 kg/m3), cement types (CEM I 42.5 and CEM II 42.5R/A-V), and water-to-cement ratios (0.50 and 0.40). Mechanical properties such as compressive strength, tensile strength, modulus of elasticity, and residual flexural strength were evaluated. Notched beams underwent three-point bending tests, and the progression of cracks was tracked using the digital image correlation method. The analysis revealed that enhancing both the fiber content and length generally bolstered the toughness and post-cracking characteristics of concrete, with a notable effect observed for fibers ranging from 38 to 50 mm in length when used at a dosage of 8 kg/m3. However, the effects depend on the fiber recovery technology and the base concrete strength, which may influence the results and should be considered as a limitation of this study. Full article
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60 pages, 7411 KB  
Article
An Integrated Methodology for Novel Algorithmic Modeling of Non-Spherical Particle Terminal Settling Velocities and Comprehensive Digital Image Analysis
by Kaan Yetilmezsoy, Fatih Ilhan and Emel Kıyan
Water 2025, 17(22), 3268; https://doi.org/10.3390/w17223268 (registering DOI) - 15 Nov 2025
Abstract
Accurate prediction of settling velocities for irregular particles offers significant advantages in various fields, including more efficient water/wastewater treatment, environmental pollution control, industrial productivity, and sustainable resource utilization. These predictions are essential for advancing sustainable hydraulic engineering and environmental management. In this study, [...] Read more.
Accurate prediction of settling velocities for irregular particles offers significant advantages in various fields, including more efficient water/wastewater treatment, environmental pollution control, industrial productivity, and sustainable resource utilization. These predictions are essential for advancing sustainable hydraulic engineering and environmental management. In this study, a new algorithmic modeling framework was proposed to estimate the terminal settling velocity of irregularly shaped particles/materials. The framework integrates advanced non-linear regression techniques with robust optimization methods. The model successfully incorporated seven key input parameters to construct a comprehensive mathematical representation of the settling process. The proposed explicit model demonstrates superior prediction accuracy compared to existing empirical and drag correlation models. The model’s validity was confirmed using a large and morphologically diverse dataset of 86 irregular materials and rigorously evaluated using an extensive battery of statistical goodness-of-fit parameters. The developed model is a robust and highly accurate tool for predicting the settling behavior of non-spherical particles in the transition flow regime. Beyond its technical merits, the model could offer significant sustainability benefits by enhancing the design and optimization of wastewater treatment systems. More precise predictions of non-spherical particle settling behavior could improve sedimentation or particle removal efficiency, potentially reducing energy consumption and mitigating adverse environmental impacts on industrial waste management and aquatic ecosystem preservation. Full article
(This article belongs to the Special Issue Mathematical Models of Fluid Dynamics)
19 pages, 3333 KB  
Article
Spatial Distribution and Environmental Impacts of Soil Nitrogen and Phosphorus in the Downstream Daliao River Basin
by Tianxiang Wang, Yexin Liu, Zixiong Wang, Tianzi Wang, Zipeng Zhang, Runfa Cui, Rongyue Ma and Guangyu Su
Water 2025, 17(22), 3267; https://doi.org/10.3390/w17223267 (registering DOI) - 15 Nov 2025
Abstract
Soil nitrogen (N) and phosphorus (P) loss in watersheds is a critical source of water pollution. This study explores the spatial distribution, release potential, and environmental impacts of soil N and P in the downstream Daliao River basin by integrating field investigations and [...] Read more.
Soil nitrogen (N) and phosphorus (P) loss in watersheds is a critical source of water pollution. This study explores the spatial distribution, release potential, and environmental impacts of soil N and P in the downstream Daliao River basin by integrating field investigations and simulation experiments. Results showed that total nitrogen content in soils ranged from 256.09 to 3362.75 mg/kg, while that in sediments ranged from 114.85 to 1640.54 mg/kg. Total phosphorus content in soils varied from 250.18 to 1142.69 mg/kg, whereas in sediments it ranged from 327.23 to 586.24 mg/kg. The ammonia nitrogen release potentials of soils collected from rice paddies, corn farmlands, roadsides, and reed wetlands were 0.75, 0.86, 0.70, and 8.65 mg/L, respectively, with corresponding total phosphorus release potentials of 0.61, 1.01, 0.31, and 1.52 mg/L. For sediments, ammonia nitrogen and total phosphorus release potentials ranged from 0.96 to 1.21 mg/L and 0.44 to 0.52 mg/L, respectively. Temperature, pH, and dissolved oxygen were important factors influencing nitrogen and phosphorus release from soils and sediments. The export of nitrogen and phosphorus from soil reached 50.50 t/a and 21.63 t/a, respectively. During the soil erosion process in the Daliao River Basin, phosphorus exhibited a high release potential and served as the primary pollutant, whereas the release mechanism of ammonia nitrogen was more complex, showing seasonal variability. Soils in the downstream Daliao River basin have large specific surface areas and may pose a high pollution risk after discharge into water bodies due to prolonged adsorption of pollutants. It is recommended to propose promoting soil testing-based fertilization, constructing ecological engineering projects, developing sponge cities, and conducting environmental dredging to reduce N and P release from agricultural lands, construction areas, natural wastelands, and sediments. Full article
19 pages, 4277 KB  
Article
Investigation of Performance Degradation in Calcium-Based Grease Under Combined SiO2 Particle and Water Contamination
by Thi-Na Ta, Shin-Yuh Chern, Jeng-Haur Horng, Chun-Wei Kuo and Sheng-Jie Liao
Lubricants 2025, 13(11), 499; https://doi.org/10.3390/lubricants13110499 (registering DOI) - 15 Nov 2025
Abstract
Environmental contamination critically affects the durability and performance of lubricants in machine components. Over long operating periods, particles and water ingress through degraded seals accelerate grease degradation and deteriorate tribological behavior. This study evaluates the effects of SiO2 particle concentration and water [...] Read more.
Environmental contamination critically affects the durability and performance of lubricants in machine components. Over long operating periods, particles and water ingress through degraded seals accelerate grease degradation and deteriorate tribological behavior. This study evaluates the effects of SiO2 particle concentration and water contamination, alone and in combination, on the performance of calcium-based grease in bearing steel contacts. Friction coefficients, grease temperatures, wear, pitting, and vibration signals were analyzed. The results show that an increase in particle concentration raised both friction and temperature, leading to more severe wear and pitting. The addition of 0.6 wt% water reduced fluctuations in friction and temperature, but when combined with high particle concentrations, it significantly worsened wear and pitting. The vibration-based energy ratio correlated strongly with pitting evolution, highlighting its potential as a sensitive parameter for monitoring surface fatigue. These findings provide insights into lubricant degradation under contaminated conditions and offer guidance for improving the reliability of lubricated systems. Full article
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23 pages, 4490 KB  
Article
A Silver (I) Complex-Loaded Lipid Nanoemulsion: A New Approach Against Candida albicans Biofilms
by Giovanna Capaldi Fortunato, Gabriel Davi Marena, Débora Eduarda Soares Silva, Tamara Renata Machado Ribeiro, Cristiano Gallina Moreira, Flávia Aparecida Resende Nogueira, Leonardo Delello Di Filippo, Marlus Chorilli, Adelino Vieira de Godoy Netto and Taís Maria Bauab
Drugs Drug Candidates 2025, 4(4), 52; https://doi.org/10.3390/ddc4040052 (registering DOI) - 15 Nov 2025
Abstract
Introduction: The increasing prevalence of fungal infections, particularly those caused by Candida albicans, presents a significant clinical challenge due to the emergence of drug-resistant strains. Silver (I) coordination complexes show promise as antifungal agents; however, their poor water solubility limits clinical [...] Read more.
Introduction: The increasing prevalence of fungal infections, particularly those caused by Candida albicans, presents a significant clinical challenge due to the emergence of drug-resistant strains. Silver (I) coordination complexes show promise as antifungal agents; however, their poor water solubility limits clinical application. Methods: In this study, we developed and characterized a lipid nanoemulsion (Ag-LN) to enhance the delivery and activity of a silver (I) complex. Results: The formulation exhibited nanoscale size, spherical morphology, and stability for up to 60 days. Ag-LN showed potent antifungal effects, preventing biofilm formation and eradicating mature biofilms. Importantly, nanoencapsulation preserved antifungal activity while reducing mutagenic potential and acute toxicity compared with the free compound. Conclusions: These findings support Ag-LN as a promising antifungal platform for future preclinical studies. Full article
(This article belongs to the Collection Bioinorganic Chemistry in Drug Discovery)
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15 pages, 2026 KB  
Article
Variability of Root and Shoot Traits Under PEG-Induced Drought Stress at an Early Vegetative Growth Stage of Maize
by Miroslav Bukan, Snježana Kereša, Ivan Pejić, Ana Lovrić and Hrvoje Šarčević
Agronomy 2025, 15(11), 2624; https://doi.org/10.3390/agronomy15112624 (registering DOI) - 15 Nov 2025
Abstract
The development of maize varieties with enhanced tolerance to drought stress has become a high-priority goal for maize breeding programs worldwide. In order to assess the variability of root and shoot traits in response to drought at an early vegetative stage, a set [...] Read more.
The development of maize varieties with enhanced tolerance to drought stress has become a high-priority goal for maize breeding programs worldwide. In order to assess the variability of root and shoot traits in response to drought at an early vegetative stage, a set of 32 maize single-cross hybrids was grown under polyethylene glycol 8000-induced drought stress and well-watered control treatments. Drought stress significantly reduced hybrid seedling root and shoot lengths (RL and SL) as well as root and shoot fresh weights (RFW and SFW), while an increase in seedling root and shoot dry matter (RDM and SDM) and root fresh weight-to-shoot fresh weight ratio (RFW/SFW) was observed. The high heritability estimates for the four directly and easily measured traits, namely, RL, SL, RFW, and SFW (0.83, 0.83, 0.74, and 0.74, respectively), and medium-to-very-strong positive correlations among these traits under drought conditions indicate their applicability for the assessment of maize drought tolerance at the seedling stage and may represent a practical contribution to maize breeding programs for improved drought tolerance. Among the studied hybrids, hybrids 30, 3, and 23 were characterized by the largest RL under drought conditions and small relative change in RL between control and drought treatments. Hybrid 30 also showed one of the smallest relative reductions in SL, RFW, and SFW between the two treatments, while hybrids 3 and 23 were among those which exhibited the highest relative RL/SL and RFW/SFW increase between the two treatments, which supports their potential as parental lines in drought-tolerant breeding. Full article
(This article belongs to the Special Issue Genetic Basis of Crop Selection and Evolution)
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19 pages, 3088 KB  
Article
Leveraging Limited ISMN Soil Moisture Measurements to Develop the HYDRUS-1D Model and Explore the Potential of Remotely Sensed Precipitation for Soil Moisture Estimates in the Northern Territory, Australia
by Muhammad Usman and Christopher E. Ndehedehe
Remote Sens. 2025, 17(22), 3723; https://doi.org/10.3390/rs17223723 - 14 Nov 2025
Abstract
Soil moisture plays a key role in the critical zone of the Earth and has extensive value in the understanding of hydrological, agricultural, and environmental processes (among others). Long-term (in situ) monitoring of soil moisture measurements is generally not practical; however, short-term measurements [...] Read more.
Soil moisture plays a key role in the critical zone of the Earth and has extensive value in the understanding of hydrological, agricultural, and environmental processes (among others). Long-term (in situ) monitoring of soil moisture measurements is generally not practical; however, short-term measurements are often found. Limited soil moisture measurements can be employed to develop a numerical model for long-term and accurate soil moisture estimations. A key input variable to the model is precipitation, which is also not easily accessible, particularly at a finer spatial resolution; hence, publicly available remote sensing data can be used as an alternative. This study, therefore, aims to develop a numerical model HYDRUS-1D to estimate soil moisture in the data-scarce state of the Northern Territory, Australia, with a land cover of shrubland and a Tropical-Savannah type climate. The HDYRUS-1D is based on the numerical solution of Richards’ equation of variably saturated flow that relies on information about the soil water retention characteristics. This study utilized the van Genuchten model parameters, which were optimized (against measured soil moisture) through parameter optimization with initial estimates obtained from the HYDRUS catalogue. Initial estimates from different sources can differ for the same soil texture (e.g., loamy sand) and can induce uncertainties in the calibrated model. Therefore, a comprehensive uncertainty analysis was conducted to address potential uncertainties in the calibration process. The HYDRUS-1D was calibrated for a period between March 2012 and February 2013 and was independently validated against three different periods between March 2013 and October 2016. Root Mean Square Error (RMSE), Pearson’s correlation coefficient (R), and Mean Absolute Error (MAE) were used to assess the efficiency of the model in simulating the measured soil moisture. The model exhibited good performance in replicating measured soil moisture during calibration (RMSE = 0.00 m3/m3, MAE = 0.005 m3/m3, and R = 0.70), during validation period 1 (RMSE = 0.035 m3/m3 and MAE = 0.023 m3/m3, and R = 0.72), validation period 2 (RMSE = 0.054 m3/m3 and MAE = 0.039 m3/m3, and R = 0.51), and validation period 3 (RMSE = 0.046 m3/m3 and MAE = 0.032 m3/m3, and R = 0.61), respectively. Remotely sensed precipitation data were used from the CHRS-PERSIANN, CHRS-CCS, and CHRS-PDIR-Now to assess their capabilities in estimating soil moisture. Efficiency evaluation metrics and visual assessment revealed that these products underestimated the soil moisture. The CHRS-CCS outperformed other products in terms of overall efficiency (average RMSE of 0.040 m3/m3, average MAE of 0.023 m3/m3, and an average R of 0.68, respectively). An integrated approach based on numerical modelling and remote sensing employed in this study can help understand the long-term dynamics of soil moisture and soil water balance in the Northern Territory, Australia. Full article
(This article belongs to the Special Issue Earth Observation Satellites for Soil Moisture Monitoring)
13 pages, 572 KB  
Review
Purinergic Signaling in Swallowing Reflex Initiation: Mechanisms and Therapeutic Implications for Oropharyngeal Dysphagia—A Narrative Review
by Junrong Qi, Mohammad Zakir Hossain, Hiroshi Ando, Rita Rani Roy and Junichi Kitagawa
Cells 2025, 14(22), 1795; https://doi.org/10.3390/cells14221795 - 14 Nov 2025
Abstract
The swallowing reflex is a highly coordinated process that is essential for safe bolus transit and airway protection. Although its neurophysiological framework has been extensively studied, the molecular mechanisms underlying reflex initiation remain incompletely understood, limiting targeted therapies for oropharyngeal dysphagia. Recent evidence [...] Read more.
The swallowing reflex is a highly coordinated process that is essential for safe bolus transit and airway protection. Although its neurophysiological framework has been extensively studied, the molecular mechanisms underlying reflex initiation remain incompletely understood, limiting targeted therapies for oropharyngeal dysphagia. Recent evidence implicates purinergic signaling as a key mediator of swallowing initiation, particularly through ATP release from taste buds and neuroendocrine cells in the hypopharyngeal and laryngeal mucosa. Experimental studies in mice demonstrate that water, acidic, and bitter chemical stimuli induce ATP release, activating purinergic receptors (P2X2, P2X3, heteromeric P2X2/P2X3, and P2Y1) on afferent sensory fibers. This receptor activation enhances input to the brainstem swallowing central pattern generator, initiating reflexive swallowing. Genetic ablation of purinergic receptor-expressing neurons or epithelial sentinel cells, as well as pharmacological antagonism of P2X or P2X3 receptors, markedly attenuates these responses. Furthermore, exogenous ATP or selective P2X3 agonists applied to swallowing-related mucosa evoke swallowing reflexes in an animal model, underscoring translational potential. While the precise upstream receptor mechanisms for water- and acid-induced ATP release, as well as species-specific differences, remain to be clarified, targeting purinergic pathways may represent a novel physiologically grounded therapeutic strategy for restoring swallowing function in patients with oropharyngeal dysphagia. Full article
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22 pages, 1134 KB  
Article
Valorization of Pear Pomace in Taro Gluten-Free Muffins: Composition, Texture, and Sensory Profile
by Dilek Demirbuker Kavak, Betül Aslan Yilmaz and Bilge Akdeniz
Foods 2025, 14(22), 3903; https://doi.org/10.3390/foods14223903 - 14 Nov 2025
Abstract
The search for high-quality gluten-free products remains challenging, as they often exhibit poor texture and nutritional deficiencies. The potential of taro (Colocasia esculenta L. Schott) flour combined with fruit by-products such as pear pomace (DP) to improve these characteristics remains largely unexplored. [...] Read more.
The search for high-quality gluten-free products remains challenging, as they often exhibit poor texture and nutritional deficiencies. The potential of taro (Colocasia esculenta L. Schott) flour combined with fruit by-products such as pear pomace (DP) to improve these characteristics remains largely unexplored. It was hypothesized that substituting taro flour with DP would enhance the nutritional profile and sensory quality of gluten-free muffins. Muffins were formulated with taro flour and DP at 0–20% substitution levels. Analyses included flour physicochemical characterization, image-based evaluation of crumb structure, multivariate sensory profiling, and assessment of antioxidant and nutritional properties. Taro flour showed high water-binding capacity, supporting product moisture. At 5% DP, total phenolics and dietary fiber increased by 55% and 32%, respectively, while maintaining control-like texture and porosity. A 10% DP substitution enhanced aroma attributes. Although 20% DP yielded the highest fiber (68%) and phenolics (155%) contents compared to the control, it increased hardness and reduced porosity. Substitution with up to 10% DP effectively balanced nutritional improvement and desirable sensory attributes, demonstrating the valorization potential of pear pomace in taro-based gluten-free muffins. Full article
14 pages, 1864 KB  
Article
Near-Infrared Spectroscopy for Oedema Quantification: An Ex Vivo Porcine Skin Model
by Mariana Castro-Montano, Meha Qassem and Panayiotis A. Kyriacou
Sensors 2025, 25(22), 6971; https://doi.org/10.3390/s25226971 - 14 Nov 2025
Abstract
Oedema is a common clinical finding in critically ill neonates and may reflect systemic illness such as congestive heart failure, hepatic cirrhosis, nephrotic syndrome, sepsis, and acute kidney injury. Oedema is characterised by tissue swelling due to water accumulation in the interstitial space. [...] Read more.
Oedema is a common clinical finding in critically ill neonates and may reflect systemic illness such as congestive heart failure, hepatic cirrhosis, nephrotic syndrome, sepsis, and acute kidney injury. Oedema is characterised by tissue swelling due to water accumulation in the interstitial space. Currently, the gold standard in clinical practice is visual assessment, which is subjective and limited in accuracy. Alternative methods, such as ultrasound and bioimpedance, have been explored; however, they are unsuitable in neonates and do not provide direct water quantification. Near-infrared spectroscopy (NIRS) is a non-invasive optical method that could measure water content through light interaction between near-infrared light and OH particles within the tissue. This study validated NIRS for oedema assessment using an ex vivo porcine skin model, where controlled oedema was induced by phosphate-buffered saline (PBS) injection. Continuous spectroscopic data were collected via optical fibres positioned perpendicularly and parallel to the tissue. Regression models were developed and evaluated using the spectral data, with partial least squares (PLS) regression outperforming ridge regression (RR) and support vector regression (SVR). Notably, spectra acquired in the parallel configuration yielded superior results (R2 = 0.97, RMSE = 0.15). These findings support the potential of NIRS as a reliable, quantitative tool for neonatal oedema assessment. Full article
(This article belongs to the Section Optical Sensors)
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25 pages, 1563 KB  
Article
AI-Augmented Water Quality Event Response: The Role of Generative Models for Decision Support
by Stephen Mounce, Richard Mounce and Joby Boxall
Water 2025, 17(22), 3260; https://doi.org/10.3390/w17223260 - 14 Nov 2025
Abstract
The global water sector faces unprecedented challenges from climate change, rapid urbanisation, and ageing infrastructure, necessitating a shift towards proactive, digital strategies. Historically characterised as “data rich but information poor,” the sector struggles with underutilised and siloed operational data. Traditional machine learning (ML) [...] Read more.
The global water sector faces unprecedented challenges from climate change, rapid urbanisation, and ageing infrastructure, necessitating a shift towards proactive, digital strategies. Historically characterised as “data rich but information poor,” the sector struggles with underutilised and siloed operational data. Traditional machine learning (ML) models have provided a foundation for smart water management, and subsequently deep learning (DL) approaches utilising algorithmic breakthroughs and big data have proved to be even more powerful under the right conditions. This paper explores and reviews the transformative potential of Generative Artificial Intelligence (GenAI) and Large Language Models (LLMs), enabling a paradigm shift towards data-centric thinking. GenAI, particularly when augmented with Retrieval-Augmented Generation (RAG) and agentic AI, can create new content, facilitate natural language interaction, synthesise insights from vast unstructured data (of all types including text, images and video) and automate complex, multi-step workflows. Focusing on the critical area of drinking water quality, we demonstrate how these intelligent tools can move beyond reactive systems. A case study is presented which utilises regulatory reports to mine knowledge, providing GenAI-powered chatbots for accessible insights and improved water quality event management. This approach empowers water professionals with dynamic, trustworthy decision support, enhancing the safety and resilience of drinking water supplies by recalling past actions, generating novel insights and simulating response scenarios. Full article
21 pages, 8458 KB  
Article
Chemo-Ultrasonication Rehabilitation of Thin-Film Composite Ultrapure Water Membrane for Spent Dialysate Recovery
by Nuhu Dalhat Mu’azu, Mukarram Zubair, Mohammad Saood Manzar, Aesha H. Alamri, Ishraq H. Alhamed, Asaad Al Alawi and Muhammad Nawaz
Membranes 2025, 15(11), 340; https://doi.org/10.3390/membranes15110340 - 14 Nov 2025
Abstract
The ever-increasing number of discarded end-of-life dialysate polyamide thin-film composite membranes (DEoLMs) from presents both environmental and economic challenges for health centers. Traditional thermo-chemical cleaning techniques have been deployed for the rehabilitation of DEoLMs. This study further investigated the application of chemo-ultrasonication rehabilitation [...] Read more.
The ever-increasing number of discarded end-of-life dialysate polyamide thin-film composite membranes (DEoLMs) from presents both environmental and economic challenges for health centers. Traditional thermo-chemical cleaning techniques have been deployed for the rehabilitation of DEoLMs. This study further investigated the application of chemo-ultrasonication rehabilitation of dialysate-production-related DEoLM for potential reuse in spent dialysate recovery considering salt and creatinine—a typical uremic toxin-removal from water. The DEoLM was rehabilitated using low-concentration citric acid (CA) and sodium lauryl sulfate (SLS) under ultrasonic waves (45 kHz, 30 min agitation). Considering different rehabilitation protocols, the synergistic effects of heating (HT) and the chemical agents, with and without and ultrasonic waves (SC) were evaluated through FTIR, SEM, and EDX analyses, and the performance of the rehabilitated DEoLM was assessed via water flux and permeance, and efficiencies for conductivity and creatinine rejection. The fully integrated protocol chemo-ultrasonication (HT + SC + chemical agents) yielded the highest performance, achieving 93.56% conductivity and 96.83% creatinine removal, with water flux of 113.48 L m−2 h−1 and permeances of 6.31 L m−2 h−1 bar−1, at markedly reduced pressures. The chemo-sonic-rehabilitated-DEoLM removed the organic–inorganic foulants beyond thermo-chemical cleaning. This suggests that the sonication waves had a great impact regarding rejuvenating the fouled DEoL dialysate membrane, offering a sustainable, cost-effective pathway for extending membrane life, and supporting sustainable water management to achieve circular economy goals within healthcare centers. Full article
(This article belongs to the Topic Separation Techniques and Circular Economy)
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32 pages, 2321 KB  
Article
Synergistic and Intelligent Hydrogel for Conducting Osteoblast Proliferation: Synthesis, Characterization, and Multifunctional Properties
by Karen Michelle Guillén-Carvajal, Benjamín Valdez-Salas, Ernesto Alonso Beltrán-Partida, Jorge Salomón Salvador-Carlos, Mario Alberto Curiel-Álvarez, Jhonathan Castillo-Saenz, Daniel González-Mendoza and Nelson Cheng
Gels 2025, 11(11), 910; https://doi.org/10.3390/gels11110910 - 14 Nov 2025
Abstract
Current trends in intelligent hydrogels design for tissue engineering demand multifunctional biomaterials that respond to external stimuli, while maintaining adhesion, controlled degradation, and cytocompatibility. The present work describes the synthesis and characterization of a novel, intelligent and synergistic hydrogel for promoting osteoblastic growth [...] Read more.
Current trends in intelligent hydrogels design for tissue engineering demand multifunctional biomaterials that respond to external stimuli, while maintaining adhesion, controlled degradation, and cytocompatibility. The present work describes the synthesis and characterization of a novel, intelligent and synergistic hydrogel for promoting osteoblastic growth and regeneration. The hydrogel comprises a complex matrix blend of natural biodegradable polymers, vitamins (A, K2, D3, and E), and bioactive components such as zinc phosphate nanoparticles and manganese-doped hydroxyapatite to improve osteoblastic functionality. The hydrogel proved to have physicochemical properties for recovery and self-healing, highlighting its potential application as an auxiliary in bone rehabilitation. Key parameters such as rheological behavior, moisture content, water absorption, solubility, swelling, biodegradability, and responsiveness to temperature and pH variations were thoroughly evaluated. Furthermore, its adhesion to different surfaces and biocompatibility were confirmed. Skin contact test revealed no inflammatory, allergic, or secondary effects, indicating its safety for medical applications. Importantly, the hydrogel showed high biocompatibility with no cytotoxicity signs, favoring cell migration and highlighting its potential for applications in regenerative medicine. Full article
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