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Search Results (1,337)

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24 pages, 8197 KiB  
Article
Reuse of Decommissioned Tubular Steel Wind Turbine Towers: General Considerations and Two Case Studies
by Sokratis Sideris, Charis J. Gantes, Stefanos Gkatzogiannis and Bo Li
Designs 2025, 9(4), 92; https://doi.org/10.3390/designs9040092 (registering DOI) - 6 Aug 2025
Abstract
Nowadays, the circular economy is driving the construction industry towards greater sustainability for both environmental and financial purposes. One prominent area of research with significant contributions to circular economy is the reuse of steel from decommissioned structures in new construction projects. This approach [...] Read more.
Nowadays, the circular economy is driving the construction industry towards greater sustainability for both environmental and financial purposes. One prominent area of research with significant contributions to circular economy is the reuse of steel from decommissioned structures in new construction projects. This approach is deemed far more efficient than ordinary steel recycling, due to the fact that it contributes towards reducing both the cost of the new project and the associated carbon emissions. Along these lines, the feasibility of utilizing steel wind turbine towers (WTTs) as part of a new structure is investigated herein, considering that wind turbines are decommissioned after a nominal life of approximately 25 years due to fatigue limitations. General principles of structural steel reuse are first presented in a systematic manner, followed by two case studies. Realistic data about the geometry and cross-sections of previous generation models of WTTs were obtained from the Greek Center for Renewable Energy Sources and Savings (CRES), including drawings and photographic material from their demonstrative wind farm in the area of Keratea. A specific wind turbine was selected that is about to exceed its life expectancy and will soon be decommissioned. Two alternative applications for the reuse of the tower were proposed and analyzed, with emphasis on the structural aspects. One deals with the use of parts of the tower as a small-span pedestrian bridge, while the second addresses the transformation of a tower section into a water storage tank. Several decision factors have contributed to the selection of these two reuse scenarios, including, amongst others, the geometric compatibility of the decommissioned wind turbine tower with the proposed applications, engineering intuition about the tower having adequate strength for its new role, the potential to minimize fatigue loads in the reused state, the minimization of cutting and joining processes as much as possible to restrain further CO2 emissions, reduction in waste material, the societal contribution of the potential reuse applications, etc. The two examples are briefly presented, aiming to demonstrate the concept and feasibility at the preliminary design level, highlighting the potential of decommissioned WTTs to find proper use for their future life. Full article
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21 pages, 6618 KiB  
Article
Comparison of Deep Learning Models for LAI Simulation and Interpretable Hydrothermal Coupling in the Loess Plateau
by Junpo Yu, Yajun Si, Wen Zhao, Zeyu Zhou, Jiming Jin, Wenjun Yan, Xiangyu Shao, Zhixiang Xu and Junwei Gan
Plants 2025, 14(15), 2391; https://doi.org/10.3390/plants14152391 - 2 Aug 2025
Viewed by 202
Abstract
As the world’s largest loess deposit region, the Loess Plateau’s vegetation dynamics are crucial for its regional water–heat balance and ecosystem functioning. Leaf Area Index (LAI) serves as a key indicator bridging canopy architecture and plant physiological activities. Existing studies have made significant [...] Read more.
As the world’s largest loess deposit region, the Loess Plateau’s vegetation dynamics are crucial for its regional water–heat balance and ecosystem functioning. Leaf Area Index (LAI) serves as a key indicator bridging canopy architecture and plant physiological activities. Existing studies have made significant advancements in simulating LAI, yet accurate LAI simulation remains challenging. To address this challenge and gain deeper insights into the environmental controls of LAI, this study aims to accurately simulate LAI in the Loess Plateau using deep learning models and to elucidate the spatiotemporal influence of soil moisture and temperature on LAI dynamics. For this purpose, we used three deep learning models, namely Artificial Neural Network (ANN), Long Short-Term Memory (LSTM), and Interpretable Multivariable (IMV)-LSTM, to simulate LAI in the Loess Plateau, only using soil moisture and temperature as inputs. Results indicated that our approach outperformed traditional models and effectively captured LAI variations across different vegetation types. The attention analysis revealed that soil moisture mainly influenced LAI in the arid northwest and temperature was the predominant effect in the humid southeast. Seasonally, soil moisture was crucial in spring and summer, notably in grasslands and croplands, whereas temperature dominated in autumn and winter. Notably, forests had the longest temperature-sensitive periods. As LAI increased, soil moisture became more influential, and at peak LAI, both factors exerted varying controls on different vegetation types. These findings demonstrated the strength of deep learning for simulating vegetation–climate interactions and provided insights into hydrothermal regulation mechanisms in semiarid regions. Full article
(This article belongs to the Section Plant Modeling)
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28 pages, 2266 KiB  
Review
Uncovering Plastic Pollution: A Scoping Review of Urban Waterways, Technologies, and Interdisciplinary Approaches
by Peter Cleveland, Donna Cleveland, Ann Morrison, Khoi Hoang Dinh, An Nguyen Pham Hai, Luca Freitas Ribeiro and Khanh Tran Duy
Sustainability 2025, 17(15), 7009; https://doi.org/10.3390/su17157009 - 1 Aug 2025
Viewed by 236
Abstract
Plastic pollution is a growing environmental and social concern, particularly in Southeast Asia, where urban rivers serve as key pathways for transporting waste to marine environments. This scoping review examines 110 peer-reviewed studies to understand how plastic pollution in waterways is being researched, [...] Read more.
Plastic pollution is a growing environmental and social concern, particularly in Southeast Asia, where urban rivers serve as key pathways for transporting waste to marine environments. This scoping review examines 110 peer-reviewed studies to understand how plastic pollution in waterways is being researched, addressed, and reconceptualized. Drawing from the literature across environmental science, technology, and social studies, we identify four interconnected areas of focus: urban pollution pathways, innovations in monitoring and methods, community-based interventions, and interdisciplinary perspectives. Our analysis combines qualitative synthesis with visual mapping techniques, including keyword co-occurrence networks, to explore how real-time tools, such as IoT sensors, multi-sensor systems, and geospatial technologies, are transforming the ways plastic waste is tracked and analyzed. The review also considers the growing use of novel theoretical frameworks, such as post-phenomenology and ecological materialism, to better understand the role of plastics as both pollutants and ecological agents. Despite progress, the literature reveals persistent gaps in longitudinal studies, regional representation, and policy translation, particularly across the Global South. We emphasize the value of participatory models and community-led research in bridging these gaps and advancing more inclusive and responsive solutions. These insights inform the development of plastic tracker technologies currently being piloted in Vietnam and contribute to broader sustainability goals, including SDG 6 (Clean Water and Sanitation), SDG 12 (Responsible Consumption and Production), and SDG 14 (Life Below Water). Full article
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13 pages, 5177 KiB  
Article
Pilot-Scale Polysulfone Ultrafiltration Patterned Membranes: Phase-Inversion Parametric Optimization on a Roll-to-Roll Casting System
by Ayesha Ilyas and Ivo F. J. Vankelecom
Membranes 2025, 15(8), 228; https://doi.org/10.3390/membranes15080228 - 31 Jul 2025
Viewed by 428
Abstract
The scalability and processability of high-performance membranes remain significant challenges in membrane technology. This work focuses on optimizing the pilot-scale production of patterned polysulfone (PSf) ultrafiltration membranes using the spray-modified non-solvent-induced phase separation (s-NIPS) method on a roll-to-roll pilot line. s-NIPS has already [...] Read more.
The scalability and processability of high-performance membranes remain significant challenges in membrane technology. This work focuses on optimizing the pilot-scale production of patterned polysulfone (PSf) ultrafiltration membranes using the spray-modified non-solvent-induced phase separation (s-NIPS) method on a roll-to-roll pilot line. s-NIPS has already been studied extensively at lab-scale to prepare patterned membranes for various applications including membrane bioreactors (MBR), reverse osmosis (RO) and forward osmosis (FO). Although studied at the lab scale, membranes prepared at a larger scale can significantly differ in performance; therefore, phase inversion parameters, including polymer concentration, molecular weight, and additive type (i.e., polyethylene glycol (PEG) or polyvinylpyrolidine (PVP)) and concentration, were systematically varied when casting on a roll-to-roll, 12″ wide pilot line to identify optimal conditions for achieving defect-free, high-performance, patterned PSf membranes. The membranes were characterized for their pure water permeance, BSA rejection, casting solution viscosities, and resulting morphology. s-NIPS patterned membranes exhibit 150–350% increase in water flux as compared to their reference flat membrane, thanks to very high pattern heights up to 825 µm and formation of finger-like macrovoids. This work bridges the gap between lab-scale and pilot-scale membrane preparation, while proposing an upscaled membrane with great potential for use in water treatment. Full article
(This article belongs to the Section Membrane Applications for Water Treatment)
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36 pages, 16047 KiB  
Article
Insights into Sea Spray Ice Adhesion from Laboratory Testing
by Paul Rübsamen-v. Döhren, Sönke Maus, Zhiliang Zhang and Jianying He
Thermo 2025, 5(3), 27; https://doi.org/10.3390/thermo5030027 - 30 Jul 2025
Viewed by 227
Abstract
Ice accretion from marine icing events accumulating on structures poses a significant hazard to ship and offshore operations in cold regions, being relevant for offshore activities like oil explorations, offshore wind, and shipping in arctic regions. The adhesion strength of such ice is [...] Read more.
Ice accretion from marine icing events accumulating on structures poses a significant hazard to ship and offshore operations in cold regions, being relevant for offshore activities like oil explorations, offshore wind, and shipping in arctic regions. The adhesion strength of such ice is a critical factor in predicting the build-up of ice loads on structures. While the adhesion strength of freshwater ice has been extensively studied, knowledge about sea spray ice adhesion remains limited. This study intends to bridge this gap by investigating the adhesion strength of sea spray icing under controlled laboratory conditions. In this study, we built a new in situ ice adhesion test setup and grew ice at −7 °C to −15 °C on quadratic aluminium samples of 3 cm to 12 cm edge length. The results reveal that sea spray ice adhesion strength is in a significantly lower range—5 kPa to 100 kPa—compared to fresh water ice adhesion and shows a low dependency on the temperature during the spray event, but a notable size effect and influence of the brine layer thickness on the adhesion strength. These findings provide critical insights into sea spray icing, enhancing the ability to predict and manage ice loads in marine environments. Full article
(This article belongs to the Special Issue Frosting and Icing)
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23 pages, 1249 KiB  
Review
Guiding Microbial Crossroads: Syngas-Driven Valorisation of Anaerobic-Digestion Intermediates into Bio-Hydrogen and Volatile Fatty Acids
by Alvaro dos Santos Neto and Mohammad J. Taherzadeh
Bioengineering 2025, 12(8), 816; https://doi.org/10.3390/bioengineering12080816 - 29 Jul 2025
Viewed by 343
Abstract
Anaerobic digestion (AD) has long been valued for producing a biogas–digestate pair, yet its profitability is tightening. Next-generation AD biorefineries now position syngas both as a supplementary feedstock and as a springboard to capture high-value intermediates, hydrogen (H2) and volatile fatty [...] Read more.
Anaerobic digestion (AD) has long been valued for producing a biogas–digestate pair, yet its profitability is tightening. Next-generation AD biorefineries now position syngas both as a supplementary feedstock and as a springboard to capture high-value intermediates, hydrogen (H2) and volatile fatty acids (VFA). This review dissects how complex natural consortia “decide” between hydrogenogenesis and acetogenesis when CO, H2, and CO2 co-exist in the feedstocks, bridging molecular mechanisms with process-scale levers. The map of the bioenergetic contest between the biological water–gas shift reaction and Wood–Ljungdahl pathways is discussed, revealing how electron flow, thermodynamic thresholds, and enzyme inhibition dictate microbial “decision”. Kinetic evidence from pure and mixed cultures is integrated with practical operating factors (gas composition and pressure, pH–temperature spectrum, culture media composition, hydraulic retention time, and cell density), which can bias consortia toward the desired product. Full article
(This article belongs to the Special Issue Anaerobic Digestion Advances in Biomass and Waste Treatment)
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47 pages, 5162 KiB  
Review
Drought Analysis Methods: A Multidisciplinary Review with Insights on Key Decision-Making Factors in Method Selection
by Abdul Baqi Ahady, Elena-Maria Klopries, Holger Schüttrumpf and Stefanie Wolf
Water 2025, 17(15), 2248; https://doi.org/10.3390/w17152248 - 28 Jul 2025
Viewed by 605
Abstract
Drought is one of the most complex natural hazards, characterized by its slow onset, persistent nature, diverse sectoral impacts (e.g., agriculture, water resources, ecosystems), and dependence on meteorological, hydrological, and socioeconomic factors. Over the years, significant scientific effort has been devoted to developing [...] Read more.
Drought is one of the most complex natural hazards, characterized by its slow onset, persistent nature, diverse sectoral impacts (e.g., agriculture, water resources, ecosystems), and dependence on meteorological, hydrological, and socioeconomic factors. Over the years, significant scientific effort has been devoted to developing methodologies that address its multifaceted nature, reflecting the interdisciplinary challenges of drought analysis. However, previous reviews have typically focused on individual methods, while this study presents a unified, multidisciplinary framework that integrates multiple drought analysis methods and links them to key factors guiding method selection. To address this gap, five widely used methods—index-based, remote sensing, threshold-level methods (TLM), impact-based methods, and the storyline approach—are critically evaluated from a multidisciplinary perspective. In addition, the study examines spatial and temporal trends in scientific publications, illustrating how the application of these methods has evolved over time and across regions. The primary objective of this review is twofold: (1) to provide a holistic, state-of-the-art synthesis of these methods, their applications, and their limitations; and (2) to evaluate and prioritize the critical decision-making factors, including drought type, data type/availability, study scale, and management objectives that influence method selection. By bridging this gap, the paper offers a conceptual decision-support framework for selecting context-appropriate drought analysis methods. However, challenges remain, including the vast diversity of methods beyond the scope of this review and the limited consideration of less influential factors such as user expertise, computational resources, and policy context. The paper concludes with insights and recommendations for optimizing method selection under varying circumstances, aiming to support both drought research and effective policy implementation. Full article
(This article belongs to the Section Hydrology)
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18 pages, 4456 KiB  
Article
Study on the Filling and Plugging Mechanism of Oil-Soluble Resin Particles on Channeling Cracks Based on Rapid Filtration Mechanism
by Bangyan Xiao, Jianxin Liu, Feng Xu, Liqin Fu, Xuehao Li, Xianhao Yi, Chunyu Gao and Kefan Qian
Processes 2025, 13(8), 2383; https://doi.org/10.3390/pr13082383 - 27 Jul 2025
Viewed by 393
Abstract
Channeling in cementing causes interlayer interference, severely restricting oilfield recovery. Existing channeling plugging agents, such as cement and gels, often lead to reservoir damage or insufficient strength. Oil-soluble resin (OSR) particles show great potential in selective plugging of channeling fractures due to their [...] Read more.
Channeling in cementing causes interlayer interference, severely restricting oilfield recovery. Existing channeling plugging agents, such as cement and gels, often lead to reservoir damage or insufficient strength. Oil-soluble resin (OSR) particles show great potential in selective plugging of channeling fractures due to their excellent oil solubility, temperature/salt resistance, and high strength. However, their application is limited by the efficient filling and retention in deep fractures. This study innovatively combines the OSR particle plugging system with the mature rapid filtration loss plugging mechanism in drilling, systematically exploring the influence of particle size and sorting on their filtration, packing behavior, and plugging performance in channeling fractures. Through API filtration tests, visual fracture models, and high-temperature/high-pressure (100 °C, salinity 3.0 × 105 mg/L) core flow experiments, it was found that well-sorted large particles preferentially bridge in fractures to form a high-porosity filter cake, enabling rapid water filtration from the resin plugging agent. This promotes efficient accumulation of OSR particles to form a long filter cake slug with a water content <20% while minimizing the invasion of fine particles into matrix pores. The slug thermally coalesces and solidifies into an integral body at reservoir temperature, achieving a plugging strength of 5–6 MPa for fractures. In contrast, poorly sorted particles or undersized particles form filter cakes with low porosity, resulting in slow water filtration, high water content (>50%) in the filter cake, insufficient fracture filling, and significantly reduced plugging strength (<1 MPa). Finally, a double-slug strategy is adopted: small-sized OSR for temporary plugging of the oil layer injection face combined with well-sorted large-sized OSR for main plugging of channeling fractures. This strategy achieves fluid diversion under low injection pressure (0.9 MPa), effectively protects reservoir permeability (recovery rate > 95% after backflow), and establishes high-strength selective plugging. This study clarifies the core role of particle size and sorting in regulating the OSR plugging effect based on rapid filtration loss, providing key insights for developing low-damage, high-performance channeling plugging agents and scientific gradation of particle-based plugging agents. Full article
(This article belongs to the Section Chemical Processes and Systems)
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35 pages, 1524 KiB  
Article
Unveiling the Interplay of Climate Vulnerability and Social Capital: Insights from West Bengal, India
by Sayari Misra, Md Saidul Islam and Suchismita Roy
Climate 2025, 13(8), 160; https://doi.org/10.3390/cli13080160 - 26 Jul 2025
Viewed by 697
Abstract
This study explores the interplay of climate vulnerability and social capital in two rural communities: Brajaballavpur, a high-climate-prone village in the Indian Sundarbans characterized by high ecological fragility, recurrent cyclones, and saline water intrusion affecting water access, livelihoods, and infrastructure; and Jemua, a [...] Read more.
This study explores the interplay of climate vulnerability and social capital in two rural communities: Brajaballavpur, a high-climate-prone village in the Indian Sundarbans characterized by high ecological fragility, recurrent cyclones, and saline water intrusion affecting water access, livelihoods, and infrastructure; and Jemua, a low-climate-prone village in the land-locked district of Paschim Bardhaman, West Bengal, India, with no extreme climate events. A total of 85 participants (44 in Brajaballavpur, 41 in Jemua) were selected through purposive sampling. Using a comparative qualitative research design grounded in ethnographic fieldwork, data were collected through household interviews, Participatory Rural Appraisals (PRAs), Focus Group Discussions (FGDs), and Key Informant Interviews (KIIs), and analyzed manually using inductive thematic analysis. Findings reveal that bonding and bridging social capital were more prominent in Brajaballavpur, where dense horizontal ties supported collective action during extreme weather events. Conversely, linking social capital was more visible in Jemua, where participants more frequently accessed formal institutions such as the Gram Panchayat, local NGOs, and government functionaries that facilitated grievance redressal and information access, but these networks were concentrated among more politically connected individuals. The study concludes that climate vulnerability shapes the type, strength, and strategic use of social capital in village communities. While bonding and bridging ties are crucial in high-risk contexts, linking capital plays a critical role in enabling long-term social structures in lower-risk settings. The study contributes to both academic literature and policy design by offering a relational and place-based understanding of climate vulnerability and social capital. Full article
(This article belongs to the Special Issue Sustainable Development Pathways and Climate Actions)
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28 pages, 5172 KiB  
Article
Machine Learning-Assisted Sustainable Mix Design of Waste Glass Powder Concrete with Strength–Cost–CO2 Emissions Trade-Offs
by Yuzhuo Zhang, Jiale Peng, Zi Wang, Meng Xi, Jinlong Liu and Lei Xu
Buildings 2025, 15(15), 2640; https://doi.org/10.3390/buildings15152640 - 26 Jul 2025
Viewed by 527
Abstract
Glass powder, a non-degradable waste material, offers significant potential to reduce cement consumption and carbon emissions in concrete production. However, existing mix design methods for glass powder concrete (GPC) fail to systematically balance economic efficiency, environmental sustainability, and mechanical performance. To address this [...] Read more.
Glass powder, a non-degradable waste material, offers significant potential to reduce cement consumption and carbon emissions in concrete production. However, existing mix design methods for glass powder concrete (GPC) fail to systematically balance economic efficiency, environmental sustainability, and mechanical performance. To address this gap, this study proposes an AI-assisted framework integrating machine learning (ML) and Multi-Objective Optimization (MOO) to achieve a sustainable GPC design. A robust database of 1154 experimental records was developed, focusing on five key predictors: cement content, water-to-binder ratio, aggregate composition, glass powder content, and curing age. Seven ML models were optimized via Bayesian tuning, with the Ensemble Tree model achieving superior accuracy (R2 = 0.959 on test data). SHapley Additive exPlanations (SHAP) analysis further elucidated the contribution mechanisms and underlying interactions of material components on GPC compressive strength. Subsequently, a MOO framework minimized unit cost and CO2 emissions while meeting compressive strength targets (15–70 MPa), solved using the NSGA-II algorithm for Pareto solutions and TOPSIS for decision-making. The Pareto-optimal solutions provide actionable guidelines for engineers to align GPC design with circular economy principles and low-carbon policies. This work advances sustainable construction practices by bridging AI-driven innovation with building materials, directly supporting global goals for waste valorization and carbon neutrality. Full article
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80 pages, 962 KiB  
Review
Advancements in Hydrogels: A Comprehensive Review of Natural and Synthetic Innovations for Biomedical Applications
by Adina-Elena Segneanu, Ludovic Everard Bejenaru, Cornelia Bejenaru, Antonia Blendea, George Dan Mogoşanu, Andrei Biţă and Eugen Radu Boia
Polymers 2025, 17(15), 2026; https://doi.org/10.3390/polym17152026 - 24 Jul 2025
Viewed by 963
Abstract
In the rapidly evolving field of biomedical engineering, hydrogels have emerged as highly versatile biomaterials that bridge biology and technology through their high water content, exceptional biocompatibility, and tunable mechanical properties. This review provides an integrated overview of both natural and synthetic hydrogels, [...] Read more.
In the rapidly evolving field of biomedical engineering, hydrogels have emerged as highly versatile biomaterials that bridge biology and technology through their high water content, exceptional biocompatibility, and tunable mechanical properties. This review provides an integrated overview of both natural and synthetic hydrogels, examining their structural properties, fabrication methods, and broad biomedical applications, including drug delivery systems, tissue engineering, wound healing, and regenerative medicine. Natural hydrogels derived from sources such as alginate, gelatin, and chitosan are highlighted for their biodegradability and biocompatibility, though often limited by poor mechanical strength and batch variability. Conversely, synthetic hydrogels offer precise control over physical and chemical characteristics via advanced polymer chemistry, enabling customization for specific biomedical functions, yet may present challenges related to bioactivity and degradability. The review also explores intelligent hydrogel systems with stimuli-responsive and bioactive functionalities, emphasizing their role in next-generation healthcare solutions. In modern medicine, temperature-, pH-, enzyme-, light-, electric field-, magnetic field-, and glucose-responsive hydrogels are among the most promising “smart materials”. Their ability to respond to biological signals makes them uniquely suited for next-generation therapeutics, from responsive drug systems to adaptive tissue scaffolds. Key challenges such as scalability, clinical translation, and regulatory approval are discussed, underscoring the need for interdisciplinary collaboration and continued innovation. Overall, this review fosters a comprehensive understanding of hydrogel technologies and their transformative potential in enhancing patient care through advanced, adaptable, and responsive biomaterial systems. Full article
18 pages, 4721 KiB  
Article
Study on Stability and Fluidity of HPMC-Modified Gangue Slurry with Industrial Validation
by Junyu Jin, Xufeng Jin, Yu Wang and Fang Qiao
Materials 2025, 18(15), 3461; https://doi.org/10.3390/ma18153461 - 23 Jul 2025
Viewed by 318
Abstract
HPMC, regulating slurry properties, is widely used in cement-based materials. Research on the application of HPMC in gangue slurry is still in its early stages. Moreover, the interactive effects of various factors on gangue slurry performance have not been thoroughly investigated. The work [...] Read more.
HPMC, regulating slurry properties, is widely used in cement-based materials. Research on the application of HPMC in gangue slurry is still in its early stages. Moreover, the interactive effects of various factors on gangue slurry performance have not been thoroughly investigated. The work examined the effects of slurry concentration (X1), maximum gangue particle size (X2), and HPMC dosage (X3) on slurry performance using response surface methodology (RSM). The microstructure of the slurry was characterized via scanning electron microscopy (SEM) and polarized light microscopy (PLM), while low-field nuclear magnetic resonance (LF-NMR) was employed to analyze water distribution. Additionally, industrial field tests were conducted. The results are presented below. (1) X1 and X3 exhibited a negative correlation with layering degree and slump flow, while X2 showed a positive correlation. Slurry concentration had the greatest impact on slurry performance, followed by maximum particle size and HPMC dosage. HPMC significantly improved slurry stability, imposing the minimum negative influence on fluidity. Interaction terms X1X2 and X1X3 significantly affected layering degree and slump flow, while X2X3 significantly affected layering degree instead of slump flow. (2) Derived from the RSM, the statistical models for layering degree and slump flow define the optimal slurry mix proportions. The gangue gradation index ranged from 0.40 to 0.428, with different gradations requiring specific slurry concentration and HPMC dosages. (3) HPMC promoted the formation of a 3D floc network structure of fine particles through adsorption-bridging effects. The spatial supporting effect of the floc network inhibited the sedimentation of coarse particles, which enhanced the stability of the slurry. Meanwhile, HPMC only converted a small amount of free water into floc water, which had a minimal impact on fluidity. HPMC addition achieved the synergistic optimization of slurry stability and fluidity. (4) Field industrial trials confirmed that HPMC-optimized gangue slurry demonstrated significant improvements in both stability and flowability. The optimized slurry achieved blockage-free pipeline transportation, with a maximum spreading radius exceeding 60 m in the goaf and a maximum single-borehole backfilling volume of 2200 m3. Full article
(This article belongs to the Section Construction and Building Materials)
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16 pages, 1188 KiB  
Article
Preparation and Performance Evaluation of Modified Amino-Silicone Supercritical CO2 Viscosity Enhancer for Shale Oil and Gas Reservoir Development
by Rongguo Yang, Lei Tang, Xuecheng Zheng, Yuanqian Zhu, Chuanjiang Zheng, Guoyu Liu and Nanjun Lai
Processes 2025, 13(8), 2337; https://doi.org/10.3390/pr13082337 - 23 Jul 2025
Viewed by 339
Abstract
Against the backdrop of global energy transition and strict environmental regulations, supercritical carbon dioxide (scCO2) fracturing and oil displacement technologies have emerged as pivotal green approaches in shale gas exploitation, offering the dual advantages of zero water consumption and carbon sequestration. [...] Read more.
Against the backdrop of global energy transition and strict environmental regulations, supercritical carbon dioxide (scCO2) fracturing and oil displacement technologies have emerged as pivotal green approaches in shale gas exploitation, offering the dual advantages of zero water consumption and carbon sequestration. However, the inherent low viscosity of scCO2 severely restricts its sand-carrying capacity, fracture propagation efficiency, and oil recovery rate, necessitating the urgent development of high-performance thickeners. The current research on scCO2 thickeners faces a critical trade-off: traditional fluorinated polymers exhibit excellent philicity CO2, but suffer from high costs and environmental hazards, while non-fluorinated systems often struggle to balance solubility and thickening performance. The development of new thickeners primarily involves two directions. On one hand, efforts focus on modifying non-fluorinated polymers, driven by environmental protection needs—traditional fluorinated thickeners may cause environmental pollution, and improving non-fluorinated polymers can maintain good thickening performance while reducing environmental impacts. On the other hand, there is a commitment to developing non-noble metal-catalyzed siloxane modification and synthesis processes, aiming to enhance the technical and economic feasibility of scCO2 thickeners. Compared with noble metal catalysts like platinum, non-noble metal catalysts can reduce production costs, making the synthesis process more economically viable for large-scale industrial applications. These studies are crucial for promoting the practical application of scCO2 technology in unconventional oil and gas development, including improving fracturing efficiency and oil displacement efficiency, and providing new technical support for the sustainable development of the energy industry. This study innovatively designed an amphiphilic modified amino silicone oil polymer (MA-co-MPEGA-AS) by combining maleic anhydride (MA), methoxy polyethylene glycol acrylate (MPEGA), and amino silicone oil (AS) through a molecular bridge strategy. The synthesis process involved three key steps: radical polymerization of MA and MPEGA, amidation with AS, and in situ network formation. Fourier transform infrared spectroscopy (FT-IR) confirmed the successful introduction of ether-based CO2-philic groups. Rheological tests conducted under scCO2 conditions demonstrated a 114-fold increase in viscosity for MA-co-MPEGA-AS. Mechanistic studies revealed that the ether oxygen atoms (Lewis base) in MPEGA formed dipole–quadrupole interactions with CO2 (Lewis acid), enhancing solubility by 47%. Simultaneously, the self-assembly of siloxane chains into a three-dimensional network suppressed interlayer sliding in scCO2 and maintained over 90% viscosity retention at 80 °C. This fluorine-free design eliminates the need for platinum-based catalysts and reduces production costs compared to fluorinated polymers. The hierarchical interactions (coordination bonds and hydrogen bonds) within the system provide a novel synthetic paradigm for scCO2 thickeners. This research lays the foundation for green CO2-based energy extraction technologies. Full article
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13 pages, 2020 KiB  
Article
Micro-Gas Flow Sensor Utilizing Surface Network Density Regulation for Humidity-Modulated Ion Transport
by Chuanjie Liu and Zhihong Liu
Gels 2025, 11(8), 570; https://doi.org/10.3390/gels11080570 - 23 Jul 2025
Viewed by 258
Abstract
As a bridge for human–machine interaction, the performance improvement of sensors relies on the in-depth understanding of ion transport mechanisms. This study focuses on the surface effect of resistive gel sensors and designs a polyacrylic acid/ferric ion hydrogel (PAA/Fe3+) gas flow [...] Read more.
As a bridge for human–machine interaction, the performance improvement of sensors relies on the in-depth understanding of ion transport mechanisms. This study focuses on the surface effect of resistive gel sensors and designs a polyacrylic acid/ferric ion hydrogel (PAA/Fe3+) gas flow sensor. Prepared by one-pot polymerization, PAA/Fe3+ forms a three-dimensional network through the entanglement of crosslinked and uncrosslinked PAA chains, where the coordination between Fe3+ and carboxyl groups endows the material with excellent mechanical properties (tensile strength of 80 kPa and elongation at break of 1100%). Experiments show that when a gas flow acts on the hydrogel surface, changes in surface humidity alter the density of the network structure, thereby regulating ion migration rates: the network loosens to promote ion transport during water absorption, while it tightens to hinder transport during water loss. This mechanism enables the sensor to exhibit significant resistance responses (ΔR/R0 up to 0.55) to gentle breezes (0–13 m/s), with a response time of approximately 166 ms and a sensitivity 40 times higher than that of bulk deformation. The surface ion transport model proposed in this study provides a new strategy for ultrasensitive gas flow sensing, showing potential application values in intelligent robotics, electronic skin, and other fields. Full article
(This article belongs to the Special Issue Polymer Gels for Sensor Applications)
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23 pages, 2274 KiB  
Review
Nature-Based Solutions for Water Management in Europe: What Works, What Does Not, and What’s Next?
by Eleonora Santos
Water 2025, 17(15), 2193; https://doi.org/10.3390/w17152193 - 23 Jul 2025
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Abstract
Nature-based solutions (NbS) are increasingly recognized as strategic alternatives and complements to grey infrastructure for addressing water-related challenges in the context of climate change, urbanization, and biodiversity decline. This article presents a critical, theory-informed review of the state of NbS implementation in European [...] Read more.
Nature-based solutions (NbS) are increasingly recognized as strategic alternatives and complements to grey infrastructure for addressing water-related challenges in the context of climate change, urbanization, and biodiversity decline. This article presents a critical, theory-informed review of the state of NbS implementation in European water management, drawing on a structured synthesis of empirical evidence from regional case studies and policy frameworks. The analysis found that while NbS are effective in reducing surface runoff, mitigating floods, and improving water quality under low- to moderate-intensity events, their performance remains uncertain under extreme climate scenarios. Key gaps identified include the lack of long-term monitoring data, limited assessment of NbS under future climate conditions, and weak integration into mainstream planning and financing systems. Existing evaluation frameworks are critiqued for treating NbS as static interventions, overlooking their ecological dynamics and temporal variability. In response, a dynamic, climate-resilient assessment model is proposed—grounded in systems thinking, backcasting, and participatory scenario planning—to evaluate NbS adaptively. Emerging innovations, such as hybrid green–grey infrastructure, adaptive governance models, and novel financing mechanisms, are highlighted as key enablers for scaling NbS. The article contributes to the scientific literature by bridging theoretical and empirical insights, offering region-specific findings and recommendations based on a comparative analysis across diverse European contexts. These findings provide conceptual and methodological tools to better design, evaluate, and scale NbS for transformative, equitable, and climate-resilient water governance. Full article
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