Search Results (14)

This study investigates the effect of 3-glycidoxypropyltrimethoxysilane (GPTMS) concentration on the mechanical, interfacial, and fracture behavior of epoxy/microfibrillated cellulose (MFC) composites derived from oil palm empty fruit bunch (OPEFB). GPTMS was incorporated at 1, 3, and 5 Phr to improve compatibility between hydrophilic MFC and the hydrophobic epoxy matrix. Mechanical testing revealed that GPTMS concentration significantly influenced composite performance in a concentration-dependent manner, with 1 Phr GPTMS providing the most balanced reinforcement. At this concentration, tensile strength increased by 14.5% from 32.88 ± 3.61 MPa to 37.65 ± 1.42 MPa, while flexural strength improved by 5.55% from 70.24 ± 5.30 MPa to 74.14 ± 4.10 MPa compared with the unmodified composite. Tensile modulus also increased from 2.07 ± 0.06 GPa to 2.21 ± 0.16 GPa, accompanied by improved flexural modulus from 2.39 ± 0.12 GPa to 2.47 ± 0.21 GPa. SEM analysis revealed that the optimized formulation promoted more uniform MFC dispersion, improved interfacial integrity, reduced void formation, and enhanced fracture resistance through tortuous crack propagation, localized radial crack branching, and matrix tearing. In contrast, higher GPTMS concentrations (3 and 5 Phr) reduced mechanical efficiency, with flexural strength declining to 65.27 ± 5.33 MPa and 66.16 ± 4.23 MPa, respectively, due to increased fiber pull-out, interfacial heterogeneity, and more continuous crack propagation. FTIR analysis suggested possible silane-related interfacial modifications consistent with GPTMS incorporation, although these findings are interpreted as supportive rather than definitive evidence of grafting. Overall, the results demonstrate that moderate GPTMS incorporation (1 Phr) is the optimum strategy for enhancing epoxy/MFC composite performance, offering a practical pathway for developing sustainable lightweight bio-based composites with balanced strength, stiffness, and fracture resistance. This research contributes to SDG 12 (Responsible Consumption and Production) by promoting sustainable utilization of oil palm biomass waste for advanced engineering materials. Full article

Against the backdrop of the continuous advancement of high-quality development in road infrastructure and the growing demand for waste asphalt recycling, the application limitations of traditional petroleum-based asphalt rejuvenators have become increasingly prominent due to their high resource dependence, poor compatibility with aged asphalt, and high volatility. By contrast, bio-oil, characterized by wide feedstock availability, outstanding renewability, and the inherent potential to modulate the colloidal structure and properties of aged asphalt, has gradually emerged as a critical research direction in the field of asphalt rejuvenator development. This paper provides a comprehensive review on the research, development and engineering application of bio-based rejuvenators. Firstly, the main feedstock systems, including vegetable oils, lignin derivatives and algal oils, are introduced, and the core preparation technologies (e.g., pyrolysis and alkali-catalyzed transesterification) are discussed, along with the impacts of their key process parameters on the chemical composition and storage stability of the end products. Subsequently, the performance of various bio-based rejuvenators in optimizing the rheological properties, high- and low-temperature performance, as well as fatigue and cracking resistance of aged asphalt is summarized, and the underlying rejuvenation mechanisms are generalized. Finally, the prevailing technical bottlenecks, such as inconsistent quality of as-prepared products and insufficient understanding of the long-term aging mechanism, are analyzed. Future research directions including oriented molecular modification, interfacial regulation, and full life cycle assessment (LCA) are proposed, to provide a systematic reference for their large-scale engineering application. Full article

The maritime transport sector’s reliance on fossil-based fuels remains a major contributor to global greenhouse gas emissions, underscoring the urgent need for sustainable alternatives such as marine biofuels. Thermochemical pyrolysis of biomass and plastic waste represents a promising route for producing renewable and recycled marine fuel feedstocks. This review provides an integrated analysis of the full production and upgrading chain, encompassing pyrolysis of lignocellulosic biomass and polymer-derived resources, catalytic upgrading, and qualitative evaluation of product distribution and yield trends. Particular emphasis is placed on montmorillonite-based catalysts as naturally abundant, low-cost, and environmentally benign alternatives to conventional zeolites. The review systematically examines the influence of key montmorillonite modification strategies, including acid activation, pillaring, and ion-exchanged, on acidity, textural properties, and catalytic performance in catalytic cracking and hydrodeoxygenation processes. The analysis shows that catalyst modification strongly governs the yield, selectivity, and reproducibility of biofuels. By adopting this integrated perspective, the review extends beyond existing works focused on isolated upgrading steps or zeolitic catalysts. Key research gaps are identified, particularly regarding long-term catalyst stability, deep deoxygenation of real bio-oils, and compliance with marine fuel standards. Full article

Plastic streams dominated by polyethylene (PE) including PE HD/MD (High Density/Medium Density) and PE LD/LLD (Low Density/Linear Low Density), polypropylene (PP), and polyvinyl chloride (PVC) across Europe demand a design framework that links synthesis with end of life reactivity, supporting circular economic goals and European Union waste management targets. This work integrates polymerization derived chain architecture and depolymerization mechanisms to guide selective valorization of commercial plastic wastes in the European context. Catalytic topologies such as Bronsted or Lewis acidity, framework aluminum siting, micro and mesoporosity, initiators, and strategies for process termination are evaluated under relevant variables including temperature, heating rate, vapor residence time, and pressure as encountered in industrial practice throughout Europe. The analysis demonstrates that polymer chain architecture constrains reaction pathways and attainable product profiles, while additives, catalyst residues, and contaminants in real waste streams can shift radical populations and observed selectivity under otherwise similar operating windows. For example, strong Bronsted acidity and shape selective micropores favor the formation of C₂ to C₄ olefins and Benzene, Toluene, and Xylene (BTX) aromatics, while weaker acidity and hierarchical porosity help preserve chain length, resulting in paraffinic oils and waxes. Increasing mesopore content shortens contact times and limits undesired secondary cracking. The use of suitable initiators lowers the energy threshold and broadens processing options, whereas diffusion management and surface passivation help reduce catalyst deactivation. In the case of PVC, continuous hydrogen chloride removal and the use of basic or redox co catalysts or ionic liquids reduce the dehydrochlorination temperature and improve fraction purity. Staged dechlorination followed by subsequent residue cracking is essential to obtain high quality output and prevent the release of harmful by products within European Union approved processes. Framing process design as a sequence that connects chain architecture, degradation chemistry, and operating windows supports mechanistically informed selection of catalysts, severity, and residence time, while recognizing that reported selectivity varies strongly with reactor configuration and feed heterogeneity and that focused comparative studies are required to validate quantitative structure to selectivity links. In European post consumer sorting chains, PS and PC are frequently handled as separate fractions or appear in residues with distinct processing routes, therefore they are not included in the polymer set analyzed here. Polystyrene and polycarbonate are outside the scope of this review because they are commonly handled as separate fractions and are typically optimized toward different product slates than the gas, oil, and wax focused pathways emphasized here. Full article

The growing use of reclaimed asphalt pavement (RAP) in warm-mix asphalt (WMA) presents significant challenges when RAP originates from aged polymer-modified binder (PMB) pavements, where severe oxidation and polymer degradation lead to excessive stiffness and poor cracking resistance. This study presents a multi-scale evaluation of a hybrid modification strategy combining recycled engine oil waste (REOW, 3 wt.%) and styrene–butadiene–styrene (SBS, 1–4 wt.%) to restore aged PMB-containing RAP systems under controlled binder conditions. Three binders (control, REOW-modified, and REOW–SBS hybrid) were prepared using a fixed 70/30 virgin-to-RAP binder blend and characterized through rheological analysis, and multiple stress creep recovery (MSCR). The findings show that REOW softened the binder but reduced elastic recovery, whereas SBS modification restored elastic response. Corresponding WMA mixtures with 30 wt.% RAP and 5.0 wt.% total binder content were evaluated for moisture damage, raveling, rutting, and cracking resistance. At the mixture scale, the hybrid system achieved a TSR of 83%, reduced Hamburg rut depth by ~20%, and increased SCB fracture energy by ~30% compared with the control. These findings demonstrate that combined rejuvenation–reinforcement effectively re-mobilizes aged PMB chemistry and restores polymer elasticity, enabling high-performance WMA production with RAP derived from polymer-modified pavements. Full article

To address circularity and resource recovery in modern structural applications, industry is seeking materials that are sustainable and lightweight. Although natural fiber-reinforced composites offer sustainability advantages, their mechanical properties remain inferior to those of synthetic fiber systems, limiting practical deployment. Flax fibers were selected as reinforcement due to their high specific stiffness, biodegradability, and wide availability. This study implements a three-level strategy to enhance the flexural performance of flax fiber-reinforced composites: at the process level, curing under distinct heating rates to promote a more uniform polymer network; at the material level, incorporation of a carbonaceous additive derived from fuel–oil furnace waste to strengthen interfacial adhesion; and at the structural level, adoption of a sandwich configuration with a recycled PET core to increase section bending inertia. Specimens were fabricated via vacuum-assisted resin transfer molding (VARTM) and tested using a three-point bending method. Mechanical testing shows clear improvements in flexural performance, with the sandwich architecture yielding the highest values and increasing flexural strength by up to 4.52× relative to the other conditions. For the curing series, FTIR indicates greater reaction extent, evidenced by lower intensities of the epoxide ring at 915 cm⁻¹ and glycidyl/oxirane band near 972 cm⁻¹, together with a more pronounced C–O–C stretching region, consistent with the higher flexural response. While SEM observations revealed interfacial debonding at 5% FCB, a hybrid mechanism with crack deflection appeared at 10%. This transition created tortuous crack paths, consistent with the higher flexural strength and modulus at 10% FCB. A distinctive feature of this work is the integration of three reinforcement strategies—controlled curing, waste-derived carbon additive, and recycled PET sandwich design. This integration not only enhances the performance of natural fiber composites but also emphasizes sustainability by valorizing recycled and waste-derived resources, thereby supporting the development of greener composite materials. Full article

It has been proven that the performance of fluid catalytic cracking (FCC), as the most important oil refining process for converting low-value heavy oils into high-value transportation fuels, light olefins, and feedstocks for petrochemicals, depends strongly on the quality of the feedstock. For this reason, characterization of feedstocks and their relationships to FCC performance are issues deserving special attention. This study systematically reviews various publications dealing with the influence of feedstock characteristics on FCC performance, with the aim of identifying the best characteristic descriptors allowing prediction of FCC feedstock cracking capability. These characteristics were obtained by mass spectrometry, SARA analysis, elemental analysis, and various empirical methods. This study also reviews published research dedicated to the catalytic cracking of biomass and waste oils, as well as blends of petroleum-derived feedstocks with sustainable oils, with the aim of searching for quantitative relationships allowing prediction of FCC performance during co-processing. Correlation analysis of the various FCC feed characteristics was carried out, and regression techniques were used to develop correlations predicting the conversion at maximum gasoline yield and that obtained under constant operating conditions. Artificial neural network (ANN) analysis and nonlinear regression techniques were applied to predict FCC conversion from feed characteristics at maximum gasoline yield, with the aim of distinguishing which technique provided the more accurate model. It was found that the correlation developed in this work based on the empirically determined aromatic carbon content according to the n-d-M method and the hydrogen content calculated via the Dhulesia correlation demonstrated highly accurate calculation of conversion at maximum gasoline yield (standard error of 1.3%) compared with that based on the gasoline precursor content determined by mass spectrometry (standard error of 1.5%). Using other data from 88 FCC feedstocks characterized by hydrogen content, saturates, aromatics, and polars contents to develop the ANN model and the nonlinear regression model, it was found that the ANN model demonstrated more accurate prediction of conversion at maximum gasoline yield, with a standard error of 1.4% versus 2.3% for the nonlinear regression model. During the co-processing of petroleum-derived feedstocks with sustainable oils, it was observed that FCC conversion and yields may obey the linear mixing rule or synergism, leading to higher yields of desirable products than those calculated according to the linear mixing rule. The exact reason for this observation has not yet been thoroughly investigated. Full article

The development of renewable sources for energy production has assumed a vital role in recent years, particularly with regard to the preservation of energy supplies and the environment. In this regard, municipal green waste (MGW) can be a potential renewable energy source if it is integrated with emerging technology, like pyrolysis. Therefore, this study aimed at investigating the effect of residence time and particle size on the yield and composition of oil derived from MGW using fast pyrolysis in an auger reactor. The residence time and particle size were varied from 1 min to 4 min and 1 mm to 10 mm, respectively, while keeping the temperature constant at 500 °C. At a residence time of 3 min, a 2 mm particle size provided the highest bio-oil yield (39.86%). At this experimental setting, biochar yield of 27.16% and syngas yield of 32.98% were obtained. The characterization of produced bio-oil revealed that a total of nine functional groups were present in the bio-oil. The phenols were highest in amount, followed by aromatics and ketones. The increase in residence time decreased the amount of acidic compounds present in the bio-oil. The water content was decreased by ~11% and the calorific value was increased by ~6% with the increase in particle size from 1 mm to 10 mm. Other properties, such as viscosity, density, cetane number, and flash point, did not change significantly with the change in experimental conditions. With a calorific value of 25+ MJ/kg, although the bio-oil produced from MGW can be used for heating (such as in boilers and furnaces), the use of MGW bio-oil in engines requires appropriate upgrading through procedures like hydrodeoxygenation, catalytic cracking, esterification, etc. Full article

The pyrolysis of vegetable oil waste is an alternative way to convert biomass into high-quality second-generation biofuels, with social, economic and environmental sustainability. The present work deals with the pyrolysis of oleic acid as a model compound and an industrial vegetable oil residue on CuNiAl mixed oxide catalysts, derived from layered double hydroxides. Reactions of the oils pre-adsorbed on the catalysts (catalyst:oil mass ratio of 5:1) were performed at 550 °C on a micro-pyrolysis system and the analyses of volatile products were carried out online using GC/MS. Copper addition to NiAl catalysts increased the cracking of oleic acid. Increasing copper content also decreased the formation of aromatics and coke precursors, as well as oxygenated compounds. The CuNiAl catalyst with a Cu/Ni ratio of 0.4 showed strong catalytic activity in the conversion of an industrial vegetable oil residue with a high volume of free fatty acids produced. Compared to the non-catalytic reaction, the catalyst reduced the content of oxygenates and increased the content of hydrocarbons, particularly in the gasoline range (C5–C9). The CuNiAl oxide catalyst was able to convert vegetable oil residues into hydrocarbons in the range of gasoline, kerosene and diesel, and also linear alkylbenzenes as chemical precursors for surfactant production. Full article

The significant reduction in CO₂ emissions arising from the cementitious composites industry is one of the highest priorities for the construction sector’s movement towards climate neutrality and sustainable development. One of the approaches to cope with this issue is to partially substitute cement with supplementary cementitious materials. Recently, various oil refinery wastes (ORW) have attracted researchers’ attention in terms of being investigated for such an application. As such, the present paper shows the preliminary results of investigations conducted on cement pastes with the addition of a spent fluid catalytic cracking catalyst derived from a Polish oil refinery company. It is worth mentioning that the incorporation of ORW in cementitious composites might enable the production of more environmentally friendly construction materials without sacrificing quality, whilst, simultaneously providing an opportunity for recycling petrochemical wastes. Full article

Biodiesel production through transesterification or catalytic hydrogenation using vegetable oil is a sustainable method, but it has the downsides of by-product generation and a higher cost. Therefore, in this study, waste cooking oil was selected as a raw material, and fluidized catalytic cracking was carried out on the catalyst (LDO-75) through a fixed-fluidized-bed (FFB) reactor. The effects of the reaction temperature, catalyst–oil ratio and weight hourly space velocity (WHSV) on the yield of pyrolysis gas, gasoline, diesel and heavy oil fractions were studied. The composition of the pyrolysis gas was determined by gas chromatography (GC), the composition of the gasoline fraction was analyzed by gas chromatography-mass spectrometry (GC-MS), and the characteristics of the diesel and heavy oil fractions were determined by nuclear magnetic resonance (NMR). The results show that light olefins are the main products of pyrolysis gases, and the liquid products are mainly composed of aromatic compounds. In addition, the catalytic cracking process of waste cooking oil fluid is proposed, indicating that the process of the catalytic cracking of waste cooking oil fluid includes deoxygenation, oligoaromatization and hydrodeoxygenation. The results of this study will provide a basis for the high value-added utilization of waste cooking oil. Full article

Urban waste management is a hard task: more than 30% of the world’s total production of Municipal Solid Wastes (MSW) is not adequately handled, with landfilling remaining as a common practice. Another source of wastes is the road pavement industry: with a service life of about 10–15 years, asphalts become stiff, susceptible to cracks, and therefore no longer adapted for road paving, so they become wastes. To simultaneously solve these problems, a circular economy-based approach is proposed by the ReScA project, suggesting the use of pyrolysis to treat MSW (or its fractions as Refuse Derived Fuels, RDFs), whose residues (oil and char) can be used as added-value ingredients for the asphalt cycle. Char can be used to prepare better performing and durable asphalts, and oil can be used to regenerate exhaust asphalts, avoiding their landfilling. The proposed approach provides a different and more useful pathway in the end-of-waste (EoW) cycle of urban wastes. This proof of concept is suggested by the following two observations: (i) char is made up by carbonaceous particles highly compatible with the organic nature of bitumens, so its addition can reinforce the overall bitumen structure, increasing its mechanical properties and slowing down the molecular kinetics of its aging process; (ii) oil is rich in hydrocarbons, so it can enrich the poor fraction of the maltene phase in exhaust asphalts. These hypotheses have been proved by testing the residues derived from the pyrolysis of RDFs for the improvement of mechanical characteristics of a representative bitumen sample and its regeneration after aging. The proposed approach is suggested by the physico-chemical study of the materials involved, and aims to show how the chemical knowledge of complex systems, like bituminous materials, can help in solving environmental issues. We hope that this approach will be considered as a model method for the future. Full article

At present, the majority of available road and jet biofuels are produced from oleochemical feedstocks that include vegetable oils and biowastes such as waste cooking oils and animal fats. Additionally, one of the most promising ways to achieve long-term environmental goals is to sustainably use lignocellulosic residues. These resources must be treated through a deoxygenation process and subsequent upgrading processes to obtain high-quality road and jet biofuels. Accordingly, in this review, we explore recent advancements in the deoxygenation of oleochemical and lignocellulosic feedstocks in the absence of hydrogen to produce high-quality road and jet biofuels, mainly focusing on the use of nanomaterials as catalysts and the valorization of lipid-rich biowastes and lignocellulosic residues. As a result, we found that regardless of the catalyst particle size, the coexistence of basic sites and weak/medium acid sites is highly important in catalytic systems. Basic sites can enhance the removal of oxygenates via decarboxylation and decarbonylation reactions and inhibit coke formation, while weak/medium acid sites can enhance the cracking reaction. Additionally, the extraction of value-added derivatives from lignocellulosic residues and their subsequent upgrade require the use of advanced methods such as the lignin-first approach and condensation reactions. Full article

Solid acid catalyzed cracking of waste oil-derived fatty acids is an attractive route to hydrocarbon fuels. HZSM-5 is an effective acid catalyst for fatty acid cracking; however, its microporous nature is susceptible to rapid deactivation by coking. We report the synthesis and application of hierarchical HZSM-5 (h-HZSM-5) in which silanization of pre-crystallized zeolite seeds is employed to introduce mesoporosity during the aggregation of growing crystallites. The resulting h-HZSM-5 comprises a disordered array of fused 10–20 nm crystallites and mesopores with a mean diameter of 13 nm, which maintain the high surface area and acidity of a conventional HZSM-5. Mesopores increase the yield of diesel range hydrocarbons obtained from oleic acid deoxygenation from ~20% to 65%, attributed to improved acid site accessibility within the hierarchical network. Full article