Search Results (8,776)

Accurate detection of chlorophyll-a (Chl-a) is critical for monitoring water quality in inland waters, where high concentrations of coloured dissolved organic matter (CDOM) complicate retrieval process. Reliable Chl-a estimation depends on the precise determination of the phytoplankton absorption coefficient (a_ph). This study evaluates Chl-a detection from in situ a_ph measurements and assesses the accuracy of phytoplankton absorption retrieval from Sentinel-2/MSI (S2) and Sentinel-3/OLCI (S3) using the Case-2-Regional-Coast-Colour (C2RCC) processor across diverse optical water types (OWTs) in boreal lakes. OWTs were classified based on remote sensing reflectance features, representing Clear, Moderate, Turbid, Very Turbid, and Brown conditions. CDOM absorption strongly influenced the underwater light field, particularly in Brown and Turbid waters. Linear relationships between a_ph and Chl-a were generally strong across OWTs, with improved relationships in the red spectral region (670 nm). Satellite-derived a_pig estimates showed a weak relationship with in situ data (R² = 0.26–0.45). Both sensors overestimated small a_ph values, while S3 underestimated larger ones. S2 underestimated a_ph in Clear and Brown OWTs, with median absolute percentage differences near 100% for all OWTs. These findings emphasize the challenges posed by bio-optical complexity in boreal lakes and highlight the need for OWT-specific algorithms to improve satellite-based absorption and Chl-a retrieval accuracy. Full article

Adobe is a sustainable yet highly porous construction material, inherently vulnerable to moisture and environmental pollution, which poses challenges for both contemporary construction and heritage conservation. This study presents multifunctional coatings that combine hydrophobic/oleophobic and photocatalytic properties to enhance adobe durability. The coatings incorporate nano-heterostructured LaFeO₃ photocatalysts into water-repellent and hydro-oleo-repellent formulations, selected to preserve the characteristic dark brown color of adobe. Microstructural analyses revealed the formation of non-uniform protective layers, particularly in hydro-oleo-repellent systems, which influenced performance. The treated surfaces exhibited significant water and oil repellency, while maintaining adequate vapor permeability. Durability tests confirmed improved resistance to water ingress, reduced capillary absorption, and enhanced erosion resistance compared to untreated adobe. Sustainability assessments highlighted the environmental and economic benefits of the proposed approach, especially when using locally sourced materials. Overall, this work proposes a scalable and multifunctional strategy that integrates protective and photocatalytic functionalities to extend the service life of both historical and modern adobe structures. Full article

Fibrin gel, a protein-based polymer naturally generated during coagulation, has garnered attention in the biomedical field for applications such as fibrin glue, due to its specific physical and biological properties. Despite it, low mechanical strength and rapid degradation limited its utilization for biomedical applications. This study presents a reproducible protocol for the synthesis of pure fibrin hydrogels, aimed at achieving predictable structural properties through the precise calibration of fibrinogen and thrombin concentrations. By examining the mechanical and morphological characteristics, as well as the relationship between reagent concentrations and structural integrity, this research assesses impacts on swelling behavior, water absorption, and overall stability. Through a comprehensive analytical approach, we identified an optimal formulation, specifically 2.25 mg/mL fibrinogen and 1.375 U/mL thrombin, that effectively balances structural integrity with high cytocompatibility. The results demonstrate that this calibrated approach ensures high procedural reproducibility and a well-defined hydrogel architecture without the need for exogenous chemical cross-linkers. This work provides a robust methodological framework to overcome the common lack of reproducibility in fibrin-based hydrogel studies, positioning these materials as highly reliable candidates for advanced 3D in vitro models and biomedical applications. Full article

Wheat bran, as a major nutrient-rich agricultural by-product, is underutilized due to poor functional properties. This study investigated the synergistic effects of steam explosion (SE), enzymatic hydrolysis (EH), and SE combined with EH (SE-EH) on wheat bran to improve the dough properties, bread quality, and in vitro starch digestion. Results showed that SE destroyed the dense structure of wheat bran to form a porous surface morphology and promoted the conversion of insoluble dietary fiber (IDF) to soluble dietary fiber (SDF). This structural loosening facilitated further fiber degradation for subsequent EH and achieved the obvious improvements in hydration properties after combined treatment. For the dough system, the addition of SE-EH bran increased the water absorption, hardness, and viscosity, but reduced the development and stability time of the dough, in comparison with the control dough. These changes suggested that the modified bran altered dough hydration behavior and gluten network continuity, contributing to the increment of bread’s specific volume. The starch hydrolysis rate of bread adding SE-EH wheat bran was decreased; the slowly digestible starch (SDS) and resistant starch (RS) contents were 2.59-fold and 1.31-fold higher than the control group, respectively. Additionally, the incorporation of modified wheat bran delayed bread hardening during storage, with the SE-modified group showing the best effect. Wheat bran modification enhanced its processing functionality, providing a feasible approach for bread production to improve storage stability and nutritional quality. Full article

Background: Prostate cancer (PCa) is the leading male urinary malignancy globally. Our previous article demonstrated the anti-PCa activity of Euphorbia humifusa Willd water extract (EHW) and some of its compounds via downregulating AR expression, but the anti-PCa active compounds from Euphorbia humifusa Willd (EH) and their mechanisms of action are yet to be clarified. Thus, the current article studied the in vitro anti-PCa effects of 3,3′-di-O-methylellagic acid (3,3′-di-O-Me-EA) derived from EHW and the related mechanism involved. Methods: 3,3’-di-O-Me-EA was isolated from EHW applying bioassay-guided fractionation. The spectroscopic methods were used to determining the structure of 3,3′-di-O-Me-EA. The drug-likeness and ADMET properties (absorption, distribution, metabolism, excretion, and toxicity) of 3,3′-di-O-Me-EA were analyzed in silico. Molecular docking and real-time surface plasmon resonance (SPR) analysis were performed to measure the interaction of 3,3′-di-O-Me-EA and VDAC1 protein. The viability and apoptosis of 22RV-1 and DU145 PCa cells were determined using MTT and Annexin V-FITC staining assay, respectively. q-PCR and Western blot experiments were used to analyzing the gene and protein expressions of VDAC1. Results: 3,3′-di-O-Me-EA was isolated and purified from EHW with a purity of ≥90.06%, and its structure was identified by HRTOF mass, NMR, and an authentic standard. In silico ADMET analysis indicated its favorable drug-like and pharmacokinetic properties. Molecular docking and SPR results confirmed that 3,3′-di-O-Me-EA could bind with the VDAC1 protein. Moreover, 3,3′-di-O-Me-EA dose- and time-dependently inhibited 22RV-1 and DU145 PCa cell viability, and induced apoptosis in a dose-dependent manner (p < 0.05). RT-qPCR and Western blot results showed that 3,3′-di-O-Me-EA dose-dependently up-regulated VDAC1 gene and protein expression levels in 22RV-1 and DU145 cells (p < 0.05). Meanwhile, in VDAC1-depleted 22RV-1 and DU145 cells, 3,3′-di-O-Me-EA down-regulated VDAC1 gene and protein expression levels, increased cell viability, and inhibited apoptosis compared to 22RV-1 and DU145 cells (p < 0.05). Furthermore, 3,3′-di-O-Me-EA enhanced VDAC1 gene and protein expression levels, inhibited cell viability, and induced apoptosis in VDAC1-overexpressed 22RV-1 and DU145 cells compared with 22RV-1 and DU145 cells (p < 0.05). Overall, EH active compound 3,3′-di-O-Me-EA may inhibit viability and induce apoptosis of 22RV-1 and DU145 PCa cells via up-regulating VDAC1 gene and protein expression levels. Conclusion: The results indicated that the 22RV1 and DU145 PCa cell viability inhibitory effects of 3,3′-di-O-Me-EA isolated from EH may be mediated by induction of apoptosis through up-regulation of VDAC1 gene and protein expression levels. Full article

This study investigates the development of high-strength biofiber cement boards with enhanced thermal insulation properties by utilizing recycled biofibers derived from cement packaging bags, combined with a water-based adhesive to enhance the curing efficiency of Portland cement through a cementation–curing process. This approach reduces waste from cement packaging and other biofiber residues through recycling, thereby promoting environmental sustainability. Moreover, it does not require the use of additional chemicals for the disposal or treatment of fiber waste, nor does it require the incineration of biofiber waste. Recycled biofiber from cement bags, composed primarily of cellulose (60 wt%), lignin (15 wt%), and hemicellulose (10 wt%), serves as a reinforcing phase, while the cement and adhesive mixture functions as a strong binding matrix. The fabrication of composite materials using undamaged cement bag fibers preserves fiber integrity and enables a well-ordered one-dimensional (1D) fiber alignment, which promotes more effective reinforcement than two-dimensional (2D) or three-dimensional (3D) orientations, in accordance with the rule of mixtures. In addition, the incorporation of a water-based PVAc adhesive accelerates the curing rate of the cement phase, promoting the formation of a strong interconnected network structure, and facilitates a more complete curing process. The physical, mechanical, chemical, and thermal properties of the biofiber cement boards were evaluated in accordance with relevant industrial standards, including TISI 878:2023, BS 874, ASTM C1185, ASTM D570, ASTM C518, ISO 8301, and JIS A1412. The results indicate that an optimal cement mortar to water-based adhesive ratio of 1:2, combined with an increased number of biofiber sheet layers, significantly enhances material performance, particularly in Formulas (7)–(9). Among these, Formula (9) exhibits the lowest water absorption (0.0835 ± 0.0102%), the highest tensile strength (19.489 ± 0.670 MPa), the highest flexural strength (20.867 ± 2.505 MPa), the highest Young’s modulus (5735.068 ± 387.032 MPa), and low thermal conductivity (0.152 W/m.K). The resulting boards demonstrate strong bonding ability, enhanced resistance to fire, moisture, and weathering, and a longer service life compared to lower cement-to-adhesive ratios (1:1 and 1:0). These findings demonstrate the potential of recycled biofiber composites, combined with water-based adhesives, as sustainable alternative materials for thermal insulation and structural applications, including ceilings and walls in building construction. Full article

A zinc complex of chelidonic acid (4-oxo-4H-pyran-2,6-dicarboxylic acid) was obtained by reaction with zinc oxide under isothermal conditions. Its composition was confirmed by elemental and thermogravimetric analyses, and its molecular structure was characterized using NMR and IR spectroscopy. Single-crystal X-ray diffraction revealed that the complex crystallizes as a one-dimensional coordination polymer, [ZnChel(H₂O)₄]_n, in the triclinic space group P-1, featuring a distorted octahedral Zn(II) center coordinated by two chelidonate ligands and four water molecules. This six-coordinate arrangement contrasts with previously described tetra-coordinated Zn–chelidonate complexes. Quantum-chemical calculations and molecular dynamics simulations indicated that, in aqueous solution, Zn(II) preferentially forms a monodentate ZnChel(H₂O)₅ species, consistent with the solid-state coordination environment. The interaction of the complex with bovine serum albumin (BSA) was examined by fluorescence, UV–Vis absorption, and circular dichroism spectroscopy, revealing a mixed static–dynamic quenching mechanism, moderate binding affinity, and hydrogen-bonding/van der Waals contributions accompanied by alterations in BSA secondary structure. These results expand the structural chemistry of chelidonic acid and provide biophysical insight into the protein-binding behavior of zinc chelidonate, supporting its potential relevance as a zinc-based bioactive compound. Full article

Mycelium-based composites (MBCs) have already been applied in various fields, like construction, architecture, packaging, waste management and many others, as sustainable replacement materials. The composites created from such materials are lightweight, biodegradable and can take many different geometrical shapes. As there are many different combinations of fungal mycelium and organic substrates, it is not only important to investigate and determine which of these combinations perform best from an acoustic perspective but also from an environmental point of view. The sound absorption qualities of these biocomposites have been investigated. It was found that the sound absorption coefficients range from 0.33 to 0.49 in the mid-high frequency range for the four different mixtures of substrate and oyster mushroom (Pleurotus ostreatus). The results from the acoustic testing are promising, but the environmental impact of these mycelium-based composites also needs to be determined. The impacts from water and especially from energy, used during the growth and preparation cycles, are the main contributors to the environmental impact of MBCs, which is also confirmed by the relevant literature. A cradle-to-grave life cycle assessment (LCA) was conducted, utilizing the ReCiPe method, with selected environmental impact categories, based on real-world production data and the scientific literature. The results obtained were also compared with a commercially produced acoustical stone wool panel. The influence on environmental impact of the different substrates is also analyzed, determining which MBC is the most environmentally friendly and has the best acoustical properties. Full article

The clinical effectiveness of clear orthodontic aligners mainly depends on the thermomechanical stability of the polymers in this challenging hydrothermal environment. In this study, we compare the water-induced viscoelastic changes and glass transition temperature (Tg) stability of four polymers with different microarchitectures. Specifically, we examined directly printed photopolymer networks (Tera Harz TC-85 and LuxCreo 4D Aligner), a monolithic thermoplastic (Duran+), and a multilayer thermoplastic (ClearCorrect). Samples were immersed in physiological saline (0.9 wt.% NaCl) at 37 °C for 7 days, and Dynamic Mechanical Analysis (DMA) was performed in three conditions: dry, after immersion, and after a 2 h desorption step, mimicking a typical clinical 22:2 wear cycle. All polymers showed a decrease in Tg after immersion, with TC-85 exhibiting the greatest reduction relative to the dry baseline. Tg recovery after a 2 h ambient desorption step was incomplete and was significantly associated with the amount of water retained after 2 h drying (expressed as % of initial uptake; R² = 0.419), whereas total water absorption after 7 days was not associated with short-term thermal recovery. Full article

The world’s growing need for energy, fueled by industrial expansion and a rising population, continues to be a challenge for the scientific community. The heavy reliance on fossil fuels that contribute to environmental degradation and public health concerns, is shifting toward sustainable alternatives, with hydrogen production via advanced catalysts as an energy source emerging as a promising solution. This transition addresses the challenges posed by harmful combustion emissions. In this study, we developed an innovative PANI@Cu-NA-MOF nanocomposite catalyst through a sol–gel synthesis approach that strategically integrates conducting polymers with metal–organic frameworks. The catalyst was characterized using different sets of techniques. Surface morphology and elemental composition were investigated using SEM-EDX, while structural analysis was carried out with FTIR that helped to identify the chemical bonds and functional groups, and UV-Vis spectroscopy provided information on its light absorption properties. In addition, TGA was used to evaluate thermal behavior, and XPS offered detailed surface chemical analysis. It was observed by morphology that PANI@Cu-NA-MOF is a noncapsular-like structure. It is thermally highly stable; a TGA study showed that up to 550 °C, almost 2.5% of weight was lost. The single peak in UV-Vis is the preparation of a successful composite. XPS and FTIR reveal the required peaks of functional groups and elements. The PANI@Cu-NA-MOF composite turned out to be quite effective for water electrolysis, requiring an overpotential of just 0.47 V to drive the reaction. When tested against the reversible hydrogen electrode, we observed onset potentials of 1.6 V/RHE for the oxygen evolution reaction and 0.2 V/RHE for the hydrogen evolution reaction. What makes this particularly interesting is that such performance significantly cuts down on the energy needed for electrolysis, which could make hydrogen production much more practical. Since hydrogen burns cleanly and offers a real alternative to fossil fuels, having an efficient catalyst like this brings us one step closer to sustainable energy. Full article

The urban heat island effect is strongly linked to the use of dense mineral pavements with high thermal inertia and lacking passive heat dissipation mechanisms. This article evaluates the potential of evaporatively cooled concrete pavers, based on capillary action and evaporation by incorporating recycled, bio-based, and lightweight materials to develop functional porosity. Ten paver formulations were developed using natural or recycled sand, hemp fibers and shives, and lightweight aggregates. Compressive strength, density, capillary absorption, and thermal behavior were characterized. Tests were conducted outdoors in full sunlight over 48 h in comparison with reference urban materials. The results show that capillary action alone is insufficient to induce effective cooling. The raw recycled sand formulation exhibits high capillary absorption but reaches maximum temperatures of 43–44 °C, which may be due to its low interconnected porosity that limits evaporation. Conversely, formulations incorporating bio-based materials or lightweight aggregates showed a more favorable balance between water availability, reduced density, and surface cooling performance. Hemp-based pavers reach maximum temperatures of 38–40 °C, while those incorporating expanded clay range between 37 and 39 °C, representing a reduction of 7 to 13 °C compared to bitumen and maintaining mechanical strengths suitable for pedestrian use. The results suggest that effective evaporative cooling is associated with sufficient capillary absorption, efficient water transfer toward the surface, and moderate density limiting heat storage. This study demonstrates that high capillary absorption alone does not ensure effective evaporative cooling. By systematically comparing recycled, bio-based and lightweight aggregates, the results reveal that evaporative cooling efficiency probably depends on the functional connectivity of the pore network and on a moderate material density limiting heat storage. Full article

The transition from starch-dominated to protein-enriched gluten-free systems represents a critical step in improving the functional and nutritional quality of composite flours. This study investigated the effects of progressive substitution of Amaranthus caudatus (amaranth) with Lupinus mutabilis (Andean lupin) on the physicochemical, rheological, and antioxidant properties of gluten-free flour blends. A multimodal dataset comprising 33 variables across six measurement domains (proximal composition, hydration properties, thermomechanical behavior, pasting profiles, particle size, and antioxidant activity) was analyzed using an integrated framework combining univariate inference (FDR-adjusted p-values), PCA, Multiple Factor Analysis (MFA), and sparse Partial Least Squares Discriminant Analysis (sPLS-DA). Results revealed that increasing lupin content (10–40%) significantly increased protein and fiber levels while decreasing starch content, leading to higher water absorption capacity and reduced peak viscosity and setback. Multivariate models showed that the protein/fiber–starch trade-off was the principal axis of compositional differentiation (PC1, ~41% variance), while PC2 captured rheological and antioxidant variability, with formulations containing higher proportions of amaranth exhibiting greater antioxidant activity. The sPLS-DA model achieved 72% separation accuracy with moisture, protein, water absorption, and torque parameters as top discriminants. These findings provide an evidence-based framework for gluten-free flour optimization using Andean crops and highlight how statistical modeling can inform targeted formulation decisions. The approach is transferable to other compositional transitions in food systems, underscoring the utility of multivariate analytics in applied food research. The multivariate framework further suggests that intermediate substitution levels may offer an optimal balance between nutritional enrichment and rheological functionality. Full article

Reinforced concrete structures must balance immediate structural performance with long-term durability against environmental degradation, particularly carbonation-induced corrosion. While traditional cast-in-place concrete covers serve as the primary barrier, their substitution with prefabricated permanent formworks made of fiber-reinforced cementitious composites often fails to provide the necessary protective qualities required for aggressive environments. This study evaluates the durability and mechanical behavior of sisal-fiber-reinforced cementitious composites specifically engineered for use as permanent formwork. Short sisal fibers, treated by hornification to enhance dimensional stability and fiber–matrix adhesion, were incorporated at dosages of 2%, 4%, and 6% by weight. The experimental program included tests for water absorption, ultrasonic pulse velocity, axial compression, three-point flexural strength, and accelerated carbonation. The results indicated that composites with 2% and 4% of fibers exhibited reduced water absorption, sorptivity, compressive strength, and modulus of elasticity compared to the reference cement matrix. Residual stress values further demonstrated that the composites maintain significant post-cracking strength and stress transfer capacity, confirming their viability for structural elements. Although sisal-fiber-reinforced cementitious composites exhibit higher porosity and water absorption than conventional concrete used as reinforcement cover, they show sufficient resistance to carbonation to ensure a service life exceeding 50 years for reinforced concrete elements. Full article

Beryllium (Be), a critical strategic metal element, is predominantly extracted from beryl, which serves as a key mineral combining significant strategic importance with essential industrial applications. Significant debate remains, however, regarding the mineralogical characteristics and color-causing mechanisms of beryl. In this study, we integrate Electron Probe Microanalysis (EPMA), Fourier transform infrared spectrometer (FTIR), laser Raman spectrometer (LRS), X-ray diffractometer (XRD), and ultraviolet–visible spectrophotometer (UV-VIS) to elucidate the mineralogy and spectral characteristics of pegmatitic beryl from Xinjiang, Northwest China. The results indicate that the beryl mainly presents a yellowish-green color, associated with minerals such as feldspar, quartz, and garnet. The EPMA results confirm the chemical composition of the typical beryl and indicate that the Al content is lower than the theoretical value, reflecting the substitution of Al³⁺. The FTIR shows characteristic vibrations of Si-O tetrahedral groups within the range of 1400~400 cm⁻¹, along with distinct bending and stretching vibration peaks of H₂O molecules observed in the range of 1700~1500 cm⁻¹ and 3500~3800 cm⁻¹, respectively. Combined with spectral analysis, it can be determined that both Type I water and Type II H₂O are present in the samples. Raman spectroscopy reveals that the two distinct peaks of beryl are located at approximately 685 cm⁻¹ (attributed to the stretching vibration of Be-O) and 1067 cm⁻¹ (corresponding to the bending vibration of Si-O), respectively. The XRD analysis shows that the ratio of unit cell parameters c/a of the samples ranges from 0.9950 to 1.0068, and the isomorphous substitution in its structure is mainly manifested as the replacement of octahedral coordination sites by Al³⁺. The UV-VIS shows that Fe³⁺ exhibits a broad absorption band in the range of 200~300 nm, while no obvious absorption peaks are observed in the range of 300~800 nm. The above characteristics indicate that Fe³⁺ has a significant impact on the color of beryl. For green beryl samples, a portion of Fe³⁺ occupies the structural channel sites and interacts with H₂O molecules within the channels, which contributes to the yellowish hue of beryl. Our study highlights crucial data for mineralogical identification, genetic tracing, as well as efficient utilization of beryl resources. Full article

Oxalis tuberosa (Oca) is traditionally cultivated in the high Andean regions of Peru and represents a promising alternative source of starch with potential industrial uses, ranking among the most essential tubers after the potato. This study aimed to evaluate the physicochemical, morphological, techno-functional, and thermal properties of starch isolated from three specific varieties of Oca (yellow, black, and white) harvested at the Ccanccayllo production center in Andahuaylas, Peru. The isolated starches exhibited high purity, characterized by high luminosity (L* > 92.28) and a whiteness index exceeding 92.10. Moisture content ranged from 9.36% to 10.01%, correlating with low water activity (a_w = 0.44), indicating stability. Notably, the amylose content was significantly higher than that of other previously studied Oca varieties. This composition contributed to a favorable water absorption capacity, solubility index, swelling power, and viscosity, with the white variety displaying superior functional performance. Colloidal stability in aqueous media was moderate, as indicated by zeta potential analysis. Particle size analysis revealed granules ranging from 26.32 to 27.74 μm, with elongated and oval morphologies confirmed by SEM, displaying characteristic functional groups. Thermal analysis (DSC) demonstrated gelatinization temperatures between 52.73 and 53.12 °C and enthalpies ranging from 4.92 to 6.11 J/g, while Thermogravimetric Analysis (TGA) indicated thermal degradation up to approximately 74–80%. These findings suggest that the studied Oca starches possess significant potential for application in the food and pharmaceutical industries due to their distinct functional properties. Full article