Search Results (478)

Boil-off from cryogenic liquids is a significant economic, operational, and safety challenge across the global energy industry, yet existing models lack the scope and predictive capability needed to simulate boil-off across a range of fluids and storage conditions. This work introduces a new, one-dimensional lumped parameter model for predicting boil-off from a variety of fluids under a range of storage conditions. The new model divides the liquid into discrete, homogeneous layers coupled by a set of heat and mass transfer equations and can capture liquid-phase thermal stratification effects and compositional changes as the tank both self-pressurises and operates isobarically. During pressurisation, the model simulates convection within the liquid by dividing it into conduction and convection domains and calculating boundary layer and recirculation flowrates within the latter. During isobaric operation, the model applies a shortcut convection term that allows ambient heat ingress into a layer to be transferred to the liquid surface where it generates boil-off instead of heating the liquid. Unlike previously published works, this model does not require manipulation of adjustable parameters to describe pressurisation and boil-off rates relative to experimental data. It thus offers improved predictive capability compared to existing homogeneous-phase models, with applications to the design of boil-off handling systems, maritime shipping, and long-term storage of cryogenic liquids. Full article

The use of liquid hydrogen (LH₂) as a zero-emission energy carrier is increasingly relevant for next-generation transport systems, requiring reliable cryogenic storage solutions operating at approximately −253 °C. This study presents a computational analysis of LH₂ storage tanks, focusing on the coupled thermal–structural behavior of insulated cryogenic vessels under varying design parameters. The present work expands upon our previous effort by employing the Finite Element Method (FEM) to perform a parametric investigation of these tanks. This is accomplished by examining the effect of the insulating material and the change in the storage volume of LH₂, as well as the change in the selected hydrogen boil-off rate (BOR). Results show that increasing the BOR from 0.1%/h to 1.0%/h reduces the required insulation thickness and mass by approximately 90% across all configurations, significantly altering system-level mass distribution. Substituting polyurethane foam (PUR-64) with lower-density equivalent (PUR-32) yields heat-flow reductions of up to 19.5% in two configurations, while producing an unexpected increase of approximately 10% in one case due to nonlinear thermal-gradient effects. Furthermore, increasing the hydrogen storage volume from 50 m³ to 150 m³ enhances gravimetric efficiency by 58%, 75%, and up to 104% depending on tank geometry. The results demonstrate the demand for robust numerical models, due to the nonlinear dependence of the materials involved with temperature. Full article

End-of-life thermoset composite coatings removed from fuel storage infrastructure represent a difficult waste stream because they combine a cross-linked polymer matrix, glass fibre reinforcement, functional layers and possible contamination from long-term contact with petroleum products. This study presents a preliminary assessment of an epoxy-glass laminate removed from the internal surface of a large vertical diesel fuel storage tank. The work combined a simplified numerical analysis of the technical role of the coating with thermogravimetric analysis and microscopic examination of solid residues after thermal conversion. The numerical results confirmed that the coating had a real reinforcing function, reducing the maximum equivalent stress in the corroded steel shell from 228.80 MPa to 191.85 MPa. TG/DTG analysis showed that the main mass loss of the laminate occurred below 500–600 °C, while the residual mass depended strongly on the process atmosphere. The highest residue was obtained after pyrolysis (28.75%), followed by CO₂-assisted conversion (26.17%) and combustion (20.87%). Microscopic observations showed that pyrolysis favoured morphological preservation of the fibrous/mineral fraction, but the glass fibres remained partly associated with carbonised epoxy resin and graphite-containing particles. Combustion removed the organic fraction more completely, but the remaining fibres showed signs of degradation. The results indicate that pyrolysis should be treated as a promising preliminary pretreatment route when morphological preservation of the fibrous/mineral fraction is prioritised, although the retained mechanical performance and phase composition of the fibres were not assessed. The study should be regarded as a thermogravimetric and microscopic screening of a real post-service epoxy-glass coating, supporting preliminary selection of end-of-life management pathways rather than a complete recycling or environmental assessment. By linking the thermal behaviour of a real post-service composite coating with feasible end-of-life pathways, the study contributes to sustainable waste management by supporting more informed decisions on material preservation, energy recovery, industrial co-processing and avoidance of landfilling for difficult thermoset composite wastes. Full article

The safety and stability of onboard Liquid Hydrogen (LH₂) storage systems depend strongly on gas–liquid two-phase flow, heat transfer, and phase change under sloshing; however, the coupled influence of filling ratio and sloshing on thermo-hydrodynamic behavior remains underexplored. We develop a Volume of Fluid (VOF)-based two-phase Computational Fluid Dynamics (CFD) model in ANSYS Fluent to quantify interfacial dynamics, pressure response, and temperature-field evolution in LH₂ tanks subjected to sinusoidal acceleration for filling ratios from 10% to 90%. Increasing the filling ratio strengthens net condensation in the ullage and thus intensifies depressurization. As the filling ratio increases from 10% to 90%, the pressure reduction over the 2.0 s sloshing process increases from 0.418 kPa to 2.410 kPa, and the corresponding initial depressurization rate rises from 0.209 to 1.205 kPa s⁻¹. Free-surface motion decreases with filling ratio: at 10%, large interface excursions can induce gas-cavity formation and splashing, increasing the risk of intermittent propellant supply, whereas at 90% the interface is constrained and oscillations are suppressed. Higher filling ratios lead to faster ullage cooling and larger temperature oscillations. The liquid warms modestly, and its warming rate decreases nonlinearly with filling ratio, consistent with the larger effective thermal mass at higher fillings. Overall, the obtained mechanistic understanding can support the engineering design of onboard LH₂ tanks, including filling-ratio selection and thermal-management optimization under sloshing conditions. Full article

During fast-fill, large type IV polymer composite hydrogen storage tanks experience significant temperature gradients associated with both the compression of the gas and a Joule–Thomson effect that can compromise vessel integrity, significantly affecting overall safety. In order to remedy this concern, the current work proposes a novel active mixing approach in which the tank rotates, which leads to enhanced internal convective heat transfer and consequently minimizes temperature gradients. Transient CF simulations were performed using the Redlich–Kwong real-gas equation of state, capturing the high-pressure thermodynamic behavior of hydrogen precisely. The study, based on the 1000 s fast-refueling of a tank of 20.56 m³ internal volume, was carried out to assess the tangential speeds of rotation at 10, 30, and 50 rad/s, respectively. Results also show that thermal performance has a strongly nonlinear dependence on rotational speed. At 10 rad/s, a reasonably even temperature profile develops with a much lower energy cost. The most significant suppression of peak temperatures, and therefore the most efficient cooling, is seen at 30 rad/s. Nevertheless, when the rotation speed further elevates to 50 rad/s, abundant viscous dissipation heating results in an unwanted secondary temperature increase while partially counteracting the benefits brought about by improved mixing. On the whole, the results indicate that an ideal operating window more closely correlated with 30 rads/s is seen to provide the most beneficial compromise between temperature uniformity, maximum temperature limitation, and energy consumption for rapid refueling of large composite hydrogen storage systems. Full article

Focusing on the thermodynamic response of onboard liquid hydrogen tanks under dynamic sloshing conditions, this study investigates the flow-thermal coupling mechanism between the gas-phase space and the main chamber by establishing a numerical model that includes the gas-phase space. The results show that the gas-phase space enhances the initiative and efficiency of system pressure regulation through pressure-difference-driven mass transfer. The evolution of the gas–liquid two-phase temperature field sequentially undergoes four typical stages: pressure-difference-driven jet dominance, thermal stratification maintenance, turbulent mixing, and thermal stratification disappearance. The magnitude of the initial pressure difference significantly affects the temperature response and pressure equilibration time of the two chambers. The gas-phase space achieves thermal uniformity in approximately 4.1 s under sloshing, demonstrating its role as a “dynamic thermal buffer.” The research reveals the critical function of the gas-phase space in the dynamic thermal management of liquid hydrogen storage tanks, providing guidance for enhancing the safety and stability of the onboard hydrogen storage system. Full article

Marine transportation and storage of liquid hydrogen (LH2) has gained increasing interest, while potential LH2 membrane-type tanks could utilize 316L corrugated austenitic stainless-steel sheets. The corrugation process results in a strain-induced martensitic transformation in the material, introducing rapid diffusion pathways for hydrogen atoms and promoting the formation of hydrogen-trapping sites that alter hydrogen transport and reduce the material’s resistance to hydrogen embrittlement. In this study, 316L sheets were subjected to different levels of uniaxial pre-strain (10, 20, 30, and 40%) with two different strain-rates, to replicate the varying degrees of pre-deformation caused by the corrugation. Microstructural analysis using Electron Backscatter Diffraction (EBSD) (Thermo Fisher Scientific, Waltham, MA, USA) and X-Ray Diffraction (XRD) (Bruker, Billerica, MA, USA) combined with quantitative phase analysis using the Rietveld Method on XRD data, provided valuable insights into the induced phase transformations. Cathodic hydrogen charging method was implemented on as-received and pre-strained material, followed by slow strain rate tensile testing (SSRT) and thermal desorption spectroscopy (TDS) to examine the hydrogen effect on each condition. Experimental results indicated that although 316L exhibits considerable phase stability, it undergoes strain-induced phase transformation resulting in a significant amount of martensite, reaching 5% in the 40% pre-strained condition. Pre-deformation increased hydrogen embrittlement, as evidenced by fractographic analysis which indicated a Relative Reduction of Area (RRA) of 0.83, and by increased hydrogen uptake. These findings contribute to a better understanding of phase transformations and the role of hydrogen in austenitic stainless steels. Full article

Hydrogen refueling protocols such as SAE J2601 are designed to limit the temperature rise of hydrogen within the storage tank during refueling. However, the temperature distribution inside the tank is inherently non-uniform, and resulting thermal stratification may cause local temperatures to exceed prescribed limits when the protocol is applied based solely on measurements from a single thermocouple. Therefore, it is very important to estimate the maximum temperature behavior inside the tank during the filling process. A total of 64 CFD simulations are carried out to investigate the effect of the spatial temperature inhomogeneity. The results reveal that the temperature limit (<85 °C) imposed by SAE J2601 is satisfied even by the maximum temperatures in all the 64 cases. However, in some cases for the largest tank (10 kg) filling, it is found that the mass flow rate limit (<60 g/s) is exceeded at low initial pressure conditions. Mass flow rates of 75 g/s or more are calculated under conditions of 25 °C or lower. The increased mass flow rate is understood as the effect of assumption that the pressure drop from a hydrogen refueling station to the inlet of an on-board tank is neglected. Full article

The frequent occurrence of extreme climate events poses a severe challenge to the reliability of building energy systems. Hydrogen energy, with its long-term storage capacity, has become a key technology carrier for enhancing building resilience. This study constructs a resilience–environment–economy co-optimization framework that couples dynamic simulation and emergy analysis. Through a five-in-one approach of physical modeling, climate scenario generation, resilience quantification, emergy accounting, and multi-objective optimization, the resilience performance of building hydrogen energy systems under the scenario of extreme heat waves combined with grid failure is evaluated. The results show that the thermal time constant deviation of the electrolyzer is 4.06%, the correlation coefficient between the generated heat wave scenario sequence and the historical measured data is 0.94, the prediction deviation of the once-in-a-century extreme temperature is 0.5%, the environmental load rate is 4.33, the Pareto front contains 127 non-dominated solutions, and the comprehensive performance of the co-optimal solution is improved by 42% to 88%. Engineering suggestions: For public buildings in hot summer and cold winter regions, the hydrogen energy system should adopt a configuration of 50–60 kW electrolyzers and 50–70 kg hydrogen storage tanks, with a key load guarantee rate of no less than 95%, and the ecological cost is 35% lower than that of diesel backup. This study provides a quantitative decision-making tool for the resilience planning of building hydrogen energy systems under extreme climate conditions and can be extended to other high climate risk areas. Full article

Effective thermal insulation of cryogenic liquid hydrogen (LH₂) storage tanks remains a critical engineering challenge, as conventional vacuum-based or monolithic systems are constrained by manufacturing complexity, mechanical vulnerability, and poor geometric adaptability. This study presents the design and numerical verification of a four-layer octagonal composite thermal shield fabricated via additive manufacturing: an AA5083 structural layer (5 mm), a boron nitride-doped ceramic plate (1 mm), up to 290 stacked graphene sheets in a sealed compartment, and an outer Fe₃S₄-TiO₂ nanocomposite layer (~30 µm). Steady-state and transient FEA in ANSYS evaluated three convective boundary conditions (h = 10, 15, and 20 W/m²·K), with the inner wall fixed at 20 K. Temperature distributions remained essentially invariant across all cases (20 K inner, ~20.12 K outer), confirming that thermal performance is governed by the multilayer architecture rather than convective intensity. The shield achieved a mean heat flux of 1684 W/m², R_total ≈ 0.163 m²K/W, and a boil-off rate of 13.9 g/hour. Comparative FEA against NASA US9617069 (q = 193.35 W/m²) and JP2018-119634A (q = 37.975 W/m²) highlights the compactness advantage of the proposed 6 mm shield; the coupled thermo-structural assessment yielded a safety factor of 64,182, confirming elastic-regime operation at 20 K. Full article

In Brazil, more than 80% of households rely on electricity for water heating, representing approximately 13% of residential electricity consumption and significantly contributing to peak grid demand. As a prominent alternative for supplying household thermal energy and reducing grid stress, this study experimentally evaluates, under tropical climate conditions, the performance of a modular water-based photovoltaic–thermal (PVT) system and compares it with a conventional photovoltaic (PV) system operating simultaneously under identical environmental conditions. The PVT system, based on commercial PV modules coupled to roll-bond heat exchangers, a storage tank, and a shower outlet, was tested under three hydraulic regimes: natural thermosiphon, closed-loop, and Forced circulation. A dedicated ESP32-based data acquisition system, integrated with a cloud platform, continuously monitors electrical, thermal, and meteorological variables. Results show that PVT modules exhibit a small electrical efficiency reduction due to increased cell temperatures, which is largely compensated by the simultaneous thermal generation, yielding overall efficiency gains of 74.04%, 76.53%, and 7.62% over the reference PV system for Normal, Forced, and Closed circulation, respectively. The comparative analysis identifies Forced-circulation scheduling and the matching between thermal generation and consumption as key factors for performance optimization. The findings provide practical guidelines for deploying PVT systems to replace electric showers in tropical regions, reducing residential electricity consumption and mitigating peak-demand stress on the grid. Full article

This study analyzes the impact of thermal and electrical storage solutions coupled with Photovoltaic (PV) and Concentrating Solar Power (CSP) plants, proposing an innovative model to test a Hybrid Energy Storage System (HESS). The work presents an innovative Mixed Integer Linear Programming (MILP) model to determine the optimal configuration and operational strategy of a HESS within a grid-connected Microgrid (MG). The research focuses on the synergistic integration of PV with Lithium-ion Electrical Energy Storage (EES) and CSP with Thermal Energy Storage (TES). The MG includes dynamic residential, commercial, and hospital loads. The MILP model is optimized over a 24 h horizon across four season-representative days, utilizing a multi-criteria objective function that balances economic performance and CO₂ emissions via a weighting factor ω ∈ [0, 1]. Three distinct CSP options such as Parabolic Trough Collectors with varying Heat Transfer Fluids (molten salt or thermal oil) and TES types (direct and indirect dual-tank, or Phase Change Material) are analyzed, each coupled with a Rankine or Organic Rankine Cycle. Key constraints address energy balances, component efficiencies, power limits, and storage dynamics. The comprehensive results identify the most suitable technology portfolio mix and optimal hour-by-hour operational rules, providing transparent decision-making criteria based on storage size, process temperatures, and specific demand profiles. Full article

In a tank farm, even if the separation distance meets the codes and standards, a pool fire in one tank may spread quickly to another tank. Most destructive and uncontrollable fire accidents are induced with multiple pool fires. In current work, the thermal buckling behaviors of a fixed-roof tank subjected to one (two) neighboring pool fire(s) (burning tanks) are numerically studied. The effects of the number of the pool fires, the separation distance between two pool fires, and the distance between the adjacent tank and pool fires are analyzed. The results indicate that the thermal buckling zone of the target tank subjected to two pool fires is larger than that subjected to one pool fire, and the maximum displacement for two pool fires is almost equal to that for one pool fire. The target tank subjected to one pool fire loses stability and reaches a new stable state faster than that subjected to two pool fires. The thermal buckling zone expands as the distance between the two pool fires increases but decreases with increasing separation distance between the pool fire and the target tank. The findings provide useful guidance for the structural optimization of steel storage tanks against pool fire exposure and offer theoretical support for emergency response and fire rescue in tank farms. Full article

The growing global demand for cooling technologies, driven by climate change and increasing energy consumption, creates a need for effective solutions to reduce energy use and carbon footprint. One promising approach is the application of Cold Thermal Energy Storage (CTES) systems, which enable the temporal shifting of electricity demand and the optimization of cooling system operation. This paper presents an experimental analysis of a hybrid PCM–water storage tank using the commercially available material RT11HC (Rubitherm^®). The measurement results demonstrated that the integration of PCMs increases the duration of thermal comfort provision and enhances system flexibility, while an appropriate PCM fraction significantly affects the dynamics of cold energy storage and release. The introduction of a copper matrix as a heat transfer enhancement element accelerated the phase change process by more than 20% and ensured a more uniform charging and discharging behavior of the storage tank. A numerical simulation performed in ANSYS software confirmed the experimental results with minimal deviations. The proposed hybrid storage tank concept demonstrates high application potential in both building and industrial applications, contributing to reduced energy demand and supporting sustainable operation. Full article

To improve the flexibility of coal-fired power units and support renewable energy integration, molten salt thermal storage has been widely considered a promising retrofit option. However, under unified operating conditions, the comparative effects of different heat-release pathways and steam extraction ratios on flexibility, full-cycle thermodynamic performance, and economic performance have not been sufficiently clarified. In this study, a thermodynamic model of a 600 MW subcritical coal-fired power unit coupled with a two-tank molten salt thermal storage system was established in Ebsilon and validated against the design heat-balance data under typical load conditions, with maximum relative deviations of 0.06% for power output, 0.95% for main steam flow rate, and 1.24% for heat consumption rate. Three representative heat-release pathways were comparatively investigated under identical heat-storage conditions, with steam extraction ratios ranging from 2% to 18%. The results show that increasing the extraction ratio raises the thermal storage capacity from 9.762 to 84.636 MWh and enhances the downward peak-shaving capability, but weakens the full-cycle thermodynamic performance. Among the three schemes, Scheme 2 exhibits the strongest upward peak-shaving performance, with upward peak-shaving energy increasing from 2.893 to 24.395 MWh, and also yields the highest annual net profit (0.546–4.342 million CNY). Scheme 3 exhibits the best full-cycle thermal and exergy efficiencies, with full-cycle thermal efficiency of 42.76–41.56% and full-cycle exergy efficiency of 38.34–37.27%. In addition, Schemes 1 and 2 show significantly higher round-trip efficiencies than Scheme 3, with Scheme 2 becoming more advantageous at higher extraction ratios. Scheme 1 exhibits the shortest static payback period (7.12–7.63 years) and the highest internal rate of return (12.77–11.65%). These results indicate that the three schemes have distinct advantages in peak-shaving performance, full-cycle thermodynamic performance, and economic performance, and provide a comparative basis for engineering selection and parameter optimization of molten-salt-based flexibility retrofits in coal-fired power units. Full article