Search Results (5,329)

The development of electrode materials that combine high capacity with high anion selectivity is critical for chloride separation from complex aqueous matrices. Here, a NiFe LDH/BiOCl composite film electrode was fabricated on carbon paper via sequential electrodeposition and employed for electrically switched ion exchange (ESIX) of chloride. The composite delivers higher reversible chloride uptake than either NiFe LDH or BiOCl alone under identical electrochemical conditions, together with enhanced selectivity in mixed−anion solutions. Mechanistically, the synergy originates from the combination of (i) the high anion−exchange capacity and redox−tunable layer charge of NiFe LDH and (ii) halide−affinitive BiOCl domains that facilitate voltage−gated uptake/release; the heterointerface further improves charge/ion transport, enabling more effective electrochemical utilization. The electrode maintains stable cycling performance with high regeneration efficiency over repeated ESIX operation. Compared with representative LDH− or BiOX−based ESIX electrodes reported for halide capture, the proposed composite shows competitive chloride selectivity and reversible cycling, supporting its potential for electrochemical separations and water treatment. Full article

Understanding the dynamic characteristics of droplets in the orientated flow channels of Proton Exchange Membrane Fuel Cells (PEMFCs) is crucial for their effective heat and water management and bipolar plate design. Therefore, the transient transport dynamics of liquid water within orientated gas flow channels (OGFCs) of PEMFCs are investigated, and a two-phase model based on the volume of fluid (VOF) method is established in the current study. Moreover, the impacts of the size of droplets and the geometrical parameters of baffles on the removal dynamics of liquid water are examined. The results show that baffles effectively promote droplet breakup and accelerate their detachment from the Gas Diffusion Layer (GDL) surface by increasing flow instability and local shear forces. The morphology of water is altered by the high velocity of gaseous flow, which can break up into several smaller droplets and distribute them on the surface of GDL by the gas flow. The shape of the liquid water film changes from a regular cuboid to a big droplet due to the surface tension of the liquid water droplets and the hydrophobicity of the GDL surfaces. Increasing the baffle height can reduce the time needed for the removal of droplets. With the increase in L1* from 0.25 to 0.75, the drainage time decreases slightly; however, for L1* increasing from 0.75 to 1.25, the drainage time remains almost the same. The impacts of different leeward lengths, L2*, on the water coverage ratio and pressure drop are minor. Full article

Metal ions exemplify one of the most harmful and environmentally detrimental contaminants of water systems. This work describes the creation of an innovative chelated carbon-doped nickel and titanium oxide (C-NiTiO₂) hybrid as an adsorbent for the effective elimination of metal ions. The dominance of the TiO₂ anatase phase with a ≈ 61 nm crystallite size was verified by XRD and Raman investigation. Morphology investigations exposed polygonal nanoparticles consisting of Ti, C, Ni, and O. The nanostructure exhibited a surface area of 17 m²·g⁻¹, a pore diameter of ≈1.5 nm, and a pore volume of 0.0315 cm³·g⁻¹. The nanostructure was evaluated for the elimination of Zn (II) ions from an aqueous solution. The metal ion adsorption onto the hybrid nanomaterial was described and comprehended using adsorption kinetics and equilibrium models. The adsorption data matched well with the pseudo-second-order kinetics and Langmuir adsorption models, indicating a monolayer chemisorption mechanism and achieving a maximum Zn (II) ion elimination of 369 mg·g⁻¹. Mechanistic investigation indicated film diffusion-controlled adsorption through inner-sphere complexation. The nanosorbent could be regenerated and reused for four rounds without appreciable activity loss, thus demonstrating its potential for water cleanup applications. Full article

The environmental threat posed by small, single-use sachets sourced from 48% annual waste from excessive packaging has been assessed by investigating the development of nano-incorporated bioplastic films from the high-yield plant, maguey (Agave cantala). Maguey cellulose was acetylated (using 10 and 15 mL of acetic anhydride for 16, 24, and 32 h), successfully yielding a high of 81.34% maguey cellulose acetate (MCA). MCA was confirmed to contain acetate groups (C=O, C-H, C-O) via FT-IR and exhibited a hydrophobicity of a 121.897° contact angle. Bioplastic films were fabricated using MCA solution combined with 15% (w/w) commercial cellulose acetate (CCA)/MCA and reinforced with nanoclay (NC) at 0.5%, 1%, and 3% (w/w) concentrations. Nanomaterial incorporation generally improved properties; however, mechanical strength declined with increasing NC concentration, recording tensile strengths of 2.01 MPa, 0.89 MPa, and 0.78 MPa for the 0.5%, 1%, and 3% NC films, respectively. Conversely, the 3% NC film showed the best barrier property, with a water vapor transmission rate (WVTR) of 31.14 g/m² h. Surface morphology confirmed NC integration (nanomaterial sizes 29.74 nm to 107.3 nm), and the 0.5% NC film displayed the smooth structure ideal for sustainable packaging. The slight increase in contact angle observed between the 0% NC (60.768°) and 0.5 NC (62.904°) films suggested limitations in NC dispersion. Overall, the findings demonstrate the potential of using regenerated maguey cellulose acetate to create nano-bioplastic films with tailored mechanical and barrier properties for sustainable packaging, though optimization of NC loading and dispersion is necessary to maximize strength. Full article

Due to its amphiphilicity, the natural fibrous structural protein, silk fibroin (SF), can adsorb at the oil/water interface, form protective viscoelastic layers, and stabilize emulsions. Biocompatible SF-stabilized emulsions can be used in different fields of cosmetics, food, drug delivery, and biomedicine. Depending on the silk processing method, various emulsion types can be obtained, such as film-stabilized emulsions stabilized by SF molecules and Pickering emulsions stabilized by nanostructured SF or SF particles. Nanostructured SF and SF particles, with β-sheet dominated secondary structures, can overcome the drawback of SF molecules with unstable conformation transition during application, and thus endow higher emulsion stability than SF molecules. The emulsions stabilized by SF nanoparticles can endure heat and high ionic strength, while the emulsions stabilized by SF nanofibers show superior stability at high temperature, high salinity, and low pH due to the strong interfacial entangled nanofiber networks. In this review, the recent progress in research on SF-stabilized emulsions is summarized and generalized, including a systematic comparison of the stabilization mechanisms for different SF morphologies, and the influences of the emulsion fabrication technique, component type and proportions, and environmental conditions on the microstructures and properties of SF-stabilized emulsions. Understanding the stabilization mechanism and factors influencing the emulsion stability is of great significance for the design, preparation and application of SF-stabilized emulsions. Full article

Surface mulching and nitrogen (N) application are widely used to enhance crop yield and water productivity (WP). However, their combined effects remain unclear. Here, a three-year field experiment was conducted to comprehensively assess the effects of surface mulching (no mulching, B; straw mulching, S; and plastic film mulching, F) and N fertilization (no N application, N0; split application of urea, N1; 1:2 mixture of controlled-release urea and urea, N2) on maize growth, yield, and WP on the Loess Plateau. Application of nitrogen (N) significantly increased evapotranspiration (ET), grain yield, and WP by 4.58%, 176% (from 5215.43 kg ha⁻¹ in N0 to 14,548.21 kg ha⁻¹ in N2), and 166% (from 11.36 kg ha⁻¹ mm⁻¹ in N0 to 30.63 kg ha⁻¹ mm⁻¹ in N2), respectively. Compared with B and S, F increased ET during the pre-silking stage by 16.75% and 23.99%, respectively, and shortened the vegetative period of maize by 3–9 days but extended the duration from the milky stage (R3) to physiological maturity (R6) in the reproductive period by 5–13 days. F significantly increased yield and WP by 9.18% and 8.26% compared with S. Under F combined with N application, deep soil water (100–200 cm) consumption during R1–R3 increased by 15.75 mm and 13.15 mm compared with B and S, respectively. The combination of F and N2 achieved the highest yield (15,648.28 kg ha⁻¹) and WP (32.44 kg ha⁻¹ mm⁻¹) without causing detectable depletion of soil water within the 0–200 cm profile during the study period, providing an effective strategy for enhancing crop yield and improving water–fertilizer use efficiency in semi-arid regions. Full article

Polyethylene film (PE) mulching produces substantial “white pollution,” prompting the use of biodegradable film (BF) alternatives, yet their performance in rice systems on Northeast black soils is still uncertain. We compared three BFs with different induction periods (45 d, BF₄₅; 60 d, BF₆₀; 80 d, BF₈₀), PE and a no-film control (CK) to quantify their effects on soil hydrothermal conditions, rice growth, yield, grain quality, irrigation water use efficiency (IWUE) and soil C, N. Results showed that mulching increased soil temperature and soil moisture. Across the growing season, the mean soil temperature at the 0–5 cm depth under PE was 5.5% and 2.2–5.5% higher than that under CK and BFs, respectively. Specifically, compared with CK, PE increased grain yield by 31–77% and IWUE by 75–123%, while BFs improved yield by 25–73% and IWUE by 48–101%. PE only slightly outperformed BF₈₀ in yield (by 2.3% in 2023 and 2.1% in 2024) but achieved higher IWUE (11.0–11.7%). Grain chalkiness and sensory scores under BFs were comparable to PE and better than CK. At 0–20 cm, PE increased SOC (2.3–6.8%) and the C/N ratio (0–0.8%) but reduced total nitrogen (TN) (2.7–3.9%) and total carbon (TC) (2.5–3.1%), whereas BFs increased Org-N by 0.4–4.2%, SOC by 2.9–7.1%, and TN by 0.2–0.7%, with BF₈₀ showing the greatest stimulatory effect. Overall, BFs—particularly BF₈₀—are promising substitutes for PE in black soil rice systems, supporting sustainable rice production with strong application potential. Full article

The coefficient of friction (COF) in superlubrication systems exhibits highly strong correlation with experimental parameters. However, previous studies mainly reported the stable superlubrication formed at small sliding radii (2–5 mm), often without clearly specifying the friction radius. This lack of critical parametric not only affects the reproducibility of the experimental results but also hinders the fundamental understanding of superlubrication formation. In this work, the effects of friction radius and linear velocity on lubrication performance were investigated by using a graphene oxide–ethylene glycol (GO-EG) model lubricant in ball-on-disk rotational sliding. The results showed that superlubricity is also achievable within a large radius range (>5 mm). The GO-EG lubricant attained a stable superlubrication state with a minimum COF of 0.0065 under the conditions of a linear velocity of 0.40 m/s and a friction radius of 6 mm. This value was approximately 50% lower than that under a 2 mm radius condition. Even when the friction radius is increased to 8 mm while maintaining the same linear velocity, stable superlubricity can still be retained. Subsequently, a systematic analysis of the tribological experimental data revealed that at different fixed velocity ranges, the average COF showed different radius dependence. At low linear velocity (<0.2 m/s), the COF decreased with increasing radius, whereas at higher velocity (>0.3 m/s), the COF first decreased and then increased with radius. Mechanistic analysis showed that friction radius governed the COF by modulating rotational speed, shear rate, running-in states, and water-film evolution, including evaporation-driven viscosity changes and hydration-layer stability. This study enhances the understanding of superlubrication formation conditions and provides guidance for the evaluation and measurement of lubrication systems. Full article

Low gas recovery in the Sebei-2 gas field is linked to residual gas trapping under water encroachment. This study investigates the pore-scale trapping behaviour of residual gas in three types of layer: conventional, low-resistivity, and low-acoustic high-resistivity. High-fidelity pore structures were reconstructed by integrating mercury intrusion porosimetry with thin-section data and microfluidic models were designed using the Quartet Structure Generation Set method and fabricated by wet etching. Visualized displacement experiments were performed under different wettability conditions and water invasion rates, and image analysis was used to quantify the distribution of trapped gas. Results show that the low-resistivity gas layer exhibits the highest residual gas saturation (30.57%), followed by the low-acoustic high-resistivity gas layer (20.20%), while the conventional gas layer has the lowest (15.29%). These values correspond to apparent pore-scale gas recoveries of about 48.95%, 65.01%, and 72.14% for the low-resistivity, low-acoustic high-resistivity and conventional gas layers, respectively. In hydrophilic systems, wetting-film thickening and flow diversion are the main trapping processes, whereas in hydrophobic systems, flow diversion dominates and residual gas decreases markedly. Increasing the water invasion rate reduces trapped gas in the conventional and low-resistivity layers, whereas in the strongly heterogeneous low-acoustic high-resistivity layer, higher invasion intensity strengthens preferential channelling/viscous fingering, leading to a non-monotonic residual gas response. These findings clarify the differentiated pore-scale trapping mechanisms of gas under water encroachment and highlight that mitigating water film-controlled trapping in low-resistivity layers and flow diversion trapping in low-acoustic high-resistivity layers is essential for mobilizing trapped gas, improving dynamic reserves, and ultimately enhancing the economic recovery of water-bearing gas reservoirs similar to the Sebei-2 gas field. Full article

Chromium-doped diamond-like carbon (DLC-Cr) nanocomposite films were successfully deposited using a high-power impulse magnetron sputtering (HiPIMS) system. The Cr content in the films was controlled by adjusting the Cr target powers. The influence of Cr content on the microstructure, mechanical properties, tribological performance, and wettability of the films was systematically investigated. The results show that the Cr content and deposition rate of the films increased with increases in the target power. The surface topography of the films evolved from smooth to rough as the Cr target increased from 10 W to 70 W. At low Cr doping rates, the film mainly exhibited an amorphous structure, whereas the nanocomposite structure was formed at proper Cr doping rates. Raman and XPS analyses revealed that Cr incorporation altered the I_D/I_G ratio and promoted the formation of Cr-C bonds, leading to a more graphitic and nanocomposite-like structure. The nanoindentation results show that an optimal Cr content enhances both hardness and elastic modulus, while higher Cr concentrations lead to a decline in mechanical strength due to more graphitization and decreasing stress. Tribological tests exhibited a significant reduction in the friction coefficient (0.21) and wear rate (0.63 × 10⁻¹⁴ m³/N·m) at a moderate Cr level. Additionally, the surface wettability evolved toward enhanced hydrophilicity with increasing Cr power, as evidenced by reduced water contact angles and increased surface energy. These findings demonstrate that controlled Cr incorporation effectively tailors the structure, stress state, and surface chemistry of DLC films, offering a tunable pathway to achieving optimal mechanical performance and tribological stability for advanced engineering applications. Full article

The automated localization of the flange interface in LNG tanker loading and unloading imposes stringent requirements for accuracy and illumination robustness. Traditional monocular vision methods are prone to localization failure under extreme illumination conditions, such as intense glare or low light, while LiDAR, despite being unaffected by illumination, suffers from limitations like a lack of texture information. This paper proposes an illumination-robust localization method for LNG tanker flange interfaces by fusing monocular vision and LiDAR, with three scenario-specific innovations beyond generic multi-sensor fusion frameworks. First, an illumination-adaptive fusion framework is designed to dynamically adjust detection parameters via grayscale mean evaluation, addressing extreme illumination (e.g., glare, low light with water film). Second, a multi-constraint flange detection strategy is developed by integrating physical dimension constraints, K-means clustering, and weighted fitting to eliminate background interference and distinguish dual flanges. Third, a customized fusion pipeline (ROI extraction-plane fitting-3D circle center solving) is established to compensate for monocular depth errors and sparse LiDAR point cloud limitations using flange radius prior. High-precision localization is achieved via four key steps: multi-modal data preprocessing, LiDAR-camera spatial projection, fusion-based flange circle detection, and 3D circle center fitting. While basic techniques such as LiDAR-camera spatiotemporal synchronization and K-means clustering are adapted from prior works, their integration with flange-specific constraints and illumination-adaptive design forms the core novelty of this study. Comparative experiments between the proposed fusion method and the monocular vision-only localization method are conducted under four typical illumination scenarios: uniform illumination, local strong illumination, uniform low illumination, and low illumination with water film. The experimental results based on 20 samples per illumination scenario (80 valid data sets in total) show that, compared with the monocular vision method, the proposed fusion method reduces the Mean Absolute Error (MAE) of localization accuracy by 33.08%, 30.57%, and 75.91% in the X, Y, and Z dimensions, respectively, with the overall 3D MAE reduced by 61.69%. Meanwhile, the Root Mean Square Error (RMSE) in the X, Y, and Z dimensions is decreased by 33.65%, 32.71%, and 79.88%, respectively, and the overall 3D RMSE is reduced by 64.79%. The expanded sample size verifies the statistical reliability of the proposed method, which exhibits significantly superior robustness to extreme illumination conditions. Full article

Waterborne polyurethane (WPU) and waterborne poly(urethane-urea) (WPUU) dispersions allow safer and more sustainable manufacturing of rechargeable batteries via water-based processing, while offering tunable adhesion and segmented-domain mechanics. Beyond conventional roles as binders and coatings, WPU/WPUU chemistries also support separator/interlayer and polymer-electrolyte designs for lithium-ion and lithium metal systems, where interfacial integrity, stress accommodation, and ion transport must be balanced. Here, we review WPU/WPUU fundamentals (building blocks, dispersion stabilization, morphology, and film formation) and review prior studies through a battery-centric structure–processing–property lens. We point out key performance-limiting trade-offs—adhesion versus electrolyte uptake and ionic conductivity versus storage modulus—and relate them to practical formulation variables, including soft-/hard-segment selection, ionic center/counterion design, molecular weight/topology control, and crosslinking strategies. Applications are reviewed for (i) electrode binders (graphite/Si; cathodes such as LFP and NMC), (ii) separator coatings and functional interlayers, and (iii) gel/solid polymer electrolytes and hybrid composites, with a focus on practical design guidelines for navigating these trade-offs. Future advancements in WPU/WPUU chemistries will depend on developing stable, low-impedance interlayers, enhancing electrochemical behavior, and establishing application-specific design guidelines to optimize performance in lithium metal batteries (LMB). Full article

The results show that the numerical simulation error based on the RPI two-phase boiling heat transfer model is less than 5%, which is in good agreement with the test results. Compared with the original engine, the temperature near the spark plugs’ position of improvement in scheme 2 decreased by 8.4 K, and the maximum temperature difference between the cylinder head intake and exhaust decreased by 14 K. Moreover, the overheating degree of the water jacket wall is the lowest, avoiding the occurrence of film boiling, and the local maximum vaporization rate is less than 50%. The prototype tests also confirmed that the improvement scheme effectively enhanced the heat transfer performance of the water jacket. The inlet flow rate and temperature of the coolant have significant and complex effects on two-phase boiling heat transfer. Both too low a flow rate and too high a temperature will lead to local film boiling, deteriorating heat transfer. Too high a flow rate will blow away bubbles, while too low an inlet temperature will not cause boiling, both of which can only enforce convective heat transfer. Appropriately reducing the flow rate and increasing the temperature can effectively utilize the enhanced heat transfer potential of subcooled boiling, while also save pump power consumption and improving engine fuel economy. The average heat flux density of boiling heat transfer in this paper is 13.9% higher than that of the forced convective heat transfer. When designing a water jacket with boiling heat transfer, attention should be paid to the transport effect of convective motion on bubbles, controlling subcooled boiling in the high-temperature zone and preventing film boiling. Full article

Radiative cooling (RC) offers a passive pathway to reduce surface and system temperatures by emitting thermal radiation through the atmospheric window, yet its daytime effectiveness is often constrained by geometry, angular solar exposure, and practical integration limits. This work experimentally investigates the use of passive non-imaging optics, specifically compound parabolic concentrators (CPCs), as enhancers of RC performance under realistic conditions. A three-tier experimental methodology is followed. First, controlled indoor screening using an infrared lamp quantifies the intrinsic heat gain suppression of a commercial RC film, showing a temperature reduction of nearly 88 °C relative to a black-painted reference. Second, outdoor rooftop experiments on aluminum plates assess partial RC coverage, with and without CPCs, under varying orientations and tilt angles, revealing peak daytime temperature reductions close to 8 °C when CPCs are integrated. Third, system-level validation is conducted using a modified GUNT ET-202 solar thermal unit to evaluate the transfer of RC effects to a water circuit absorber. While RC strips alone produce modest reductions in water temperature, the addition of CPC optics amplifies the effect by factors of approximately three for ambient water and nine for water at 70 °C. Across all configurations, statistical analysis confirms stable, repeatable measurements. These results demonstrate that coupling commercially available RC materials with non-imaging optics provides consistent and measurable performance gains, supporting CPC-assisted RC as a scalable and retrofit-friendly strategy for urban and building energy applications while calling for longer-term experiments, durability assessments, and techno-economic analysis before deriving definitive deployment guidelines. Full article

The “bauxite gas reservoir” in the Ordos Basin represents a novel exploration domain, yet the mechanisms governing its widespread aluminous fracture fillings remain unclear. This study integrates core observation, thin-section analysis, geochemical simulation, and rock physics to investigate the formation and impact of these fracture systems. Results identify a characteristic filling evolutionary sequence of “wall-lining film → oolitic/globular → plug-like → vermicular.” Geochemical simulations confirm that increasing pH and decreasing Eh driven by water–rock interactions are the key drivers for aluminous mineral precipitation. A distinct well log response model characterized by high GR, DEN, and CNL values coupled with low AC and RT is established for effective identification. Seepage experiments reveal that while Al–Si colloidal fracture fillings reduce permeability, they act as natural proppants to preserve effective flow channels, acting as a crucial high-permeability network for gas migration despite the mineral occlusion. These findings refine the accumulation theory for bauxite series reservoirs and provide geological evidence for deep tight gas exploration. Full article