Search Results (64)

Fluorite, a key accessory mineral associated with rare earth element (REE) deposits, exerts a significant influence on REE migration and precipitation through complexation, adsorption, and lattice substitution within fluorine-bearing fluid systems. It therefore provides a valuable archive for constraining REE enrichment processes. The Weishan alkaline–carbonatite-related REE deposit, the third-largest LREE deposit in China, is formed through a multistage magmatic–hydrothermal evolution of the carbonatite system. However, limited mineralogical constraints on REE enrichment and precipitation have hindered a comprehensive understanding of its metallogenic processes and exploration potential. Here, cathodoluminescence imaging and LA-ICP-MS trace element analyses were conducted on fluorite of multiple generations from the Weishan deposit to constrain the physicochemical conditions of mobility and precipitation mechanisms of this REE deposit. Four generations of fluorite are recognized, recording progressive evolution of the ore-forming fluids. Type I fluorite, which coexists with bastnäsite and calcite, is LREE-enriched and exhibits negative Eu anomalies, indicating precipitation from high-temperature, weakly acidic, and reducing fluids. Type II fluorite occurs as overgrowths on Type I, while Type III fluorite replaces Type II fluorite, with both displaying LREE depletion and MREE-Y enrichment, consistent with cooling during continued hydrothermal evolution. Type IV fluorite, which is interstitial between calcite grains and associated with mica, is formed under low-temperature, oxidizing conditions, reflecting REE exhaustion and the terminal stage of fluorite precipitation. Systematic shifts in REE patterns among the four generations track progressive cooling of the system. The decreasing trend in La/Ho and Tb/La further suggests that these fluorites record dissolution–reprecipitation events and associated element remobilization during fluid evolution. Full article

Thorium-rare earth-iron oxide deposits of the Lemhi Pass district, Idaho and Montana, are enriched in the middle rare earth elements (REE), and particularly neodymium (Nd). Overall, thorium (Th) and total rare earth oxide (TREO) grades of the deposits are sub equal at 0.4 wt. % but locally exceed 1 wt. % TREO. Nd-monazite, the major REE phase (35 wt. % Nd₂O₃) occurs in hydrothermal Th-REE mineralized quartz veins and biotite-rich shear zones of enigmatic origin. Hosted in Mesoproterozoic metasedimentary rocks, the deposits are modest in size but present over a large area with no obvious source pluton exposed. This paper documents the geochemistry of the monazite and provides the first geochronological data to constrain its origin. Elemental mapping and U-Th-total Pb EPMA dating of the monazite and thorite document a Paleozoic age for mineralization centered in the Late Devonian at approximately 355 Ma ± 20 Ma. A second period of volumetrically minor Th and REE remobilization is dated as Mesozoic (ca. 100 Ma). For context, a reactivated passive continental margin was present during the Devonian in eastern Idaho, while the Mesozoic was a time of major accretionary tectonics and arc magmatism further west. Nd and Pb isotopic data require a significant interaction of the fluids with an ancient crustal component represented by regional Mesoproterozoic metasedimentary rocks and granitoids. A source–transport–deposition model is hypothesized with metasomatic fractionation and enrichment of Nd during regional hydrothermal circulation. The aqueous fluids were hot, oxidizing, and likely saline, but the exact source of the Th and REEs and the mechanism of enrichment remains problematic. Additional analytical work and increased knowledge of the regional and district geology will improve this unconventional hypothesis for formation of Lemhi Pass’ unusual Nd-rich Th-REE-Fe mineralization. Full article

Rare earth elements (REEs) and trace elements, due to their relative stability during sedimentary processes, are effective geochemical proxies for sediment provenance. In the Dongdaohaizi Depression of the eastern Junggar Basin, the provenance of the Middle Jurassic Sangonghe Formation remains contentious. In this study, representative sandstone samples were systematically collected from all three members of the Sangonghe Formation in both the Dongdaohaizi Depression and its western margin. Through comprehensive petrographic and geochemical analyses, we obtained the following results. The Sangonghe Formation is primarily composed of feldspathic lithic sandstones, lithic sandstones, and minor lithic–feldspathic sandstones. The heavy mineral assemblage includes zircon, garnet, chromite, and rutile, suggesting source rocks of intermediate to acidic igneous, metamorphic, and mafic lithologies. The total REE contents range from 101.84 to 192.68 μg/g, with an average of 161.80 μg/g. The ∑LREE/∑HREE ratios vary from 6.59 to 13.25 (average 10.96), and the average δEu values are close to 1. The δCe value ranges from 1.09 to 1.13 (average 1.11). Trace element discrimination diagrams, including La-Th-Sc, Th-Co-Zr/10, Th-Sc-Zr/10, and La/Y-Sc/Cr ternary plots, indicate that most samples fall within the continental island arc domain, with a few plotting in the passive continental margin field. Comparison with potential surrounding source regions reveals dual provenances: an eastern source from the Kalamaili Mountains and a western source from the Zhayier Mountains. During the Early Jurassic, these two orogenic belts acted as distinct sediment sources. The Zhayier Mountains provided stronger input, with fluvial and tidal processes transporting sediments into the basin, establishing the primary subsidence center in the west of the depression. By the Middle Jurassic, continued thrusting of surrounding fold belts caused a migration of the lake center and the main depocenter to the western edge of the Dongdaohaizi Depression, while the former depocenter gradually diminished. Furthermore, sustained erosion and denudation of the Mosowan Uplift during the Early–Middle Jurassic reduced its function as a structural barrier, thereby promoting increased mixing between eastern and western sediment sources. The study not only refines existing paleogeographic models of the Junggar Basin, but also demonstrates the utility of REE–trace geochemistry in deciphering complex provenance systems in tectonically active basins. Full article

Membrane transporters are vital for solute movement and localisation across cellular compartments, particularly in extremophilic organisms such as Galdieriales. These red algae thrive in geothermal and metal-rich environments, where adaptive transporter systems contribute to their metabolic flexibility. While inventories of transporter genes in the species Galdieria sulphuraria have previously been compiled, their phylogenetic origins remain incompletely resolved. Here, we conduct a comparative phylogenetic analysis of three transporter families—Major Facilitator Superfamily (MFS). Amino acid–Polyamine–Organocation (APC) and the natural resistance–associated macrophage protein (Nramp)—selected from overexpressed transcripts in G. sulphuraria strain SAG 107.79. Using sequences from six Galdieriales species and orthologs from diverse taxa, we reconstructed maximum likelihood trees to assess conservation and potential horizontal gene transfer (HGT). The MFS subfamilies revealed contrasting patterns: sugar porters (SPs) exhibited polyphyly and fungal affinity, suggesting multiple HGT events, while phosphate:H⁺ symporters (PHSs) formed a coherent monophyletic group. APC sequences were exclusive in G. sulphuraria and extremophilic prokaryotes, indicating a likely prokaryotic origin. In contrast, Nramp transporters were broadly conserved across eukaryotes and prokaryotes, showing no signs of recent HGT. Together, these findings highlight the mosaic evolutionary history of membrane transporters in Galdieriales, shaped by a combination of vertical inheritance and taxon-specific gene acquisition events, and provide new insight into the genomic strategies underpinning environmental resilience in red algae. Full article

The current work records for the first time the rare-metal pegmatites with mixed NYF-LCT located at Wadi Sikait, south Eastern Desert of the Egyptian Nubian Shield. Most of the Sikait pegmatites are associated with sheared granite and are surrounded by an alteration zone cross-cutting through greisen bodies. Sikait pegmatites show zoned and complex types, where the outer wall zones are highly mineralized (Nb, Ta, Y, Th, Hf, REE, U) than the barren cores. They consist essentially of K-feldspar, quartz, micas (muscovite, lepidolite, and zinnwaldite), and less albite. They contain a wide range of accessory minerals, including garnet, columbite, fergusonite-(Y), cassiterite, allanite, monazite, bastnaesite (Y, Ce, Nd), thorite, zircon, beryl, topaz, apatite, and Fe-Ti oxides. In the present work, the discovery of Li-bearing minerals for the first time in the Wadi Sikait pegmatite is highly significant. Sikait pegmatites are highly mineralized and yield higher maximum concentrations of several metals than the associated sheared granite. They are strongly enriched in Li (900–1791 ppm), Nb (1181–1771 ppm), Ta (138–191 ppm), Y (626–998 ppm), Hf (201–303 ppm), Th (413–685 ppm), Zr (2592–4429 ppm), U (224–699 ppm), and ∑REE (830–1711 ppm). The pegmatites and associated sheared granite represent highly differentiated peraluminous rocks that are typical of post-collisional rare-metal bearing granites. They show parallel chondrite-normalized REE patterns, enriched in HREE relative to LREE [(La/Lu)_n = 0.04–0.12] and strongly negative Eu anomalies [(Eu/Eu*) = 0.03–0.10]. The REE patterns show an M-type tetrad effect, usually observed in granites that are strongly differentiated and ascribed to hydrothermal fluid exchange. The pegmatite has mineralogical and geochemical characteristics of the mixed NYF-LCT family and shows non-CHARAC behavior due to a hydrothermal effect. Late-stage metasomatism processes caused redistribution, concentrated on the primary rare metals, and drove the development of greisen and quartz veins along the fracture systems. The genetic relationship between the Sikait pegmatite and the surrounding sheared granite was demonstrated by the similarities in their geochemical properties. The source magmas were mostly derived from the juvenile continental crust of the Nubian Shield through partial melting and subsequently subjected to a high fractional crystallization degree. During the late hydrothermal stage, the exsolution of F-rich fluids transported some elements and locally increased their concentrations to the economic grades. The investigated pegmatite and sheared granite should be considered as a potential resource to warrant exploration for REEs and other rare metals. Full article

As emerging contaminants, rare earth elements (REEs) have undergone significant anthropogenic enrichment in aquatic systems. This study investigates the REE concentrations, major metal elements, and grain size in surface sediments from the East Tiaoxi (ETX) River in eastern China, a small urban river subjected to substantial anthropogenic influences. Total REE concentrations of surface sediments ranged from 133.62 to 222.92 mg/kg with MREE enrichment and HREE depletion. REE concentration and fractionation were strongly correlated with Ca, Fe, Mg, and Mn, which may reflect the control of clay minerals, Fe-Mn oxides, and specific heavy minerals, and differences in REE behavior between riparian sediments and riverbed sediments highlighted the impact of hydrodynamic sorting and chemical weathering on REE distribution. Anthropogenic activities, particularly urbanization, were found to increase REE concentrations, especially at urban-adjacent sites (e.g., RBS2 and RS2), while natural processes such as soil transport and chemical weathering primarily contributed to REE variation at other sites. The enrichment factor and ecological risk assessment revealed that the enrichment and moderate risks associated with REEs occurred in river sediments adjacent to urbanized areas, though agricultural impacts were less pronounced. The findings emphasize the combined influence of urbanization and natural processes on REE distribution and ecological risks in the ETX River basin and underscore the need to prioritize urban-derived REE contamination in environmental management strategies. Full article

Rare earth elements (REEs) are increasingly present in the environment owing to their extensive use in modern industries, yet their interactions with plants remain poorly understood. This review explores the soil–plant continuum of REEs, focusing on their geochemical behavior in soil, the mechanisms of plant uptake, and fractionation processes. While REEs are not essential for plant metabolism, they interact with plant structures and interfere with the normal functioning of biological macromolecules. Accordingly, the influence of REEs on the fundamental physiological functions of plants is reviewed, including calcium-mediated signalling and plant morphogenesis. Special attention is paid to the interaction of REEs with photosynthetic machinery and, particularly, the thylakoid membrane. By examining both the beneficial effects at low concentrations and toxicity at higher levels, this review provides some mechanistic insights into the hormetic action of REEs. It is recommended that future research should address knowledge gaps related to the bioavailability of REEs to plants, as well as the short- and long-range transport mechanisms responsible for REE fractionation. A better understanding of REE–plant interactions will be critical in regard to assessing their ecological impact and the potential risks in terms of agricultural and natural ecosystems, to ensure that the benefits of using REEs are not at the expense of environmental integrity or human health. Full article

The Maoniuping Rare Earth Elements (REE) deposit, the second largest light REE deposit in the world, has been mined for decades, with serious impacts on the surrounding environment. However, the impact of mining on heavy metals in the downstream area (Nanhe River Basin) has not been systematically documented. To address this issue, this study explored the extent, transport, and accumulation of heavy metal contamination in the Nanhe River Basin through field surveys (2946 topsoil samples and four vertical soil sections) and regional geographic attributes (e.g., mining area, river, and elevation) combined with a variety of methods such as statistics, geostatistics, spatial analysis, geo-accumulation index, and potential ecological risk index. The results showed that soils in the Nanhe River Basin presented different degrees of heavy metal pollution, with Pb and Cd being the most abundant, and the soils as a whole showed moderate-heavy ecological risks. The spatial distribution and correlation of heavy metals exhibited similar distribution patterns and sources. Further analyses revealed that mining of REE in Maoniuping was the main source of heavy metal pollution in the Nanhe River Basin, with heavy metals entering the soil through runoffs. At the same time, mining activities led to the migration of heavy metals in different directions in the Nanhe watershed, i.e., about 1.3 km horizontally, 16 km longitudinally, and more than 1 m vertically. In addition, about 38.1 km² of the watershed is contaminated by mine wastes, which is 6.6 times the size of the mining area. In order to mitigate the threat of heavy metals, the local government has implemented water diversion projects and crop conversion in the Nanhe River Basin. This study provides a reference for research on the environmental problems caused by the exploitation of REE mines and other mineral resources. Full article

The depositional environments, weathering and provenance, organic matter enrichment, and preservation in the Gondwana and post-Gondwana units of the Lesser Himalayas, Nepal, are studied through geochemical and mineralogical analyses using petrography, X-ray diffraction, XRF, and ICP-MS. Mineralogical findings indicate that shales comprise 55% to 72% clay, 25% to 55% quartz, and less than 10% carbonate minerals, with a significant presence of illite, suggesting a transition from fluvial to shallow marine environments during post-Gondwana deposition. The thin sections of the post-Gondwana sandstone reveal an increase in quartz, feldspar, and plagioclase content, with rounded to sub-angular quartz grains indicating moderate transportation before lithification, resulting from the Indo-Asian collision. Geochemical data, including major, trace, and rare earth elements (REE), along with bivariate discrimination diagrams, reveal distinct environmental changes; Gondwana sediments exhibit oxic, arid conditions with continental provenance, while post-Gondwana deposits indicate humid environments favorable for organic matter enrichment, primarily sourced from felsic-intermediate igneous rocks. The TOC is less than 1 wt.% in the Gondwana and is 0.75 to 2 wt.% in the post-Gondwana shale, indicating better organic matter preservation. The existing geological structural data and the research findings highlight the pivotal role of Himalayan tectonism in enhancing the thermal maturity and hydrocarbon generation potential of organic-rich post-Gondwana shales, attributed to their substantial organic matter content. Full article

In the Campania region (Southern Italy), in the Matese Mts. (Albian to Turonian/Coniacian) and Caserta district (Albian to Cenomanian), two karst bauxite deposits outcrop, consisting of flat lenses over shallow karst carbonate. Although the mineralogy and geochemistry of Campania bauxite deposits have been widely studied in recent years, new major and trace elements relationships were provided to highlight paleoclimatic and paleoenvironmental conditions that occurred during their formation. The purpose of this research is to provide for the first time information on the paleoclimatic and paleoenvironmental conditions that affected the bauxites of Campania. These deposits formed during different periods since the Matese deposit formed during intense weathering processes with more abundant precipitation while the Caserta district deposit experienced a more long-lasting exposure event. During the formation of the studied bauxites, the drier conditions favored the replacement of kaolinite by boehmite. R-mode factor analysis showed geochemical affinity among Al₂O₃, TiO_2, and Nb. REEs minerals are mainly associated with the bauxite matrix while Zr, Hf, and V were mainly concentrated in detrital minerals during the later stages of bauxitization. Parental affinity indices (Eu/Eu* vs. Sm/Nd; Eu/Eu* vs. TiO₂/Al₂O₃) assessed the origin of the protolith of the Campania bauxites by rejecting the hypothesis of the dissolution of the bedrock carbonate. The results confirmed the eolian transport of parental material with an Upper Continental Crust and an intermediate to mafic magmatic composition. Full article

A groundbreaking remote sensing approach that uses three Bastnäsite Indices (BI) to detect rare earth elements (REEs) was initially developed using ore samples from the Sulfide Queen mine in California and later applied to various well-studied ground-based, drone-based, airborne, and spaceborne imaging spectrometers across a wide range of scales, from micrometers to tens of meters. In this work, those same innovative techniques have revealed the existence of a potential site for extracting REEs. Data from AVIRIS-NG, AVIRIS-Classic, HISUI, DESIS, EnMAP, EO-1 Hyperion, PRISMA, and EMIT were utilized to map Ivanpah Dry Lake, which is located fourteen kilometers northeast of the Sulfide Queen mine. Although this area was not previously associated with REE deposits, BI maps have indicated the presence of a site that has remained enriched in REEs for decades, suggesting an opportunity for further exploration and mining. Historically, a pipeline transported wastewater from facilities at the Sulfide Queen mine to evaporation ponds on or near Ivanpah Dry Lake, where wastewater may have contained concentrated REEs. This research highlights imaging spectroscopy not only as a valuable tool for rapidly identifying and efficiently extracting REEs, but also as a means of recovering REEs from supposed waste. Full article

The transportation sector is experiencing a profound shift, driven by the urgent need to reduce greenhouse gas (GHG) emissions from internal combustion engine vehicles (ICEVs). As electric vehicle (EV) adoption accelerates, the sustainability of the materials used in their production, particularly in electric motors, is becoming a critical focus. This paper examines the sustainability of both traditional and emerging materials used in EV traction motors, with an emphasis on permanent magnet synchronous motors (PMSMs), which remain the dominant technology in the industry. Key challenges include the environmental and supply-chain concerns associated with rare earth elements (REEs) used in permanent magnets, as well as the sustainability of copper windings. Automakers are exploring alternatives such as REE-free permanent magnets, soft magnetic composites (SMCs) for reduced losses in the core, and carbon nanotube (CNT) windings for superior electrical, thermal, and mechanical properties. The topic of materials for EV traction motors is discussed in the literature; however, the focus on environmental, social, and economic sustainability is often lacking. This paper fills the gap by connecting the technological aspects with sustainability considerations, offering insights into the future configuration of EV motors. Full article

Sediment transport to the sea by rivers is crucial for the stability of estuaries and coasts. The Yangtze River, the largest river in China, like many large rivers worldwide, is experiencing a decrease in sediment load reaching the coast. However, the tidal flat around Qidong Cape, located at the entrance of the North Branch of the Yangtze Estuary, is undergoing extensive siltation. The source of this sediment is unclear. In this study, a sediment core was collected and the geochemical characteristics of rare earth elements (REE) were analyzed using inductively coupled plasma mass spectrometry (ICP-MS). The results indicate the following: (1) The average content of REE is 178.57 μg/g, and the average ratio between LREE and HREE is 8.66, which is comparable to sediments from the South Yellow Sea. The chondrite-normalized and UCC-normalized patterns resemble those of the Yangtze River and the South Yellow Sea, indicating a negative gradient, a weak Ce-negative anomaly, and a distinct Eu-negative anomaly. (2) The continental shelf deposits in eastern China are primarily derived from sediment flux delivered by rivers. The sediments in the South Yellow Sea mainly originate from the Yangtze River and the Yellow River, exhibiting characteristics of a mixed source due to long-term geological processes, namely geochemical processes. The REEs in the tidal flat around Qidong Cape inherit the source area’s characteristics and originate from the weathering of upper continental rock in mainland China. Moreover, the tidal flat around Qidong Cape is influenced by both runoff and tidal actions, leading to strong land–sea interactions and reducing the environment, explaining the Eu-negative anomaly. (3) Hydrodynamic forces in the North Branch of the Yangtze River have shifted from runoff to tidal dominance since the 1930s. However, marine hydrodynamics outside the estuary have remained unchanged. Consequently, the Subei coastal current plays a key role in sediment transport and diffusion. Sediments from the south wing of the Radiative Sand Ridge in the South Yellow Sea are transported southward by the Subei coastal current, and under tidal influence, suspended sediment is deposited in the tidal flat around Qidong Cape. Therefore, the sediment source has gradually shifted from the Yangtze River to the South Yellow Sea. Full article

The unique electromagnetic properties of rare earth elements (REEs) have led to rapid technological advances, creating a sharp increase in demand for these materials. The inherent challenges of separating REEs and the significant drawbacks of existing processes have driven the development of a new method known as field-effect separation (FES). This technology leverages electrical and magnetic fields to achieve separation by exploiting the differences in magnetic moments or effective charges of REEs in solution. Experiments on REEs were conducted using a microchannel based separation device, which confines fluid flow to facilitate separation within a field, with metal cations in solution being transported based on their respective electrostatic or magnetic properties. The results demonstrate that separation based on effective charge or paramagnetic properties is achievable. The confinement of fluid flow to microchannels allowed advective and osmotic forces to be suppressed sufficiently such that a reasonable separation of ions was achieved, though the impact of these forces were not completely removed. This innovative approach promises to improve the efficiency and effectiveness of REE separation, addressing both the growing demand and the limitations of current methods. Full article

The Xifanping deposit is a distinct Cenozoic porphyry Cu (Au) deposit located in the Sanjing porphyry metallogenic belt 100–150 km east of the JinshajFiang fault in the western Yangtze craton. We present new zircon U–Pb–Lu–Hf isotopic studies and geochemical data of the ore-bearing quartz monzonite porphyry from the Xifanping deposit to determine their petrogenesis and geodynamic mechanisms. LA–ICP–MS zircon U–Pb dating yielded precise emplacement ages of 31.87 ± 0.41 Ma (MSWD = 0.86) and 32.24 ± 0.61 Ma (MSWD = 1.8) for quartz monzonite porphyry intrusions, and 254.9 ± 5.1 Ma (MSWD = 1.7) for inherited zircons of the monzonite porphyry. The ore-bearing monzonite porphyry is characterized by high-K calc–alkaline to shoshonite and peraluminous series, relatively enriched in light over heavy REEs, with no distinct Eu anomalies, as well as enrichment in LILEs and depletion of HFSEs, with adakitic affinities. The zircon Lu–Hf isotope data ranged from εHf(t) values of −2.94 to +3.68 (average −0.47) with crustal model (T_DM2) ages ranging from 0.88 to 1.30 Ga, whereas the inherited zircons displayed positive εHf(t) values ranging from +1.83 to +7.98 (average +5.82), with crustal model (T_DM2) ages ranging from 0.77 to 1.17 Ga. Results suggest that the Xifanping porphyry Cu (Au) deposit is related to two periods of magmatic activities. Early magmas were generated from the Paleo-Tethys oceanic subduction during the Late Permian. The subsequent porphyry magma was likely formed by the remelting of previously subduction-modified arc lithosphere, triggered by the continental collision between the Indian and Asian plates in the Cenozoic. The deep magmas and late hydrothermal fluids took advantage of the early magma transport channels along tectonically weak zones during the transition from an extrusive to an extensional–tensional tectonic environment. Early dikes from remelted and assimilated crust contributed to the two age ranges observed in the porphyry intrusions from the Xifanping deposit. The juvenile lower crust materials of the early magmatic arc were potential sources of the Cenozoic porphyry magmas, which has significant implications for mineral exploration and the geological understanding of porphyry Cu deposits in this region. Full article