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24 pages, 3066 KB  
Article
Online Parameter Identification of a Fractional-Order Chaotic System for Lithium-Ion Battery RC Equivalent Circuit Using a State Observer
by Yanzeng Gao, Donghui Xu, Haiou Wen and Liqin Xu
Batteries 2025, 11(10), 377; https://doi.org/10.3390/batteries11100377 - 16 Oct 2025
Viewed by 198
Abstract
Due to the highly nonlinear, dynamic, and slowly time-varying nature of lithium-ion batteries (LIBs) during operation, achieving accurate and real-time parameters online identification in first-order RC equivalent circuit models (ECMs) remains a significant challenge, including low accuracy and poor real-time performance. This paper [...] Read more.
Due to the highly nonlinear, dynamic, and slowly time-varying nature of lithium-ion batteries (LIBs) during operation, achieving accurate and real-time parameters online identification in first-order RC equivalent circuit models (ECMs) remains a significant challenge, including low accuracy and poor real-time performance. This paper establishes a fractional-order chaotic system for first-order RC-ECM based on a charge-controlled memristor. The system exhibits chaotic behavior when parameters are tuned. Then, based on the principle of the state observer, an identification observer is designed for each unknown parameter of the first-order RC-ECM, achieving online identification of these unknown parameters of the first-order RC-ECM of LIB. The proposed method addresses key limitations of traditional parameter identification techniques, which often rely on large sample datasets and are sensitive to variations in ambient temperature, road conditions, load states, and battery chemistry. Experimental validation was conducted under the HPPC, DST, and UDDS conditions. Using the actual terminal voltage of a single cell as a reference, the identified first-order RC-ECM parameters enabled accurate prediction of the online terminal voltage. Comparative results demonstrate that the proposed state observer achieves significantly higher accuracy than the forgetting factor recursive least squares (FFRLS) algorithm and Kalman filter (KF) algorithm, while offering superior real-time performance, robustness, and faster convergence. Full article
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21 pages, 3305 KB  
Article
A Power Flow Sensitivity-Based Approach for Distributed Voltage Regulation and Power Sharing in Droop-Controlled DC Distribution Networks
by Nan Jiang, He Gao, Xingyu Zhang, Zhe Zhang, Yufei Peng and Dong Liang
Energies 2025, 18(20), 5382; https://doi.org/10.3390/en18205382 - 13 Oct 2025
Viewed by 160
Abstract
Aiming at the challenges of design complexity and parameter adjustment difficulties in existing distributed controllers, a novel power flow sensitivity-based distributed cooperative control approach is proposed for voltage regulation and power sharing in droop-controlled DC distribution networks (DCDNs). Firstly, based on the power [...] Read more.
Aiming at the challenges of design complexity and parameter adjustment difficulties in existing distributed controllers, a novel power flow sensitivity-based distributed cooperative control approach is proposed for voltage regulation and power sharing in droop-controlled DC distribution networks (DCDNs). Firstly, based on the power flow model of droop-controlled DCDNs, a comprehensive sensitivity model is established that correlates bus voltages, voltage source converter (VSC) loading rates, and VSC reference power adjustments. Leveraging the sensitivity model, a discrete-time linear state-space model is developed for DCDNs, using all VSC reference power as control variables, along with the weighted sum of the voltage deviation at the VSC connection point and the loading rate deviation of adjacent VSCs as state variables. A distributed consensus controller is then designed to alleviate the communication burden. The feedback gain design problem is formulated as an unconstrained multi-objective optimization model, which simultaneously enhances dynamic response speed, suppresses overshoot and oscillation, and ensures stability. The model can be efficiently solved by global optimization algorithms such as the genetic algorithm, and the feedback gains can be designed in a systematic and principled manner. The simulation results on a typical four-terminal DCDN under large power disturbances demonstrate that the proposed distributed control method achieves rapid voltage recovery and converter load sharing under a sparse communication network. The design complexity and parameter adjustment difficulties are greatly reduced without losing the control performance. Full article
(This article belongs to the Section A1: Smart Grids and Microgrids)
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11 pages, 2701 KB  
Article
Simulation-Based Performance Assessment of Bulk Junctionless FET with Asymmetric Source/Drain for Ultrasensitive Detection of Biomolecules
by Jeongmin Son, M. Meyyappan and Kihyun Kim
Biosensors 2025, 15(9), 597; https://doi.org/10.3390/bios15090597 - 10 Sep 2025
Viewed by 420
Abstract
Bio field-effect transistors (BioFETs) have attracted attention for their ability to rapidly detect physiological data with a simple structure. While conventional BioFETs offer high sensitivity, they often require reference electrodes or involve complex fabrication processes. A recently proposed bulk junctionless BioFET (Bulk JL-BioFET) [...] Read more.
Bio field-effect transistors (BioFETs) have attracted attention for their ability to rapidly detect physiological data with a simple structure. While conventional BioFETs offer high sensitivity, they often require reference electrodes or involve complex fabrication processes. A recently proposed bulk junctionless BioFET (Bulk JL-BioFET) features a simple fabrication process to address these issues. This structure utilizes a depletion region formed by a p-n junction, as the active layer is directly in contact with a substrate of the opposite type. As a result, the device can operate effectively with only two terminals—drain and source—without the need for a reference electrode. In this study, we propose a novel Bulk JL-BioFET, incorporating a doped field stop layer and an asymmetric source/drain structure, and verify its performance through simulations. The doped field stop layer blocks the electric field expansion, enhancing channel modulation, while the asymmetric source/drain structure promotes electron injection, reducing the on-off swing voltage and turn-on voltage. This improves the electrical performance, enabling lower power consumption and higher sensitivity. Simulation results show that the combination of these two novel features results in a sensitivity increase of approximately 30-fold. Moreover, high sensitivity was observed below the turn-on voltage region for all the structures when analyzing the sensitivity with overdrive voltage, identifying the optimal operating conditions. This study suggests that the combination of the doped field stop layer and asymmetric source/drain structure is an effective design strategy to maximize the sensing performance of BioFETs while minimizing power consumption. Full article
(This article belongs to the Special Issue Transistor-Based Biosensors and Their Applications)
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30 pages, 7066 KB  
Article
Development and Analysis of a Fast-Charge EV-Charging Station Model for Power Quality Assessment in Distribution Systems
by Pathomthat Chiradeja, Suntiti Yoomak, Panu Srisuksai, Jittiphong Klomjit, Atthapol Ngaopitakkul and Santipont Ananwattanaporn
Appl. Sci. 2025, 15(17), 9645; https://doi.org/10.3390/app15179645 - 2 Sep 2025
Viewed by 878
Abstract
With the rapid rise in electric vehicle (EV) adoption, the deployment of EV charging infrastructure—particularly fast-charging stations—has expanded significantly to meet growing energy demands. While fast charging offers the advantage of reduced charging time and improved user convenience, it imposes considerable stress on [...] Read more.
With the rapid rise in electric vehicle (EV) adoption, the deployment of EV charging infrastructure—particularly fast-charging stations—has expanded significantly to meet growing energy demands. While fast charging offers the advantage of reduced charging time and improved user convenience, it imposes considerable stress on existing power distribution systems due to its high power and current requirements. This study investigated the impact of EV fast charging on power quality within Thailand’s distribution network, emphasizing compliance with accepted standards such as IEEE Std 519-2014. We developed a control-oriented EV-charging station model in power systems computer-aided design and electromagnetic transients, including DC (PSCAD/EMTDC), which integrates grid-side vector control with DC fast-charging (CC/CV) behavior. Active/reactive power setpoints were mapped onto dq current references via Park’s transformation and regulated by proportional integral (PI) controllers with sinusoidal pulse-width modulation (SPWM) to command the voltage source converter (VSC) switches. The model enabled dynamic studies across battery state-of-charge and staggered charging schedules while monitoring voltage, current, and total harmonic distortion (THD) at both transformer sides, charger AC terminals, and DC adapters. Across all scenarios, the developed control achieved grid-current THDi of <5% and voltage THD of <1.5%, thereby meeting IEEE 519-2014 limits. These quantitative results show that the proposed, implementation-ready approach maintains acceptable power quality under diverse fast-charging patterns and provides actionable guidance for planning and scaling EV fast-charging infrastructure in Thailand’s urban networks. Full article
(This article belongs to the Topic Innovation, Communication and Engineering)
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16 pages, 2734 KB  
Article
A 13-Bit 100 kS/s Two-Step Single-Slope ADC for a 64 × 64 Infrared Image Sensor
by Qiaoying Gan, Wenli Liao, Weiyi Zheng, Enxu Yu, Zhifeng Chen and Chengying Chen
Eng 2025, 6(8), 180; https://doi.org/10.3390/eng6080180 - 1 Aug 2025
Viewed by 486
Abstract
An Analog-to-Digital Converter (ADC) is an indispensable part of image sensor systems. This paper presents a silicon-based 13-bit 100 kS/s two-step single-slope analog-to-digital converter (TS-SS ADC) for infrared image sensors with a frame rate of 100 Hz. For the charge leakage and offset [...] Read more.
An Analog-to-Digital Converter (ADC) is an indispensable part of image sensor systems. This paper presents a silicon-based 13-bit 100 kS/s two-step single-slope analog-to-digital converter (TS-SS ADC) for infrared image sensors with a frame rate of 100 Hz. For the charge leakage and offset voltage issues inherent in conventional TS-SS ADC, a four-terminal comparator was employed to resolve the fine ramp voltage offset caused by charge redistribution in storage and parasitic capacitors. In addition, a current-steering digital-to-analog converter (DAC) was adopted to calibrate the voltage reference of the dynamic comparator and mitigate differential nonlinearity (DNL)/integral nonlinearity (INL). To eliminate quantization dead zones, a 1-bit redundancy was incorporated into the fine quantization circuit. Finally, the quantization scheme consisted of 7-bit coarse quantization followed by 7-bit fine quantization. The ADC was implemented using an SMIC 55 nm processSemiconductor Manufacturing International Corporation, Shanghai, China. The post-simulation results show that when the power supply is 3.3 V, the ADC achieves a quantization range of 1.3 V–3 V. Operating at a 100 kS/s sampling rate, the proposed ADC exhibits an effective number of bits (ENOBs) of 11.86, a spurious-free dynamic range (SFDR) of 97.45 dB, and a signal-to-noise-and-distortion ratio (SNDR) of 73.13 dB. The power consumption of the ADC was 22.18 mW. Full article
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28 pages, 4399 KB  
Article
Enhancing Lithium Titanate Battery Charging: Investigating the Benefits of Open-Circuit Voltage Feedback
by Danijel Pavković, Mihael Cipek, Karlo Kvaternik, Nursultan Faiz and Alua Shambilova
Energies 2025, 18(15), 3946; https://doi.org/10.3390/en18153946 - 24 Jul 2025
Viewed by 666
Abstract
In applications where it is crucial that a battery is recharged from the partially discharged state in the minimum time, it is crucial to honor the technological constraints related to maximum safe battery terminal voltage and maximum continuous charging current prescribed by the [...] Read more.
In applications where it is crucial that a battery is recharged from the partially discharged state in the minimum time, it is crucial to honor the technological constraints related to maximum safe battery terminal voltage and maximum continuous charging current prescribed by the battery cell manufacturer. To this end, this contribution outlines the design and comprehensive simulation analysis of an adaptive battery charging system relying on battery open-circuit voltage estimation in real time. A pseudo-random binary sequence test signal and model reference adaptive system are used for the estimation of lithium titanate battery cell electrical circuit model parameters, with the design methodology based on the Lyapunov stability criterion. The proposed adaptive charger is assessed against the conventional constant-current/constant-voltage charging system. The effectiveness of the real-time parameter estimator, along with both the adaptive and traditional charging systems for the lithium titanate battery cell, is validated through simulations and experiments on a dedicated battery test bench. Full article
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19 pages, 12234 KB  
Article
Non-Singular Terminal Sliding Mode Control for a Three-Phase Inverter Connected to an Ultra-Weak Grid
by Abdullah M. Noman, Abu Sufyan, Mohsin Jamil and Sulaiman Z. Almutairi
Electronics 2025, 14(14), 2894; https://doi.org/10.3390/electronics14142894 - 19 Jul 2025
Viewed by 337
Abstract
The quality of a grid-injected current in LCL-type grid-connected inverters (GCI) degrades under ultra-weak grid conditions, posing serious challenges to the stability of the GCI system. For this purpose, the sliding mode control (SMC) approach has been utilized to integrate DC energy seamlessly [...] Read more.
The quality of a grid-injected current in LCL-type grid-connected inverters (GCI) degrades under ultra-weak grid conditions, posing serious challenges to the stability of the GCI system. For this purpose, the sliding mode control (SMC) approach has been utilized to integrate DC energy seamlessly into the grid. The control performance of a GCI equipped with an LCL filter is greatly reduced when it is operating in a power grid with varying impedance and fluctuating grid voltages, which may result in poor current quality and possible instability in the system. A non-singular double integral terminal sliding mode (DIT-SMC) control is presented in this paper for a three-phase GCI with an LCL filter. The proposed method is presented in the α, β frame of reference without adopting an active or passive damping approach, reducing the computational burden. MATLAB/Simulink Version R2023b is leveraged to simulate the mathematical model of the proposed control system. The capability of the DIT-SMC method is validated through the OPAL-RT hardware-in-loop (HIL) platform. The effectiveness of the proposed method is first compared with SMC and integral terminal SMC, and then the DIT-SMC method is rigorously analyzed under resonance frequency events, grid impedance variation, and grid voltage distortions. It is demonstrated by the experimental results that the proposed control is highly effective in delivering a high-quality current into the grid, in spite of the simultaneous occurrence of power grid impedance variations in 6 mH and large voltage distortions. Full article
(This article belongs to the Topic Power Electronics Converters, 2nd Edition)
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16 pages, 2521 KB  
Article
A Multimodal CMOS Readout IC for SWIR Image Sensors with Dual-Mode BDI/DI Pixels and Column-Parallel Two-Step Single-Slope ADC
by Yuyan Zhang, Zhifeng Chen, Yaguang Yang, Huangwei Chen, Jie Gao, Zhichao Zhang and Chengying Chen
Micromachines 2025, 16(7), 773; https://doi.org/10.3390/mi16070773 - 30 Jun 2025
Viewed by 1075
Abstract
This paper proposes a dual-mode CMOS analog front-end (AFE) circuit for short-wave infrared (SWIR) image sensors, which integrates a hybrid readout circuit (ROIC) and a 12-bit two-step single-slope analog-to-digital converter (TS-SS ADC). The ROIC dynamically switches between buffered-direct-injection (BDI) and direct-injection (DI) modes, [...] Read more.
This paper proposes a dual-mode CMOS analog front-end (AFE) circuit for short-wave infrared (SWIR) image sensors, which integrates a hybrid readout circuit (ROIC) and a 12-bit two-step single-slope analog-to-digital converter (TS-SS ADC). The ROIC dynamically switches between buffered-direct-injection (BDI) and direct-injection (DI) modes, thus balancing injection efficiency against power consumption. While the DI structure offers simplicity and low power, it suffers from unstable biasing and reduced injection efficiency under high background currents. Conversely, the BDI structure enhances injection efficiency and bias stability via an input buffer but incurs higher power consumption. To address this trade-off, a dual-mode injection architecture with mode-switching transistors is implemented. Mode selection is executed in-pixel via a low-leakage transmission gate and coordinated by the column timing controller, enabling low-current pixels to operate in low-noise BDI mode, whereas high-current pixels revert to the low-power DI mode. The TS-SS ADC employs a four-terminal comparator and dynamic reference voltage compensation to mitigate charge leakage and offset, which improves signal-to-noise ratio (SNR) and linearity. The prototype occupies 2.1 mm × 2.88 mm in a 0.18 µm CMOS process and serves a 64 × 64 array. The AFE achieves a dynamic range of 75.58 dB, noise of 249.42 μV, and 81.04 mW power consumption. Full article
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31 pages, 11216 KB  
Article
An Optimal Integral Fast Terminal Synergetic Control Scheme for a Grid-to-Vehicle and Vehicle-to-Grid Battery Electric Vehicle Charger Based on the Black-Winged Kite Algorithm
by Ishak Aris, Yanis Sadou and Abdelbaset Laib
Energies 2025, 18(13), 3397; https://doi.org/10.3390/en18133397 - 27 Jun 2025
Viewed by 647
Abstract
The utilization of electric vehicles (EVs) has grown significantly and continuously in recent years, encouraging the creation of new implementation opportunities. The battery electric vehicle (BEV) charging system can be effectively used during peak load periods, for voltage regulation, and for the improvement [...] Read more.
The utilization of electric vehicles (EVs) has grown significantly and continuously in recent years, encouraging the creation of new implementation opportunities. The battery electric vehicle (BEV) charging system can be effectively used during peak load periods, for voltage regulation, and for the improvement of power system stability within the smart grid. It provides an efficient bidirectional interface for charging the battery from the grid and discharging the battery into the grid. These two operation modes are referred to as grid-to-vehicle (G2V) and vehicle-to-grid (V2G), respectively. The management of power flow in both directions is highly complex and sensitive, which requires employing a robust control scheme. In this paper, an Integral Fast Terminal Synergetic Control Scheme (IFTSC) is designed to control the BEV charger system through accurately tracking the required current and voltage in both G2V and V2G system modes. Moreover, the Black-Winged Kite Algorithm is introduced to select the optimal gains of the proposed IFTS control scheme. The system stability is checked using the Lyapunov stability method. Comprehensive simulations using MATLAB/Simulink are conducted to assess the safety and efficacy of the suggested optimal IFTSC in comparison with IFTSC, optimal integral synergetic, and conventional PID controllers. Furthermore, processor-in-the-loop (PIL) co-simulation is carried out for the studied system using the C2000 launchxl-f28379d digital signal processing (DSP) board to confirm the practicability and effectiveness of the proposed OIFTS. The analysis of the obtained quantitative comparison proves that the proposed optimal IFTSC provides higher control performance under several critical testing scenarios. Full article
(This article belongs to the Section D: Energy Storage and Application)
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28 pages, 6396 KB  
Article
Three-Layer Framework Integrating Optimal Placement of Supervisory, Control, and Acquisition System Measurements with Clustering-Based Electric Substations Selection for State Estimation of Medium-Voltage Distribution Networks
by Vasilica Dandea, Stefania Galbau, Mihai-Alexandru Baciu and Gheorghe Grigoras
Appl. Sci. 2025, 15(4), 1942; https://doi.org/10.3390/app15041942 - 13 Feb 2025
Viewed by 806
Abstract
One of the biggest challenges, both from a technical and economic point of view, of the Distribution Network Operators refers to identifying the locations (electric distribution substations) integrated into a supervisory, control, and acquisition (SCADA) system to perform on-site measurements used in the [...] Read more.
One of the biggest challenges, both from a technical and economic point of view, of the Distribution Network Operators refers to identifying the locations (electric distribution substations) integrated into a supervisory, control, and acquisition (SCADA) system to perform on-site measurements used in the state estimation of the electric distribution networks (EDNs). In response to this challenge, a robust and resilient three-layer methodology has been proposed to solve the state estimate issue of the EDNs based on an optimal placement algorithm of the remote terminal units integrated into the SCADA system at the level of the EDSs. The first layer allows a clustering algorithm-based determination of the classes of the EDSs with similar features of the load profiles. The second layer identifies the “candidate” classes and decides the pilot EDSs with on-site SCADA measurements. The third layer allows the state estimation of the EDN based on the load values measured in the pilot EDEs. The framework was tested and validated using a medium voltage EDN of a Romanian DNO supplying an urban area. The results obtained highlighted that the accuracy had been ensured for on-site measurements in 12 of 39 EDSs (representing approximately 30% of EDSs integrated into the SCADA system), leading to a mean average percentage error of 2.6% for the load estimation and below 1% for the state variables determined by a power flow calculation at the level of the EDN. Consequently, the framework can significantly decrease the investments associated with integrating the SCADA system by the DNOs, with great benefits regarding the state estimation of the EDNs. Full article
(This article belongs to the Special Issue Advanced Forecasting Techniques and Methods for Energy Systems)
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22 pages, 7192 KB  
Article
An Adaptive Voltage Reference-Based Multi-Objective Optimal Control Method for the Power Flow Symmetry of Multi-Terminal DC Systems with the Large-Scale Integration of Offshore Wind Farms
by Yuanshi Zhang, Yiwen Feng, Tongxin Xu, Yilei Li, Xinye Du, Chaoyang Yuan and Hongrui Chen
Symmetry 2025, 17(1), 105; https://doi.org/10.3390/sym17010105 - 11 Jan 2025
Cited by 1 | Viewed by 1181
Abstract
The optimization of the symmetry of MTDC systems after a contingency is crucial for the stable and economic operation of the MTDC systems. In this paper, a multi-objective optimal control method for the power flow symmetry of MTDC systems for the large-scale integration [...] Read more.
The optimization of the symmetry of MTDC systems after a contingency is crucial for the stable and economic operation of the MTDC systems. In this paper, a multi-objective optimal control method for the power flow symmetry of MTDC systems for the large-scale integration of offshore wind farms is proposed. A mirror relationship between the available headroom of DC lines and VSCs and their actual power flow distribution performance is established. A corresponding symmetry index is established for the MTDC network, and the multi-objective optimization problem is converted into a series of single-objective problems by the normal boundary intersection method, and solved by the original dyadic interior point method, so as to obtain the Pareto optimal solution with uniform distribution. The compromise optimal solution is decided according to the entropy weight double-basis point method, which provides decision-making guidance for the operators. The simulation results show that the normal boundary intersection method can solve the multi-objective dynamic optimal control problem of the VSC-HVDC system quickly and efficiently, and improve the symmetry of the power flow in an MTDC network. Full article
(This article belongs to the Special Issue Symmetry/Asymmetry Studies in Modern Power Systems)
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12 pages, 2361 KB  
Article
A High-Precision Curvature Compensation Reference Circuit for a Cable Accessory Image Acquisition Device
by Ning Xiao, Yuewei Tian, Xiaosong Peng, Weijun Wang, Wenqiang Zou, Chao Yuan and Qian Zhou
Energies 2025, 18(1), 120; https://doi.org/10.3390/en18010120 - 31 Dec 2024
Cited by 1 | Viewed by 756
Abstract
High-voltage cables are widely used in power transmission and distribution systems, and their accessories (such as connectors, terminals, and insulators) are key parts to ensure the safe and reliable operation of power systems. These accessories may be affected by factors such as temperature, [...] Read more.
High-voltage cables are widely used in power transmission and distribution systems, and their accessories (such as connectors, terminals, and insulators) are key parts to ensure the safe and reliable operation of power systems. These accessories may be affected by factors such as temperature, humidity, and mechanical stress during long-term operation, resulting in performance degradation or failure. In high-voltage environments, performance monitoring of cable accessories is crucial. The reference voltage circuit can withstand the influence of temperature changes and power supply fluctuations, support accurate current and voltage measurement, and thus detect potential faults in time to ensure the safe and stable operation of the power system. However, the traditional reference voltage circuit has a low-temperature curvature loss, which results in an inaccurate reference voltage, resulting in equipment damage. Therefore, in order to solve the problem of curvature loss in this part, this paper proposes a curvature compensation circuit, which realizes a high-precision reference voltage circuit through a high-temperature curvature compensation circuit, thereby meeting the current reference voltage requirements for cable accessory monitoring. Full article
(This article belongs to the Section F: Electrical Engineering)
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29 pages, 14607 KB  
Article
Development of Dopant-Free N,N′-Bicarbazole-Based Hole Transport Materials for Efficient Perovskite Solar Cells
by Muhammad Adnan, Hira Naz, Muzammil Hussain, Zobia Irshad, Riaz Hussain and Hany W. Darwish
Int. J. Mol. Sci. 2024, 25(23), 13117; https://doi.org/10.3390/ijms252313117 - 6 Dec 2024
Cited by 6 | Viewed by 1542
Abstract
Efficient and stable hole-transport material (HTM) is essential for enhancing the efficiency and stability of high-efficiency perovskite solar cells (PSCs). The commonly used HTMs such as spiro-OMeTAD need dopants to produce high efficiency, but those dopants degrade the perovskite film and cause instability. [...] Read more.
Efficient and stable hole-transport material (HTM) is essential for enhancing the efficiency and stability of high-efficiency perovskite solar cells (PSCs). The commonly used HTMs such as spiro-OMeTAD need dopants to produce high efficiency, but those dopants degrade the perovskite film and cause instability. Therefore, the development of dopant-free N,N′-bicarbazole-based HTM is receiving huge attention for preparing stable, cost-effective, and efficient PSCs. Herein, we designed and proposed seven distinct small-molecule-based HTMs (B1–B7), which are synthesized and do not require dopants to fabricate efficient PSCs. To design this new series, we performed synergistic side-chain engineering on the synthetic reference molecule (B) by replacing two methylthio (–SCH3) terminal groups with a thiophene bridge and electron-withdrawing acceptor. The enhanced phase inversion geometry of the proposed molecules resulted in reduced energy gaps and better electrical, optical, and optoelectronic properties. Density functional theory (DFT) and time-dependent DFT simulations have been used to study the precise photo-physical and optoelectronic properties. We also looked into the effects of holes and electrons and the materials’ structural and photovoltaic properties, including light harvesting energy, frontier molecular orbital, transition density matrix, density of states, electron density matrix, and natural population analysis. Electron density difference maps identify the interfacial charge transfer from the donor to the acceptor through the bridge, and natural population analysis measures the amount of charge on each portion of the donor, bridge, and acceptor, which most effectively represents the role of the end-capped moieties in facilitating charge transfer. Among these designed molecules, the B6 molecule has the greatest absorbance (λmax of 444.93 nm in dichloromethane solvent) and a substantially shorter optical band gap of 3.93 eV. Furthermore, the charge transfer analysis reveals superior charge transfer with improved intrinsic characteristics. Furthermore, according to the photovoltaic analysis, the designed (B1–B7) HTMs have the potential to provide better fill factor and open-circuit voltages, which will ultimately increase the power conversion efficiency (PCE) of PSCs. Therefore, we recommend these molecules for the next-generation PSCs. Full article
(This article belongs to the Special Issue Advancements in Perovskite and Tandem Solar Cell Technologies)
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21 pages, 6398 KB  
Article
Early Internal Short Circuit Diagnosis for Lithium-Ion Battery Packs Based on Dynamic Time Warping of Incremental Capacity
by Meng Zhang, Qiang Guo, Ke Fu, Xiaogang Du, Hao Zhang, Qi Zuo, Qi Yang and Chao Lyu
Batteries 2024, 10(11), 378; https://doi.org/10.3390/batteries10110378 - 28 Oct 2024
Cited by 3 | Viewed by 2286
Abstract
Timely identification of early internal short circuit faults, commonly referred to as micro short circuits (MSCs), is essential yet poses significant challenges for the safe and reliable operation of lithium-ion battery (LIB) energy storage systems. This paper introduces an innovative diagnostic method for [...] Read more.
Timely identification of early internal short circuit faults, commonly referred to as micro short circuits (MSCs), is essential yet poses significant challenges for the safe and reliable operation of lithium-ion battery (LIB) energy storage systems. This paper introduces an innovative diagnostic method for early internal short circuits in LIB packs, utilizing dynamic time warping (DTW) applied to incremental capacity (IC). Initially, the terminal voltages of all cells within the LIB pack are ordered at any moment to determine the median terminal voltage, which is then used to generate the median IC curve. This curve acts as a reference benchmark that represents the condition of healthy cells in the pack. Subsequently, the DTW algorithm is utilized to measure the similarity between each cell’s IC curve and the median IC curve. Cells exhibiting similarity scores that exceed a specified threshold are identified as having MSC faults. Lastly, for the cells diagnosed with MSC conditions, a method for estimating short-circuit resistance (SR) based on variations in maximum charging voltage is devised to quantitatively evaluate the severity and evolution of the MSC. Experimental findings reveal that the proposed method effectively identifies MSC cells in the LIB pack and estimates their SRs without the necessity of a battery model, thereby affirming the method’s validity. Full article
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11 pages, 4401 KB  
Article
High-Performance UV–Visible Broad Spectral Phototransistors Based on CuPc/Cs3Bi2I9 Heterojunction
by Yurui Wang, Benfu Jiang, Xijun Zhao, Yuxing Chen, Xinxin Pan, Qing Yu and Bo Yao
Coatings 2024, 14(8), 966; https://doi.org/10.3390/coatings14080966 - 2 Aug 2024
Cited by 1 | Viewed by 1492
Abstract
Phototransistors are three-terminal photodetectors that usually have a higher photocurrent gain than photodiodes due to the amplification of the gate electrode. In this work, a broad spectral phototransistor based on copper phthalocyanine (CuPc) and a Cs3Bi2I9 (CBI) heterojunction [...] Read more.
Phototransistors are three-terminal photodetectors that usually have a higher photocurrent gain than photodiodes due to the amplification of the gate electrode. In this work, a broad spectral phototransistor based on copper phthalocyanine (CuPc) and a Cs3Bi2I9 (CBI) heterojunction is fabricated by the full vacuum evaporation method. Due to the complementary UV–visible absorption of CuPc and CBI, the device exhibits superior performance under three different types of visible light illumination. The experimental results show that the structure of the organic/perovskite heterojunction active layer has the characteristics of good compatibility and a simple process. Meanwhile, by utilizing the superior light-absorption characteristics of perovskite materials and the strong exciton dissociation efficiency of a hetero-type heterojunction interface, the CuPc/CBI-PT exhibits a higher photoresponsivity, photosensitivity, specific detection rate, and lower operating voltage than the CuPc reference device. The stability test shows that the CuPc/CBI-PT can still obtain a 0.73 A/W photoresponsivity under 660 nm light illumination after being stored in the air for 360 h without any packaging. This indicates that the organic/perovskite heterojunction PT may be a good choice for the preparation of high-performance photodetectors. Full article
(This article belongs to the Special Issue Vacuum Deposition Technologies and Semiconductor Applications)
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