Search Results (113)

Air density and pressure above the Earth’s surface in the tropospheric region depend on altitude relative to sea level. When a given amount of pollutant gas enters the atmosphere at sea level, it produces a contaminated air mixture; if the same amount of pollutant gas enters the atmosphere at a location situated at higher altitude, atmospheric pollution certainly also occurs. However, the relative compositions are not the same in both cases due to the greater air density present at sea level compared to the air density at higher altitude. Current regulatory frameworks, including the National Ambient Air Quality Standards (NAAQS) of the United States Environmental Protection Agency and the Air Quality Guidelines (AQG) of the World Health Organization, establish constant numerical values for air quality standards uniformly applicable at all geographic locations, regardless of altitude, resulting in inadequate health protection for millions of people. To address this critical gap, a universal adjustment factor for atmospheric pollutant gas concentrations at different altitudes has been derived from first principles of atmospheric physics; this factor is $f=e^{-0.000115 h}$, where h is expressed in meters, assuming air at constant temperature given that small temperature variations do not substantially influence atmospheric density and pressure or pollutant concentrations at different altitudes. The factor was systematically applied to the NAAQS and WHO AQG, demonstrating that for altitudes of 3500 m, representative of cities such as Cusco, Peru, the adjusted standards are approximately 67% of the nominal values established at sea level, preserving the gaseous pollutant–air proportionality. Experimental measurements of atmospheric density in six Peruvian cities distributed along an altitudinal gradient of 0–3826 m validated the theoretical model with relative deviations less than 5%, confirming the physical consistency of the derived factor. The importance of this research lies in adequately regulating air quality standards related to public health and the environment, supporting the implementation of equitable environmental policies aligned with the United Nations (UN) 2030 Sustainable Development Goals, and establishing that the constant values defined at sea level must be adjusted according to the aforementioned factor when geographic altitude is considered. Full article

The thermal processing of walnut shells was investigated through pyrolysis within the range of 100–650 °C, highlighting the influence of thermal engineering parameters on biomass conversion. The resulting biochar was subjected to chemical activation with phosphoric acid, and its physicochemical properties were evaluated to determine how thermal processing enhances its performance as a cathode material for lithium–sulfur (Li–S) batteries. This approach underscores the role of thermal engineering in bridging biomass valorization with energy storage technologies. In parallel, the gaseous fraction generated during walnut shell fast pyrolysis was collected, and for the first time, volatile organic compounds (VOCs) under atmospheric conditions were identified using solid-phase microextraction (SPME) coupled with gas chromatography–mass spectrometry (GC–MS). The composition of the VOCs was characterized, quantifying aromatic compounds, hydrocarbons, furans, and oxygenated species. This study further linked the thermal decomposition pathways of these compounds to their atmospheric implications by estimating tropospheric lifetimes and evaluating their potential contributions to air quality degradation at the local, regional, and global scales. Full article

Tropical cyclones (TCs) over the Arabian Sea pose significant threats to coastal populations and result in substantial economic losses, yet their variability in response to major climate modes remains insufficiently understood. This study examines the relationship between the El Niño–Southern Oscillation (ENSO), the Indian Ocean Dipole (IOD), and the Indo-Pacific Warm Pool (IPWP) with TC activity over the Arabian Sea from 1982 to 2021. Utilizing the India Meteorological Department (IMD)’s best-track data, reanalysis datasets, and composite analysis, we find that ENSO and IOD phases affect TC activity differently across seasons. The pre-monsoon season shows a limited association between TC activity and both ENSO and IOD, with minimal variation in frequency, intensity, and energy metrics. However, during the post-monsoon season, El Niño enhances TC intensity, resulting in a higher frequency of intense storms, leading to increased accumulated cyclone energy (ACE) and power dissipation index (PDI) in a statistically significant way. In contrast, La Niña favors the development of weaker TC systems and an increased frequency of depressions. While negative IOD (nIOD) phases tend to suppress TC formation, positive IOD (pIOD) phases are associated with increased TC activity, characterized by longer durations and higher ACE and PDI (statistically significant). Genesis sites shift with ENSO: El Niño favors genesis in the eastern Arabian Sea, causing westward or northeastward tracks, while La Niña shifts genesis toward the central-western basin, promoting northwestward movement. Composite analysis indicates that higher sea surface temperatures (SSTs), reduced vertical wind shear (VWS), increased mid-tropospheric humidity, and lower sea level pressure (SLP) during El Niño and pIOD phases create favorable conditions for TC intensification. In contrast, La Niña and nIOD phases are marked by drier mid-level atmospheres and less favorable SST patterns. The Indo-Pacific Warm Pool (IPWP), particularly its westernmost edge in the southeastern Arabian Sea, provides a favorable thermodynamic environment for genesis and exhibits a moderate positive correlation with TC activity. Nevertheless, its influence on interannual variability over the basin is less significant than that of dominant large-scale climate patterns like ENSO and IOD. These findings highlight the critical role of SST-related teleconnections (ENSO, IOD, and IPWP) in regulating Arabian Sea TC activity, offering valuable insights for seasonal forecasting and risk mitigation in vulnerable areas. Full article

Our study focuses on investigating the present-day influence of wildfires on the global atmosphere. To achieve this, we utilized four observational biomass burning (BB) emissions datasets for present-day simulations employing the TM5 Chemical Transport Model (CTM). To assess how different emissions estimates influence the model’s ability to simulate the atmosphere, we compared the following datasets over the period 2003–2015: GFED4s, GFASv1.2, FEERv1.0-G1.2 and QFEDv2.6r1. Our study aims to investigate the role of wildfires in affecting important trace gases and aerosols. Their impact on atmospheric composition and their interactions with solar radiation affect the radiative balance at the Earth’s surface and, consequently, temperature trends in the troposphere. Full article

Methane (CH₄), the second-largest global greenhouse gas and a key driver of tropospheric ozone formation, critically influences climate change and air quality. As the world’s largest CH₄ emitter, China must develop targeted mitigation strategies to support its carbon peak and neutrality goals while reducing ozone pollution. Here, we analyzed the spatiotemporal evolution of provincial CH₄ emissions in China from 2000 to 2023 using spatial autocorrelation, hotspot detection, trend analysis, and K-means clustering. Our results revealed a triphasic emission trajectory—rapid growth followed by stabilization and a recent resurgence—with all provinces except Tibet showing increasing trends. The energy sector emerged as the primary contributor, particularly in Inner Mongolia, Shanxi, and Shaanxi, whereas agricultural emissions dominated in pastoral regions, such as Inner Mongolia and Sichuan, and rice-growing areas, such as Hunan and Hubei. Coastal provinces, including Shandong, Jiangsu, and Guangdong, exhibited waste disposal as their predominant CH₄ source. Based on these patterns, we classified the emission zones into four distinct typologies: coal-dominant, waste-dominant, oil-agriculture composite, and multifactorial systems, proposing tailored mitigation frameworks that integrate CH₄ and ozone co-reduction. This study provides a spatially resolved foundation for synergistic climate and air quality governance in China. Full article

As a key precursor of tropospheric ozone and secondary particulate matter, nitrogen oxides (NO_x) exert significant impacts on air quality. Traffic emissions represent a dominant source of near-surface NO_x. The widespread adoption of new energy vehicles (NEVs) has progressively transformed the automobile fleet composition, leading to measurable reductions in NO_x emissions. This study developed a NO_x emission inventory model to quantify the impact of NEV penetration on emission trends in Guangdong (2013–2022), under the assumption that the emission shares of internal combustion engine vehicles (ICEVs) and NEVs have no significant change in adjacent years. Results demonstrate that total vehicular NO_x emissions peaked in 2019 at 55.69 × 10⁴ tons (a 16.6% increase from 2018), followed by a consistent decline. ICEVs exhibited a declining emission share from 0.037 × 10⁴ tons/year in 2013 to 0.022 × 10⁴ tons/year in 2019—a 40.5% reduction, attributable to progressive technological advancements. Following a marginal increase (2019–2021), the emission share declined significantly to 0.019 × 10⁴ tons/year in 2022. In contrast, NEVs contributed to emissions reduction, with maximal mitigation observed in 2021 (−0.241 × 10⁴ tons). ICEVs initially demonstrated emission reductions (2014–2017), succeeded by a transient increase (11.7 × 10⁴ tons through 2021) before resuming decline in 2022. The NEV-driven mitigation effect intensified progressively from 2018 to 2021, with modest attenuation in 2022. Full article

The formation and evolution of haze layers in planetary atmospheres play a critical role in shaping their chemical composition, radiative balance, and optical properties. In the outer solar system, the atmospheres of Titan and the giant planets exhibit a wide range of compositional and seasonal variability, creating environments favorable for the production of complex organic molecules under low-temperature conditions. Among them, Uranus—the smallest of the ice giants—has, since Voyager 2, emerged as a compelling target for future exploration due to unanswered questions regarding the composition and structure of its atmosphere, as well as its ring system and diverse icy moon population (which includes four possible ocean worlds). Titan, as the only moon to harbor a dense atmosphere, presents some of the most complex and unique organics found in the solar system. Central to the production of these organics are chemical processes driven by low-energy photons and electrons (<50 eV), which initiate reaction pathways leading to the formation of organic species and gas phase precursors to high-molecular-weight compounds, including aerosols. These aerosols, in turn, remain susceptible to further processing by low-energy UV radiation as they are transported from the upper atmosphere to the lower stratosphere and troposphere where condensation occurs. In this review, I aim to summarize the current understanding of low-energy (<50 eV) photon- and electron-induced chemistry, drawing on decades of insights from studies of Titan, with the objective of evaluating the relevance and extent of these processes on Uranus in anticipation of future observational and in situ exploration. Full article

To determine the long-term effect of Australian bushfires on the upper tropospheric composition in the South Pacific, we investigated the variation in CO and hydrocarbon species in the South Pacific according to the extent of Australian bushfires (2004–2020). We conducted analyses using satellite data on hydrocarbon and CO from the Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS), and on fire (fire count, burned area, and fire radiative power) from the Moderate Resolution Imaging Spectroradiometer (MODIS). Additionally, we compared the effects of bushfires between Northern and Southeastern Australia (N_Aus and SE_Aus, respectively). Our analyses show that Australian bushfires in austral spring (September to November) result in the largest increase in CO and hydrocarbon species in the South Pacific and even in the west of South America, indicating the trans-Pacific transport of smoke plumes. In addition to HCN (a well-known wildfire indicator), CO and other hydrocarbon species (C₂H₂, C₂H₆, CH₃OH, HCOOH) are also considerably increased by Australian bushfires. A unique finding in this study is that the hydrocarbon increase in the South Pacific mostly relates to the bushfires in N_Aus, implying that we need to be more vigilant of bushfires in N_Aus, although the severe Australian bushfire in 2019–2020 occurred in SE_Aus. Due to the surface conditions in springtime, bushfires on grassland in N_Aus during this time account for most Australian bushfires. All results show that satellite data enables us to assess the long-term effect of bushfires on the air composition over remote areas not having surface monitoring platforms. Full article

Methane (CH₄) is a potent greenhouse gas with a significant impact on short- and medium-term climate forcing, and its atmospheric concentration has been increasing rapidly in recent decades. This study aims to analyze spatio-temporal patterns of atmospheric methane concentrations between 2019 and 2025, focusing on comparisons between regions characterized by high and low emission intensities. Level-3 XCH₄ data from the TROPOspheric Monitoring Instrument (TROPOMI) onboard the Sentinel-5 Precursor satellite were used, which were aggregated into seasonal and annual composites. High-emission regions, such as the Mekong Delta, Nile Delta, Eastern Uttar Pradesh and Bihar, Central Thailand, Lake Victoria Basin, and Eastern Arkansas, were contrasted with low-emission areas including Patagonia, the Mongolian Steppe, Northern Scandinavia, the Australian Outback, the Sahara Desert, and the Canadian Shield. The results show that high-emission regions exhibit substantially higher seasonal amplitude in XCH₄ concentrations, with an average seasonal variation of approximately 30.00 ppb, compared to 17.39 ppb in low-emission regions. Methane concentrations generally peaked at the end of the year (Q4) and reached their lowest levels during the first half of the year (Q1 or Q2), particularly in agriculturally dominated regions. Principal component and cluster analyses further confirmed a strong spatial differentiation between high- and low-emission regions based on both temporal trends and seasonal behavior. These findings demonstrate the potential of satellite remote sensing to monitor regional methane dynamics and highlight the need for targeted mitigation strategies in major agricultural and wetland zones. Full article

The 2020 wildfire season in the Western U.S. was historic in its intensity and impact on the land and atmosphere. This study aims to characterize satellite retrievals of carbon monoxide (CO), a tracer of combustion and signature of those fires, from two key satellite instruments: the Cross-track Infrared Sounder (CrIS) and the Tropospheric Monitoring Instrument (TROPOMI). We evaluate them during this event and assess their synergies. These two retrievals are matched temporally, as the host satellites are in tandem orbit and spatially by aggregating TROPOMI to the CrIS resolution. Both instruments show that the Western U.S. displayed significantly higher daily average CO columns compared to the Central and Eastern U.S. during the wildfires. TROPOMI showed up to a factor of two larger daily averages than CrIS during the most intense fire period, likely due to differences in the vertical sensitivity of the two instruments and representative of near-surface CO abundance near the fires. On the other hand, there was excellent agreement between the instruments in downwind free tropospheric plumes (scatter plot slopes of 0.96–0.99), consistent with their vertical sensitivities and indicative of mostly lofted smoke. Temporally, TROPOMI CO column peaks were delayed relative to the Fire Radiative Power (FRP), and CrIS peaks were delayed with respect to TROPOMI, particularly during the intense initial weeks of September, suggesting boundary layer buildup and ventilation. Satellite retrievals were evaluated using ground-based CO column estimates from the Network for the Detection of Atmospheric Composition Change (NDACC) and the Total Carbon Column Observing Network (TCCON), showing Normalized Mean Errors (NMEs) for CrIS and TROPOMI below 32% and 24%, respectively, when compared to all stations studied. While Normalized Mean Bias (NMB) was typically low (absolute value below 15%), there were larger negative biases at Pasadena, likely associated with sharp spatial gradients due to topography and proximity to a large city, which is consistent with previous research. In situ CO profiles from AirCore showed an elevated smoke plume for 15 September 2020, highlighted consistency between TROPOMI and CrIS CO columns for lofted plumes. This study demonstrates that both CrIS and TROPOMI provide complementary information on CO distribution. CrIS’s sensitivity in the middle and lower free troposphere, coupled with TROPOMI’s effectiveness at capturing total columns, offers a more comprehensive view of CO distribution during the wildfires than either retrieval alone. By combining data from both satellites as a ratio, more detailed information about the vertical location of the plumes can potentially be extracted. This approach can enhance air quality models, improve vertical estimation accuracy, and establish a new method for assessing lower tropospheric CO concentrations during significant wildfire events. Full article

Based on a laboratorial analysis of nitrous oxide (N₂O) concentrations collected in gas bottles (glass flask) at the Zhongshan Station on the East Antarctic coast from 2008 to 2021, the variation characteristics and trends in the background concentration of N₂O at the station were analyzed and compared with the N₂O data from other Antarctic stations. The results showed that the annual average concentration of atmospheric N₂O along the East Antarctic coast increased from 320.40 ppb in 2008 to 333.31 ppb in 2021, with an overall increasing trend of 0.99 ppb per year. Pronounced seasonal variability was observed, with elevated concentrations occurring during austral spring–summer and reduced levels in autumn–winter, consistent with the seasonal patterns documented at other Antarctic sites. The overall variation trend of the N₂O concentration at Zhongshan Station is basically consistent with the observation results at other stations in Antarctica, suggesting that the station’s background N₂O measurements are representative of continental-scale atmospheric composition dynamics. Combined with the analysis of air mass tracks, this seasonal variation in N₂O is mainly related to the mass movement of air mass and, to a certain extent, is influenced by the seasonal melting of sea ice and the exchange between the troposphere and stratosphere. The results supplement important basic data on N₂O concentrations along the East Antarctic coast and have potential reference significance for further understanding the causes of atmospheric N₂O variations in the Antarctic region. Full article

Earth’s atmospheric methane (CH₄) concentration has risen more than 162% since pre-industrial levels in the mid-18th century, and about 30% of the rise in global temperatures since the pre-industrial era is due to CH₄ The build-up of methane in the atmosphere in 2020–2022 was the largest since systematic measurements started in 1983, more than double the average yearly growth rate measured over the previous 17 years (15.2 ppb yr⁻¹ vs. 5.71 ppb yr⁻¹, respectively). During 2020, with a growth rate of 14.81 ppb yr⁻¹, the level of atmospheric CH₄ broke the previous record (which was set in 1991), and it was broken again immediately the following year, with an increase of 17.64 ppb yr⁻¹ in 2021. For 2022, the final estimate is 13.25 ppb yr⁻¹, the fourth largest annual growth rate. The most recent explanations for this surge in tropospheric CH₄ include increased emissions from tropical wetlands, more floods, and increased temperatures. For 2020 and part of 2021, a reduction in the oxidative capacity of the atmosphere due to COVID-19 lockdowns was also proposed. Our main hypothesis is that this CH₄ surge in 2020–2021 may also be caused by reduced sulfate emissions, which have been shown to decrease methanotrophy and increase methanogenesis rates in wetlands. Then, for the CH₄ slowdown in 2022–2024, our hypotheses are that the emissions from wetlands remained high, but that there was an even higher increase in the oxidative capacity of the atmosphere due to multiple other parameters that are detailed in this article. This perspective review paper is mainly qualitative; it demonstrates that coupled climate–chemistry models will also need to integrate biochemistry, as the evolution of the atmospheric composition is multifactorial and non-linear. Full article

In contemporary times, wastewater treatment plants (WWTPs) were recognized as substantial sources of odorous emissions, potentially impacting nearby communities’ sensory experience. This study investigates the half-lives (T½) of odorous compounds emitted from WWTPs and their degradation due to atmospheric hydroxyl radicals (•OH) in different environmental settings. The calculated half-lives of specific odorants in rural areas ranged from 31.36 min to 517.33 days, in urban areas from 42.50 min to 1550 days, and in the marine boundary layer from 42.50 min to 129,861 days. These results show that compounds with high reactivity and short T½, such as methanethiol and ethanethiol, degrade rapidly and are less likely to contribute to long-term odor nuisances. In contrast, compounds with longer half-lives, such as carbonyl sulfide and ammonia, persist longer in the atmosphere, with higher potential for sustained odor issues. The findings suggest that •OH plays a significant role in degrading odorous compounds. These insights into odorant–oxidant kinetics may aid in predicting atmospheric half-lives and their contribution to secondary aerosol formation, thus informing regulatory and mitigation strategies to improve air quality. Full article

The UV–Visible Working Group of the Network for the Detection of Atmospheric Composition Changes (NDACC) focuses on the monitoring of air-quality-related stratospheric and tropospheric trace gases in support of trend analysis, satellite validation and model studies. Tropospheric measurements are based on MAX-DOAS-type instruments that progressively emerged in the years 2010 onward. In the interest of improving the overall consistency of the NDACC MAX-DOAS network and facilitating its further extension to the benefit of satellite validation, the ESA initiated, in late 2016, the FRM4DOAS project, which aimed to set up the first centralised data processing system for MAX-DOAS-type instruments. Developed by a consortium of European scientists with proven expertise in measurements, data extraction algorithms and software design specialities, the system has now reached pre-operational status and has demonstrated its ability to deliver a set of quality-controlled atmospheric composition data products with a latency of one day. The processing system has been designed using a highly modular approach, making it easy to integrate new tools or processing updates. It incorporates advanced algorithms selected by community consensus for the retrieval of total ozone, lower tropospheric and stratospheric NO₂ vertical profiles and formaldehyde profiles. The ozone and NO₂ products are currently generated from a total of 22 stations and delivered daily to the NDACC rapid delivery (RD) repository, with an additional mirroring to the ESA Validation Data Centre (EVDC). Although it is still operated in a pre-operational/demonstrational mode, FRM4DOAS was already used for several validation and science studies, and it was also deployed in support of field campaigns for the validation of the TROPOMI and GEMS satellite missions. It recently went through a CEOS-FRM self-assessment process aiming at assessing the level of maturity of the service in terms of instrumentation, operations, data sampling, metrology and verification. Based on this evaluation, it falls under class C, which is a good rating but also implies that further improvements are needed to reach full compliance with FRM standards, i.e., class A. Full article

The Constellation Observing System for Meteorology, Ionosphere, and Climate 2 (COSMIC-2) collects data covering latitudes primarily between 40 degrees north and south, providing abundant data for tropical cyclone (TC) research. The radio occultation data provide valuable information on the boundary layer. However, quality control of the data within the boundary layer remains a challenging issue. The aim of this study is to obtain a more accurate COSMIC-2 radio occultation (RO) dataset through quality control (QC) and use this dataset to validate warm core structures and explore the planetary boundary layer (PBL) structures of TCs. In this study, COSMIC-2 data are used to analyze the distribution of the relative local spectral width (LSW) and the confidence parameter characterizing the random error of the bending angle. An LSW less than 20% is set as a data QC threshold, and the warm core and PBL composite structures of TCs at three intensities in the Northwest Pacific Ocean are investigated. We reproduce the warm core intensity and warm core height characteristics of TCs. In the radial direction of the typhoon eyewall, the impact height of the PBL increases from 3.45 km to 4 km, with the tropopause ranging from 160 hPa to 100 hPa. At the bottom of the troposphere, the variations in the positive and negative bias between the RO-detected and background field bending angles correspond well to the PBL heights, and the variations in the positive bias between the RO-detected and background field refractivity reach 14%. This research provides an effective QC method and reveals that the bending angle is sensitive to the PBL height. Full article