Comprehensive Validation of MODIS-MAIAC Aerosol Products and Long-Term Aerosol Detection over an Urban–Rural Area Around Rome in Central Italy

Aerosols play a crucial role in air quality, climate regulation, and public health; their timely monitoring is hence fundamental. The aerosol optical depth (AOD) is the parameter used to investigate the spatial–temporal distribution of aerosols from space. Specifically, the AOD retrieved from the Multi-Angle Implementation of Atmospheric Correction (MAIAC) algorithm applied to a Moderate Resolution Imaging Spectroradiometer (MODIS) is suitable for aerosol investigation at a local scale by exploiting its high spatial resolution (1 km × 1 km). In this study, the MAIAC AOD retrieval over Rome (Italy) was validated for the first time, using ground-based data provided by an AERONET station operating in a semi-rural environment close to the city, over a time series from January 2001 to December 2022. Moreover, AOD trends were evaluated in a study area encompassing Rome and its surroundings, characterized by a transition zone between urban and rural environments. The results show a general underestimation of the MAIAC AOD; specifically, the validation process highlighted the less accurate performance of the algorithm under higher aerosol loading and with predominantly coarse mode aerosol. Interesting results were obtained concerning the influence of the geometrical configuration of satellite acquisition on the accuracy of the MAIAC product. In particular, the solar zenith angle, the relative azimuth and the scattering angle between the principal plane of the sun and satellite synergistically influence retrievals. Finally, the spatial distribution of the AOD shows a decreasing trend over the 2001–2022 period and a strong influence of the city of Rome over the whole study area.