Search Results (313)

This study evaluates the agronomic potential of two types of vermicompost—one produced solely from wine industry residues (WIR) and one incorporating sewage sludge (WIR + SS)—under rainfed and deficit irrigation conditions in Mediterranean vineyards. The vermicompost was obtained through a two-phase process involving initial thermophilic pre-composting, followed by vermicomposting using Eisenia fetida for 90 days. The conditions were optimized to ensure aerobic decomposition and maintain proper moisture levels (70–85%) and temperature control. This resulted in end products that met the legal standards required for agricultural use. However, population dynamics revealed significantly higher worm reproduction and biomass in the WIR treatment, suggesting superior substrate quality. When applied to grapevines, WIR vermicompost increased soil organic matter, nitrogen availability, and overall fertility. Under rainfed conditions, it improved vegetative growth, yield, and must quality, with increases in yeast assimilable nitrogen (YAN), sugar content, and amino acid levels comparable to those achieved using chemical fertilizers, as opposed to the no-fertilizer trial. Foliar analyses at veraison revealed stronger nutrient uptake, particularly of nitrogen and potassium, which was correlated with improved oenological parameters compared to the no-fertilizer trial. In contrast, WIR + SS compost was less favorable due to lower worm activity and elevated trace elements, despite remaining within legal limits. These results support the use of vermicompost derived solely from wine residues as a sustainable alternative to chemical fertilizers, in line with the goals of the circular economy in viticulture. Full article

Over the past few decades, pesticide application has increased significantly, driven by population growth and associated urbanization. To date, pesticide use remains crucial for sustaining global food security by enhancing crop yields and preserving quality. However, extensive pesticide application raises serious environmental and health concerns worldwide due to its chemical persistence and high toxicity to organisms, including humans. Therefore, there is an urgent need to develop rapid and reliable analytical procedures for the quantification of trace pesticide residues to support public health management. Traditional methods, such as chromatography-based detection techniques, cannot simultaneously achieve high sensitivity, selectivity, cost-effectiveness, and portability, which limits their practical application. Nanomaterial-based sensing techniques are increasingly being adopted due to their rapid, efficient, user-friendly, and on-site detection capabilities. In this review, we summarize recent advances and emerging trends in commonly used nanosensing technologies, such as optical and electrochemical sensing, with a focus on recognition elements including enzymes, antibodies, aptamers, and molecularly imprinted polymers (MIPs). We discuss the types of nanomaterials used, preparation methods, performance, characteristics, advantages and limitations, and applications of these nanosensors in detecting pesticide residues in agricultural products. Furthermore, we highlight current challenges, ongoing efforts, and future directions in the development of pesticide detection nanosensors. Full article

Macro- and microelements in waste can be returned to the soil as fertilizers and their sustainable use can reduce the need to extract natural resources. For example, the use of carbonate-clay flour, sewage sludge and waste sulfate sulfur to improve soil properties enables the natural recycling of the nutrients contained in these materials. Soil physicochemical properties with the application of waste and the bioavailability of nutrients and trace elements were assessed before and after a 3-month incubation period. This study showed that when carbonate-clay flour was applied alone or together with sewage sludge and waste sulfur, it improved the properties of the soil, inducing a reduction in acidification and an increase in the content of available P, K and Mg. Sewage sludge also provided Zn, Cu, Ni and Cr in addition to organic carbon. Sulfate did not cause soil acidification. The results indicate that the use of carbonate-clay flour alone, as well as with the addition of sewage sludge and sulfate sulfur, can be recommended for the deacidification of soil and serve as a remediation tool for, for example, the precipitation of chemical pollutants. The valorization of the waste used fits into the circular economy approach. Full article

The consumption of fresh fruit and vegetables is essential for a healthy diet as they contain a diverse composition of vitamins, minerals, fibre, and bioactive compounds. However, cross-contamination during harvest and post-harvest poses a high risk of microbial contamination. Therefore, handling fruit and vegetables during processing and contact with wet equipment and utensil surfaces is an ideal environment for microbial contamination and foodborne illness. Nevertheless, less attention has been paid to some emerging pathogens that are now increasingly recognised as transmissible to humans through contaminated fruit and vegetables, such as Arcobacter and Cronobacter species in various products, which are the main risk in fruit and vegetables. Cronobacter and Arcobacter spp. are recognised food-safety hazards because they pose a risk of foodborne disease, especially in vulnerable groups such as newborns and immunocompromised individuals. Cronobacter spp. have been linked to severe infant conditions—notably meningitis and sepsis—most often traced to contaminated powdered infant formula. Although Arcobacter spp. have been less extensively studied, they have also been associated with foodborne disease, chiefly from dairy products and meat. With this in mind, this review provides an overview of the main chemical and physical sanitisation methods in terms of their ability to reduce the contamination of fresh fruit and vegetable products caused by two emerging pathogens: Arcobacter and Cronobacter. Emerging chemical (organic acid compounds, extracts, and essential oils) and physical methods (combination of UV-C with electrolysed water, ultrasound, and cold atmospheric plasma) offer innovative and environmentally friendly alternatives to traditional approaches. These methods often utilise natural materials, less toxic solvents, and novel techniques, resulting in more sustainable processes compared with traditional methods that may use harsh chemicals and environmentally harmful processes. This review provides the fruit and vegetable industry with a general overview of possible decontamination alternatives to develop optimal and efficient processes that ensure food safety. Full article

Titanium dioxide (TiO₂) is a wide-bandgap semiconductor material with broad application potential, known for its excellent photocatalytic performance, high chemical stability, low cost, and non-toxicity. These properties make it highly attractive for applications in photovoltaic energy, environmental remediation, and optoelectronic devices. For instance, TiO₂ is widely used as a photocatalyst for hydrogen production via water splitting and for degrading organic pollutants, thanks to its efficient photo-generated electron–hole separation. Additionally, TiO₂ exhibits remarkable performance in dye-sensitized solar cells and photodetectors, providing critical support for advancements in green energy and photoelectric conversion technologies. Boron-doped diamond (BDD) is renowned for its exceptional electrical conductivity, high hardness, wide electrochemical window, and outstanding chemical inertness. These unique characteristics enable its extensive use in fields such as electrochemical analysis, electrocatalysis, sensors, and biomedicine. For example, BDD electrodes exhibit high sensitivity and stability in detecting trace chemicals and pollutants, while also demonstrating excellent performance in electrocatalytic water splitting and industrial wastewater treatment. Its chemical stability and biocompatibility make it an ideal material for biosensors and implantable devices. Research indicates that the combination of TiO₂ nanostructures and BDD into heterostructures can exhibit unexpected optical and electrical performance and transport behavior, opening up new possibilities for photoluminescence and rectifier diode devices. However, applications based on this heterostructure still face challenges, particularly in terms of photodetector, photoelectric emitter, optical modulator, and optical fiber devices under high-temperature conditions. This article explores the potential and prospects of their combined heterostructures in the field of optoelectronic devices such as photodetector, light emitting diode (LED), memory, field effect transistor (FET) and sensing. TiO₂/BDD heterojunction can enhance photoresponsivity and extend the spectral detection range which enables stability in high-temperature and harsh environments due to BDD’s thermal conductivity. This article proposes future research directions and prospects to facilitate the development of TiO₂ nanostructured materials and BDD-based heterostructures, providing a foundation for enhancing photoresponsivity and extending the spectral detection range enables stability in high-temperature and high-frequency optoelectronic devices field. Further research and exploration of optoelectronic devices based on TiO₂-BDD heterostructures hold significant importance, offering new breakthroughs and innovations for the future development of optoelectronic technology. Full article

Urbanisation and land-use change are among the main pressures on soil health in periurban areas, but the multifunctionality of grassland soils is still not sufficiently recognised. In this study, the physical and chemical properties of soils under grassland, forest and croplands in the periurban area of Zagreb were investigated in a two-year period. Grasslands consistently exhibited multifunctional benefits, including high organic matter content (4.68% vs. 2.24% in cropland), improved bulk density (1.14 vs. 1.24 g cm⁻³) and an active carbon cycle indicated by increased CO₂ emissions (up to 1403 kg ha⁻¹ day⁻¹ in 2021). Forest soils showed the highest aggregate stability (91.4%) and infiltration (0.0006 cm s⁻¹), while croplands showed signs of structural degradation with the highest bulk density and lowest water retention (39.9%). Temporal variation showed that grassland was particularly responsive to favourable climatic conditions, with soil porosity and water content improving yearly. Principal component analysis showed that soil structure, biological activity and moisture regulation were linked, with grassland plots favourably positioned along the axes of resilience. The absence of tillage and the presence of permanent vegetation cover contributed to their high capacity for climate and water regulation and carbon sequestration. These results emphasise the importance of protecting and managing grasslands as an important component of urban green areas. Practices such as mulching, minimal disturbance and continuous cover can maximise the ecosystem services of grassland soils. In addition, the results highlight the potential risk of trace metal accumulation in cropland and grassland soils located near urban and farming infrastructure, underlining the need for regular monitoring in periurban environments. Integrating grassland functions into urban planning and policy is essential for improving the sustainability and resilience of periurban landscapes. Full article

Camelina seeds are rich in α-linolenic acid (ALA), but also contain small amounts of erucic acid, which is considered toxic to laboratory rats. This experiment compares the dietary inclusion of camelina oil to that of flaxseed oil, a well-known source of ALA, and evaluates their effects on the nutritional and metabolic status of growing rats. The oils were chemically analyzed and incorporated into a semi-purified diet for 4 weeks. The experiment was divided into 3 groups: PO (control-fed palm oil with a trace of ALA), FO (comparative-fed flaxseed oil), and CO (experimental-fed camelina seed oil). Both CO and FO showed a higher percentage of lean body mass, greater lean mass gain, and a lower fat percentage compared to PO. Similar to the body composition, the blood lipid profile also improved in CO and FO, with higher HDL cholesterol and lower triglyceride levels, which was associated with upregulation of the peroxisome proliferator-activated receptor γ gene. However, in FO and CO, higher plasma liver enzyme activity and malondialdehyde concentrations were observed in the heart and liver. The results suggest that camelina oil has a similarly beneficial impact on the metabolic processes of the growing body as flaxseed oil, while also indicating a potential for increased organ-specific lipid peroxidation and hepatic burden when consumed in excess. Full article

Geothermal systems play a crucial role in understanding Earth’s heat dynamics. The Yunkai Uplift in southern China exemplifies a geothermally rich region characterized by ancient lithologies and high heat flow. This study investigates the geochemical characteristics of geothermal waters in the Yunkai Uplift. Both geothermal and non-thermal water samples were collected along the Xinyi–Lianjiang (XL) Fault Zone and the Cenxi–Luchuan (CL) Fault Zone flanking the core of the Yunkai Mountains. Analytical techniques were applied to examine major ions, trace elements, and dissolved CO₂ and H₂, as well as isotopic characteristics of O, H, Sr, C, and He in water samples, allowing for an investigation of geothermal reservoir temperatures, circulation depths, and mixing processes. The findings indicate that most geothermal waters are influenced by water–rock interactions primarily dominated by granites. The region’s diverse lithologies, change from ancient Caledonian granites and medium–high-grade metamorphic rocks in the central hinterland (XL Fault Zone) to low-grade metamorphic rocks and sedimentary rocks in the western margin (CL Fault Zone). The chemical compositions of geothermal waters are influenced through mixing contacts between diverse rocks of varying ages, leading to distinct geochemical characteristics. Notably, δ¹³C_CO2 values reveal that while some samples exhibit significant contributions from metamorphic CO₂ sources, others are characterized by organic CO₂ origins. Regional heat flow results from the upwelling of mantle magma, supplemented by radioactive heat generated from crustal granites. Isotopic evidence from δ²H and δ¹⁸O indicates that the geothermal waters originate from atmospheric sources, recharged by precipitation in the northern Yunkai Mountains. After infiltrating to specific depths, meteoric waters are heated to temperatures ranging from about 76.4 °C to 178.5 °C before ascending through the XL and CL Fault Zones under buoyancy forces. During their upward migration, geothermal waters undergo significant mixing with cold groundwater (54–92%) in shallow strata. As part of the western boundary of the Yunkai Uplift, the CL Fault Zone may extend deeper into the crust or even interact with the upper mantle but exhibits weaker hydrothermal activities than the XL Fault Zone. The XL Fault Zone, however, is enriched with highly heat-generating granites, is subjected more to both the thermal and mechanical influences of upwelling mantle magma, resulting in a higher heat flow and tension effect, and is more conducive to the formation of geothermal waters. Our findings underscore the role of geotectonic processes, lithological variation, and fault zone activity in shaping the genesis and evolution of geothermal waters in the Yunkai Uplift. Full article

Sustainable land management in arid regions such as the Jordan Valley (JV) is essential as climate pressures and water shortages intensify. The extended use of treated wastewater (TWW) for irrigation, while necessary, brings potential risks related to the accumulation of trace elements and their impact on soil health and food safety. This study examined the spatial distribution, variability, and potential sources of five trace elements (Co, Hg, Mo, Mn, and Ni) in agricultural soils across a 305 km² area. A total of 127 surface soil samples were collected from fields irrigated with either TWW or freshwater (FW). Trace element concentrations were consistently higher in TWW-irrigated soils, although all values remained below WHO/FAO recommended thresholds for agricultural use. Spatial modeling was conducted using both ordinary kriging (OK) and empirical Bayesian kriging (EBK), with EBK showing greater prediction accuracy based on cross-validation statistics. To explore potential sources, semivariogram modeling, principal component analysis (PCA), and hierarchical clustering were employed. PCA, spatial distribution patterns, correlation analysis, and comparisons between TWW and FW sources suggest that Co, Mn, Mo, and Ni are primarily influenced by anthropogenic inputs, including TWW irrigation, chemical fertilizers, and organic amendments. Co exhibited a stronger association with TWW, whereas Mn, Mo, and Ni were more closely linked to fertilizer application. In contrast, Hg appears to originate predominantly from geogenic sources. These findings provide a foundation for improved irrigation management and fertilizer application strategies, contributing to long-term soil sustainability in water-limited environments like the JV. Full article

Carbon nanotubes (CNTs) functionalized with metal oxides exhibit synergistic properties that enhance their performance across various applications, particularly in electrochemistry. Recent advancements have highlighted the potential of CNT–metal oxide heterostructures, with a specific focus on their electrochemical properties, which are pivotal for applications in sensors, supercapacitors, batteries, and catalytic systems. Among these, nickel oxide (NiO)-modified CNTs have garnered significant attention due to their cost-effectiveness, facile synthesis, and promising gas-sensing capabilities. This study employs quantum-chemical calculations within the framework of density functional theory (DFT) to elucidate the interaction mechanisms between CNTs and NiO. The results demonstrate that the adsorption process leads to the formation of stable CNT-NiO complexes, with detailed analysis of adsorption energies, equilibrium distances, and electronic structure modifications. The single-electron spectra and density of states (DOS) of the optimized complexes reveal significant alterations in the electronic properties, particularly the modulation of the energy gap induced by surface and edge functionalization. Furthermore, the interaction of CNT-NiO composites with acetone (C₃H₆O) and carbon dioxide (CO₂) is modeled, revealing a physisorption-dominated mechanism. The adsorption of these gases induces notable changes in the electronic properties and charge distribution within the system, underscoring the potential of CNT-NiO composites for gas-sensing applications. This investigation provides a foundational understanding of the role of metal oxide modifications in tailoring the sensory activity of CNTs toward trace amounts of diverse substances, including metal atoms, inorganic molecules, and organic compounds. The findings suggest that CNT-NiO systems can serve as highly sensitive and selective sensing elements, with potential applications in medical diagnostics and environmental monitoring, thereby advancing the development of next-generation sensor technologies. Full article

The Mekong Delta, an important agricultural and economic hub in Vietnam, has suffered from severe water quality issues caused by both natural and anthropogenic forces. This paper aims to conduct a rational statistical approach to evaluate the current situation of surface water quality in the Mekong Delta, applying Factor Analysis (FA), Principal Component Analysis (PCA), and Agglomerative Hierarchical Clustering (AHC) to a database of 3117 samples collected by national and provincial monitoring stations. The results revealed significant contamination with organic pollutants (BOD5: 3.50–172.870 mg/L, COD: 6.493–472.984 mg/L), pesticides (e.g., DDTs: n.d to 1.227 mg/L), trace metals (As: 0.006–0.046 mg/L, Cr: n.d–1.960 mg/L), and microbial indicators (Coliforms: n.d–45,100 MPN/100 mL), often higher than the WHO drinking water threshold. PCA/AHC analysis identified the following five major pollution components: (1) organic pollution and sewage/industrial and deposited chemicals (PCA1—23.08% variance); (2) pesticide and agricultural runoff derived contamination with Hg (PCA2—15.44%); (3) microbial pollution of the water was found to correlate positively with Zn and Cu content (PCA3—8.90%); (4) salinity was found to mobilize As and Cr (PCA4—8.00%); (5) nutrient/microbial pollution presumably from agricultural and sewage inputs (PCA5—7.22%). AHC showed some spatial variability that grouped samples in urban/industrial (Cluster 1), rural/agricultural (Cluster 2), and a highly contaminated one, where water was toxic and presented with microbial and Cd contamination (Cluster 3). Levels of pesticides, Cr, and microbial pollution were higher than reported in previous Mekong Delta studies and exceeded regional trends. These results emphasize the importance of holistic water management strategies, including better wastewater treatment, pesticide control, sustainable farming, and climate-adaptive measures to reduce saltwater intrusion and safeguard drinking water quality for the Mekong Delta. Full article

The Minghuazhen Formation in the Cangdong Sag of the Bohai Bay Basin is a key sedimentary unit for investigating regional provenance evolution, paleoclimate variations, and hydrocarbon potential in Eastern China. This study integrates mineralogical and geochemical analyses to explore sedimentary characteristics. Techniques include X-ray diffraction (XRD), major/trace element compositions, rare earth element (REE) distributions, and organic carbon content. XRD data and elemental ratios (e.g., Al/Ti, Zr/Sc) suggest a predominant felsic provenance, sourced from acidic magmatic rocks. The enrichment with light rare earth elements (LREE: La–Eu) and notable negative Eu anomalies in the REE patterns support the interpretation of a provenance from the Taihangshan and Yanshan Orogenic Belts. Geochemical proxies, such as the Chemical Index of Alteration (CIA) and trace element ratios (e.g., U/Th, V/Cr, Ni/Co), indicate a warm and humid depositional environment, characterized by predominantly oxic freshwater conditions. Organic geochemical parameters, including total organic carbon (TOC), total nitrogen (TN), and C/N ratios, suggest that organic matter primarily originates from aquatic algae and plankton, with C/N values predominantly below 10 and a strong correlation between TOC and TN. The weak correlation between TOC and total carbon (TC) indicates that the organic carbon is mainly biological in origin rather than carbonate-derived. Although the warm and humid climate promoted the production of organic matter, the prevailing oxic conditions hindered its preservation, resulting in a relatively low hydrocarbon generation potential within the Minghuazhen Formation of the Cangdong Sag. These findings provide new insights into the sedimentary evolution and hydrocarbon potential of the Bohai Bay Basin. Full article

PM₁₀ samples were collected at an urban site of Zhuozhou, the southern gateway of Beijing, from 28 December 2021 to 29 January 2022, in order to explore the chemical composition, sources and physical and chemical formation processes of prominent components. The results showed that five trace elements (Mn, Cu, As, Zn and Pb) had high enrichment in PM₁₀ and were closely related with anthropogenic combustion and vehicle emissions; organic and element carbon had a high correlation due to the same primary sources and similar evolution; nitrate dominated SNA (sulfate, nitrate, ammonium) and nitrate/sulfate ratios reached 2.35 on the polluted days owing to the significant contribution of motor vehicle emissions. Positive matrix factorization analysis indicated that secondary source, traffic, biomass burning, industry, coal combustion and crustal dust were the main sources of PM₁₀, contributing 32.5%, 20.9%, 15.0%, 13.9%, 9.4% and 8.3%, respectively; backward trajectories and potential source contribution function analysis showed that short-distance airflow was the dominant cluster and accounted for nearly 50% of total trajectories. The Weather Research and Forecasting model with Chemistry, with integrated process rate analysis, showed that dominant gas-phase reactions (heterogeneous reaction) during daytime (nighttime) in presence of ammonia led to a significant enhancement of nitrate in Zhuozhou, contributing 12.6 μg/m³ in episode 1 and 22.9 μg/m³ in episode 2. Full article

Selenium (Se) is essential for various metabolic and physiological functions in the human body. However, the mechanisms of Se cycling in soils, particularly under different parent materials and land uses, remain understudied. This study investigates the spatial distribution and influencing factors of total Se in surface soils derived from limestone and sandstone in paddy and dryland systems in a Se-rich karst region of Southwest China. The mean Se content was 0.5 mg/kg, with 100% of samples exceeding national and global background levels, confirming Zheng’an County as a newly recognized Se-rich area. Soil Se concentrations, along with environmental variables such as soil organic matter (SOM), pH, elevation, slope, and trace elements (V, Cr, and Zn), were analyzed. One-way ANOVA revealed significant differences in Se content between parent materials and land-use types. Stepwise multiple regression identified SOM as the strongest predictor of Se, while Spearman correlation showed significant associations with topographic and chemical factors. These findings highlight the complex interactions between geology, land use, and topography in Se dynamics. Given the global distribution of karst landscapes, this research provides valuable insights into Se behavior in similar environments worldwide, with implications for land management and nutritional security. Full article

Nitrate (NO₃⁻) pollution resulting from anthropogenic activities represents one of the most prevalent environmental issues in karst spring catchments of northern China. In June 2021, a comprehensive study was conducted in the Jinan Spring Catchment (JSC), where 30 groundwater and surface water samples were collected. The sources and spatial distribution of nitrate pollution were systematically investigated through hydrochemical analysis combined with dual-isotope tracing techniques (δ¹⁵N_NO3 and δ¹⁸O_NO3). Analytical results revealed that the predominant anion and cation sequences were HCO₃⁻ > SO₄²⁻ > Cl⁻ > NO₃⁻ and Ca²⁺ > Na⁺ > Mg²⁺ > K⁺, respectively, with HCO₃·SO₄-Ca identified as the primary hydrochemical type. Notably, the average NO₃⁻ concentration in groundwater (46.62 mg/L) significantly exceeded that in surface water (4.96 mg/L). Among the water samples, 11 locations exhibited substantial nitrate pollution, demonstrating an exceedance rate of 42%. Particularly, the NO₃⁻-N concentrations in both the upstream recharge area and downstream drainage area were markedly higher than those in the runoff area. The spatial distribution of NO₃⁻ concentrations was primarily influenced by mixing processes, with no significant evidence of denitrification observed. The isotopic compositions ranged from −1.42‰ to 12.79‰ for δ¹⁵N_NO3 and 0.50‰ to 15.63‰ for δ¹⁸O_NO3. Bayesian isotope mixing model (MixSIAR) analysis indicated that domestic sewage and manure constituted the principal nitrate sources, contributing 37.1% and 56.9% to groundwater and surface water, respectively. Secondary sources included soil organic nitrogen, rainfall and fertilizer NH₄⁺, and chemical fertilizers, while atmospheric deposition showed the lowest contribution rate. Additionally, potential mixing of soil organic nitrogen with chemical fertilizer was identified. Full article