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28 pages, 4848 KiB  
Article
Mineralogical and Geochemical Features of Soil Developed on Rhyolites in the Dry Tropical Area of Cameroon
by Aubin Nzeugang Nzeukou, Désiré Tsozué, Estelle Lionelle Tamto Mamdem, Merlin Gountié Dedzo and Nathalie Fagel
Standards 2025, 5(3), 20; https://doi.org/10.3390/standards5030020 (registering DOI) - 6 Aug 2025
Abstract
Petrological knowledge on weathering processes controlling the mobility of chemical elements is still limited in the dry tropical zone of Cameroon. This study aims to investigate the mobility of major and trace elements during rhyolite weathering and soil formation in Mobono by understanding [...] Read more.
Petrological knowledge on weathering processes controlling the mobility of chemical elements is still limited in the dry tropical zone of Cameroon. This study aims to investigate the mobility of major and trace elements during rhyolite weathering and soil formation in Mobono by understanding the mineralogical and elemental vertical variation. The studied soil was classified as Cambisols containing mainly quartz, K-feldspar, plagioclase, smectite, kaolinite, illite, calcite, lepidocrocite, goethite, sepiolite, and interstratified clay minerals. pH values ranging between 6.11 and 8.77 indicated that hydrolysis, superimposed on oxidation and carbonation, is the main process responsible for the formation of secondary minerals, leading to the formation of iron oxides and calcite. The bedrock was mainly constituted of SiO2, Al2O3, Na2O, Fe2O3, Ba, Zr, Sr, Y, Ga, and Rb. Ce and Eu anomalies, and chondrite-normalized La/Yb ratios were 0.98, 0.67, and 2.86, respectively. SiO2, Al2O3, Fe2O3, Na2O, and K2O were major elements in soil horizons. Trace elements revealed high levels of Ba (385 to 1320 mg kg−1), Zr (158 to 429 mg kg−1), Zn (61 to 151 mg kg−1), Sr (62 to 243 mg kg−1), Y (55 to 81 mg kg−1), Rb (1102 to 58 mg kg−1), and Ga (17.70 to 35 mg kg−1). LREEs were more abundant than HREEs, with LREE/HREE ratio ranging between 2.60 and 6.24. Ce and Eu anomalies ranged from 1.08 to 1.21 and 0.58 to 1.24 respectively. The rhyolite-normalized La/Yb ratios varied between 0.56 and 0.96. Mass balance revealed the depletion of Si, Ca, Na, Mn, Sr, Ta, W, U, La, Ce, Pr, Nd, Sm, Gd and Lu, and the accumulation of Al, Fe, K, Mg, P, Sc, V, Co, Ni, Cu, Zn, Ga, Ge, Rb, Y, Zr, Nb, Cs, Ba, Hf, Pb, Th, Eu, Tb, Dy, Ho, Er, Tm and Yb during weathering along the soil profile. Full article
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16 pages, 540 KiB  
Article
Comparison of Dietary Inorganic and Small-Peptide Chelating Trace Minerals on Growth Performance, Immunity, Meat Quality, and Environmental Release in Litopenaeus vannamei
by Jingshen Chen, Nan Liu, Shumeng Wang, Hailong Wang, Kun Ouyang, Yuxuan Wang, Junyi Luo, Jiajie Sun, Qianyun Xi, Yuping Sun, Yongguo Si, Yongliang Zhang and Ting Chen
Animals 2025, 15(15), 2297; https://doi.org/10.3390/ani15152297 - 6 Aug 2025
Abstract
The present study evaluated the effect of adding 0% (control), 30%, 40% and 50% SPMs (small-peptide chelating trace minerals) to replace ITMs (inorganic trace minerals) in the diets of Litopenaeus vannamei; 720 shrimp were randomly assigned to four treatments (six replicates per [...] Read more.
The present study evaluated the effect of adding 0% (control), 30%, 40% and 50% SPMs (small-peptide chelating trace minerals) to replace ITMs (inorganic trace minerals) in the diets of Litopenaeus vannamei; 720 shrimp were randomly assigned to four treatments (six replicates per group, 30 shrimp per replicate) in a 42-day feeding trial. There were no significant differences (p > 0.05) among the control, 40% SPM and 50% SPM groups in terms of the survival rate, weight gain rate, specific growth rate, hepatosomatic index, condition factor, feed intake, feed conversion ratio, or protein efficiency ratio; however, protein efficiency ratio was reduced in the 30% SPM group (p < 0.05). Glucose, triglyceride, and aspartate aminotransferase levels in the hemolymph of the 30% SPM group were significantly increased (p < 0.05), while the glucose and aspartate aminotransferase levels were also significantly increased in the 40% SPM group (p < 0.05). In the 50% SPM group, the glucose and triglyceride levels were also significantly increased (p < 0.05). Hepatopancreatic alkaline phosphatase activity was elevated at 40% SPM, and alkaline phosphatase, acid phosphatase, glutathione peroxidase, and total antioxidant capacity activities were significantly increased in the 50% SPM group (p < 0.05). The moisture content and drip loss were reduced in both the 40% and 50% SPM groups (p < 0.05). Therefore, replacing 40–50% ITMs with SPMs can maintain growth performance while enhancing physiological functions. In conclusion, the results of this study demonstrate that the incorporation of 30–50% SPMs into one’s diet constitutes a viable alternative to 100% ITMs. Full article
(This article belongs to the Section Aquatic Animals)
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11 pages, 225 KiB  
Article
Influence of Trace Mineral Sources and Levels on Growth Performance, Carcass Traits, Bone Characteristics, Oxidative Stress, and Immunity of Broiler
by Tassanee Trairatapiwan, Rachakris Lertpatarakomol, Sucheera Chotikatum, Achara Lukkananukool and Jamlong Mitchaothai
Animals 2025, 15(15), 2287; https://doi.org/10.3390/ani15152287 - 5 Aug 2025
Abstract
This study investigated the effects of reducing organic trace minerals below commercial inclusion levels and compared them with both low-dose and commercial levels of inorganic trace minerals, focusing on growth performance, carcass traits, tibia characteristics, oxidative stress (superoxide dismutase [SOD] and malondialdehyde [MDA]), [...] Read more.
This study investigated the effects of reducing organic trace minerals below commercial inclusion levels and compared them with both low-dose and commercial levels of inorganic trace minerals, focusing on growth performance, carcass traits, tibia characteristics, oxidative stress (superoxide dismutase [SOD] and malondialdehyde [MDA]), and immune response (serum IgG) in broilers. A total of 384 one-day-old Ross 308 chicks were randomly assigned to three dietary treatments: (1) commercial-level inorganic trace minerals (ILI; Zn 100 ppm; Cu 15 ppm; Fe 100 ppm; Mn 80 ppm; Se 0.2 ppm; I 3 ppm); (2) low-level organic trace minerals (LLO; Zn 30 ppm; Cu 4 ppm; Fe 11 ppm; Mn 30 ppm; Se 0.225 ppm; I 3 ppm), and (3) low-level inorganic trace minerals (LLI; Zn 30 ppm; Cu 4 ppm; Fe 11 ppm; Mn 30 ppm; Se 0.2 ppm; I 3 ppm). Each treatment consisted of eight replicates with 16 birds per replicate, and diets were provided in two phases: starter (days 1–21) and grower (days 22–35). The results showed that the LLO group demonstrated a significantly improved feed conversion ratio (FCR) during the starter phase, 2.4% better than that of the ILI and LLI groups (p = 0.02). Additionally, filet and thigh muscle yields in the LLO group were higher by 11.9% (p = 0.03) and 13.9% (p = 0.02), respectively, compared to the ILI group. Other carcass traits, as well as pH and drip loss, were not significantly affected. However, tibia breaking strength at day 35 was 15.1% lower in the LLO group compared to the ILI group (p = 0.02). No significant differences were observed in oxidative stress markers or IgG levels among groups. This study demonstrated that reducing the inclusion level of inorganic trace minerals did not negatively affect broiler growth performance, whereas supplementation with low levels of organic trace minerals improved both growth performance and carcass quality. Full article
(This article belongs to the Section Animal Nutrition)
15 pages, 6688 KiB  
Article
Integrated Additive Manufacturing of TGV Interconnects and High-Frequency Circuits via Bipolar-Controlled EHD Jetting
by Dongqiao Bai, Jin Huang, Hongxiao Gong, Jianjun Wang, Yunna Pu, Jiaying Zhang, Peng Sun, Zihan Zhu, Pan Li, Huagui Wang, Pengbing Zhao and Chaoyu Liang
Micromachines 2025, 16(8), 907; https://doi.org/10.3390/mi16080907 (registering DOI) - 2 Aug 2025
Viewed by 159
Abstract
Electrohydrodynamic (EHD) printing offers mask-free, high-resolution deposition across a broad range of ink viscosities, yet combining void-free filling of high-aspect-ratio through-glass vias (TGVs) with ultrafine drop-on-demand (DOD) line printing on the same platform requires balancing conflicting requirements: for example, high field strengths to [...] Read more.
Electrohydrodynamic (EHD) printing offers mask-free, high-resolution deposition across a broad range of ink viscosities, yet combining void-free filling of high-aspect-ratio through-glass vias (TGVs) with ultrafine drop-on-demand (DOD) line printing on the same platform requires balancing conflicting requirements: for example, high field strengths to drive ink into deep and narrow vias; sufficiently high ink viscosity to prevent gravity-induced leakage; and stable meniscus dynamics to avoid satellite droplets and charge accumulation on the glass surface. By coupling electrostatic field analysis with transient level-set simulations, we establish a dimensionless regime map that delineates stable cone-jetting regime; these predictions are validated by high-speed imaging and surface profilometry. Operating within this window, the platform achieves complete, void-free filling of 200 µm × 1.52 mm TGVs and continuous 10 µm-wide traces in a single print pass. Demonstrating its capabilities, we fabricate transparent Ku-band substrate-integrated waveguide antennas on borosilicate glass: the printed vias and arc feed elements exhibit a reflection coefficient minimum of −18 dB at 14.2 GHz, a −10 dB bandwidth of 12.8–16.2 GHz, and an 8 dBi peak gain with 37° beam tilt, closely matching full-wave predictions. This physics-driven, all-in-one EHD approach provides a scalable route to high-performance, glass-integrated RF devices and transparent electronics. Full article
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21 pages, 5375 KiB  
Article
Controllability-Oriented Method to Improve Small-Signal Response of Virtual Synchronous Generators
by Antonija Šumiga, Boštjan Polajžer, Jožef Ritonja and Peter Kitak
Appl. Sci. 2025, 15(15), 8521; https://doi.org/10.3390/app15158521 (registering DOI) - 31 Jul 2025
Viewed by 103
Abstract
This paper presents a method for optimizing the inertia constants and damping coefficients of interconnected virtual synchronous generators (VSGs) using a genetic algorithm. The goal of optimization is to find a balance between minimizing the rate of change of frequency (RoCoF) and enhancing [...] Read more.
This paper presents a method for optimizing the inertia constants and damping coefficients of interconnected virtual synchronous generators (VSGs) using a genetic algorithm. The goal of optimization is to find a balance between minimizing the rate of change of frequency (RoCoF) and enhancing controllability. Five controllability-based metrics are tested: the minimum eigenvalue, the sum of the two smallest eigenvalues, the maximum eigenvalue, the trace, and the determinant of the controllability Gramian matrix. The approach includes the oscillatory modes’ damping ratio constraints to ensure the small-signal stability of the entire system. The results of optimization on the IEEE 9-bus system with three VSGs show that the proposed method improves controllability, reduces RoCoF, and maintains the desired oscillation damping. The proposed approach was tested through time-domain simulations. Full article
(This article belongs to the Special Issue Control of Power Systems, 2nd Edition)
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21 pages, 4163 KiB  
Article
Digital Twin-Based Ray Tracing Analysis for Antenna Orientation Optimization in Wireless Networks
by Onem Yildiz
Electronics 2025, 14(15), 3023; https://doi.org/10.3390/electronics14153023 - 29 Jul 2025
Viewed by 300
Abstract
Efficient antenna orientation of transmitters is essential for improving wireless signal quality and coverage, especially in large-scale and complex 6G networks. Identifying the best antenna angles is difficult due to the nonlinear interaction among orientation, signal propagation, and interference. This paper introduces a [...] Read more.
Efficient antenna orientation of transmitters is essential for improving wireless signal quality and coverage, especially in large-scale and complex 6G networks. Identifying the best antenna angles is difficult due to the nonlinear interaction among orientation, signal propagation, and interference. This paper introduces a digital twin-based evaluation approach utilizing ray tracing simulations to assess the influence of antenna orientation on critical performance metrics: path gain, received signal strength (RSS), and signal-to-interference-plus-noise ratio (SINR). A thorough array of orientation scenarios was simulated to produce a dataset reflecting varied coverage conditions. The dataset was utilized to investigate antenna configurations that produced the optimal and suboptimal performance for each parameter. Additionally, three machine learning models—k-nearest neighbors (KNN), multi-layer perceptron (MLP), and XGBoost—were developed to forecast ideal configurations. XGBoost had superior prediction accuracy compared to the other models, as evidenced by regression outcomes and cumulative distribution function (CDF) analyses. The proposed workflow demonstrates that learning-based predictors can uncover orientation refinements that conventional grid sweeps overlook, enabling agile, interference-aware optimization. Key contributions include an end-to-end digital twin methodology for rapid what-if analysis and a systematic comparison of lightweight machine learning predictors for antenna orientation. This comprehensive method provides a pragmatic and scalable solution for the data-driven optimization of wireless systems in real-world settings. Full article
(This article belongs to the Special Issue Advances in Wireless Communication Performance Analysis)
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15 pages, 2361 KiB  
Article
Geochemical Characteristics of the Hida Granitoids in the Unazuki and Katakaigawa Areas, Central Japan
by Kazuki Oishi, Rui Kuwahara, Kazuya Shimooka and Motohiro Tsuboi
Geosciences 2025, 15(8), 285; https://doi.org/10.3390/geosciences15080285 - 29 Jul 2025
Viewed by 256
Abstract
The Hida Belt in central Japan is a key geological unit for understanding the crustal growth of the Eurasian continent in the Mesozoic. However, while previous studies have focused primarily on geochronology, the geochemical characteristics of its rocks and minerals remain largely unexplored. [...] Read more.
The Hida Belt in central Japan is a key geological unit for understanding the crustal growth of the Eurasian continent in the Mesozoic. However, while previous studies have focused primarily on geochronology, the geochemical characteristics of its rocks and minerals remain largely unexplored. This study investigates the geochemical characteristics and magmatic processes of the Hida granitoids, including adakitic rocks, distributed in the Unazuki and Katakaigawa areas. Whole-rock major oxides and trace elements, as well as Rb-Sr isotopes, were analyzed. Based on Rb–Sr isotopic compositions, the Hida granitoids are classified into two types. The younger and older granitoids in the Unazuki area, categorized as Type I, exhibit a narrow range of isotopic ratios, whereas the older granitoids in the Katakaigawa area, classified as Type II, display significantly higher values than those of Type I. The geochemical data suggest that the adakitic rocks in the older granitoids originated from interaction with alkali-rich melts or fluids, while those in the younger granitoids were derived from hydrous felsic magmas sourced from subducted oceanic crust. These findings provide new insights into the formation and evolution of granitic magmatism in the Hida Belt. Full article
(This article belongs to the Section Geochemistry)
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22 pages, 5896 KiB  
Article
Point Cloud Generation Method Based on Dual-Prism Scanning with Multi-Parameter Optimization
by Yuanfeng Zhao, Zhen Zheng and Hong Chen
Photonics 2025, 12(8), 764; https://doi.org/10.3390/photonics12080764 - 29 Jul 2025
Viewed by 199
Abstract
This study addresses two critical challenges in biprism-based laser scanning systems: the lack of a comprehensive mathematical framework linking prism parameters to scanning performance, and unresolved theoretical gaps regarding parameter effects on point cloud quality. We propose a multi-parameter optimization method for point [...] Read more.
This study addresses two critical challenges in biprism-based laser scanning systems: the lack of a comprehensive mathematical framework linking prism parameters to scanning performance, and unresolved theoretical gaps regarding parameter effects on point cloud quality. We propose a multi-parameter optimization method for point cloud generation using dual-prism scanning. By establishing a beam pointing mathematical model, we systematically analyze how prism wedge angles, refractive indices, rotation speed ratios, and placement configurations influence scanning performance, revealing their coupled effects on deflection angles, azimuth control, and coverage. The non-paraxial ray tracing method combined with the Möller–Trumbore algorithm enables efficient point cloud simulation. Experimental results demonstrate that our optimized parameters significantly enhance point cloud density, uniformity, and target feature integrity while overcoming limitations of traditional database construction methods. This work provides both theoretical foundations and practical solutions for high-precision 3D reconstruction in high-speed rendezvous scenarios such as missile-borne laser fuzes, offering advantages in cost-effectiveness and operational reliability. Full article
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33 pages, 8681 KiB  
Review
AI-Empowered Electrochemical Sensors for Biomedical Applications: Technological Advances and Future Challenges
by Yafeng Liu, Xiaohui Liu, Xuemei Wang and Hui Jiang
Biosensors 2025, 15(8), 487; https://doi.org/10.3390/bios15080487 - 28 Jul 2025
Viewed by 326
Abstract
Biomarkers play a pivotal role in disease diagnosis, therapeutic efficacy evaluation, prognostic assessment, and drug screening. However, the trace concentrations of these markers in complex physiological environments pose significant challenges to efficient detection. It is necessary to avoid interference from non-specific signals, which [...] Read more.
Biomarkers play a pivotal role in disease diagnosis, therapeutic efficacy evaluation, prognostic assessment, and drug screening. However, the trace concentrations of these markers in complex physiological environments pose significant challenges to efficient detection. It is necessary to avoid interference from non-specific signals, which may lead to misjudgment of other substances as biomarkers and affect the accuracy of detection results. With the rapid advancements in electrochemical technologies and artificial intelligence (AI) algorithms, intelligent electrochemical biosensors have emerged as a promising approach for biomedical detection, offering speed, specificity, high sensitivity, and accuracy. This review focuses on elaborating the latest applications of AI-empowered electrochemical biosensors in the biomedical field, including disease diagnosis, treatment monitoring, drug development, and wearable devices. AI algorithms can further improve the accuracy, sensitivity, and repeatability of electrochemical sensors through the screening and performance prediction of sensor materials, as well as the feature extraction and noise reduction suppression of sensing signals. Even in complex physiological microenvironments, they can effectively address common issues such as electrode fouling, poor signal-to-noise ratio, chemical interference, and matrix effects. This work may provide novel insights for the development of next-generation intelligent biosensors for precision medicine. Full article
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22 pages, 6689 KiB  
Article
Design and Implementation of a Sun Outage Simulation System with High Uniformity and Stray Light Suppression Capability
by Zhen Mao, Zhaohui Li, Yong Liu, Limin Gao and Jianke Zhao
Sensors 2025, 25(15), 4655; https://doi.org/10.3390/s25154655 - 27 Jul 2025
Viewed by 354
Abstract
To enable accurate evaluation of satellite laser communication terminals under solar outage interference, this paper presents the design and implementation of a solar radiation simulation system targeting the 1540–1560 nm communication band. The system reconstructs co-propagating interference conditions through standardized and continuously tunable [...] Read more.
To enable accurate evaluation of satellite laser communication terminals under solar outage interference, this paper presents the design and implementation of a solar radiation simulation system targeting the 1540–1560 nm communication band. The system reconstructs co-propagating interference conditions through standardized and continuously tunable output, based on high irradiance and spectral uniformity. A compound beam homogenization structure—combining a multimode fiber and an apodizator—achieves 85.8% far-field uniformity over a 200 mm aperture. A power–spectrum co-optimization strategy is introduced for filter design, achieving a spectral matching degree of 78%. The system supports a tunable output from 2.5 to 130 mW with a 50× dynamic range and maintains power control accuracy within ±0.9%. To suppress internal background interference, a BRDF-based optical scattering model is established to trace primary and secondary stray light paths. Simulation results show that by maintaining the surface roughness of key mirrors below 2 nm and incorporating a U-shaped reflective light trap, stray light levels can be reduced to 5.13 × 10−12 W, ensuring stable detection of a 10−10 W signal at a 10:1 signal-to-background ratio. Experimental validation confirms that the system can faithfully reproduce solar outage conditions within a ±3° field of view, achieving consistent performance in spectrum shaping, irradiance uniformity, and background suppression. The proposed platform provides a standardized and practical testbed for ground-based anti-interference assessment of optical communication terminals. Full article
(This article belongs to the Section Communications)
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20 pages, 9529 KiB  
Article
Geochemistry and Geochronology of the Late Permian Linxi Formation in the Songliao Basin, China: Tectonic Implications for the Paleo-Asian Ocean
by Xin Huang, Haihua Zhang, Liang Qiu, Gongjian Li, Yujin Zhang, Wei Chen, Shuwang Chen and Yuejuan Zheng
Minerals 2025, 15(8), 784; https://doi.org/10.3390/min15080784 - 25 Jul 2025
Viewed by 142
Abstract
The Central Asian Orogenic Belt (CAOB) represents a crucial area for understanding the tectonic evolution of the Paleo-Asian Ocean and surrounding orogenic systems. This study investigates the petrology, geochronology, and geochemistry of volcanic and clastic rocks from Well HFD3 in the northern Songliao [...] Read more.
The Central Asian Orogenic Belt (CAOB) represents a crucial area for understanding the tectonic evolution of the Paleo-Asian Ocean and surrounding orogenic systems. This study investigates the petrology, geochronology, and geochemistry of volcanic and clastic rocks from Well HFD3 in the northern Songliao Basin, which provides key insights into the tectonic development of this region. Zircon U–Pb dating of tuff samples from the Linxi Formation provides an accurate age of 251.1 ± 1.1 Ma, corresponding to the late Permian. Geochemical analyses show that the clastic rocks are rich in SiO2 (63.5%) and Al2O3 (13.7%), with lower K2O/Na2O ratios (0.01–1.55), suggesting low compositional maturity. Additionally, the trace element data reveal enrichment in light rare earth elements (LREEs) and depletion in Nb, Sr, and Ta, with a negative Eu anomaly, which indicates a felsic volcanic arc origin. The Chemical Index of Alteration (CIA) values (53.2–65.8) reflect weak chemical weathering, consistent with cold and dry paleo-climatic conditions. These findings suggest that the Linxi Formation clastic rocks are derived from felsic volcanic arcs in an active continental margin environment, linked to the subduction of the Paleo-Asian Ocean slab. The sedimentary conditions reflect a gradual transition from brackish to freshwater environments, corresponding with the final stages of subduction or the onset of orogeny. Full article
(This article belongs to the Special Issue Selected Papers from the 7th National Youth Geological Congress)
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13 pages, 3688 KiB  
Article
Influence Mechanisms of Trace Rare-Earth Ce on Texture Development of Non-Oriented Silicon Steel
by Feihu Guo, Yuhao Niu, Bing Fu, Jialong Qiao and Shengtao Qiu
Materials 2025, 18(15), 3493; https://doi.org/10.3390/ma18153493 - 25 Jul 2025
Viewed by 236
Abstract
The effects of trace Ce on the microstructure and texture of non-oriented silicon steel during recrystallization and grain growth were examined using X-ray diffraction and electron backscatter diffraction. Additionally, this study focused on investigating the mechanisms by which trace Ce influences the evolution [...] Read more.
The effects of trace Ce on the microstructure and texture of non-oriented silicon steel during recrystallization and grain growth were examined using X-ray diffraction and electron backscatter diffraction. Additionally, this study focused on investigating the mechanisms by which trace Ce influences the evolution of the {114} <481> and γ-fiber textures. During the recrystallization process, as the recrystallization fraction of annealed sheets increased, the intensity of α-fiber texture decreased, while the intensities of α*-fiber and γ-fiber textures increased. The {111} <112> grains preferentially nucleated in the deformed γ-grains and their grain-boundary regions and tended to form a colony structure with a large amount of nucleation. In addition, the {100} <012> and {114} <481> grains mainly nucleated near the deformed α-grains, which were evenly distributed but found in relatively small quantities. The hindering effect of trace Ce on dislocation motion in cold-rolled sheets results in a 2–7% lower recrystallization ratio for the annealed sheets, compared to conventional annealed sheets. Trace Ce suppresses the nucleation and growth of γ-grains while creating opportunities for α*-grain nucleation. During grain growth, trace Ce reduces γ-grain-boundary migration rate in annealed sheets, providing growth space for {114} <418> grains. Consequently, the content of the corresponding {114} <481> texture increased by 6.4%, while the γ-fiber texture content decreased by 3.6%. Full article
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23 pages, 12729 KiB  
Article
Genetic Mineralogical Characteristics of Pyrite and Quartz from the Qiubudong Silver Deposit, Central North China Craton: Implications for Ore Genesis and Exploration
by Wenyan Sun, Jianling Xue, Zhiqiang Tong, Xueyi Zhang, Jun Wang, Shengrong Li and Min Wang
Minerals 2025, 15(8), 769; https://doi.org/10.3390/min15080769 - 22 Jul 2025
Viewed by 273
Abstract
The Qiubudong silver deposit on the western margin of the Fuping ore cluster in the central North China Craton is a representative breccia-type deposit characterized by relatively high-grade ores, thick mineralized zones, and extensive alteration, indicating considerable potential for economic resource development and [...] Read more.
The Qiubudong silver deposit on the western margin of the Fuping ore cluster in the central North China Craton is a representative breccia-type deposit characterized by relatively high-grade ores, thick mineralized zones, and extensive alteration, indicating considerable potential for economic resource development and further exploration. Previous studies on this deposit have not addressed its genetic mineralogical characteristics. This study focuses on pyrite and quartz to investigate their typomorphic features, such as crystal morphology, trace element composition, thermoelectric properties, and luminescence characteristics, and their implications for ore-forming processes. Pyrite crystals are predominantly cubic in early stages, while pentagonal dodecahedral and cubic–dodecahedral combinations peak during the main mineralization stage. The pyrite is sulfur-deficient and iron-rich, enriched in Au, and relatively high in Ag, Cu, Pb, and Bi contents during the main ore-forming stage. Rare earth element (REE) concentrations are low, with weak LREE-HREE fractionation and a strong negative Eu anomaly. The thermoelectric coefficient of pyrite ranges from −328.9 to +335.6 μV/°C, with a mean of +197.63 μV/°C; P-type conduction dominates, with an occurrence rate of 58%–100% and an average of 88.78%. A weak–low temperature and a strong–high temperature peak characterize quartz thermoluminescence during the main mineralization stage. Fluid inclusions in quartz include liquid-rich, vapor-rich, and two-phase types, with salinities ranging from 10.11% to 12.62% NaCl equiv. (average 11.16%) and densities from 0.91 to 0.95 g/cm3 (average 0.90 g/cm3). The ore-forming fluids are interpreted as F-rich, low-salinity, low-density hydrothermal fluids of volcanic origin at medium–low temperatures. The abundance of pentagonal dodecahedral pyrite, low Co/Ni ratios, high Cu contents, and complex quartz thermoluminescence signatures are key mineralogical indicators for deep prospecting. Combined with thermoelectric data and morphological analysis, the depth interval around 800 m between drill holes ZK3204 and ZK3201 has high mineralization potential. This study fills a research gap on the genetic mineralogy of the Qiubudong deposit and provides a scientific basis for deep exploration. Full article
(This article belongs to the Special Issue Using Mineral Chemistry to Characterize Ore-Forming Processes)
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19 pages, 7940 KiB  
Article
High-Salinity Fluid Downslope Flow on Regolith Layer Examined by Laboratory Experiment: Implications for Recurring Slope Lineae on Martian Surfaces
by Yoshiki Tabuchi, Arata Kioka, Takeshi Tsuji and Yasuhiro Yamada
Fluids 2025, 10(7), 183; https://doi.org/10.3390/fluids10070183 - 12 Jul 2025
Viewed by 339
Abstract
Numerous dark linear recurrent features called Recurring Slope Lineae (RSL) are observed on Martian surfaces, hypothesized as footprints of high-salinity liquid flow. This paper experimentally examined this “wet hypothesis” by analyzing the aspect ratios (length/width) of the flow traces on the granular material [...] Read more.
Numerous dark linear recurrent features called Recurring Slope Lineae (RSL) are observed on Martian surfaces, hypothesized as footprints of high-salinity liquid flow. This paper experimentally examined this “wet hypothesis” by analyzing the aspect ratios (length/width) of the flow traces on the granular material column to investigate how they vary with the granular material column, liquid and its flow rate, and inclination. While pure water produced low aspect ratios (<1.0) on the Martian regolith simulant column, high-salinity fluid (CaCl2(aq)) traces exhibited significantly higher aspect ratios (>4.0), suggesting that pure water alone is insufficient to explain RSL formulation. Furthermore, the aspect ratios of high-salinity fluid traces on Martian regolith simulants were among the highest observed across all studied granular materials with similar particle sizes, aligning closely with actual RSL observed on Martian slopes. The results further suggest that variable ARs of actual RSL at the given slope can partly be explained by variable flow rates of high-salinity flow as well as salinity (i.e., viscosity) of flow. The results can be attributed to the unique granular properties of Martian regolith, characterized by the lowest permeability and Beavers–Joseph slip coefficient among the studied granular materials. This distinctive microstructure surface promotes surface flow over Darcy flow within the regolith column, leading to a narrow and long-distance feature with high aspect ratios observed in Martian RSL. Thus, our findings support that high-salinity flows are the primary driver behind RSL formation on Mars. Our study suggests the presence of salts on the Martian surface and paves the way for further investigation into RSL formulation processes. Full article
(This article belongs to the Section Geophysical and Environmental Fluid Mechanics)
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21 pages, 3369 KiB  
Article
Thermal Runaway Critical Threshold and Gas Release Safety Boundary of 18,650 Lithium-Ion Battery in State of Charge
by Jingyu Zhao, Kexin Xing, Xinrong Jiang, Chi-Min Shu and Xiangrong Sun
Processes 2025, 13(7), 2175; https://doi.org/10.3390/pr13072175 - 8 Jul 2025
Viewed by 711
Abstract
In this study, we systematically investigated the characteristic parameter evolution laws of thermal runaway with respect to 18,650 lithium-ion batteries (LIBs) under thermal abuse conditions at five state-of-charge (SOC) levels: 0%, 25%, 50%, 75%, and 100%. In our experiments, we combined infrared thermography, [...] Read more.
In this study, we systematically investigated the characteristic parameter evolution laws of thermal runaway with respect to 18,650 lithium-ion batteries (LIBs) under thermal abuse conditions at five state-of-charge (SOC) levels: 0%, 25%, 50%, 75%, and 100%. In our experiments, we combined infrared thermography, mass loss analysis, temperature monitoring, and gas composition detection to reveal the mechanisms by which SOC affects the trigger time, critical temperature, maximum temperature, mass loss, and gas release characteristics of thermal runaway. The results showed that as the SOC increases, the critical and maximum temperatures of thermal runaway increase notably. At a 100% SOC, the highest temperature on the positive electrode side reached 1082.1 °C, and the mass loss increased from 6.90 g at 0% SOC to 25.75 g at 100% SOC, demonstrating a salient positive correlation. Gas analysis indicated that under high-SOC conditions (75% and 100%), the proportion of flammable gases such as CO and CH4 produced during thermal runaway significantly increases, with the CO/CO2 ratio exceeding 1, indicating intensified incomplete combustion and a significant increase in fire risk. In addition, flammability limit analysis revealed that the lower explosive limit for gases is lower (17–21%) at a low SOC (0%) and a high SOC (100%), indicating greater explosion risks. We also found that the composition of gases released during thermal runaway varies substantially at different SOC levels, with CO, CO2, and CH4 accounting for over 90% of the total gas volume, while toxic gases, such as HF, although present in smaller proportions, pose noteworthy hazards. Unlike prior studies that relied on post hoc analysis, this work integrates real-time multi-parameter monitoring (temperature, gas composition, and mass loss) and quantitative explosion risk modeling (flammability limits via the L-C formula). This approach reveals the unique dynamic SOC-dependent mechanisms of thermal runaway initiation and gas hazards. This study provides theoretical support for the source tracing of thermal runaway fires and the development of preventive LIB safety technology and emphasizes the critical influence of the charge state on the thermal safety of batteries. Full article
(This article belongs to the Special Issue Machine Learning Optimization of Chemical Processes)
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