Search Results (5,610)

Deep hard-rock and geothermal drilling expose polycrystalline diamond compact (PDC) cutter chamfers to coupled thermal shock, abrasive wear, and intermittent impact, which accelerates edge spalling and degrades the quality of on-bit monitoring signals. This bench-scale proof-of-concept study evaluates a surface-gradient architecture that combines shallow cobalt leaching in the chamfer region with a thin silicon carbide (SiC) interlayer and a nanocrystalline diamond topcoat. Commercial 13 mm PDC cutters were treated within a surface-gradient design window of $t_{\mathrm{SiC}}=0$–1.0 $\mathsf{\mu }$m and $L_{\mathrm{deCo}}=0$–200 $\mathsf{\mu }$m, and were examined by cross-sectional microscopy, XPS/ToF-SIMS, Raman stress mapping, scratch adhesion, apparent fracture toughness, laser-flash thermal transport, thermal-shock cycling, 400 ${}^{\circ }$C pin-on-disc wear, instrumented impact loading, bench granite-drilling signal acquisition, and finite-element correlation. The optimized configuration ($t_{\mathrm{SiC}}\approx 0.7\mathsf{\mu }\mathrm{m}$, $t_{\mathrm{D}}\approx 5\mathsf{\mu }\mathrm{m}$, and $L_{\mathrm{deCo}}\approx 100\mathsf{\mu }\mathrm{m}$) reduced the 95th-percentile tensile residual stress at the chamfer from about 0.48 to 0.26 GPa, reached a scratch critical load of about 28 N, compared with about 16 N for the topcoat-only condition and about 25 N for the SiC-plus-topcoat condition, cut high-temperature wear volume by about 40%, and shifted the characteristic spalling energy from about 0.8 to 1.3 J. In bench-scale granite drilling, the same design stabilized frictional response and improved simple pre-spall discrimination metrics, raising ROC-AUC from about 0.65 to 0.87. These bench-scale results provide proof-of-concept evidence that surface-gradient design can improve PDC chamfer durability and signal discriminability, while the proposed signal metrics have yet to be validated under field-scale downhole conditions. Full article

Polyurethane cement (PUC) is a high-performance composite that combines the high toughness of polymers with the durability of cementitious materials, showing potential in the field of structural strengthening. However, when used alone, its crack confinement capability is limited. To investigate the strengthening effect of wire mesh–polyurethane cement (WM-PUC) composite on the shear performance of damaged reinforced concrete (RC) beams, static loading tests were conducted on four RC beams. All strengthened beams were preloaded to induce initial damage and subsequently retrofitted on the sides using the two composite materials. Their shear performance was evaluated through single-point monotonic loading. The failure modes, load–displacement curves, shear capacity, and crack development patterns of the strengthened beams were analyzed in detail. The experimental results indicated that after strengthening with PUC and WM-PUC, the shear capacity of the damaged beams was effectively enhanced. The ultimate loads of the damaged beams strengthened with PUC and WM-PUC were 360 kN and 390 kN, respectively, representing increases of 12.5% and 21.88% compared to the unstrengthened beam. Compared to the PUC-strengthened beam, the ultimate load of the WM-PUC-strengthened beam increased by 8.3%, indicating that the incorporation of wire mesh further enhanced the strengthening effectiveness of the polyurethane cement composite. In terms of crack control, WM-PUC strengthening was more effective than PUC strengthening in restraining the initiation and propagation of diagonal cracks. The findings demonstrate that WM-PUC composite exhibits favorable applicability for the shear strengthening of damaged RC beams, with overall performance superior to that of PUC-only strengthening, thereby providing a technical reference for high-performance shear strengthening of existing concrete structures. Full article

High-entropy perovskite oxides attract considerable attention due to their outstanding properties and extensive applications. In this work, the lattice distortion and the mechanical, thermal and electronic structure properties of high-entropy (Ca_0.2Sr_0.2Ba_0.2La_0.2Pb_0.2)TiO₃ (CSBLPT) are investigated through first-principles calculations. The results suggest that the influence of O atoms on lattice distortion is predominant, and the effect of overall A-site atoms plays a distinctly greater role than that of the B-site atoms. The mechanical results show that the high-entropy CSBLPT has a lower Young’s modulus and higher fracture toughness than ternary SrTiO₃. The Debye temperature also indirectly indicates that the thermal expansion coefficient of the studied high-entropy perovskite is greater than that of SrTiO₃. As for thermal conductivity, the obtained result of CSBLPT is also appreciably lower than that of SrTiO₃, and the lowest thermal conductivity is along the [100] direction. The Fermi level of high-entropy CSBLPT is transferred to the conduction band, exhibiting a degenerate n-type semiconductor behavior with metallic-like characteristics, and the Bader charge values are also related to the local lattice distortion, which may cause differences in thermomechanical properties between high-entropy CSBLPT and SrTiO₃. Above all, high-entropy CSBLPT is a preferable TBC material with excellent performance under working conditions compared to SrTiO₃. Full article

To study the influence of polyoxymethylene (POM) fibers on the mechanical properties of shotcrete for tunnel support, this research conducted four-point bending tests on concrete with different POM fiber dosages (0, 5, 7, and 9 kg/m³) and lengths (30 mm, 36 mm, and 42 mm). The mechanical properties are analyzed in terms of failure modes, flexural strength, and the toughness index. The results show that, with the increase fiber length and dosage, the incorporation of POM fibers can enhance the toughness of concrete and significantly improve the flexural performance of shotcrete, with the peak flexural strength increasing by 15.31% to 89.46%. Additionally, through scanning electron microscopy (SEM) image analysis, the reinforcing mechanism of POM fibers is revealed: when shotcrete with POM fibers is subjected to flexural loading, it undergoes four stages: elastic, elastic–plastic, yield, and failure. The addition of POM fibers increases the density and uniformity of concrete, and the flexural strength is indirectly enhanced by increasing frictional energy dissipation through the formation of fiber–matrix interfaces between fibers and concrete. The research findings provide a theoretical basis and design reference for the application of POM fiber-reinforced shotcrete in tunnel support. Full article

This paper provides a comprehensive review on the effects of plant fibers on cement-based materials, focusing on the enhancement of mechanical properties and durability. Plant fibers, as a sustainable and renewable resource, are increasingly recognized for their potential in improving the performance of cement-based composites. The review begins with an exploration of fiber composition and structure, followed by a detailed discussion of interfacial modification strategies that enhance the bond between plant fibers and cement matrices. Key mechanisms such as fiber dispersion, bridging, and internal curing are examined to explain how plant fibers impact hydration, pore structure, and mechanical properties like compressive strength, flexural strength, splitting tensile strength, and impact toughness. The paper also reviews the role of plant fibers in enhancing the durability of cement-based materials, particularly in terms of resistance to alkali degradation, acid attack, freeze–thaw cycles, chloride ion penetration, and self-healing behavior. The findings suggest that plant fibers offer a dual benefit by improving both the mechanical and durability performance of cement-based materials. The paper concludes with recommendations for future research directions, emphasizing the need for better understanding the interactions between plant fibers and cement matrices to optimize the long-term performance of plant fiber-reinforced cementitious composites. Full article

This study investigates the effect of chemical modification of xylite—a fraction derived from Polish lignite—using succinic anhydride (SA) on the morphology and mechanical performance of isotactic polypropylene (iPP) composites. Xylite was incorporated at loadings of 1, 10, and 25 wt% and in two particle size ranges (40–63 µm and 63–125 µm), with and without SA (0.5 and 2 wt%). The composites were characterized by wide-angle X-ray scattering (WAXS), Fourier-transform infrared spectroscopy (FTIR), and tensile testing to evaluate crystallinity (Xc), β-phase content (kβ), and mechanical properties. Unmodified xylite reduced crystallinity (Xc down to ~37%) and significantly decreased ductility, with elongation at break strongly negatively correlated with filler content (r ≈ −0.68), indicating poor dispersion and weak interfacial adhesion. In contrast, SA addition (0.5–2 wt%) partially restored crystallinity (up to ~48%) and increased stiffness (Young’s modulus up to 2120 MPa), while altering β-phase content. FTIR analysis indicated reduced intermolecular hydrogen bonding between xylite surface hydroxyl groups in the presence of SA, consistent with interfacial chemical interactions, likely via esterification. The β-phase content showed a moderate positive correlation with xylite loading (r = +0.43) and a negative correlation with elongation at break (r = −0.46), suggesting that excessive β-phase formation may reduce toughness. Larger particles (63–125 µm) provided slightly improved elongation at break and stiffness. Overall, SA acts as both a compatibilizer and a morphology-directing agent, enabling precise control of the stiffness–ductility balance and crystalline structure in iPP/xylite composites. These results establish chemically modified lignite-derived fillers as a viable strategy for engineering cost-efficient polyolefin materials with tunable structure–property relationships, offering strong potential for scalable industrial implementation. Full article

Superhydrophobic coatings are regarded as a promising passive anti-icing strategy; however, their practical engineering application, particularly in electrical insulation, is severely hindered by the performance deterioration caused by mechanical damage and a lack of theoretical understanding of microscopic ice adhesion mechanisms. In this study, a layered polymer composite coating was designed to resolve the trade-off between abrasion resistance and low ice adhesion. The chemistry of the coating relies on a synergistic “primer–topcoat” design: the primer consists of an epoxy resin matrix chemically modified by amino silicone oil to lower its surface energy and improve toughness, while the topcoat features hierarchical SiO₂ clusters functionalized with hexamethyldisilazane (HMDS) and silane coupling agents. This architecture was fabricated via a controllable layer-by-layer spraying method. Systematic investigations revealed that the hierarchical micro/nanostructure, composed of microscale protrusions and nanoscale SiO₂ clusters, provides excellent superhydrophobicity (contact angle of 155.2°, sliding angle of 2°). Crucially, the crosslinked polymer network and stable siloxane (Si-O-Si) covalent bonding ensure that the coating maintains its functionality after a cumulative sand impact of 3 kg, demonstrating superior mechanical durability. Furthermore, differentiated theoretical models for ice adhesion in Cassie–Baxter and Wenzel states were established based on intermolecular interactions, identifying that maintaining a stable Cassie–Baxter state is key to reducing adhesion. This study offers a robust approach to balancing functionality and durability in polymer composites through synergistic structural design, providing both a scalable fabrication strategy and a quantitative theoretical framework for understanding interfacial ice adhesion. Full article

Meat from cull dairy cows is often used for human consumption; it is well known that tenderness adds value to the market, and dairy cattle meat is usually undervalued. In Mexico, most meat production comes from young bulls, mainly Bos indicus and commercial crossbreeds, whose meat tends to be tough rather than tender. The present study evaluated the association of G530A (CAPN1) and C357G (CAST) polymorphisms (PCR-RFLP) with meat tenderness using the Warner–Bratzler shear force (WBSF) method. Additionally, the color, pH, and marbling of meat cuts from culled Holstein cows were determined at 72 h postmortem. CAPN1 G530A genotype frequencies were GG (50%), AG (46%), and AA (4%), and for CAST C357G, they were CC (36%), CG (42%), and GG (22%); for both SNPs, the Hardy–Weinberg equilibrium was observed. Genotypes for CAPN1G530A and CAST C357G did not have a significant effect on WBSF (p > 0.05). Shear force (kg) for CAPN1 G530A genotypes was 4.02 ± 0.14 (GG), 3.99 ± 0.13 (AG) and 4.43 ± 0 (AA); and for CAST C357G genotypes, it was 4.0 ± 0.17 (CC), 4.09 ± 0.13 (CG) and 3.98 ± 0.11 (GG); the polymorphisms did not affect significantly WBSF, suggesting the limited applicability of these SNPs for meat tenderness in dairy cattle. However, due to the small sample size (n = 50) and especially the low number of CAPN1 AA homozygotes (n = 2), this study should be regarded as a proof-of-concept pilot investigation. The results warrant validation in larger cohorts. Full article

Tough-on-crime policies, including mandatory minimum laws, three-strikes statutes, and habitual offender laws, have contributed to prison overcrowding and the growth of aging prison populations. As incarceration costs for prisoners increase, policymakers have increasingly considered early release policies for older incarcerated adults who pose a low risk of recidivism. This paper reviews recent trends in late-life incarceration and evaluates the policy logic and practical conditions under which early release may serve as a response to aging incarceration. Drawing on existing legal scholarship and prior research, we argue that early release of aging inmates likely represents a feasible and cost-effective strategy for addressing prison overcrowding without compromising public safety. The analysis further identifies the legal, institutional, and policy conditions under which early release programs for older prisoners are most likely to gain legitimacy and political support. By situating aging-related release within broader debates on punishment, proportionality, and public safety, this study contributes to ongoing discussions of sustainable and normatively grounded responses to mass incarceration. Full article

Semi-circular bending tests were conducted on high-elasticity asphalt concrete under different aging conditions to investigate the effects of rubber particles and polyester fiber contents on its fracture properties. Results showed that the incorporation of approximately 3% rubber particles increased the fracture energy by 15%, whereas the addition of 1.2% polyester fibers increased the fracture toughness and fracture energy by 4% and 19%, respectively. Aging-induced oxidative hardening enhanced the overall elastic modulus and interfacial constraint effect of the asphalt mixture, thereby improving the stress transfer efficiency among the rubber particles, polyester fibers, and the surrounding matrix. As a result, both the peak load and fracture toughness increased. However, compared with the unaged state, aged asphalt concrete became more susceptible to brittle fracture, with a decrease in fracture energy and a change in the crack propagation path from a curved to a straight trajectory. Full article

The need to create lightweight materials with better mechanical properties has led to the use of Fiber Reinforced Composites (FRCs)s in the aerospace and automotive industries. The mechanical behavior of FRCs is heterogeneous, especially in conditions of low-velocity impact (LVI). The impact events cause structural damage, where most of the available literature deals with mono- or bi-composites in controlled situations. This work will present the results of studying the behavior of mono, bi- and tri-hybrids with carbon, glass and Kevlar fiber-reinforced epoxy. The sequences of the laminate stacks, number of plies and laminate thickness in the drop weight testing were across velocities of 1.91 to 3.91 m/s at drop heights of 19 to 79 cm. The dominant pillars of LVI, such as peak load, energy absorption and the modes of damage, were analyzed. The glass-dominated laminates peaked at 5.67 kN, while the Kevlar-dominated laminates reached peak flow in ductile collapse with greater quantities of absorbed energy. The leaders in strength and energy were the hybrids of Kevlar–glass (KG) cross-ply at 8.08 kN and 47.28 J and quasi-isotropic Kevlar–carbon–glass (KCG) at 9.12 kN and 47.25 J, showcasing a balance of strength and toughness. The rest, holding a greater quantity of Kevlar, ranging in thickness and cross-plies, were shaped with a load center. The experimental conclusion is that hybridization improved impact resistance and ductility, which is best supported by the glass/carbon rigidity-layered laminates. Such understanding directs the design work of future composite materials for better impact control. Full article

Cast-in-place ground-supported concrete slabs (GSCSs) are used as floors in many facilities such as factories, workshops, garages, and airports (i.e., rigid pavements). These slabs may be subjected to repeated impact loads caused by vehicle loads, the dropping of heavy loads, and aircraft landing loads on runways. This research presents an experimental and numerical study to investigate the behavior of these slabs under impact loads. The experimental program consists of 18 concrete slabs with dimensions of 400 mm × 400 mm × 100 mm. Some variables were studied experimentally, such as the reinforcement ratio of these slabs and the amount of the impact force (represented by the drop height). Unreinforced slabs and slabs reinforced with steel reinforcement or a geogrid mesh made of knitted polyester ribs were tested. ABAQUS software was employed to study the failure mode and crack distribution of these slabs numerically. The accuracy of the proposed numerical model was verified by modeling the tested slabs and comparing the numerical results with the experimental results. From the study results, it is clear that the reinforcement significantly improves the impact performance of GSCSs, transforming their failure behavior from brittle to more ductile and tough. The combined use of impact strength and ductility factors provides an integrated measure of slab performance, offering valuable guidance for the design of protective structures, pavements, and industrial flooring under impact loading. Full article

This review comprehensively examines the incorporation of nanoparticles (NPs) into biopolymers for 3D printing in biomedical applications, integrating material design, processing strategies, and translational considerations within a unified framework. Different types of NPs are analyzed regarding their effects on mechanical reinforcement, rheological modulation, and structural organization of biopolymeric matrices. The discussion covers principal additive manufacturing technologies, including extrusion-based systems such as fused deposition modeling (FDM) and direct ink writing (DIW), vat photopolymerization, powder-bed fusion (SLS), and emerging in situ nanoparticle formation approaches, emphasizing how nanoparticle loading and surface functionalization govern yield stress, shear-thinning behavior, viscoelastic recovery, and dimensional fidelity while mitigating agglomeration and optimizing interfacial interactions. Comparative evaluation of compressive modulus, strength, toughness, crystallinity, and porosity establishes structure–property–processing relationships directly linked to printability and functional performance. Biomedical applications are addressed in tissue engineering, biosensing, controlled and targeted drug delivery, and bioimaging, highlighting the balance between bioactivity and manufacturability. Finally, critical challenges—including compatibility, reproducibility, biological safety, long-term stability, regulatory adaptation, and environmental impact—are discussed, alongside future perspectives focused on green nanomaterials, AI-driven predictive formulation design, and digital twins for real-time monitoring and quality control in nano-enabled additive manufacturing. Full article

Additive manufacturing (AM) using powder bed fusion (PBF) has been the predominant printing method used over the last decade. The capability of this approach to produce complex parts with high precision has attracted the attention of major industries as a potential tool for replacing traditional manufacturing technologies. 15-5 PH stainless steel is one of the alloys being studied as a candidate for PBF processes. Its superior strength and corrosion resistance have made it a highly attractive option in numerous industries, including the automotive, nuclear, and petrochemical industries. To enhance the properties of 15-5 PH stainless-steel AM parts following printing, one can use a thermal treatment such as age hardening. However, very little research exists regarding the functional properties of AM parts made from this alloy after heat treatment. This study aims to evaluate the effect of H1150M age hardening heat treatment following printing on the properties of 15-5 PH steel, particularly regarding its mechanical properties and environmental behavior. The microstructure was studied using both optical and electron microscopy, along with X-ray diffraction (XRD) analysis. The mechanical properties were examined by tensile testing and fracture toughness assessment. Corrosion behavior was analyzed in terms of potentiodynamic polarization and using impedance spectroscopy. The results obtained have shown that over-aging caused by H1150M heat treatment has a detrimental effect on the mechanical and environmental behavior of the tested alloy. This was primarily attributed to the formation of an austenitic phase within the inherent martensitic matrix, the generation of brittle phases (mainly carbonitrides of Cr and Nb) and a reduction in grain size. Full article

In order to verify the feasibility of in situ repair of underwater local dry laser welding (ULDLW) on nuclear power reactor components, this work investigates the microstructure and mechanical properties of 304L austenitic stainless steel repaired by ULDLW using ER308L filler metal. Comprehensive comparison would be made between the ULDLW and conventional in-air laser welding to evaluate their applicability. The results demonstrate that the rapid cooling rate inherent to the underwater environment significantly influences solidification behavior and microstructural evolution. The weld metal (WM) solidifies in the ferritic–austenitic (FA) mode, with an increased proportion of lathy δ-ferrite at the expense of skeletal morphology compared to the in-air welds. Electron backscatter diffraction (EBSD) analysis reveals the substantial grain refinement in underwater welds, with average grain sizes of 39.4 μm versus 47.3 μm for in-air weld bead, accompanied by a higher fraction of low-angle grain boundaries (LAGBs). These microstructural modifications yield superior mechanical properties: underwater weld bead exhibits ultimate tensile strength (UTS) of 685.6 MPa, elongation of 57.5%, and impact toughness of 22.6 J, significantly exceeding the corresponding values for in-air welds (663.9 MPa, 51.8%, and 18.6 J, respectively). Fractographic analysis confirms ductile fracture mechanisms in both conditions. The enhanced performance is attributed to grain refinement strengthening via the Hall–Petch relationship and the increased LAGBs fraction, which impedes dislocation motion and crack propagation. Full article