Search Results (254)

Ultrahigh resolution fine particulate matter (PM_2.5) mass concentration remote sensing products are crucial for atmospheric environmental monitoring, pollution source verification, health exposure risk assessment, and other fine-scale applications in urban environments. This study developed an ultrahigh resolution retrieval algorithm to estimate 30 m resolution PM_2.5 mass concentrations over urban areas from Landsat-8 and Sentinel-2A/B satellite measurements. The algorithm utilized aerosol optical depth (AOD) products retrieved from the Landsat-8 OLI and Sentinel-2 MSI measurements from 2017 to 2020, combined with multi-source auxiliary data to establish a PM_2.5-AOD relationship model across China. The results showed an overall high coefficient of determination (R²) of 0.82 and 0.76 for the model training accuracy based on samples and stations, respectively. The model prediction accuracy in Beijing and Wuhan reached R² values of 0.86 and 0.85. Applications in both cities demonstrated that ultrahigh resolution PM_2.5 has significant advantages in resolving fine-scale spatial patterns of urban air pollution and pinpointing pollution hotspots. Furthermore, an analysis of point source pollution at a typical heavy pollution emission enterprise confirmed that ultrahigh spatial resolution PM_2.5 can accurately identify the diffusion trend of point source pollution, providing fundamental data support for refined monitoring of urban air pollution and air pollution prevention and control. Full article

Accurate detection of the atmospheric boundary layer (ABL) is important for weather forecasting, urban air quality monitoring, and agricultural and ecological protection. In this study, we propose a new method for enhancing ABL height detection accuracy by integrating multi-channel polarized lidar signals at 355 nm and 532 nm wavelengths. Radiosonde observations and ERA5 reanalysis are used to validate the lidar-derived results. By calculating the gradients of signals of different wavelengths and weighted fusion, the position of the top of the boundary layer is identified, and corresponding weights are assigned to signals of different wavelengths according to the signal-to-noise ratio of the signals to obtain a more accurate atmospheric boundary layer height. This method can effectively mitigate the influence of noise and provides more stable and accurate ABL height estimates, particularly under complex aerosol conditions. Three case studies of ABL height detection over the Beijing region demonstrate the effectiveness and reliability of the proposed method. The fused ABLHs were found to be consistent with the sounding data and ERA5. This research offers a robust approach to enhancing ABL height detection and provides valuable data support for meteorological studies, pollution monitoring, and environmental protection. Full article

Aerosol optical depth (AOD) serves as a critical indicator for atmospheric aerosol monitoring and air quality assessment, and quantifies the radiative attenuation caused by airborne particulate matter. This study uses MODIS remote sensing imagery together with land use transition datasets (2000–2020) and road network density metrics (2014–2020), to investigate the spatiotemporal evolution of AOD in Zhejiang Province and its synergistic correlations with urbanization patterns and transportation infrastructure. By integrating MODIS_1KM AOD product, grid-based road network density mapping, land use dynamic degree modeling, and transfer matrix analysis, this study systematically evaluates the interdependencies among aerosol loading, impervious surface expansion, and transportation network intensification. The results indicate that during the study period (2000–2020), the provincial AOD level shows a significant declining trend, with obvious spatial heterogeneity: the AOD values in eastern coastal industrial zones and urban agglomerations continue to increase, with lower values dominating southwestern forested highlands. Meanwhile, statistical analyses confirm highly positive correlations between AOD, impervious surface coverage, and road network density, emphasizing the dominant role of anthropogenic activities in aerosol accumulation. These findings provide actionable insights for enhancing land-use zoning, minimizing vehicular emissions, and developing spatially targeted air quality management strategies in rapidly urbanizing regions. This study provides a solid scientific foundation for advancing environmental sustainability by supporting policy development that balances urban expansion and air quality. It contributes to building more sustainable and resilient cities in Zhejiang Province. Full article

Aerosols play a crucial role in air quality, climate regulation, and public health; their timely monitoring is hence fundamental. The aerosol optical depth (AOD) is the parameter used to investigate the spatial–temporal distribution of aerosols from space. Specifically, the AOD retrieved from the Multi-Angle Implementation of Atmospheric Correction (MAIAC) algorithm applied to a Moderate Resolution Imaging Spectroradiometer (MODIS) is suitable for aerosol investigation at a local scale by exploiting its high spatial resolution (1 km × 1 km). In this study, the MAIAC AOD retrieval over Rome (Italy) was validated for the first time, using ground-based data provided by an AERONET station operating in a semi-rural environment close to the city, over a time series from January 2001 to December 2022. Moreover, AOD trends were evaluated in a study area encompassing Rome and its surroundings, characterized by a transition zone between urban and rural environments. The results show a general underestimation of the MAIAC AOD; specifically, the validation process highlighted the less accurate performance of the algorithm under higher aerosol loading and with predominantly coarse mode aerosol. Interesting results were obtained concerning the influence of the geometrical configuration of satellite acquisition on the accuracy of the MAIAC product. In particular, the solar zenith angle, the relative azimuth and the scattering angle between the principal plane of the sun and satellite synergistically influence retrievals. Finally, the spatial distribution of the AOD shows a decreasing trend over the 2001–2022 period and a strong influence of the city of Rome over the whole study area. Full article

Medellín, a densely populated city in the Colombian Andes, faces significant health and environmental risks due to poor air quality. This is linked to the atmospheric dynamics of the valley in which it is located (Aburrá Valley). The region is characterized by a narrow valley and one of the most polluted areas in South America. This is a comparative study of the chemical composition of PM_2.5 (particles with diameter less than 2.5 µm) in Medellín between two periods (2014–2015 and 2018–2019) in which temporal trends and emission sources were evaluated. PM_2.5 samples were collected from urban, suburban, and rural stations following standardized protocols and compositional analyses of metals (ICP-MS), ions (ion chromatography), and carbonaceous species (organic carbon (OC) and elemental carbon (EC) by thermo-optical methods) were performed. The results show a reduction in average PM_2.5 concentrations for the two periods (from 26.74 µg/m³ to 20.10 µg/m³ in urban areas), although levels are still above WHO guidelines. Urban stations showed higher PM_2.5 levels, with predominance of carbonaceous aerosols (Total Carbon—TC = OC + EC = 35–50% of PM_2.5 mass) and secondary ions (sulfate > nitrate, 13–14% of PM_2.5 mass). Rural areas showed lower PM_2.5 concentrations but elevated OC/EC ratios, suggesting the influence of biomass burning as a major emission source. Metals were found to occupy fractions of less than 10% of the PM_2.5 mass; however, they included important toxic species associated with respiratory and cardiovascular risks. This study highlights progress in reducing PM_2.5 levels in the region, which has been impacted by local policies but emphasizes current and future challenges related mainly to secondary aerosol formation and carbonaceous aerosol emissions. Full article

This study examines the seasonality of Black Carbon (BC) and Brown Carbon (BrC) spectral absorption characteristics at a continental background site (Kozani) in southern Balkans (NW Greece). It aims to assess the seasonality and impact of different sources on light absorption properties, BC concentrations, and the fraction of BrC absorption. Moderate-to-low BC concentrations were observed, ranging from 0.05 µg m⁻³ to 2.44 µg m⁻³ on an hourly basis (annual mean: 0.44 ± 0.27 µg m⁻³; median: 0.39 µg m⁻³) with higher levels during winter (0.53 ± 0.33), reflecting enhanced emissions from residential wood burning (RWB) for heating purposes. Atmospheric conditions are mostly clean during spring (MAM) (BC: 0.34 µg m⁻³), associated with increased rainfall. BC components associated with fossil fuel combustion (BC_ff) and biomass burning (BC_bb), maximize in summer (0.36 µg m⁻³) and winter (0.28 µg m⁻³), respectively, while the absorption Ångstrôm exponent (AAE_370–880) values ranged from 1.09 to 1.93 on daily basis. The annual mean total absorption coefficient (b_abs,520) inferred by aethalometer (AE33) was 4.09 ± 2.65 Mm⁻¹ (median: 3.51 Mm⁻¹), peaking in winter (5.30 ± 3.35 Mm⁻¹). Furthermore, the contribution of BrC absorption at 370 nm, was also high in winter (36.7%), and lower during the rest of the year (17.3–29.8%). The measuring station is located at a rural background site 4 km outside Kozani City and is not directly affected by traffic and urban heating emissions. Therefore, the regional background atmosphere is composed of a significant fraction of carbonaceous aerosols from RWB in nearby villages, a characteristic feature of the Balkan’s rural environment. Emissions from the lignin-fired power plants, still operating in the region, have decreased during the last years and moderately affect the atmospheric conditions. Full article

Urbanization has been suspected to increase the allergic rate of people, and its impact on airborne fungi and potential allergens has drawn attention. In this study, aerosol samples were collected concurrently at proximate urban and rural sites of Shanghai during the four seasons to analyze the changes in abundance and community composition of airborne fungi. In summer, there were significantly higher concentrations of fungi in the urban atmosphere compared to at the rural site. Ascomycota and Basidiomycota were the top two fungal phyla, and Cladosporium was the most abundant genus year round. Alternaria was the second highest genus in spring and winter (only the rural site), whereas Nigrospora ranked second during summer and autumn due to it largely being sourced from marine organisms and predominantly marine-influenced air masses in these seasons. Airborne fungal richness was relatively higher at the rural site than in urban during winter. Allergenic fungal species were found to be more abundant in winter than in other seasons; particularly, the relative abundance of Cladosporium sp. was significantly higher (p < 0.001), and Fusarium culmorum and Cladosporium herbarum also increased more in urban than in rural areas, which may be one of the key factors contributing to the rising allergic rate in the urban population. Full article

Airborne micro and nanoplastics (MPs/NPs) are a growing issue due to their possible health hazards. Since the current bibliography lacks a thorough evaluation, this review examines the sources, environmental dynamics, and health impacts of airborne MPs/NPs. Through atmospheric transport processes, these neo-pollutants spread around the world after being released, potentially settling in urban and remote areas. This review is the first to compare active and passive aerosol sampling methods, and microscopy, thermochemical, and spectroscopy analytical techniques, with a focus on their limitations in precisely quantifying micro-nanoscale plastic particles. It also draws attention to the potential toxicological effects of inhaled MPs/NPs, which can lead to oxidative stress, respiratory inflammation, and other negative health consequences. This review concludes by examining how airborne MPs/NPs may worsen their ecological impact by serving as carriers of hazardous chemicals and microbial pollutants. Despite growing awareness, there still are many unanswered questions, especially about the impact of long-term exposure and how atmospheric conditions affect the spread of MPs/NPs. The aim of this review was to bring attention to the issue of airborne MP/NP effects and to promote the development of advanced monitoring systems, a new multidisciplinary scientific field for the study of these novel pollutants, and global regulatory frameworks. Full article

In recent years, with the rapid socioeconomic development of Wuxi City, the frequent occurrence of severe air pollution events has attracted widespread attention from both the local government and the public. Based on the real-time monitoring data of criteria pollutants and GDAS (Global Data Assimilation System) reanalysis data, the spatiotemporal variation patterns, meteorological influences, and potential sources of major air pollutants in Wuxi across different seasons during 2019 (pre-COVID-19) and 2023 (post-COVID-19 restrictions) are investigated using the Pearson correlation coefficient, potential source contribution function (PSCF), and concentration-weighted trajectory (CWT) models. The results demonstrate that the annual mean PM_2.5 concentration in Wuxi decreased significantly from 39.6 μg/m³ in 2019 to 29.3 μg/m³ in 2023, whereas the annual mean 8h O₃ concentration remained persistently elevated, with comparable levels of 104.6 μg/m³ and 105.0 μg/m³ in 2019 and 2023, respectively. The O₃ and particulate matter (PM) remain the most prominent air pollutants in Wuxi’s ambient air quality. The hourly mass concentrations of criteria pollutants, except O₃, exhibited characteristic bimodal distributions, with peak concentrations occurring post-rush hour during morning and evening commute periods. In contrast, O₃ displayed a distinct unimodal diurnal pattern, peaking between 15:00 and 16:00 local time. The spatial distribution patterns revealed significantly elevated concentrations of all monitored species, excluding O₃, in the central urban zone, compared to the northern Taihu Lake region. The statistical analysis revealed significant correlations among PM concentrations and other air pollutants. Additionally, meteorological parameters exerted substantial influences on pollutant concentrations. The PSCF and CWT analyses revealed distinct seasonal variations in the potential source regions of atmospheric pollutants in Wuxi. In spring, the Suzhou–Wuxi–Changzhou metropolitan cluster and northern Zhejiang Province were identified as significant contributors to PM_2.5 and O₃ pollution in Wuxi. The potential source regions of O₃ are predominantly distributed across the Taihu Lake-rim cities during summer, while the eastern urban agglomeration adjacent to Wuxi serves as major potential source areas for O₃ in autumn. In winter, the prevailing northerly winds facilitate southward PM_2.5 transport from central-northern Jiangsu, characterized by high emissions (e.g., industrial activities), identifying this region as a key potential source contribution area for Wuxi’s aerosol pollution. The current air pollution status in Wuxi City underscores the imperative for implementing more stringent and efficacious intervention strategies to ameliorate air quality. Full article

Atmospheric intermediate volatile organic compounds (IVOCs) are important precursors of secondary organic aerosols (SOAs), and in-depth research on them is crucial for atmospheric pollution control. This review systematically synthesizes global advancements in understanding IVOC sources, emissions characterization, compositional characteristics, ambient concentrations, SOA contributions, and health risk assessments. IVOCs include long-chain alkanes (C₁₂~C₂₂), sesquiterpenes, polycyclic aromatic hydrocarbons, monocyclic aromatic hydrocarbons, phenolic compounds, ketones, esters, organic acids, and heterocyclic compounds, which originate from primary emissions and secondary formation. Primary emissions include direct emissions from anthropogenic and biogenic sources, while secondary formation mainly results from radical reactions or particulate surface reactions. Recently, the total IVOC emissions have decreased in some countries, while emissions from certain sources, such as volatile chemical products, have increased. Ambient IVOC concentrations are generally higher in urban rather than in rural areas, higher indoors than outdoors, and on land rather than over oceans. IVOCs primarily generate SOAs via oxidation reactions with hydroxyl radicals, nitrate radicals, the ozone, and chlorine atoms, which contribute more to SOAs than traditional VOCs, with higher SOA yields. SOA tracers for IVOC species like naphthalene and β-caryophyllene have been identified. Integrating IVOC emissions into regional air quality models could significantly improve SOA simulation accuracy. The carcinogenic risk posed by naphthalene should be prioritized, while benzo[a]pyrene requires a combined risk assessment and hierarchical management. Future research should focus on developing high-resolution online detection technologies for IVOCs, clarifying the multiphase reaction mechanisms involved and SOA tracers, and conducting comprehensive human health risk assessments. Full article

The long-term monitoring of nighttime lights is essential for understanding sources of light pollution. Nighttime lights observed in space are affected by atmospheric conditions as they transmit from the Earth surface through clouds and aerosols to the top of the atmosphere. In this study, based on the monthly cloud-free VIIRS/DNB products, we analyzed the long-term nighttime lights in Hong Kong (2012–2020). We found that the monthly variations in nighttime lights were large, especially in bright regions. The 12-month average of nighttime lights ranged from 13.0 to 18.9 nWcm⁻²sr⁻¹. Public transportation facilities, such as port facilities and the airport, were the brightest, twice as bright as other urban areas. Public residential areas were slightly brighter than private ones. These urban areas were at least four times brighter than undeveloped regions, showing a significant alteration in light at night due to artificial facilities. Further, we used an unsupervised clustering method to identify specific patterns. While nighttime lights were stable in most regions, increasing trends were found at construction sites of a new artificial island and the airport expansion. Abnormal patterns, such as wildfires, were also recognized. We found that the background nighttime lights were brighter in wet months (e.g., April) and dimmer in dry months (e.g., January). The amount of water in the atmosphere affects nighttime light scattering, with a linear correlation (R = 0.68) between humidity and the occurrence of bright nighttime lights each month. The diverse sources and variations in nighttime lights call for continuous monitoring and advanced analytical methods to better understand their environmental and societal impacts. Full article

This research aims to estimate long-term aerosol radiative effects by combining radiation and Aerosol Optical Depth (AOD) observations in Barcelona, Spain. Aerosol Radiative Forcing and Aerosol Forcing Efficiency (ARF and AFE) were estimated by combining shortwave radiation measurements from a SolRad-Net CM-21 pyranometer (level 1.5) and AERONET AOD (level 2), using the direct method. The shortwave AFE was derived from the slope between net solar radiation and AOD at 440, 675, 879, and 1020 nm, and the ARF was computed by multiplying the AFE by AOD at six solar zenith angles (20°, 30°, 40°, 50°, 60°, and 70°). Clear-sky conditions were selected from all-skies days by a quadratic fitting. The aerosol was classified to investigate the forcing contributions from each aerosol type. The aerosol classification was based on Pace and Toledano’s thresholds from AOD vs. Ångström Exponent (AE). The GRASP inversions were performed by combined AOD, radiation, Degree of Linear Polarization (DoLP) by zenith angles from the polarized sun–sky–lunar photometer and the elastic signal from the UPC-ACTRIS lidar system. The long-term AFE and ARF are both negative, with an increasing tendency (in absolute value) of +24% (AFE) and +40% (ARF) in 14 years. The yearly AFE varied from −331 to −10 Wm⁻²τ⁻¹, and the ARF varied from −64 to −2 Wm⁻², associated with an AOD (440 nm) from 0.016 to 0.690. The three types of aerosols on clear-sky days are mixed aerosols (61%), desert dust (10%), and urban/industrial-biomass burning aerosols (29%). Combined with Gobbi’s method, this classification clustered the aerosols into four groups by AE analysis (two coarse- and two fine-mode aerosols). Then, the contribution of the aerosol types to the ARF showed that the desert dust forcing had the largest cooling effect in Barcelona (−61.5 to −37.4 Wm⁻²), followed by urban/industrial-biomass burning aerosols (−40.4 to −20.4 Wm⁻²) and mixed aerosols (−31.8 and −24.0 Wm⁻²). Regarding the comparison among Generalized Retrieval of Atmosphere and Surface Properties (GRASP) inversions, AERONET inversions, and direct method estimations, the AFE and ARF had some differences owing to their definitions in the algorithms. The DoLP, used as GRASP input, decreased the ARF overestimation for high AOD. Full article

In contemporary times, wastewater treatment plants (WWTPs) were recognized as substantial sources of odorous emissions, potentially impacting nearby communities’ sensory experience. This study investigates the half-lives (T½) of odorous compounds emitted from WWTPs and their degradation due to atmospheric hydroxyl radicals (•OH) in different environmental settings. The calculated half-lives of specific odorants in rural areas ranged from 31.36 min to 517.33 days, in urban areas from 42.50 min to 1550 days, and in the marine boundary layer from 42.50 min to 129,861 days. These results show that compounds with high reactivity and short T½, such as methanethiol and ethanethiol, degrade rapidly and are less likely to contribute to long-term odor nuisances. In contrast, compounds with longer half-lives, such as carbonyl sulfide and ammonia, persist longer in the atmosphere, with higher potential for sustained odor issues. The findings suggest that •OH plays a significant role in degrading odorous compounds. These insights into odorant–oxidant kinetics may aid in predicting atmospheric half-lives and their contribution to secondary aerosol formation, thus informing regulatory and mitigation strategies to improve air quality. Full article

Air quality simulations were performed for Athens (Greece) in ~1 km resolution applying the models WRF-CAMx for July and December 2019 with the secondary organic aerosol processor (SOAP) and volatility basis set (VBS) organic aerosol (OA) schemes. CAMx results were evaluated against particulate matter (PM) and OA concentrations from the regulatory monitoring network and research monitoring sites (including PM_2.5 low-cost sensors). The repartition of primary OA (POA) and secondary OA (SOA) by CAMx was compared with positive matrix factorization (PMF)-resolved OA components based on aerosol chemical speciation monitor (ACSM) measurements. In July, OA concentrations underestimation was decreased by up to 24% with VBS. In December, VBS introduced small negative biases or resulted in more pronounced (but moderate) underestimations of OA with respect to SOAP. CAMx performance for POA was much better than for SOA, while VBS decreased the overestimation of POA and the underestimation of SOA in both study periods. Despite the SOA concentrations increases by VBS, CAMx still considerably underestimated SOA (e.g., by 65% in July). Better representation of simulated OA concentrations in Athens could benefit by accounting for the missing cooking emissions, by improvements in the biomass burning emissions, or by detailed integration of processes related to OA chemical aging. Full article

Vertically retrieved optical properties by Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) were investigated in the case of three selected events over Athens and Thessaloniki with documented high pollen concentrations. Hirst-type volumetric samplers were used to detect and characterize the pollen during the CALIPSO overpasses. Only cases with a total pollen concentration greater than 400 grains m⁻³ for at least two hours per day were considered severe pollen events, while model simulations were used to exclude the presence of other depolarizing aerosol types. This study provides mean values of lidar-derived optical properties inside the detected pollen layers; i.e., optical values represent the atmosphere with the presence of pollen, in urban cities of Greece. Specifically, three observed aerosol layers, one over Athens and two over Thessaloniki with particulate color ratios of 0.652 ± 0.194, 0.638 ± 0.362, and 0.456 ± 0.284, and depolarization ratios of 8.70 ± 6.26%, 28.30 ± 14.16%, and 8.96 ± 6.87%, respectively, were misclassified by CALIPSO as marine-dusty marine, dust, and polluted dust. In cases of intense pollen presence, CALIPSO vertical profiles and aerobiological monitoring methods may be used synergistically to better characterize the atmospheric pollen layers. Full article